CN1612649A - Organic light-emitting display panel and its barrier substrate - Google Patents

Organic light-emitting display panel and its barrier substrate Download PDF

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CN1612649A
CN1612649A CN 200310104416 CN200310104416A CN1612649A CN 1612649 A CN1612649 A CN 1612649A CN 200310104416 CN200310104416 CN 200310104416 CN 200310104416 A CN200310104416 A CN 200310104416A CN 1612649 A CN1612649 A CN 1612649A
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substrate
barrier layer
display panel
layer
electroluminescence display
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CN100433354C (en
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杨富祥
李欣真
吴志豪
张毅
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RiTdisplay Corp
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Abstract

本发明涉及一种有机发光显示面板,包含一基板、数个突部、至少一阻隔层、至少一平坦层以及至少一有机发光区,其中,突部形成于基板之上;阻隔层形成于基板与突部之上;平坦层形成于阻隔层及/或基板之上;有机发光区形成于平坦层之上,且有机发光区具有至少一像素。

Figure 200310104416

The present invention relates to an organic light emitting display panel, comprising a substrate, a plurality of protrusions, at least one barrier layer, at least one flat layer and at least one organic light emitting area, wherein the protrusions are formed on the substrate; the barrier layer is formed on the substrate and the protrusions; the flat layer is formed on the barrier layer and/or the substrate; the organic light emitting area is formed on the flat layer, and the organic light emitting area has at least one pixel.

Figure 200310104416

Description

有机发光显示面板及其阻隔基板Organic light-emitting display panel and its barrier substrate

技术领域technical field

本发明涉及一种显示面板及其阻隔基板,特别是指一种有机发光显示面板及其阻隔基板。The present invention relates to a display panel and its barrier substrate, in particular to an organic light emitting display panel and its barrier substrate.

背景技术Background technique

近年来平面显示器朝着高亮度、平面化、轻薄以及省能源的趋势发展,有鉴于此,有机发光(OEL)显示装置成为目前光电产业中极欲发展的方向之一。有机发光显示装置为一种利用有机官能性材料(organic functional materials)的自发光特性来达到显示效果的装置,依照有机官能性材料的分子量不同,可分为小分子有机发光显示装置(small molecule OLED,SM-OLED)与高分子有机发光显示装置(polymer light-emitting display,PLED)两大类。In recent years, flat panel displays are developing toward high brightness, planarization, thinness, and energy saving. In view of this, organic light emitting (OEL) display devices have become one of the most promising development directions in the optoelectronic industry. An organic light-emitting display device is a device that uses the self-luminous properties of organic functional materials to achieve display effects. According to the molecular weight of organic functional materials, it can be divided into small molecule organic light-emitting display devices (small molecule OLED) , SM-OLED) and polymer light-emitting display (polymer light-emitting display, PLED) two categories.

由于有机发光元件(有机官能性材料)对于水气与氧气非常敏感,与大气接触后容易产生暗点(Dark Spot),所以,为了确保有机发光元件的使用寿命,如图1所示,目前的有机发光显示面板6利用封合膜61披覆于基板62与有机发光区63上,以隔绝水气与氧气入侵至有机发光区63。Since the organic light-emitting element (organic functional material) is very sensitive to moisture and oxygen, it is easy to produce a dark spot (Dark Spot) after contact with the atmosphere. Therefore, in order to ensure the service life of the organic light-emitting element, as shown in Figure 1, the current The organic light-emitting display panel 6 is coated on the substrate 62 and the organic light-emitting region 63 by a sealing film 61 to prevent moisture and oxygen from entering the organic light-emitting region 63 .

另一方面,随着可携式电子装置的发展,传统的玻璃基板因为厚度限制(约大于0.4mm)、较重、易碎以及大尺寸制作不易等缺点,已无法满足轻、薄、短、小的需求。所以,利用质轻、耐冲击、可挠曲的塑料基板来代替玻璃基板已成为目前发展的趋势。On the other hand, with the development of portable electronic devices, traditional glass substrates have been unable to meet the requirements of light, thin, short, small needs. Therefore, it has become a current development trend to replace glass substrates with light-weight, impact-resistant, and flexible plastic substrates.

然而,水气对于一般塑料基材的渗透度(约为10-1-10g/m2/day,室温下)远大于对于玻璃基材的渗透度(10-5g/m2/day,室温下),因此塑料基材阻绝水气与氧气的能力,无法像玻璃基材对元件一样提供足够的保护,所以如何强化塑料基板阻绝水气、氧气的能力成为目前首要突破的关键技术之一。However, the permeability of water vapor to general plastic substrates (about 10 -1 -10g/m 2 /day at room temperature) is much greater than that of glass substrates (10 -5 g/m 2 /day at room temperature Below), the ability of plastic substrates to block water vapor and oxygen cannot provide sufficient protection for components like glass substrates. Therefore, how to strengthen the ability of plastic substrates to block water vapor and oxygen has become one of the key technologies for breakthroughs.

发明内容Contents of the invention

本发明的目的在于克服现有技术的不足与缺陷,提供一种阻止水气以及氧气入侵的有机发光显示面板及其阻隔基板。The object of the present invention is to overcome the deficiencies and defects of the prior art, and provide an organic light-emitting display panel and its barrier substrate that prevent the intrusion of moisture and oxygen.

为达上述目的,依据本发明的一种有机发光显示面板,包含一基板、数个突部、至少一阻隔层、至少一平坦层以及至少一有机发光区,其中,突部形成于基板之上;阻隔层形成于基板与突部之上;平坦层形成于阻隔层及/或基板之上;有机发光区形成于平坦层之上,且有机发光区具有至少一像素。To achieve the above object, an organic light-emitting display panel according to the present invention includes a substrate, several protrusions, at least one barrier layer, at least one flat layer, and at least one organic light-emitting region, wherein the protrusions are formed on the substrate The blocking layer is formed on the substrate and the protrusion; the planar layer is formed on the blocking layer and/or the substrate; the organic light emitting region is formed on the planar layer, and the organic light emitting region has at least one pixel.

