GB1425029A - Azo dyes derived from thiophene diazo components - Google Patents

Azo dyes derived from thiophene diazo components

Info

Publication number
GB1425029A
GB1425029A GB3105172A GB3105172A GB1425029A GB 1425029 A GB1425029 A GB 1425029A GB 3105172 A GB3105172 A GB 3105172A GB 3105172 A GB3105172 A GB 3105172A GB 1425029 A GB1425029 A GB 1425029A
Authority
GB
United Kingdom
Prior art keywords
thiophene
nucleus
aromatic
azo dyes
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3105172A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3105172A priority Critical patent/GB1425029A/en
Priority to AU56986/73A priority patent/AU468842B2/en
Priority to IT2544373A priority patent/IT994896B/en
Priority to BE132697A priority patent/BE801411A/en
Priority to BR484773A priority patent/BR7304847D0/en
Priority to CA175,347A priority patent/CA997754A/en
Priority to NL7309179A priority patent/NL7309179A/xx
Priority to FR7324210A priority patent/FR2236900B3/fr
Priority to AR24887073A priority patent/AR197409A1/en
Priority to ES416529A priority patent/ES416529A1/en
Priority to DE19732333828 priority patent/DE2333828A1/en
Priority to CH968973A priority patent/CH575981A5/xx
Priority to JP7516473A priority patent/JPS4963736A/ja
Publication of GB1425029A publication Critical patent/GB1425029A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/42—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms with nitro or nitroso radicals directly attached to ring carbon atoms
    • C07D333/44—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms with nitro or nitroso radicals directly attached to ring carbon atoms attached in position 5
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00—Monoazo dyes prepared by diazotising and coupling
    • C09B29/0025—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds
    • C09B29/0059—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds the heterocyclic ring containing only sulfur as heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00—Monoazo dyes prepared by diazotising and coupling
    • C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
    • C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
    • C09B29/3604—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom
    • C09B29/3617—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom
    • C09B29/3621—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom from a pyridine ring
    • C09B29/3626—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom from a pyridine ring from a pyridine ring containing one or more hydroxyl groups (or = O)
    • C09B29/3634—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom from a pyridine ring from a pyridine ring containing one or more hydroxyl groups (or = O) from diazotized heterocyclic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Coloring (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

1425029 Azo dyes derived from thiophene diazo components IMPERIAL CHEMICAL INDUSTRIES Ltd 1 June 1973 [3 July 1972] 31051/72 Heading C4P [Also in Division C2] Novel dyestuffs of the formula (wherein the thiophene nucleus carries at least one non-ionic electron-withdrawing substituent and optionally one or more hydrocarbon radicals which may themselves carry substituents; E is the residue of a coupling component of the arylamine, naphthol, phenol, acylacetarylamide, aminopyrazole, 5-hydroxypyrazole carrying an aliphatic, aromatic or heterocyclic radical in the 1-position, or hydroxy pyridone series and n is 1 or 2, the dyes being free from SO 3 H groups and each of the CO 2 H groups being directly attached to the thiophene nucleus or to an aromatic or heterocyclic nucleus present in E or to a saturated carbon atom which forms part of a side chain present in E) are prepared by diazotizing an appropriate 2-amino-thiophene and coupling with an appropriate coupling component. They may be used for dyeing (in yellow to green shades) synthetic textile materials, e.g. cellulose acetates, polyamides, polyacrylonitrile, polyurethanes and polyesters, and their blends with natural fibres such as wool and cellulosic fibres.
GB3105172A 1972-07-03 1972-07-03 Azo dyes derived from thiophene diazo components Expired GB1425029A (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
GB3105172A GB1425029A (en) 1972-07-03 1972-07-03 Azo dyes derived from thiophene diazo components
AU56986/73A AU468842B2 (en) 1972-07-03 1973-06-15 Azo dyes
IT2544373A IT994896B (en) 1972-07-03 1973-06-15 AZO DYES
BE132697A BE801411A (en) 1972-07-03 1973-06-25 AZOIC COLORANTS
BR484773A BR7304847D0 (en) 1972-07-03 1973-06-29 BLUE DYE MANUFACTURING PROCESS
CA175,347A CA997754A (en) 1972-07-03 1973-06-29 Azo dyes
NL7309179A NL7309179A (en) 1972-07-03 1973-07-02
FR7324210A FR2236900B3 (en) 1972-07-03 1973-07-02
AR24887073A AR197409A1 (en) 1972-07-03 1973-07-02 AZOIC COLORS AND PROCEDURE FOR THE PREPARATION OF THE SAME
ES416529A ES416529A1 (en) 1972-07-03 1973-07-03 Azo dyes derived from thiophene diazo components
DE19732333828 DE2333828A1 (en) 1972-07-03 1973-07-03 AZO DYES
CH968973A CH575981A5 (en) 1972-07-03 1973-07-03
JP7516473A JPS4963736A (en) 1972-07-03 1973-07-03

