GB963735A - Coated articles including coated-sheet manifolds - Google Patents

Coated articles including coated-sheet manifolds

Info

Publication number
GB963735A
GB963735A GB26865/60A GB2686560A GB963735A GB 963735 A GB963735 A GB 963735A GB 26865/60 A GB26865/60 A GB 26865/60A GB 2686560 A GB2686560 A GB 2686560A GB 963735 A GB963735 A GB 963735A
Authority
GB
United Kingdom
Prior art keywords
coating
binder
water
casein
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26865/60A
Inventor
John Joseph Clancy
David Whitcomb Lovering
Alton Burrell Poole
Robert Channing Wells
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boxboard Research and Development Association
Original Assignee
Boxboard Research and Development Association
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boxboard Research and Development Association filed Critical Boxboard Research and Development Association
Publication of GB963735A publication Critical patent/GB963735A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0029Formation of a transparent pattern using a liquid marking fluid
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24612Composite web or sheet
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/253Cellulosic [e.g., wood, paper, cork, rayon, etc.]

Landscapes

  • Color Printing (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

An article has affixed to a surface thereof or to part of a surface, a coating which comprises an essentially continuous water-insoluble matrix of binder material having distributed throughout its entire volume multitudinous air-binder interfaces, substantially all of which have maximum dimensions between one half and one micron, so that the interfaces scatter light and make the coating opaque. The matrix is a dried uncollapsed residue of an oil-in-water emulsion in which the aqueous phase contains the binder material. If the binder is originally water-soluble it is rendered insoluble during the formation of the emulsion or after deposition of the coating. The discontinuous phase may be an organic liquid that is not a solvent for the binder, is not miscible with water, and has a boiling point higher than that of water. It may contain in solution a transparentizing agent. The coated article may be sensitive to the local application of pressure, which causes local transparentization of the coating. Binders referred to are: casein, bentonite, polyvinyl alcohol, methylcellulose, alphaprotein, animal glue, modified starches, sodium silicate, shellac, natural rubber and synthetic rubbers such as copolymers of butadiene with acrylonitrile or styrene. The natural and synthetic rubbers should preferably be used with a small proportion of non-elastic binder. Casein and alpha-protein are brought into solution with the aid of an alkaline solubilizing agent such as ammonia, sodium hydroxide, borax, sodium carbonate or tri-sodium phosphate. Casein, alpha-protein and glue may be insolubilized by reaction with a salt of copper, aluminium or chromium, or with an aldehyde. Transparentizing agents referred to are: paraffin wax, stearic acid, liquid polyamide, polyester, butadieneacrylonitrile copolymer, a silicone fluid, mineral oil, lanolin, blown soya bean oil, stearamide wax, polyethylene, polyglycol, glyceryl monostearate, petrolatum and oxidized microcrystalline wax. The emulsifying agent, if required, may be of soap, e.g. sodium or ammonium stearate, palmitate or laurate. Liquids referred to for the discontinuous phase are: xylene, kerosone, mineral spirits, high-flash naphthas, butyl methyl ketone, amyl ethyl ketone, octane, butyl acetate and amyl acetate. The coating may be coloured by adding a dye to the emulsion. Reference has been directed by the Comptroller to Specification 705,417.ALSO:An article, e.g. a sheet of paper, a board, or a wall, has affixed to a surface thereof or to part of a surface, a coating which comprises an essentially continuous water-insoluble matrix of binder material having distributed throughout its entire volume multitudinous air-binder interfaces, substantially all of which have maximum dimensions between one half and one micron, so that the interfaces scatter light and make the coating opaque. The matrix is a dried uncollapsed residue of an oil-in-water emulsion in which the aqueous phase contains the binder material. If the binder is originally water-soluble it is rendered insoluble during the formation of the emulsion or after deposition of the coating. The discontinuous phase may be an organic liquid that is not a solvent for the binder, is not miscible with water, and has a boiling point higher than that of water. It may contain in solution a transparentizing agent. The coated article may be sensitive to the local application of pressure, which causes local transparentization of the coating. Binders referred to are: casein, bentonite, polyvinyl alcohol, methylcellulose, alphaprotein, animal glue, modified starches, sodium silicate, shellac, natural rubber and synthetic rubbers such as copolymers of butadiene with acrylonitrile or styrene. The natural and synthetic rubbers should preferably be used with a small proportion of non-elastic binder. Casein and alpha-protein are brought into solution with the aid of an alkaline solubilizing agent such as ammonia, sodium hydroxide, borax, sodium carbonate or tri-sodium phosphate. Casein, alpha-protein and glue may be insolubilized by reaction with a salt of copper, aluminium or chromium, or with an aldehyde. Transparentizing agents referred to are: paraffin wax, stearic acid, liquid polyamide, polyester, butadieneacrylonitrile copolymer, a silicone fluid, mineral oil, lanolin, blown soya bean oil, stearamide wax, polyethylene, polyglycol, glyceryl