DE539494C - Process for improving fuels - Google Patents

Process for improving fuels

Info

Publication number
DE539494C
DE539494C DEB119810D DEB0119810D DE539494C DE 539494 C DE539494 C DE 539494C DE B119810 D DEB119810 D DE B119810D DE B0119810 D DEB0119810 D DE B0119810D DE 539494 C DE539494 C DE 539494C
Authority
DE
Germany
Prior art keywords
compounds
fuels
metal
addition
iron carbonyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB119810D
Other languages
German (de)
Inventor
Dr Wilhelm Gaus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEB119810D priority Critical patent/DE539494C/en
Application granted granted Critical
Publication of DE539494C publication Critical patent/DE539494C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/1241—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof metal carbonyls
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
    • C10L1/303—Organic compounds compounds not mentioned before (complexes) derived from metals boron compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C10L1/306—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond) organo Pb compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Description

Verfahren zur Verbesserung von Brennstoffen Das Hauptpatent betrifft verbesserte Brennstoffe, die durch den Zusatz von Eisencarbonyl zu flüssigen Brennstoffen erhalten werden.Process for improving fuels The main patent relates to improved fuels made by the addition of iron carbonyl to liquid fuels can be obtained.

Es wurde nun gefunden, daß man diese Brennstoffe vielfach noch weiter verbessern kann, indem man neben dem Eisencarbonyl eine oder mehrere andere in dem Brennstoff lösliche Verbindungen von Metallen oder metallähnlichen Elementen (Bor, Silicium u. dgl.) oder Phosphor zusetzt. Derartige Zusätze beeinflussen die Abscheidung der Verbrennungsprodukte des Eisencarbonyls in günstiger Weise, so daß z. B. beim Betrieb von Motoren keine Störungen durch Ansätze von Eisenoxyd an Zündkerzen u. dgl. eintreten. Diese Beeinflussung erfolgt bei den verschiedenen nach der vorliegenden Erfindung zu benutzenden Verbindungen in verschiedenem Maße und auch in verschiedener Weise. Die Verminderung von Ablagerungen kann z.B. dadurch erzielt werden, daß das Verbrennungsprodukt von Eisencarbonyl in günstiger Weise verändert wird oder dadurch, daß eine geringere Menge Eisencarbonyl erforderlich ist und deshalb eine Verminderung der Menge des Verbrennungsproduktes eintritt.It has now been found that these fuels can often be used even further can improve by adding one or more others to the iron carbonyl in the Fuel-soluble compounds of metals or metal-like elements (boron, Silicon and the like) or phosphorus is added. Such additives influence the deposition the combustion products of iron carbonyl in a favorable manner, so that, for. B. at Operation of engines no malfunctions due to deposits of iron oxide on spark plugs and the like. like. enter. This influencing takes place with the various according to the present one Invention to use compounds in different degrees and also in different Way. The reduction of deposits can be achieved, for example, by the The combustion product of iron carbonyl is favorably modified or by that a lesser amount of iron carbonyl is required and therefore a decrease the amount of combustion product occurs.

Als geeignete Verbindungen der vorgenannten Art seien erwähnt z. B. benzinlösliche Salze von organischen Säuren, insbesondere von höheren gesättigten oder ungesättigten Fettsäuren oder Naphthensäuren, und von tautomeren Verbindungen, die in Enolform aufzutreten vermögen, wie z. B. Malonsäureester und Acetessigester, ferner von Estern anorganischer Säuren. Folgende spezielle Verbindungen, die zum Teil für sich allein verwendet als Antiklopfmittel bekannt sind, seien beispielsweise angeführt: Borsäuremethyl- und -äthylester, Kieselsäureäthylester, Siliciumtetraäthyl, Trikresylphosphat, Bleitetraäthy 1. Zinkoleat, Zinkisovalerianat, Berylliumpropionat. Aluminiumpalmitat, Aluminium-, Magnesium- und Eisenacetessigester, Calciumnaphthenat u. a. m.Suitable compounds of the aforementioned type may be mentioned, for. B. petrol-soluble salts of organic acids, especially higher saturated ones or unsaturated fatty acids or naphthenic acids, and of tautomeric compounds, able to occur in enol form, such as. B. malonic acid esters and acetoacetic esters, also of esters of inorganic acids. The following special connections that go to the Partly used alone as an anti-knock agent are known, for example listed: boric acid methyl and ethyl ester, silicic acid ethyl ester, silicon tetraethyl, Tricresyl phosphate, lead tetraethy 1. Zinc oleate, zinc isovalerate, beryllium propionate. Aluminum palmitate, aluminum, magnesium and iron acetoacetic esters, calcium naphthenate i.a. m.

Außer den genannten Zusätzen können auch hier noch die in dem frühkren Zusatz> patent ¢9I 431 angegebenen organischen Halogenverbindungen zugefügt werden.In addition to the additives mentioned, those in the early horseradish can also be used here Addition> patent [9I 431 specified organic halogen compounds are added.

Claims (1)

PATrNTANSPI£NCH: Verfahren : zur_ -Verbe,.serung von Brennstoffen oder 'Treibmitteln gemäß Patent 448 62o', dadurch gekennzeichnet, daß ihnen neben Eisencarbonyl andere im Brennstoff lösliche Verbindungen von Metallen, metallähnlichen Elementen oder Phosphor, wie Salze organischer Säuren, Metallverbindungen tautomerer Körper, Ester anorganischer Säuren, ohne weiteren Zusatz von metallfreien, stickstoff-oder sauerstoffhaltigen organischen Verbindungen zugefügt werden.PATRNTANSPI £ NCH: Process: for the_ -verification, .serization of fuels or 'propellants according to patent 448 62o', characterized in that in addition to them Iron carbonyl other compounds of metals that are soluble in fuel, similar to metal Elements or phosphorus, such as salts of organic acids, metal compounds of tautomeric Body, esters of inorganic acids, without further addition of metal-free, nitrogen-free or oxygen-containing organic compounds are added.
DEB119810D 1925-05-09 1925-05-09 Process for improving fuels Expired DE539494C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB119810D DE539494C (en) 1925-05-09 1925-05-09 Process for improving fuels

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB119810D DE539494C (en) 1925-05-09 1925-05-09 Process for improving fuels

Publications (1)

Publication Number Publication Date
DE539494C true DE539494C (en) 1931-11-26

Family

ID=6995133

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB119810D Expired DE539494C (en) 1925-05-09 1925-05-09 Process for improving fuels

Country Status (1)

Country Link
DE (1) DE539494C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3131677A (en) * 1959-01-14 1964-05-05 British Petroleum Co Fuels for internal combustion piston engines and to the operation of such engines
WO2004055136A1 (en) * 2002-12-18 2004-07-01 The Associated Octel Company Limited Use of metal to prevent spark plugs fouling from iron

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3131677A (en) * 1959-01-14 1964-05-05 British Petroleum Co Fuels for internal combustion piston engines and to the operation of such engines
WO2004055136A1 (en) * 2002-12-18 2004-07-01 The Associated Octel Company Limited Use of metal to prevent spark plugs fouling from iron

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