FI955687A - Understödda metallocen-katalysator-system för polymerisering av olefiner, deras framställning och användning - Google Patents

Understödda metallocen-katalysator-system för polymerisering av olefiner, deras framställning och användning Download PDF

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Publication number
FI955687A
FI955687A FI955687A FI955687A FI955687A FI 955687 A FI955687 A FI 955687A FI 955687 A FI955687 A FI 955687A FI 955687 A FI955687 A FI 955687A FI 955687 A FI955687 A FI 955687A
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FI
Finland
Prior art keywords
olefins
polymerization
preparation
metallocene catalyst
catalyst systems
Prior art date
Application number
FI955687A
Other languages
English (en)
Finnish (fi)
Other versions
FI114640B (sv
FI955687A0 (sv
Inventor
Terry John Burkhardt
Jeffrey Lawrence Brinen
Gregory George Hlatky
Walter Spaleck
Andreas Winter
Original Assignee
Exxon Chemical Patents Inc
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc, Hoechst Ag filed Critical Exxon Chemical Patents Inc
Publication of FI955687A0 publication Critical patent/FI955687A0/sv
Publication of FI955687A publication Critical patent/FI955687A/sv
Application granted granted Critical
Publication of FI114640B publication Critical patent/FI114640B/sv

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
FI955687A 1993-05-25 1995-11-24 Understödda metallocenkatalysatorsystem för polymerisering av olefiner, framställning och användning därav FI114640B (sv)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US6674093A 1993-05-25 1993-05-25
US6674093 1993-05-25
US9405636 1994-05-20
PCT/US1994/005636 WO1994028034A1 (en) 1993-05-25 1994-05-20 Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof

Publications (3)

Publication Number Publication Date
FI955687A0 FI955687A0 (sv) 1995-11-24
FI955687A true FI955687A (sv) 1996-01-24
FI114640B FI114640B (sv) 2004-11-30

Family

ID=22071387

Family Applications (1)

Application Number Title Priority Date Filing Date
FI955687A FI114640B (sv) 1993-05-25 1995-11-24 Understödda metallocenkatalysatorsystem för polymerisering av olefiner, framställning och användning därav

Country Status (14)

Country Link
EP (1) EP0705281B1 (sv)
JP (1) JP3626186B2 (sv)
KR (1) KR100314971B1 (sv)
CN (1) CN1043474C (sv)
AU (1) AU683899B2 (sv)
CA (1) CA2163789C (sv)
DE (1) DE69408989T2 (sv)
ES (1) ES2117279T3 (sv)
FI (1) FI114640B (sv)
NO (1) NO308952B1 (sv)
RU (1) RU2126017C1 (sv)
TW (1) TW270091B (sv)
WO (1) WO1994028034A1 (sv)
ZA (1) ZA943595B (sv)