monostearate, petrolatum and oxidized microcrystalline wax. The emulsifying agent, if required, may be a soap, e.g. sodium or ammonium stearate, palmitate or laurate. Liquids referred to for the discontinuous phase are: xylene, kerosene, mineral spirits, high-flash naphthas, butyl methyl ketone, amyl ethyl ketone, octane, butyl acetate and amyl acetate. The coating may be coloured by adding a dye to the emulsion. Reference has been directed by the Comptroller to Specification 705,417.ALSO:An article, e.g. a sheet of paper, a board, or a wall, has affixed to a surface thereof or to part of a surface, a coating which comprises an essentially continuous water-insoluble matrix of binder material having distributed throughout its entire volume multitudinous air-binder interfaces, substantially all of which have maximum dimensions between one-half and one micron, so that the interfaces scatter light and make the coating opaque. The matrix is a dried uncollapsed residue of an oil-in-water emulsion in which the aqueous phase contains the binder material. If the binder is originally water-soluble it is rendered insoluble during the formation of the emulsion or after deposition of the coating. The discontinuous phase may be an organic liquid that is not a solvent for the binder, is not miscible with water, and has a boiling point higher than that of water. It may contain in solution a transparentizing agent. The coated article may be sensitive to the local application of pressure, which causes local transparentization of the coating. Binders referred to are: casein, bentonite, polyvinyl alcohol, methylcellulose, alpha-protein, animal glue, modified starches, sodium silicate, shellac, natural rubber and synthetic rubbers such as copolymers of butadiene with acrylonitrile or styrene. The natural and synthetic rubbers should preferably be used with a small proportion of non-elastic binder. Casein and alpha-protein are brought into solution with the aid of an alkaline solubilizing agent such as ammonia, sodium hydroxide, borax, sodium carbonate or tri-sodium phosphate. Casein, alpha-protein and glue may be insolubilized by reaction with a salt of copper, aluminium or chromium, or with an aldehyde. Transparentizing agents referred to are: paraffin wax, stearic acid, liquid polyamide, polyester, butadiene-acrylonitrile copolymer, a silicone fluid, mineral oil, lanolin, blown soya bean oil, stearamide wax, polyethylene, polyglycol, glycerol monostearate, petrolatum and oxidized microcrystalline wax. The emulsifying agent, if required, may be of soap, e.g. sodium or ammonium stearate, palmitate or laurate. Liquids referred to for the discontinuous phase are: xylene, kerosene, mineral spirits, high-flash naphthas, butyl methyl ketone, amyl ethyl ketone, octane, butyl acetate and amyl acetate. The coating may be coloured by adding a dye to the emulsion. A thin overcoat, e.g. of polystyrene, may be applied over the coating of the invention. Marking tapes may be made by coating a flexible backing with a pressure-sensitive coating of the invention on one side, and an adhesive on the other. Reference has been directed by the Comptroller to Specification 705,417.ALSO:An article, e.g. a sheet of paper, has affixed to a surface thereof or to part of a surface, a coating which is pressure-sensitive and comprises an essentially continuous water-insoluble matrix of binder material having distributed throughout its entire volume multitudinous air-binder interfaces, subsequentially all of which have maximum dimensions between one half and one micron, so that the interfaces scatter light and make the coating opaque. The matrix is a dried uncollapsed residue of an oil-in-water emulsion in which the aqueous phase contains the binder material. If the binder is originally water-soluble it is rendered insoluble during the formation of the emulsion or after deposition of the coating. The discontinuous phase may be an organic liquid that is not a solvent for the binder, is not miscible with water, and has a boiling point higher than that of water. It may contain in solution a transparentizing agent. The local application of pressure causes local transparentization of the coating. If the backing is coloured tissue paper or synthetic resin film, the colour will show through the transparent area and so produce a visible mark. Copies can be made by superposing several such sheets with a sheet of plain paper on top, and writing or typing on the top sheet. These copies can be fixed by subsequent heating to a temperature below that at which the coating flows. Binders referred to are: casein, bentonite, polyvinyl alcohol, methylcellulose, alphaprotein, animal glue, modified starches, sodium silicate, shellac, natural rubber and synthetic rubbers such as copolymers of butadiene with acrylonitrile or styrene. The natural and synthetic rubbers should preferably be used with a small proportion of nonelastic binder. Casein and alpha-protein are brought into solution with the aid of an alkaline solubilizing agent such as ammonia, sodium hydroxide, borax, sodium carbonate or tri-sodium phosphate. Casein, alpha-protein and glue may be insolubilized by reaction with a salt of copper, aluminium or chromium, or with an aldehyde. Transparentizing agents referred to are: paraffin wax, stearic acid, liquid polyamide, polyester, butadiene-acrylonitrile copolymer, a silicone fluid, mineral oil, lanolin, blown soya bean oil, stearamide wax, polyethylene
GB26865/60A 1957-06-04 1960-08-03 Coated articles including coated-sheet manifolds Expired GB963735A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US663415A US2961334A (en) 1957-06-04 1957-06-04 Positive printing, pressure-sensitive material and method of making it

