GB1062995A - Process for graft polymerizing alphamethylstyrene,acrylonitrile and styrene with synthetic diene rubber - Google Patents

Process for graft polymerizing alphamethylstyrene,acrylonitrile and styrene with synthetic diene rubber

Info

Publication number
GB1062995A
GB1062995A GB219665A GB219665A GB1062995A GB 1062995 A GB1062995 A GB 1062995A GB 219665 A GB219665 A GB 219665A GB 219665 A GB219665 A GB 219665A GB 1062995 A GB1062995 A GB 1062995A
Authority
GB
United Kingdom
Prior art keywords
styrene
acrylonitrile
diene rubber
monomer mixture
synthetic diene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB219665A
Inventor
Masaaki Yoshino
Masataka Isogawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanegafuchi Chemical Industry Co Ltd
Original Assignee
Kanegafuchi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DENDAT1251539D priority Critical patent/DE1251539C2/en
Priority to FR439A priority patent/FR1430214A/en
Application filed by Kanegafuchi Chemical Industry Co Ltd filed Critical Kanegafuchi Chemical Industry Co Ltd
Priority to GB219665A priority patent/GB1062995A/en
Publication of GB1062995A publication Critical patent/GB1062995A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

In manufacturing a graft copolymer of synthetic diene rubber, a -methylstyrene, acrylonitrile and styrene, firstly a monomer mixture of acrylonitrile and styrene, or these and not more than 30% of a -methylstyrene is continuously added to a latex of synthetic diene rubber, and secondly, after this graft polymerization is substantially completed, a second stage monomer mixture, consisting of acrylonitrile and a -methyl styrene, or these and not more than 30% of styrene is continuously added for graft polymerization, the amount of the said first-stage monomer mixture being 1/9 to 6/9 of the weight of said second-stage monomer mixture. The amount of a -methyl styrene in the first stage monomer mixture is preferably 0 to 30%. Examples describe graft polymerization on latices of polybutadiene and a styrenebutadiene copolymer, using a free-radical initiator system.
GB219665A 1965-01-18 1965-01-18 Process for graft polymerizing alphamethylstyrene,acrylonitrile and styrene with synthetic diene rubber Expired GB1062995A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DENDAT1251539D DE1251539C2 (en) 1965-01-18 PROCESS FOR THE PRODUCTION OF A Graft MISCLOPOLYMERIZATE
FR439A FR1430214A (en) 1965-01-18 1965-01-07 Process of polymerization by grafting alpha-methylstyrene, acrylonitrile and styrene on a synthetic diene rubber
GB219665A GB1062995A (en) 1965-01-18 1965-01-18 Process for graft polymerizing alphamethylstyrene,acrylonitrile and styrene with synthetic diene rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB219665A GB1062995A (en) 1965-01-18 1965-01-18 Process for graft polymerizing alphamethylstyrene,acrylonitrile and styrene with synthetic diene rubber

Publications (1)

Publication Number Publication Date
GB1062995A true GB1062995A (en) 1967-03-22

Family

ID=9735280

Family Applications (1)

Application Number Title Priority Date Filing Date
GB219665A Expired GB1062995A (en) 1965-01-18 1965-01-18 Process for graft polymerizing alphamethylstyrene,acrylonitrile and styrene with synthetic diene rubber

Country Status (3)

Country Link
DE (1) DE1251539C2 (en)
FR (1) FR1430214A (en)
GB (1) GB1062995A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0083946A2 (en) * 1982-01-12 1983-07-20 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Process for producing thermoplastic resin

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5278990A (en) * 1975-12-26 1977-07-02 Sumitomo Naugatuck Co Ltd Production of thermoplastic resins
DE69033618T2 (en) * 1990-06-01 2001-01-11 Bayer Antwerpen N.V., Antwerpen Graft-modified polymers containing alpha-methyl styrene and process for their preparation
JP4271250B2 (en) * 2007-07-30 2009-06-03 株式会社日立製作所 Vacuum insulation switch and vacuum insulation switchgear

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0083946A2 (en) * 1982-01-12 1983-07-20 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Process for producing thermoplastic resin
EP0083946A3 (en) * 1982-01-12 1984-05-16 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Process for producing thermoplastic resin

Also Published As

Publication number Publication date
DE1251539C2 (en) 1973-02-15
FR1430214A (en) 1966-03-04
DE1251539B (en) 1967-10-05

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