为达上述目的,依据本发明的一种有机发光显示面板,包含一基板、至少一阻隔层以及至少一有机发光区,其中,阻隔层形成于基板之上,且阻隔层为无机材质;有机发光区形成于阻隔层之上,且有机发光区具有至少一像素。To achieve the above object, an organic light-emitting display panel according to the present invention includes a substrate, at least one barrier layer, and at least one organic light-emitting region, wherein the barrier layer is formed on the substrate, and the barrier layer is made of an inorganic material; the organic light-emitting The region is formed on the barrier layer, and the organic light emitting region has at least one pixel.

为达上述目的,依据本发明的一种有机发光显示面板,包含一基板、至少一阻隔层;以及至少一有机发光区,其中,阻隔层的至少一层以光化学气相沉积法形成于基板之上;有机发光区形成于阻隔层之上,且有机发光区具有至少一像素。To achieve the above object, an organic light-emitting display panel according to the present invention includes a substrate, at least one barrier layer; and at least one organic light-emitting region, wherein at least one layer of the barrier layer is formed on the substrate by photochemical vapor deposition ; The organic light emitting region is formed on the blocking layer, and the organic light emitting region has at least one pixel.

为达上述目的,依据本发明的一种阻隔基板,包含一基板、数个突部、至少一阻隔层以及至少一平坦层,其中,突部形成于基板之上;阻隔层形成于突部及/或基板之上;平坦层形成于阻隔层及/或基板之上。To achieve the above object, a barrier substrate according to the present invention includes a substrate, several protrusions, at least one barrier layer and at least one flat layer, wherein the protrusions are formed on the substrate; the barrier layer is formed on the protrusions and and/or on the substrate; the flat layer is formed on the barrier layer and/or the substrate.

为达上述目的,依据本发明的一种阻隔基板,包含一基板以及至少一阻隔层,其中,阻隔层形成于基板之上,且阻隔层为无机材质。To achieve the above object, a barrier substrate according to the present invention includes a substrate and at least one barrier layer, wherein the barrier layer is formed on the substrate, and the barrier layer is made of an inorganic material.

承上所述,于本发明的有机发光显示面板及其阻隔基板中,于基板上形成有一层或是多层结构的阻隔层。与现有技术相比,本发明的有机发光显示面板及其阻隔基板可以避免水气与氧气经由基板入侵至有机发光区(有机发光元件),进而增长有机发光显示面板的使用寿命。又,多层结构的阻隔层能够错开阻隔层之间孔隙的位置,有效地补偿膜层的缺陷,使得水气的穿透路径增长,更进一步防止水气与氧气入侵到元件内部。且,本发明中的多层阻隔层更可由具有不同杨氏模数的阻隔层所组成,将具有较低杨氏模数的阻隔层夹置于具有较高杨氏模数的阻隔层之间以产生缓冲的作用,藉以降低阻隔层之间的应力。再者,利用数个突部使得阻隔层成波浪状,此举可以增加阻隔层与其它部分(基板与突部)的接触面积与附着力,同时更可减少热涨冷缩时所产生的应力,当可挠性基板弯曲变形时,所产生的应力较小,阻隔层亦较不易龟裂。另外,阻隔层可利用光化学气相沉积法形成,利用光化学气相沉积法不仅可以在低温(约300℃以下)下提供足够的成膜速率,又,由于低温所形成的膜层结构较为松散,可减低膜层的内应力,更可减少膜层剥落的可能性。Based on the above, in the organic light-emitting display panel and the barrier substrate thereof of the present invention, a one-layer or multi-layer barrier layer is formed on the substrate. Compared with the prior art, the organic light emitting display panel and its barrier substrate of the present invention can prevent moisture and oxygen from invading into the organic light emitting region (organic light emitting element) through the substrate, thereby prolonging the service life of the organic light emitting display panel. In addition, the barrier layer of the multi-layer structure can stagger the position of the pores between the barrier layers, effectively compensate for the defects of the film layer, increase the penetration path of water vapor, and further prevent water vapor and oxygen from invading the interior of the element. Moreover, the multi-layer barrier layer in the present invention can be composed of barrier layers with different Young's modulus, and the barrier layer with lower Young's modulus is sandwiched between the barrier layers with higher Young's modulus To produce a buffering effect, thereby reducing the stress between the barrier layers. Furthermore, several protrusions are used to make the barrier layer into a wave shape, which can increase the contact area and adhesion between the barrier layer and other parts (substrate and protrusions), and at the same time reduce the stress generated during thermal expansion and contraction , when the flexible substrate is bent and deformed, the stress generated is smaller, and the barrier layer is less likely to be cracked. In addition, the barrier layer can be formed by photochemical vapor deposition. Photochemical vapor deposition can not only provide sufficient film formation rate at low temperature (below about 300°C), but also, because the film structure formed at low temperature is relatively loose, it can reduce the The internal stress of the film layer can reduce the possibility of peeling off the film layer.

附图说明Description of drawings

图1为现有有机发光显示面板的一示意图;FIG. 1 is a schematic diagram of an existing organic light emitting display panel;

图2A与图2B为本发明第一实施例的有机发光显示面板的一组示意图;2A and 2B are a set of schematic diagrams of an organic light emitting display panel according to a first embodiment of the present invention;

图3为本发明第二实施例的有机发光显示面板的一示意图;3 is a schematic diagram of an organic light emitting display panel according to a second embodiment of the present invention;

图4为本发明第二实施例的有机发光显示面板的另一示意图;4 is another schematic diagram of an organic light emitting display panel according to a second embodiment of the present invention;

图5为本发明第三实施例的有机发光显示面板的一示意图;5 is a schematic diagram of an organic light emitting display panel according to a third embodiment of the present invention;

图6为本发明第四实施例的阻隔基板的一示意图;6 is a schematic diagram of a barrier substrate according to a fourth embodiment of the present invention;

图7为本发明第五实施例的阻隔基板的一示意图;7 is a schematic diagram of a barrier substrate according to a fifth embodiment of the present invention;

图8为本发明第五实施例的阻隔基板的另一示意图。FIG. 8 is another schematic diagram of a barrier substrate according to a fifth embodiment of the present invention.