Publications (1)

Publication Number Publication Date
GB963735A true GB963735A (en) 1964-07-15

Family

ID=24661708

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26865/60A Expired GB963735A (en) 1957-06-04 1960-08-03 Coated articles including coated-sheet manifolds

Country Status (5)

Country Link
US (1) US2961334A (en)
CH (1) CH452404A (en)
DE (1) DE1421391A1 (en)
GB (1) GB963735A (en)
NL (1) NL254530A (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1302851B (en) * 1954-12-03
US3086873A (en) * 1960-08-25 1963-04-23 Alexander H Steinbrunner Silk screen printing ink
US3108009A (en) * 1960-10-04 1963-10-22 Little Inc A Process coating a substrate with an opaque coating and resultant article
BE629012A (en) * 1962-03-01
US3309224A (en) * 1963-03-07 1967-03-14 Kimberly Clark Co Method of coating paper with pigmented protein containing oil-in-water emulsions having epoxy resin dispersed in oil phase
US3474053A (en) * 1963-03-07 1969-10-21 Kimberly Clark Co Emulsion coating composition for paper
US3328184A (en) * 1963-07-02 1967-06-27 Kimberly Clark Co Printing paper having opaque cellular coating and method and composition for forming the same
US3157533A (en) * 1963-07-17 1964-11-17 Little Inc A Starch stabilized casein coating emulsions
US3320089A (en) * 1964-03-09 1967-05-16 Judson Bigelow Inc Method of making blush coated recording sheet, coated sheet and coating composition
US3324762A (en) * 1965-08-02 1967-06-13 Sperry Rand Corp Marking method and apparatus
US3372050A (en) * 1966-02-07 1968-03-05 Robert E. Weber Paper coating composition and method of coating
US3411925A (en) * 1966-03-24 1968-11-19 Kimberly Clark Co Oxidized starch-protein composition and methods for producing and using the same
US3520757A (en) * 1967-06-22 1970-07-14 Richard Heaney Pressure printing card
US3928702A (en) * 1968-09-16 1975-12-23 Fuji Photo Film Co Ltd Process for manufacturing an activated clay-coated paper for use as a pressure-sensitive copying paper
US3637431A (en) * 1968-09-30 1972-01-25 Little Inc A Coating composition and article coated with same
US3951899A (en) * 1970-06-22 1976-04-20 Ppg Industries, Inc. Opaque, microcellular films from latex compositions, process and composition for preparing the same
JPS5014567B1 (en) * 1970-07-17 1975-05-29
US3686015A (en) * 1970-07-17 1972-08-22 Us Plywood Champ Papers Inc Pressure sensitive record system
US4977070A (en) * 1986-05-20 1990-12-11 Minnesota Mining And Manufacturing Company Transparentizable antihalation layers
JP7064701B2 (en) * 2018-05-30 2022-05-11 トヨタ自動車株式会社 Method for producing a porous body of a water-soluble polymer

