KEGG   ENZYME: 2.3.1.115
Entry
EC 2.3.1.115                Enzyme                                 
Name
isoflavone-7-O-beta-glucoside 6''-O-malonyltransferase;
flavone/flavonol 7-O-beta-D-glucoside malonyltransferase;
flavone (flavonol) 7-O-glycoside malonyltransferase;
malonyl-CoA:flavone/flavonol 7-O-glucoside malonyltransferase;
MAT-7;
malonyl-coenzyme A:isoflavone 7-O-glucoside-6''-malonyltransferase;
malonyl-coenzyme A:flavone/flavonol-7-O-glycoside malonyltransferase
Class
Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
Sysname
malonyl-CoA:isoflavone-7-O-beta-D-glucoside 6''-O-malonyltransferase
Reaction(IUBMB)
malonyl-CoA + biochanin A 7-O-beta-D-glucoside = CoA + biochanin A 7-O-(6-O-malonyl-beta-D-glucoside) [RN:R06796]
Reaction(KEGG)
R06796;
(other) R04618 R06821 R07719 R07721 R07731 R07741 R07754 R07757
Substrate
malonyl-CoA [CPD:C00083];
biochanin A 7-O-beta-D-glucoside [CPD:C05376]
Product
CoA [CPD:C00010];
biochanin A 7-O-(6-O-malonyl-beta-D-glucoside) [CPD:C12625]
Comment
The 6-position of the glucose residue of formononetin can also act as acceptor; some other 7-O-glucosides of isoflavones, flavones and flavonols can also act, but more slowly.
History
EC 2.3.1.115 created 1989
Pathway
ec00943  Isoflavonoid biosynthesis
ec00944  Flavone and flavonol biosynthesis
Orthology
K13264  isoflavone 7-O-glucoside-6''-O-malonyltransferase
Genes
GMX: 100127365(AT133) 100127426(IF7MaT)
GSJ: 114382130 114398048
CCAJ: 109811028
APRC: 113867610
MTR: 25495350 25495351
TPRA: 123906996
CAM: 101510753 101511076
LJA: 130739441
AHF: 112716510 112783540 112784357 112784721 112786683
LANG: 109354735
Reference
1  [PMID:6497385]
  Authors
Koester J, Bussmann R, Barz W.
  Title
Malonyl-coenzyme A:isoflavone 7-O-glucoside-6"-O-malonyltransferase from roots of chick pea (Cicer arietinum L.).
  Journal
Arch Biochem Biophys 234:513-21 (1984)
DOI:10.1016/0003-9861(84)90298-4
Reference
2  [PMID:6639051]
  Authors
Matern U, Feser C, Hammer D.
  Title
Further characterization and regulation of malonyl-coenzyme A: flavonoid glucoside malonyltransferases from parsley cell suspension cultures.
  Journal
Arch Biochem Biophys 226:206-17 (1983)
DOI:10.1016/0003-9861(83)90286-2
Other DBs
ExplorEnz - The Enzyme Database: 2.3.1.115
IUBMB Enzyme Nomenclature: 2.3.1.115
ExPASy - ENZYME nomenclature database: 2.3.1.115
BRENDA, the Enzyme Database: 2.3.1.115
CAS: 93585-97-8 78413-09-9
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