图中符号说明Explanation of symbols in the figure

1     有机发光显示面板1 organic light emitting display panel

11    基板11 Substrate

12    突部12 protrusions

13    阻隔层13 barrier layer

14    平坦层14 flat layers

15    有机发光区15 organic light-emitting area

151   像素151 pixels

1511  第一电极1511 first electrode

1512  有机官能层1512 organic functional layer

1513  第二电极1513 Second electrode

16    封合元件16 sealing elements

17    保护层17 protective layer

2     有机发光显示面板2 organic light emitting display panel

21    基板21 Substrate

221、222、223、22阻隔层221, 222, 223, 22 barrier layer

23    有机发光区23 organic light-emitting area

231   像素231 pixels

2311  第一电极2311 first electrode

2312  有机官能层2312 organic functional layer

2313  第二电极2313 Second electrode

24    封合元件24 sealing elements

25    突部25 protrusion

26    平坦层26 flat layers

3     有机发光显示面板3 organic light emitting display panel

31    基板31 Substrate

32    阻隔层32 barrier layer

33    有机发光区33 organic light-emitting area

331   像素331 pixels

3311  第一电极3311 first electrode

3312  有机官能层3312 organic functional layer

3313  第二电极3313 Second Electrode

34    封合元件34 sealing elements

4     阻隔基板4 barrier substrate

41    基板41 Substrate

42    突部42 protrusion

43    阻隔层43 barrier layer

44    平坦层44 flat layers

5     阻隔基板5 barrier substrate

51    基板51 Substrate

52    阻隔层52 barrier layer

53    平坦层53 flat layers

54    突部54 protrusion

6     有机发光显示面板6 organic light emitting display panel

61    封合膜61 sealing film

62    基板62 Substrate

63    有机发光区63 organic light-emitting area

具体实施方式Detailed ways

以下将参照相关附图,说明依据本发明较佳实施例的有机发光显示面板及其阻隔基板。The organic light emitting display panel and its barrier substrate according to preferred embodiments of the present invention will be described below with reference to related drawings.

第一实施例first embodiment

如图2A及图2B所示,依据本发明第一实施例的有机发光显示面板1,至少包含一基板11、数个突部12、一阻隔层13、一平坦层14以及一有机发光区15,其中,突部12形成于基板11之上;阻隔层13形成于基板11与突部12之上;平坦层14形成于阻隔层13及/或基板11之上;有机发光区15形成于平坦层14之上,且有机发光区15具有数个像素151。As shown in FIG. 2A and FIG. 2B , the organic light emitting display panel 1 according to the first embodiment of the present invention at least includes a substrate 11 , several protrusions 12 , a barrier layer 13 , a flat layer 14 and an organic light emitting region 15 , wherein, the protrusion 12 is formed on the substrate 11; the barrier layer 13 is formed on the substrate 11 and the protrusion 12; the flat layer 14 is formed on the barrier layer 13 and/or the substrate 11; the organic light emitting region 15 is formed on the flat On the layer 14 , and the organic light emitting region 15 has several pixels 151 .

于本实施例中,基板11可以是可挠性(flexible)基板或是刚性(rigid)基板。另外,基板11为高分子基板,其中高分子可以是塑料(plastic)、聚碳酸酯(polycarbonate,PC)基板、聚酯(polyester,PET)基板、环烯共聚物(cyclic olefin copolymer,COC)基板或金属铬合物基材-环烯共聚物(metallocene-based cyclic olefin copolymer,mCOC)基板等等。In this embodiment, the substrate 11 may be a flexible substrate or a rigid substrate. In addition, the substrate 11 is a polymer substrate, wherein the polymer can be plastic (plastic), polycarbonate (polycarbonate, PC) substrate, polyester (polyester, PET) substrate, cyclic olefin copolymer (cyclic olefin copolymer, COC) substrate Or metal chromium substrate-cycloolefin copolymer (metallocene-based cyclic olefin copolymer, mCOC) substrate and so on.

另外,如图2A及图2B所示,本实施例的突部12形成于基板11之上。于本实施例中,突部12相互连接(如图2A所示)。当然,突部12亦可以独立设置(如图2B所示)。In addition, as shown in FIG. 2A and FIG. 2B , the protrusion 12 of this embodiment is formed on the substrate 11 . In this embodiment, the protrusions 12 are connected to each other (as shown in FIG. 2A ). Of course, the protruding portion 12 can also be provided independently (as shown in FIG. 2B ).

于本实施例中,突部12的材质为防水性材料,例如但不限定为感光材料(例如光阻)或二氧化硅。In this embodiment, the material of the protruding portion 12 is waterproof material, such as but not limited to photosensitive material (such as photoresist) or silicon dioxide.

再者,本实施例的突部12的形状可以是点块状或是长条块状等等。另外,于本实施例中,如图2A所示,突部12的侧面与基板11之间的夹角θ约大于或等于90°,其是为了避免后续所形成的阻隔层13发生不连续的情形,而使得水气与氧气经由孔隙进入。Furthermore, the shape of the protruding portion 12 in this embodiment may be a block shape, a long block shape, or the like. In addition, in this embodiment, as shown in FIG. 2A , the angle θ between the side surface of the protrusion 12 and the substrate 11 is greater than or equal to 90°, which is to avoid discontinuity of the barrier layer 13 formed subsequently. Situation, so that water vapor and oxygen enter through the pores.

另外,如图2A及图2B所示,阻隔层13形成于基板11与突部12之上。由于阻隔层13形成于突部12及/或基板11之上,使得阻隔层13呈现类似波浪状的结构,此种结构不仅增加了阻隔层13与其它部分(突部12与基板11)之间的接触面积以及附着力,更可减少热涨冷缩的应力。另外,当基板11为可挠性基板时,基板11发生弯曲变形时,阻隔层13所产生的应力较小且亦较不易龟裂。In addition, as shown in FIG. 2A and FIG. 2B , the barrier layer 13 is formed on the substrate 11 and the protruding portion 12 . Since the barrier layer 13 is formed on the protrusion 12 and/or the substrate 11, the barrier layer 13 presents a wave-like structure, which not only increases the gap between the barrier layer 13 and other parts (the protrusion 12 and the substrate 11). The contact area and adhesion can reduce the stress of thermal expansion and contraction. In addition, when the substrate 11 is a flexible substrate, when the substrate 11 is bent and deformed, the barrier layer 13 generates less stress and is less likely to crack.