Families Citing this family (106)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW454020B (en) † 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
DE69520370T2 (de) 1994-12-15 2001-10-31 Exxon Chemical Patents, Inc. Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
AU706842B2 (en) * 1995-05-16 1999-06-24 Univation Technologies Llc Production of polyethylene using stereoisomeric metallocenes
KR100427159B1 (ko) * 1995-07-06 2004-06-16 엑손모빌 케미칼 패턴츠 인코포레이티드 예비중합되고지지된메탈로센촉매계의제조방법
EP0856526B1 (en) 1995-10-18 2002-08-28 Chisso Corporation Olefin (co)polymer composition, process for producing the same, catalyst for (co)polymerizing olefin, and process for producing the same
DE19548288A1 (de) 1995-12-22 1997-06-26 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
FI104825B (sv) * 1996-01-26 2000-04-14 Borealis As Polymeriseringskatalysatorsystem för olefiner, dess framställning och användning
FI104826B (sv) 1996-01-30 2000-04-14 Borealis As Heteroatom-substituerade metallosenföreningar för katalytsystem i olefin polymerisation och förfarande för framställning av dem
DE59703441D1 (de) 1996-07-04 2001-05-31 Basf Ag Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren
KR20000048478A (ko) * 1996-09-24 2000-07-25 엑손 케미칼 패턴츠 인코포레이티드 지지된 메탈로센 촉매 시스템을 제조하기위한 개선된 방법
US6245856B1 (en) 1996-12-17 2001-06-12 Exxon Chemical Patents, Inc. Thermoplastic olefin compositions
DE19703502A1 (de) 1997-01-31 1998-08-06 Basf Ag Nicht selbstentzündlicher Feststoff
CN1130406C (zh) 1997-02-07 2003-12-10 埃克森美孚化学专利公司 结合有聚乙烯大分子单体的丙烯聚合物
TW425414B (en) * 1997-02-18 2001-03-11 Chisso Corp Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method
DE19757563A1 (de) * 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
EP0972800A4 (en) 1997-04-02 2004-06-16 Chisso Corp MODIFIED OLEFIN (CO) POLYMER COMPOSITION, METHOD FOR THE PRODUCTION THEREOF AND MODIFIED OLEFIN (CO) POLYMER MOLD
US6143683A (en) * 1997-04-09 2000-11-07 Fina Technology, Inc. Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
TW504515B (en) 1997-08-07 2002-10-01 Chisso Corp Olefin (co)polymer composition
DE69810781T2 (de) 1997-08-15 2003-09-25 Chisso Corp., Osaka Polydisperses propylenpolymer und verfahren zu dessen herstellung
EP1026177A4 (en) * 1997-10-22 2004-12-08 Chisso Corp SUPPORTED METALLOCENE CATALYST, METHOD FOR THE PRODUCTION THEREOF AND METHOD FOR PRODUCING OLEFIN POLYMERS
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
WO1999032530A1 (en) * 1997-12-23 1999-07-01 Exxon Chemical Patents Inc. Ethylene polymerization process in a liquid reaction medium
DE19811934A1 (de) 1998-03-19 1999-09-23 Basf Ag Ethylencopolymere mit enger Comonomerverteilung
CA2327497A1 (en) 1998-05-13 1999-11-18 Exxon Chemical Patents, Inc. Propylene homopolymers and methods of making the same
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
DE19821949A1 (de) 1998-05-15 1999-11-18 Basf Ag Verfahren zur Herstellung geträgerter Katalysatoren
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
CA2341167A1 (en) 1998-08-26 2000-03-09 Exxon Chemical Patents Inc. Branched polypropylene compositions
DE19949235A1 (de) 1998-10-16 2000-05-11 Chisso Corp Propylen/Ethylen/alpha-Olefin-Terpolymere und Verfahren zu ihrer Herstellung
GB9826874D0 (en) 1998-12-07 1999-01-27 Borealis As Process
WO2000043123A1 (fr) 1999-01-21 2000-07-27 Idemitsu Petrochemical Co., Ltd. CATALYSEURS DESTINES A LA PRODUCTION DE α-OLEFINE ET PROCEDES DE FABRICATION DE α-OLEFINE
KR100367463B1 (ko) * 1999-03-03 2003-01-14 주식회사 엘지화학 메탈로센 화합물 및 이를 이용한 올레핀 중합
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
DE19927766A1 (de) 1999-06-17 2000-12-21 Basf Ag Trägerkatalysator zur Olefinpolymerisation
AU7540700A (en) 1999-10-02 2001-05-10 Borealis Technology Oy Modified supported catalysts for the polymerization of olefins
ES2210015T3 (es) 1999-11-04 2004-07-01 Exxonmobil Chemical Patents Inc. Espumas de copolimero de propileno y su uso.