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1783442A (en) * 1928-02-04 1930-12-02 Charles W Mayer Recording paper
US2306525A (en) * 1938-01-06 1942-12-29 Interchem Corp Method of preparing multitone coated articles
US2310795A (en) * 1939-08-31 1943-02-09 Stein Hall & Co Inc Emulsion for treating textiles
US2299694A (en) * 1940-03-09 1942-10-20 Ncr Co Manifolding material
US2299991A (en) * 1941-01-18 1942-10-27 Mc Laurin Jones Co Chart paper
BE479430A (en) * 1942-06-19 1900-01-01
US2519660A (en) * 1947-09-06 1950-08-22 Little Inc A Recording material
US2648924A (en) * 1949-12-16 1953-08-18 Brewster Ernest Billings Label structure
US2739909A (en) * 1950-06-29 1956-03-27 Nashua Corp Coated paper suitable for stylus inscription and method of making the same
USRE24554E (en) * 1951-02-02 1958-10-21 Heat-sensitive copying-paper
US2655453A (en) * 1952-04-23 1953-10-13 Ncr Co Manifold sheet having a crushresistant transfer film

Also Published As

Publication number Publication date
US2961334A (en) 1960-11-22
NL254530A (en)
CH452404A (en) 1968-05-31
DE1421391A1 (en) 1968-10-17

Similar Documents

Publication Publication Date Title
GB963735A (en) Coated articles including coated-sheet manifolds
US2800077A (en) Planographic printing plates and methods for manufacturing same
GB550332A (en) Improvements in or relating to transfer copying materials
NO933935D0 (en) VERY SLIPPING MATERIALS
SE7906055L (en) PROCEDURE FOR MANUFACTURING A PRINTABLE COPY SET
GB546750A (en) Improvements in manifolding materials
GB646926A (en) Improvements relating to record materials and the manufacture thereof
GB985176A (en) Image transfer
GB1479060A (en) Method of adhering together sheets of sheet material
GB1330737A (en) Pressure sensitive record system
US2022276A (en) Adhesive carbon paper
US2190405A (en) Decalcomania
JPS56155790A (en) Thermal recording type magnetic ticket paper
US2425653A (en) Decalcomania paper
JPS555953A (en) Remoistening adhesive paper
GB802112A (en) Improvements in magnetically imageable planographic printing plates and in a method of duplicating magnetic recordings utilising said plates
JPH0551469B2 (en)
GB873696A (en) Improvements relating to magnetic print transfer medium
GB942397A (en) Improvements in or relating to pressure sensitive transfer sheets and typewriter ribbons
US2540158A (en) Planographic printing and adhesive sheeting for use therein
GB1115306A (en) Release coating composition
GB544942A (en) Improvements in decalcomania papers
GB946761A (en) Transfer of dye images
SE8504229D0 (en) BACK COVER WITH HIGH STANDARD AND SHEET COATED
GB941827A (en) Photo copying process