于本实施例中,阻隔层13可利用光化学气相沉积法形成,其中光化学气相沉积法可以是真空紫外光(Vacuum Ultra-Violet,VUV)化学气相沉积法。In this embodiment, the barrier layer 13 can be formed by photochemical vapor deposition, wherein the photochemical vapor deposition can be vacuum ultraviolet (Vacuum Ultra-Violet, VUV) chemical vapor deposition.

由于光化学气相沉积法利用光子来分解激发反应气体,所以反应得以在低温(约为300℃以下)环境进行。另外,于本实施例中,由于光化学气相沉积法所形成的阻隔层13结构较为松散,可降低膜层的内应力,所以能够避免阻隔层13剥离脱落。当然,阻隔层13亦可利用溅镀法形成。Since the photochemical vapor deposition method uses photons to decompose the excited reaction gas, the reaction can be carried out at a low temperature (below about 300° C.). In addition, in this embodiment, since the structure of the barrier layer 13 formed by the photochemical vapor deposition method is relatively loose, the internal stress of the film layer can be reduced, so the barrier layer 13 can be prevented from peeling off. Of course, the barrier layer 13 can also be formed by sputtering.

于本实施例中,阻隔层13为无机材质,其中,阻隔层13选自氧化硅(SiOx)、类钻石薄膜(Diamond Like Carbon,DLC)、氮化硅(SiNx)、氮氧化硅(SiOxNy)、三氧化二铝(Al2O3)及金属(包括但不限于铝、铜、金以及银)至少其中之一。于此,阻隔层13具有防水性,可提高有机发光显示面板1的可靠度。In this embodiment, the barrier layer 13 is an inorganic material, wherein the barrier layer 13 is selected from silicon oxide (SiO x ), diamond-like carbon (DLC), silicon nitride (SiN x ), silicon oxynitride ( At least one of SiO x N y ), aluminum oxide (Al 2 O 3 ) and metals (including but not limited to aluminum, copper, gold and silver). Here, the barrier layer 13 is waterproof, which can improve the reliability of the organic light emitting display panel 1 .

另外,再请参考图2A与图2B,平坦层14形成于阻隔层13及/或基板11之上。本实施例中,平坦层14用以包覆不平坦的阻隔层13,作为平坦化之用。同时,平坦层14更可包覆制程中所存在的微粒子。另外,平坦层14亦具有防水以及防氧的功能,可保护后续形成的有机发光区15不受水气与氧气的影响。In addition, referring to FIG. 2A and FIG. 2B again, the flat layer 14 is formed on the barrier layer 13 and/or the substrate 11 . In this embodiment, the flat layer 14 is used to cover the uneven barrier layer 13 for planarization. At the same time, the planar layer 14 can cover the fine particles existing in the manufacturing process. In addition, the flat layer 14 also has waterproof and oxygen-proof functions, which can protect the subsequently formed organic light-emitting region 15 from moisture and oxygen.

于本实施例中,平坦层14为无机材质,且平坦层14选自氧化硅、类钻石薄膜、氮化硅、氮氧化硅以及三氧化二铝至少其中之一。In this embodiment, the flat layer 14 is made of inorganic material, and the flat layer 14 is selected from at least one of silicon oxide, diamond-like film, silicon nitride, silicon oxynitride, and aluminum oxide.

另外,再请参考图2A及图2B,有机发光区15具有数个像素151,像素151依序包含一第一电极1511、至少一有机官能层1512及一第二电极1513,而第一电极1511位于平坦层14之上。In addition, please refer to FIG. 2A and FIG. 2B again, the organic light-emitting region 15 has several pixels 151, and the pixels 151 include a first electrode 1511, at least one organic functional layer 1512 and a second electrode 1513 in sequence, and the first electrode 1511 Located on the planar layer 14.

于本实施例中,第一电极1511利用溅镀(sputtering)方式或是离子电镀(ion plating)方式形成于平坦层14上。在此,第一电极1511通常作为阳极且其材质通常为一透明的可导电的金属氧化物,例如氧化铟锡(ITO)、氧化铝锌(AlZnO)或是氧化铟锌(IZO)。In this embodiment, the first electrode 1511 is formed on the flat layer 14 by sputtering or ion plating. Here, the first electrode 1511 is usually used as an anode and its material is usually a transparent conductive metal oxide, such as indium tin oxide (ITO), aluminum zinc oxide (AlZnO) or indium zinc oxide (IZO).

另外,有机官能层1512通常包含一电洞注入层、一电洞传递层、一发光层、一电子传递层以及一电子注入层(图中未显示)。其中,有机官能层1512利用蒸镀(evaporation)、旋转涂布(spin coating)、喷墨印刷(ink jet printing)或是印刷(printing)等方式形成于第一电极1511上。此外,有机官能层1512所发射的光线可为蓝光、绿光、红光、白光、其它的单色光或单色光组合成的彩色光。In addition, the organic functional layer 1512 generally includes a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer and an electron injection layer (not shown in the figure). Wherein, the organic functional layer 1512 is formed on the first electrode 1511 by evaporation, spin coating, ink jet printing or printing. In addition, the light emitted by the organic functional layer 1512 may be blue light, green light, red light, white light, other monochromatic light or a color light formed by combining monochromatic light.