DE19957384A1 (de) 1999-11-29 2001-05-31 Targor Gmbh Hochmolekulares Polypropylen mit breiter Molekulargewichtsverteilung und geringer isotaktischer Sequenzlänge
BR0111317A (pt) 2000-05-31 2003-06-10 Basell Polyolefine Gmbh Processo para preparar compostos, composto, sistema de catalisador, e, usos de um composto e de um sistema de catalisador
GB0023662D0 (en) 2000-09-27 2000-11-08 Borealis Tech Oy Supported catalyst
DE10057009A1 (de) 2000-11-17 2002-05-29 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
WO2003000744A1 (en) 2001-06-22 2003-01-03 Borealis Technology Oy Metallocene catalysts containing an idenyl moiety substituted at the 4-, 5-, 6- or 7-position by a siloxy or germyloxy group
DE10130229A1 (de) 2001-06-22 2003-01-02 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
WO2003002583A2 (en) 2001-06-29 2003-01-09 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
ES2321806T3 (es) 2001-12-19 2009-06-12 Borealis Technology Oy Produccion de catalizadores soportados para la polimerizacion de olefinas.
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
EP1860130A1 (en) * 2002-01-31 2007-11-28 Mitsubishi Chemical Corporation Soft propylene-based resin composition
DE10208252A1 (de) 2002-02-26 2003-09-04 Celanese Ventures Gmbh Konvalent fixierte Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
JP2005525897A (ja) 2002-05-13 2005-09-02 エス．シー． ジョンソン アンド サン、インコーポレイテッド 調和した芳香・光・音の発生
US6884749B2 (en) * 2002-10-17 2005-04-26 Equistar Chemicals L.P. Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof
CA2515250C (en) 2003-02-07 2008-09-23 S. C. Johnson & Son, Inc. Diffuser with light emitting diode nightlight
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
EP1846158B1 (en) 2004-12-31 2011-06-29 Borealis Technology Oy Process to prepare a solid olefin polymerisation catalyst
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
US7598329B2 (en) 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
EP1803743B1 (en) 2005-12-30 2016-08-10 Borealis Technology Oy Catalyst particles
DE602006018132D1 (de) 2006-07-10 2010-12-23 Borealis Tech Oy Biaxial orientierte Polypropylenfolie
EP1883080B1 (en) 2006-07-10 2009-01-21 Borealis Technology Oy Electrical insulation film
EP1892264A1 (en) 2006-08-25 2008-02-27 Borealis Technology Oy Extrusion coated substrate
EP1900764B1 (en) 2006-08-25 2009-04-01 Borealis Technology Oy Polypropylene foam
EP1903070B9 (en) 2006-08-25 2009-12-23 Borealis Technology Oy Blown film of polypropylene
DE602006013137D1 (de) 2006-09-25 2010-05-06 Borealis Tech Oy Koaxiales Kabel
ATE424424T1 (de) 2006-12-28 2009-03-15 Borealis Tech Oy Verfahren zur herstellung von verzweigtem polypropylen
ATE438666T1 (de) 2007-05-08 2009-08-15 Borealis Tech Oy Folie zur elektrischen isolierung
BRPI0703586B1 (pt) 2007-10-19 2018-02-06 Braskem S.A Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular
WO2009054832A1 (en) 2007-10-25 2009-04-30 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo-and copolymers
EP2235071A2 (en) 2007-10-25 2010-10-06 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
CN101910216A (zh) 2007-10-25 2010-12-08 鲁姆斯诺沃伦技术公司 柄型金属茂化合物的外消旋选择性合成、柄型金属茂化合物、含有该化合物的催化剂、通过使用该催化剂制备烯烃聚合物的方法和烯烃均聚物及共聚物
EP2363433B1 (en) 2007-12-17 2018-02-07 Borealis Technology OY Heterophasic polypropylene with high flowability and excellent low temperature impact properties
ES2337195T5 (es) 2007-12-18 2013-03-01 Borealis Technology Oy Polipropileno heterofásico con elevadas propiedades de impacto
EP2113541A1 (en) 2008-04-28 2009-11-04 Borealis AG Adhesive propylene polymer composition suitable for extrusion coating of paper substrates
EP2133389A1 (en) 2008-06-12 2009-12-16 Borealis AG Polypropylene composition
US7897705B2 (en) 2008-08-08 2011-03-01 Sumitomo Chemical Company, Limited Process for producing olefin polymer
US7960486B2 (en) 2008-08-08 2011-06-14 Sumitomo Chemical Company, Limited Process for producing olefin polymer
