GB865497A - Improvements relating to the cleaning and phosphate coating of metallic surfaces - Google Patents

Improvements relating to the cleaning and phosphate coating of metallic surfaces

Info

Publication number
GB865497A
GB865497A GB3171958A GB3171958A GB865497A GB 865497 A GB865497 A GB 865497A GB 3171958 A GB3171958 A GB 3171958A GB 3171958 A GB3171958 A GB 3171958A GB 865497 A GB865497 A GB 865497A
Authority
GB
United Kingdom
Prior art keywords
borax
ethylene oxide
cleaned
active agent
phenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3171958A
Inventor
Dennis Brian Freeman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pyrene Co Ltd
Original Assignee
Pyrene Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pyrene Co Ltd filed Critical Pyrene Co Ltd
Priority to GB3171958A priority Critical patent/GB865497A/en
Priority to DE1959M0042893 priority patent/DE1170220B/en
Publication of GB865497A publication Critical patent/GB865497A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/78—Pretreatment of the material to be coated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

A metal surface is cleaned (see Group II) by "forcefully" spraying on to it an aqueous alkaline solution containing borax, an alkali metal orthophosphate, and a surface-active agent consisting of a condensation product of nonyl phenol or m-methyl-p-octyl-phenol and ethylene oxide, containing 6-11 ethylene oxide groups per molecule. The concentration of borax (calculated as Na2B4O7.10H2O) is pre ferably 1-5 g/l, the ratio of borax to phosphate (calculated as Na2HPO4) is from 65:35 to 35:65, and the concentration of surface-active agent is 0.01-0.5 g/l. Solid compositions suitable for dissolving in water are disclosed.ALSO:A metal surface is cleaned by "forcefully" spraying on to it an aqueous alkaline solution containing borax, an alkali metal orthophosphate, and a surface-active agent consisting of a condensation product of nonyl phenol or m-methyl-p-octyl phenol and ethylene oxide, containing 6-11 ethylene oxide groups per molecule. Surfaces of e.g. iron, steel, zinc, aluminium and copper, may be cleaned at below 120 DEG F., and then phosphated at 120 DEG F or below using an accelerated phosphating solution, e.g. a zinc phosphate solution containing nitrite, nitrate, sulphite, peroxide, bromate, picric acid or m-nitrobenzene sulphonate and, optionally, sodium ethylene diamine tetraacetate. The phosphate coating may be rinsed in dilute chromic acid solution.
GB3171958A 1958-10-03 1958-10-03 Improvements relating to the cleaning and phosphate coating of metallic surfaces Expired GB865497A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB3171958A GB865497A (en) 1958-10-03 1958-10-03 Improvements relating to the cleaning and phosphate coating of metallic surfaces
DE1959M0042893 DE1170220B (en) 1958-10-03 1959-09-29 Process for cleaning metal surfaces

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3171958A GB865497A (en) 1958-10-03 1958-10-03 Improvements relating to the cleaning and phosphate coating of metallic surfaces

Publications (1)

Publication Number Publication Date
GB865497A true GB865497A (en) 1961-04-19

Family

ID=10327381

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3171958A Expired GB865497A (en) 1958-10-03 1958-10-03 Improvements relating to the cleaning and phosphate coating of metallic surfaces

Country Status (2)

Country Link
DE (1) DE1170220B (en)
GB (1) GB865497A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2155960A (en) * 1984-03-09 1985-10-02 Pyrene Chemical Services Ltd Processes and compositions for coating metal surfaces
US5700525A (en) * 1995-03-29 1997-12-23 Betzdearborn Inc. Passivation method and composition for galvanized metal surfaces
CZ297641B6 (en) * 2005-02-08 2007-02-21 Hauser@Ladislav Degreasing and phosphatizing apparatus

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2951600A1 (en) * 1979-12-21 1981-07-02 Gerhard Collardin GmbH, 5000 Köln METHOD FOR PRE-TREATING METAL SURFACES BEFORE PHOSPHATING
DE3213649A1 (en) * 1982-04-14 1983-10-27 Gerhard Collardin GmbH, 5000 Köln METHOD FOR CLEANING AND GREASING AND ACTIVATING METAL SURFACES
JPS6024381A (en) * 1983-07-19 1985-02-07 Nippon Steel Corp Single-sided galvanized steel sheet with excellent chemical conversion treatment properties and its manufacturing method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2155960A (en) * 1984-03-09 1985-10-02 Pyrene Chemical Services Ltd Processes and compositions for coating metal surfaces
AU575380B2 (en) * 1984-03-09 1988-07-28 Metallgesellschaft Aktiengesellschaft Zinc accelerated acidic phosphating spray process
US5700525A (en) * 1995-03-29 1997-12-23 Betzdearborn Inc. Passivation method and composition for galvanized metal surfaces
US5772740A (en) * 1995-03-29 1998-06-30 Betzdearborn Inc. Passivation method and composition for galvanized metal surfaces
CZ297641B6 (en) * 2005-02-08 2007-02-21 Hauser@Ladislav Degreasing and phosphatizing apparatus

Also Published As

Publication number Publication date
DE1170220B (en) 1964-05-14

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