再请参考图2A及图2B,第二电极1513位于有机官能层1512上。于此,第二电极1513使用蒸镀或是溅镀(sputtering)等方法形成于有机官能层1512上。另外,第二电极1513的材质可选自但不限定为铝(Al)、钙(Ca)、镁(Mg)、铟(In)、锡(Sn)、锰(Mn)、银(Ag)、金(Au)及含镁的合金(例如镁银(Mg:Ag)合金、镁铟(Mg:In)合金、镁锡(Mg:Sn)合金、镁锑(Mg:Sb)合金及镁碲(Mg:Te)合金)等。Referring to FIG. 2A and FIG. 2B again, the second electrode 1513 is located on the organic functional layer 1512 . Here, the second electrode 1513 is formed on the organic functional layer 1512 by evaporation or sputtering. In addition, the material of the second electrode 1513 can be selected from but not limited to aluminum (Al), calcium (Ca), magnesium (Mg), indium (In), tin (Sn), manganese (Mn), silver (Ag), Gold (Au) and alloys containing magnesium (such as magnesium silver (Mg:Ag) alloy, magnesium indium (Mg:In) alloy, magnesium tin (Mg:Sn) alloy, magnesium antimony (Mg:Sb) alloy and magnesium tellurium ( Mg:Te) alloy), etc.

再请参考图2A,本实施例的有机发光显示面板1更包含一封合元件16,其设置于平坦层14之上。于此,封合元件16可以是盖板,其以一黏着胶贴合于平坦层14之上。由于有机发光区15(有机发光元件)对于水分与氧气非常敏感,在与大气接触后容易产生暗点,所以加上封合元件16以避免有机发光区15受到水分与氧气的影响。Referring to FIG. 2A again, the organic light emitting display panel 1 of this embodiment further includes a sealing element 16 disposed on the planar layer 14 . Here, the sealing element 16 can be a cover plate, which is bonded to the flat layer 14 with an adhesive. Since the organic light-emitting region 15 (organic light-emitting element) is very sensitive to moisture and oxygen, dark spots are likely to occur after contact with the atmosphere, so the sealing element 16 is added to prevent the organic light-emitting region 15 from being affected by moisture and oxygen.

另外,再请参考图2B,本实施例的有机发光显示面板1更包含一保护层17,其披覆于有机发光区15与平坦层14之上。于此,保护层17亦用以避免有机发光区15受到水分与氧气的影响。In addition, referring to FIG. 2B again, the organic light emitting display panel 1 of this embodiment further includes a protective layer 17 covering the organic light emitting region 15 and the flat layer 14 . Here, the protective layer 17 is also used to prevent the organic light-emitting region 15 from being affected by moisture and oxygen.

第二实施例second embodiment

如图3所示,依据本发明第二实施例的有机发光显示面板2至少包含一基板21、数个阻隔层22以及一有机发光区23,其中,阻隔层22形成于基板21之上,且阻隔层为无机材质;有机发光区23形成于阻隔层22之上,且有机发光区23具有数个像素231。As shown in FIG. 3, the organic light emitting display panel 2 according to the second embodiment of the present invention at least includes a substrate 21, several barrier layers 22 and an organic light emitting region 23, wherein the barrier layer 22 is formed on the substrate 21, and The barrier layer is made of inorganic material; the organic light emitting region 23 is formed on the barrier layer 22 , and the organic light emitting region 23 has several pixels 231 .

于本实施例中,阻隔层22中的至少一层可利用光化学气相沉积法形成。当然,阻隔层22中的至少一层亦可利用溅镀法形成。In this embodiment, at least one of the barrier layers 22 can be formed by photochemical vapor deposition. Of course, at least one of the barrier layers 22 can also be formed by sputtering.

如上所述,利用光化学气相沉积法所形成的阻隔层22结构较为松散,可降低膜层的内应力,所以能够避免阻隔层22剥离脱落。As mentioned above, the structure of the barrier layer 22 formed by the photochemical vapor deposition method is relatively loose, which can reduce the internal stress of the film layer, so that the barrier layer 22 can be prevented from peeling off.

于本实施例中,阻隔层22为无机材质,其中,阻隔层22选自氧化硅、类钻石薄膜、氮化硅、氮氧化硅、三氧化二铝及金属(包括但不限于铝、铜、金以及银)至少其中之一。于此,阻隔层22具有防水性,可进一步提高有机发光显示面板2的可靠度。In this embodiment, the barrier layer 22 is an inorganic material, wherein the barrier layer 22 is selected from silicon oxide, diamond-like film, silicon nitride, silicon oxynitride, aluminum oxide and metals (including but not limited to aluminum, copper, gold and silver) at least one of them. Here, the barrier layer 22 is waterproof, which can further improve the reliability of the organic light emitting display panel 2 .

再者,本实施例的阻隔层22亦可同时具有防水性以及缓冲功能。例如:如图3所示,阻隔层221、223(材质如氮化硅、氮氧化硅、类钻石薄膜、三氧化二铝及金属(例如、铝、铜、金以及银))具有极高的防水性,能够有效防止水气以及氧气的入侵;而夹置于阻隔层221、223之间的阻隔层222(材质如氧化硅)则具有较小的机械强度,使其具有缓冲功能,能够有效地降低阻隔层22的内应力。此种多层结构能够错开阻隔层22之间孔隙的位置,有效地补偿膜层的缺陷,另外更使得水气的穿透路径增长,进一步加强防水的效果。Furthermore, the barrier layer 22 of this embodiment can also have waterproof and cushioning functions at the same time. For example: as shown in Figure 3, barrier layers 221, 223 (materials such as silicon nitride, silicon oxynitride, diamond-like film, aluminum oxide and metals (such as aluminum, copper, gold and silver)) have extremely high Water resistance can effectively prevent the intrusion of water vapor and oxygen; and the barrier layer 222 (material such as silicon oxide) sandwiched between the barrier layers 221 and 223 has a small mechanical strength, so that it has a buffer function and can effectively The internal stress of the barrier layer 22 is reduced as much as possible. This kind of multi-layer structure can stagger the positions of the pores between the barrier layers 22, effectively compensate for the defects of the film layer, and also increase the penetration path of water vapor, further enhancing the waterproof effect.