US20100036068A1 (en) 2008-08-08 2010-02-11 Sumitomo Chemical Company, Limited Hydrogenation catalyst and process for producing olefin polymer
KR100992715B1 (ko) 2008-08-21 2010-11-05 삼성토탈 주식회사 폴리올레핀 중합용 촉매의 제조방법 및 그를 이용한 폴리올레핀 중합체 제조방법
JP2010065068A (ja) 2008-09-08 2010-03-25 Sumitomo Chemical Co Ltd ポリオレフィンの製造装置および製造方法
EP2184301A1 (en) 2008-11-07 2010-05-12 Borealis AG Process for the preparation of a hafnium catalyst system
WO2010052264A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
EP2186834B1 (en) 2008-11-18 2011-01-12 Borealis AG Propylene-hexene random copolymer produced in the presence of a metallocene catalyst
PL2319885T3 (pl) 2009-10-29 2012-05-31 Borealis Ag Heterofazowa żywica polipropylenowa z rozgałęzieniem długołańcuchowym
EP2316882A1 (en) 2009-10-29 2011-05-04 Borealis AG Heterophasic polypropylene resin
EP2325248B1 (en) 2009-11-16 2012-05-16 Borealis AG Melt blown fibers of polypropylene compositions
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
WO2011072851A1 (en) * 2009-12-18 2011-06-23 Basell Polyolefine Gmbh Process for the preparation of supported catalysts
EP2338920A1 (en) 2009-12-22 2011-06-29 Borealis AG Preparation of single-site catalysts
ES2535323T3 (es) 2009-12-22 2015-05-08 Borealis Ag Preparación de catalizadores de sitio único
US8829128B2 (en) 2009-12-22 2014-09-09 Borealis Ag Preparation of polypropylene in the presence of a single-site catalyst
EP2341086A1 (en) 2009-12-30 2011-07-06 Borealis AG Bopp-film
EP2341088B1 (en) 2009-12-30 2012-06-20 Borealis AG BOPP with homogeneous film morphology
EP2385073A1 (en) 2010-05-07 2011-11-09 Borealis AG Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins
EP2386584A1 (en) 2010-05-11 2011-11-16 Borealis AG Polypropylene composition suitable for extrusion coating
EP2418237A1 (en) 2010-08-12 2012-02-15 Borealis AG Easy tear polypropylene film without notch
EP2743293B1 (en) 2010-08-12 2016-11-30 Borealis AG Easy tear polypropylene film without notch
EP2426171A1 (en) 2010-08-30 2012-03-07 Borealis AG Heterophasic polypropylene with high flowability and enhanced mechanical properties
EP2492293B1 (en) 2011-02-28 2017-09-20 Borealis AG Polypropylene composition suitable for extrusion coating
EP2520425B1 (en) 2011-05-02 2017-11-08 Borealis AG Polypropylene for foam and polypropylene foam
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
WO2018091653A1 (en) 2016-11-18 2018-05-24 Borealis Ag Catalyst
KR102225972B1 (ko) * 2016-12-06 2021-03-09 주식회사 엘지화학 폴리프로필렌의 제조 방법
CN112409515B (zh) * 2019-08-23 2023-10-20 中国石油化工股份有限公司 茂金属聚丙烯催化剂的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59107973D1 (de) * 1990-11-12 1996-08-08 Hoechst Ag Verfahren zur Herstellung eines hochmolekularen Olefinpolymers
DE4119343A1 (de) * 1991-06-12 1992-12-17 Basf Ag Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
FI112233B (sv) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalysator för polymerisering av olefiner, förfarande för framställning av denna och användning av denna
JP3193110B2 (ja) * 1992-04-15 2001-07-30 三菱化学株式会社 プロピレン重合体の製造法
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
TW294669B (sv) * 1992-06-27 1997-01-01 Hoechst Ag

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AU683899B2 (en) 1997-11-27
CA2163789C (en) 2006-10-24
ZA943595B (en) 1995-12-14
DE69408989T2 (de) 1998-11-05
EP0705281A1 (en) 1996-04-10
RU2126017C1 (ru) 1999-02-10
NO954780D0 (no) 1995-11-24
KR100314971B1 (ko) 2002-07-03
JP3626186B2 (ja) 2005-03-02
EP0705281B1 (en) 1998-03-11
DE69408989D1 (de) 1998-04-16
ES2117279T3 (es) 1998-08-01
FI114640B (sv) 2004-11-30
NO308952B1 (no) 2000-11-20
FI955687A0 (sv) 1995-11-24
JPH08511044A (ja) 1996-11-19
CA2163789A1 (en) 1994-12-08
TW270091B (sv) 1996-02-11
NO954780L (no) 1996-01-15
AU7041394A (en) 1994-12-20
WO1994028034A1 (en) 1994-12-08
CN1130912A (zh) 1996-09-11
KR960702484A (ko) 1996-04-27
CN1043474C (zh) 1999-05-26
WO1994028034A9 (en) 1999-07-29

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