KEGG   ENZYME: 4.2.3.112
Entry
EC 4.2.3.112                Enzyme                                 
Name
(+)-alpha-terpineol synthase
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
geranyl-diphosphate diphosphate-lyase [cyclizing, (+)-alpha-terpineol-forming]
Reaction(IUBMB)
geranyl diphosphate + H2O = (+)-alpha-terpineol + diphosphate [RN:R09968]
Reaction(KEGG)
R09968
Substrate
geranyl diphosphate [CPD:C00341];
H2O [CPD:C00001]
Product
(+)-alpha-terpineol [CPD:C09902];
diphosphate [CPD:C00013]
Comment
The enzyme has been characterized from Santalum album (sandalwood). Also forms some (-)-limonene and traces of other monoterpenoids. See EC 4.2.3.16 (4S)-limonene synthase.
History
EC 4.2.3.112 created 2012
Orthology
K21926  (+)-alpha-terpineol/(4S)-limonene synthase
Genes
EGR: 104440568
RARG: 115731130 115733698 115747624 115752364 125312647 125312648 125312649
RCU: 8276874
MEAN: 126656275
CSIN: 114273830 114302023
Reference
1  [PMID:18541135]
  Authors
Jones CG, Keeling CI, Ghisalberti EL, Barbour EL, Plummer JA, Bohlmann J
  Title
Isolation of cDNAs and functional characterisation of two multi-product terpene synthase enzymes from sandalwood, Santalum album L.
  Journal
Arch Biochem Biophys 477:121-30 (2008)
DOI:10.1016/j.abb.2008.05.008
  Sequence
[ag:ACF24767]
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.112
IUBMB Enzyme Nomenclature: 4.2.3.112
ExPASy - ENZYME nomenclature database: 4.2.3.112
BRENDA, the Enzyme Database: 4.2.3.112
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