再请参照图3,有机发光区23具有数个像素231,像素231依序包含一第一电极2311、至少一有机官能层2312及一第二电极2313,而第一电极2311位于阻隔层22之上。Referring to FIG. 3 again, the organic light-emitting region 23 has several pixels 231, the pixels 231 sequentially include a first electrode 2311, at least one organic functional layer 2312 and a second electrode 2313, and the first electrode 2311 is located on the barrier layer 22 superior.

本实施例中的基板21、有机发光区23、像素231、第一电极2311、有机官能层2312及第二电极2313的特征与功能与第一实施例中相同元件相同,在此亦不再赘述。The features and functions of the substrate 21, the organic light emitting region 23, the pixel 231, the first electrode 2311, the organic functional layer 2312, and the second electrode 2313 in this embodiment are the same as those in the first embodiment, and will not be repeated here. .

再请参照图3,本实施例的有机发光显示面板2更包含一封合元件24。Referring to FIG. 3 again, the organic light emitting display panel 2 of this embodiment further includes a sealing element 24 .

另外,本实施例的有机发光显示面板2更包含一保护层(未示于图中)披覆于有机发光区23与阻隔层22之上。In addition, the organic light emitting display panel 2 of this embodiment further includes a protection layer (not shown in the figure) covering the organic light emitting region 23 and the blocking layer 22 .

于本实施例中,封合元件24与保护层的特征与功能皆与第一实施例中相同元件相同,在此不再赘述。In this embodiment, the features and functions of the sealing element 24 and the protective layer are the same as those of the same elements in the first embodiment, and will not be repeated here.

另外,再请参考图4,本实施例的有机发光显示面板2更包含数个突部25,突部25形成于基板21之上。于此,突部25的特征与功能皆与第一实施例中的突部12相同,在此亦不再赘述。In addition, referring to FIG. 4 again, the organic light emitting display panel 2 of this embodiment further includes a plurality of protrusions 25 formed on the substrate 21 . Here, the features and functions of the protruding portion 25 are the same as those of the protruding portion 12 in the first embodiment, and will not be repeated here.

另外,再请参照图4,本实施例的有机发光显示面板2更包含一平坦层26,平坦层26形成于阻隔层22及/或基板21与有机发光区23之间,于此,平坦层26的特征与功能与第一实施例的平坦层14的特征与功能相同,在此亦不再赘述。In addition, referring to FIG. 4 again, the organic light-emitting display panel 2 of this embodiment further includes a flat layer 26, which is formed between the barrier layer 22 and/or between the substrate 21 and the organic light-emitting region 23. Here, the flat layer The features and functions of 26 are the same as those of the flat layer 14 in the first embodiment, and will not be repeated here.

第三实施例third embodiment

再请参考图5,本发明第三实施例的有机发光显示面板3至少包含一基板31、一阻隔层32以及一有机发光区33,其中,阻隔层32以光化学气相沉积法形成于基板31之上;有机发光区33形成于阻隔层32之上,且有机发光区33具有数个像素331。Please refer to FIG. 5 again. The organic light-emitting display panel 3 according to the third embodiment of the present invention includes at least a substrate 31, a barrier layer 32 and an organic light-emitting region 33, wherein the barrier layer 32 is formed on the substrate 31 by photochemical vapor deposition. top; the organic light emitting region 33 is formed on the blocking layer 32 , and the organic light emitting region 33 has several pixels 331 .

于此,像素331依序包含一第一电极3311、至少一有机官能层3312及一第二电极3313,而第一电极3311位于阻隔层32之上。Here, the pixel 331 sequentially includes a first electrode 3311 , at least one organic functional layer 3312 and a second electrode 3313 , and the first electrode 3311 is located on the barrier layer 32 .

另外,如图5所示,阻隔层32以光化学气相沉积法形成于基板31之上。于此,其中光化学气相沉积法可以是真空紫外光(VacuumUltra-Violet,VUV)化学气相沉积法。如上所述,利用光化学气相沉积法所形成的阻隔层32结构较为松散,可降低膜层的内应力,所以能够避免阻隔层32剥离脱落。再者,阻隔层32的材质与第一实施例中的阻隔层13相同,在此亦不再赘述。In addition, as shown in FIG. 5 , the barrier layer 32 is formed on the substrate 31 by photochemical vapor deposition. Herein, the photochemical vapor deposition method may be vacuum ultraviolet (Vacuum Ultra-Violet, VUV) chemical vapor deposition method. As mentioned above, the structure of the barrier layer 32 formed by the photochemical vapor deposition method is relatively loose, which can reduce the internal stress of the film layer, so the barrier layer 32 can be prevented from peeling off. Furthermore, the material of the barrier layer 32 is the same as that of the barrier layer 13 in the first embodiment, and will not be repeated here.

再者,本实施例中的基板31、有机发光区33、像素331、第一电极3311、有机官能层3312及第二电极3313的特征与功能皆与第一实施例中的相同元件相同,在此亦不再赘述。Furthermore, the features and functions of the substrate 31, the organic light emitting region 33, the pixel 331, the first electrode 3311, the organic functional layer 3312, and the second electrode 3313 in this embodiment are the same as those in the first embodiment. This will not be repeated here.

再请参照图5,本实施例的有机发光显示面板3更包含一封合元件34。Referring to FIG. 5 again, the organic light emitting display panel 3 of this embodiment further includes a sealing element 34 .

另外,本实施例的有机发光显示面板3更包含一保护层(未示于图中)披覆于有机发光区33与阻隔层32之上。In addition, the organic light emitting display panel 3 of this embodiment further includes a protection layer (not shown in the figure) covering the organic light emitting region 33 and the blocking layer 32 .

于本实施例中,封合元件34与保护层的特征与功能皆与第一实施例中相同元件相同,在此不再赘述。In this embodiment, the features and functions of the sealing element 34 and the protective layer are the same as those of the same elements in the first embodiment, and will not be repeated here.

第四实施例Fourth embodiment

如图6所示,本发明第四实施例的阻隔基板4至少包含一基板41、数个突部42、一阻隔层43以及一平坦层44,其中,突部42形成于基板41之上;阻隔层43形成于突部42及/或基板41之上;平坦层44形成于阻隔层43及/或基板41之上。As shown in FIG. 6, the barrier substrate 4 of the fourth embodiment of the present invention at least includes a substrate 41, several protrusions 42, a barrier layer 43 and a flat layer 44, wherein the protrusions 42 are formed on the substrate 41; The barrier layer 43 is formed on the protrusion 42 and/or the substrate 41 ; the flat layer 44 is formed on the barrier layer 43 and/or the substrate 41 .

本实施例中的基板41、突部42、阻隔层43以及平坦层44的特征与功能皆与第一实施例中的相同元件相同,在此亦不再赘述。The features and functions of the substrate 41 , the protruding portion 42 , the barrier layer 43 and the flat layer 44 in this embodiment are the same as those in the first embodiment, and will not be repeated here.

第五实施例fifth embodiment

如图7所示,本发明第五实施例的阻隔基板5至少包含一基板51以及数个阻隔层52,其中,阻隔层52形成于基板51之上,且阻隔层52为无机材质。As shown in FIG. 7 , the barrier substrate 5 of the fifth embodiment of the present invention includes at least one substrate 51 and several barrier layers 52 , wherein the barrier layer 52 is formed on the substrate 51 and the barrier layer 52 is made of inorganic material.

本实施例的基板51与阻隔层52的特征与功能皆与第二实施例中相同元件相同,在此亦不再赘述。The features and functions of the substrate 51 and the barrier layer 52 in this embodiment are the same as those in the second embodiment, and will not be repeated here.

如图8所示,本实施例的阻隔基板5更包含数个突部54,形成于基板51之上。As shown in FIG. 8 , the barrier substrate 5 of this embodiment further includes several protrusions 54 formed on the substrate 51 .

如图8所示,本实施例的阻隔基板5更包含一平坦层53,形成于基板51及/或阻隔层52之上。As shown in FIG. 8 , the barrier substrate 5 of this embodiment further includes a flat layer 53 formed on the substrate 51 and/or the barrier layer 52 .

本实施例中的突部54与平坦层53的特征与功能皆与第二实施例中的相同元件相同,在此亦不再赘述。The features and functions of the protruding portion 54 and the flat layer 53 in this embodiment are the same as those in the second embodiment, and will not be repeated here.

于本发明的有机发光显示面板及其阻隔基板中,于基板上形成有一层或是多层结构的阻隔层。与现有技术相比,本发明的有机发光显示面板及其阻隔基板可以避免水气与氧气经由基板入侵至有机发光区(有机发光元件),进而增长有机发光显示面板的使用寿命。又,多层结构的阻隔层能够错开阻隔层之间孔隙的位置,有效地补偿膜层的缺陷,使得水气的穿透路径增长,更进一步防止水气与氧气入侵到元件内部。且,本发明中的多层阻隔层更可由具有不同杨氏模数的阻隔层所组成,将具有较低杨氏模数的阻隔层夹置于具有较高杨氏模数的阻隔层之间以产生缓冲的作用,藉以降低阻隔层之间的应力。再者,利用数个突部使得阻隔层成波浪状,此举可以增加阻隔层与其它部分(基板与突部)的接触面积与附着力,同时更可减少热涨冷缩时所产生的应力,当可挠性基板弯曲变形时,所产生的应力较小,阻隔层亦较不易龟裂。另外,阻隔层可利用光化学气相沉积法形成,利用光化学气相沉积法不仅可以在低温(约300℃以下)下提供足够的成膜速率,又,由于低温所形成的膜层结构较为松散,可减低膜层的内应力,更可减少膜层剥落的可能性。In the organic light-emitting display panel and its barrier substrate of the present invention, a one-layer or multi-layer barrier layer is formed on the substrate. Compared with the prior art, the organic light emitting display panel and its barrier substrate of the present invention can prevent moisture and oxygen from invading into the organic light emitting region (organic light emitting element) through the substrate, thereby prolonging the service life of the organic light emitting display panel. In addition, the barrier layer of the multi-layer structure can stagger the position of the pores between the barrier layers, effectively compensate for the defects of the film layer, increase the penetration path of water vapor, and further prevent water vapor and oxygen from invading the interior of the element. Moreover, the multi-layer barrier layer in the present invention can be composed of barrier layers with different Young's modulus, and the barrier layer with lower Young's modulus is sandwiched between the barrier layers with higher Young's modulus To produce a buffering effect, thereby reducing the stress between the barrier layers. Furthermore, several protrusions are used to make the barrier layer into a wave shape, which can increase the contact area and adhesion between the barrier layer and other parts (substrate and protrusions), and at the same time reduce the stress generated during thermal expansion and contraction , when the flexible substrate is bent and deformed, the stress generated is smaller, and the barrier layer is less likely to be cracked. In addition, the barrier layer can be formed by photochemical vapor deposition. Photochemical vapor deposition can not only provide sufficient film formation rate at low temperature (below about 300°C), but also, because the film structure formed at low temperature is relatively loose, it can reduce the The internal stress of the film layer can reduce the possibility of peeling off the film layer.

以上所述仅为举例性,而非为限制性者。任何未脱离本发明的精神与范畴,而对其进行的等效修改或变更,均应包含于权利要求书的范围中。The above descriptions are illustrative only, not restrictive. Any equivalent modification or change without departing from the spirit and scope of the present invention shall be included in the scope of the claims.

Claims (36)

1. an organic electroluminescence display panel is characterized in that, comprises:
One substrate;
Several teats are formed on the substrate;
At least one barrier layer is formed on substrate and the teat;
At least one flatness layer is formed on barrier layer and/or the substrate; And
At least one organic luminous zone, it is formed on the flatness layer, and organic luminous zone has at least one pixel.
2. organic electroluminescence display panel as claimed in claim 1, wherein, substrate be selected from rigid substrates, flexible base plate and polymeric substrate at least one of them.
3. organic electroluminescence display panel as claimed in claim 1, wherein, the material of teat is a waterproof material.
4. organic electroluminescence display panel as claimed in claim 1, wherein, barrier layer and flatness layer are inorganic.
5. organic electroluminescence display panel as claimed in claim 4, wherein, barrier layer be selected from silica, silicon nitride, class diamond film, silicon oxynitride, alundum (Al and metal at least one of them.
6. organic electroluminescence display panel as claimed in claim 4, wherein, flatness layer be selected from silica, class diamond film, silicon nitride, silicon oxynitride and alundum (Al at least one of them.
7. organic electroluminescence display panel as claimed in claim 1, wherein, barrier layer has water proofing property.
8. organic electroluminescence display panel as claimed in claim 1, wherein, so one deck at least of barrier layer forms with photo chemical vapor deposition method or sputtering method.
9. organic electroluminescence display panel as claimed in claim 1, wherein, pixel comprises one first electrode, at least one organic functional layer and one second electrode in regular turn.
10. an organic electroluminescence display panel is characterized in that, comprises:
One substrate;
At least one barrier layer is formed on the substrate, and barrier layer is an inorganic; And
At least one organic luminous zone, it is formed on the barrier layer, and organic luminous zone has at least one pixel.
11. organic electroluminescence display panel as claimed in claim 10, wherein, substrate be selected from rigid substrates, flexible base plate and polymeric substrate at least one of them.
12. organic electroluminescence display panel as claimed in claim 10, wherein, barrier layer be selected from silica, silicon nitride, class diamond film, silicon oxynitride, alundum (Al and metal at least one of them.
13. organic electroluminescence display panel as claimed in claim 10, wherein, barrier layer has water proofing property.
14. organic electroluminescence display panel as claimed in claim 10, wherein, one deck at least of barrier layer has resiliency.
15. organic electroluminescence display panel as claimed in claim 10, wherein, so one deck at least of barrier layer forms with photo chemical vapor deposition method or sputtering method.
16. organic electroluminescence display panel as claimed in claim 10, wherein, pixel comprises one first electrode, at least one organic functional layer and one second electrode in regular turn.
17. organic electroluminescence display panel as claimed in claim 10 more comprises:
Several teats are formed between substrate and the barrier layer.
18. organic electroluminescence display panel as claimed in claim 17, wherein, the material of teat is a waterproof material.
19. organic electroluminescence display panel as claimed in claim 17 more comprises:
At least one flatness layer is formed between barrier layer and/or substrate and the organic luminous zone.
20. an isolating substrate is characterized in that, comprises:
One substrate;
Several teats are formed on the substrate;
At least one barrier layer is formed on teat and the substrate; And
At least one flatness layer is formed on barrier layer and/or the substrate.
21. isolating substrate as claimed in claim 20, wherein, substrate be selected from rigid substrates, flexible base plate, glass substrate and polymeric substrate at least one of them.
22. isolating substrate as claimed in claim 20, wherein, the material of teat is a waterproof material.
23. isolating substrate as claimed in claim 20, wherein, barrier layer and flatness layer are inorganic.
24. isolating substrate as claimed in claim 23, wherein, barrier layer be selected from silica, class diamond film, silicon nitride, silicon oxynitride, alundum (Al and metal at least one of them.
25. isolating substrate as claimed in claim 23, wherein, flatness layer be selected from silica, class diamond film, silicon nitride, silicon oxynitride and alundum (Al at least one of them.
26. isolating substrate as claimed in claim 20, wherein, barrier layer has water proofing property.
27. isolating substrate as claimed in claim 20, wherein, so one deck at least of barrier layer forms with photo chemical vapor deposition method or sputtering method.
28. an isolating substrate comprises:
One substrate; And
At least one barrier layer is formed on the substrate, and barrier layer is an inorganic.
29. isolating substrate as claimed in claim 28, wherein, substrate be selected from rigid substrates, flexible base plate, glass substrate and polymeric substrate at least one of them.
30. isolating substrate as claimed in claim 28, wherein, barrier layer be selected from silica, class diamond film, silicon nitride, silicon oxynitride, alundum (Al and metal at least one of them.
31. isolating substrate as claimed in claim 28, wherein, barrier layer has water proofing property.
32. isolating substrate as claimed in claim 28, wherein, one deck at least of barrier layer has resiliency.
33. isolating substrate as claimed in claim 28, wherein, so one deck at least of barrier layer forms with photo chemical vapor deposition method or sputtering method.
34. isolating substrate as claimed in claim 28 more comprises:
Several teats are formed between substrate and the barrier layer.
35. isolating substrate as claimed in claim 34, wherein, the material of teat is a waterproof material.
36. isolating substrate as claimed in claim 34 more comprises:
At least one flatness layer is formed on substrate and/or the barrier layer.
CNB200310104416XA 2003-10-29 2003-10-29 Organic light emitting display panel and barrier substrate thereof Expired - Fee Related CN100433354C (en)

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CN111863927A (en) * 2020-08-21 2020-10-30 京东方科技集团股份有限公司 Flexible display substrate and flexible display device
CN112631004A (en) * 2020-12-23 2021-04-09 武汉华星光电技术有限公司 Liquid crystal display device having a plurality of pixel electrodes
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CN104183620A (en) * 2013-05-21 2014-12-03 三星显示有限公司 Organic light emitting diode display and method of manufacturing the same
US10038161B2 (en) 2013-05-21 2018-07-31 Samsung Display Co., Ltd. Organic light emitting diode display and method of manufacturing the same
CN104183620B (en) * 2013-05-21 2018-10-19 三星显示有限公司 Organic light emitting diode display and its manufacturing method
US11145838B2 (en) 2013-05-21 2021-10-12 Samsung Display Co., Ltd. Organic light emitting diode display and method of manufacturing the same
CN105140240A (en) * 2015-08-21 2015-12-09 京东方科技集团股份有限公司 Flexible substrate and manufacturing method thereof and display device
CN105140240B (en) * 2015-08-21 2020-01-03 京东方科技集团股份有限公司 Flexible substrate, manufacturing method thereof and display device
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CN112631004A (en) * 2020-12-23 2021-04-09 武汉华星光电技术有限公司 Liquid crystal display device having a plurality of pixel electrodes

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