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3105172A GB1425029A (en) 1972-07-03 1972-07-03 Azo dyes derived from thiophene diazo components

Publications (1)

Publication Number Publication Date
GB1425029A true GB1425029A (en) 1976-02-18

Family

ID=10317230

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3105172A Expired GB1425029A (en) 1972-07-03 1972-07-03 Azo dyes derived from thiophene diazo components

Country Status (13)

Country Link
JP (1) JPS4963736A (en)
AR (1) AR197409A1 (en)
AU (1) AU468842B2 (en)
BE (1) BE801411A (en)
BR (1) BR7304847D0 (en)
CA (1) CA997754A (en)
CH (1) CH575981A5 (en)
DE (1) DE2333828A1 (en)
ES (1) ES416529A1 (en)
FR (1) FR2236900B3 (en)
GB (1) GB1425029A (en)
IT (1) IT994896B (en)
NL (1) NL7309179A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4804747A (en) * 1985-10-18 1989-02-14 Imperial Chemical Industries Plc Azo compound having one or two aliphatic or cycloaliphatic groups containing a total of 8 to 40 carbon atoms therein
US20120309945A1 (en) * 2011-06-03 2012-12-06 Eduardo Torres Thiophene Azo Carboxylate Dyes and Laundry Care Compositions Containing the Same
US8715368B2 (en) 2010-11-12 2014-05-06 The Procter & Gamble Company Thiophene azo dyes and laundry care compositions containing the same
US8888865B2 (en) 2011-06-03 2014-11-18 The Procter & Gamble Company Thiophene azo carboxylate dyes and laundry care compositions containing the same
CN115368339A (en) * 2022-09-05 2022-11-22 浙江迪邦化工有限公司 High-yield continuous synthesis method of 2-acetamido-3, 5-dinitrothiophene
CN116217542A (en) * 2023-03-21 2023-06-06 浙江万丰化工股份有限公司 Preparation method of dye intermediate 3, 5-binitro-2-acetamido thiophene

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1480923A (en) * 1974-12-05 1977-07-27 Ici Ltd Process for the manufacture of 2-amino-3-cyanothiophenes
GB9219418D0 (en) * 1992-09-14 1992-10-28 Ici Plc Disperse dyes
KR20000057281A (en) 1996-11-27 2000-09-15 해리 제이. 그윈넬 Method for preparing light-absorbing polymeric compositions

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4804747A (en) * 1985-10-18 1989-02-14 Imperial Chemical Industries Plc Azo compound having one or two aliphatic or cycloaliphatic groups containing a total of 8 to 40 carbon atoms therein
US4946629A (en) * 1985-10-18 1990-08-07 Imperial Chemical Industries, Plc Optical element having non-linear optical properties including a substrate having a coating of an azo compound
US9856439B2 (en) 2010-11-12 2018-01-02 The Procter & Gamble Company Thiophene azo dyes and laundry care compositions containing the same
US8715368B2 (en) 2010-11-12 2014-05-06 The Procter & Gamble Company Thiophene azo dyes and laundry care compositions containing the same
US8979946B2 (en) 2010-11-12 2015-03-17 The Procter & Gamble Company Thiophene azo dyes and laundry care compositions containing the same
US9487740B2 (en) 2010-11-12 2016-11-08 The Procter & Gamble Company Thiophene azo dyes and laundry care compositions containing the same
US10435651B2 (en) 2010-11-12 2019-10-08 The Procter & Gamble Company Thiophene azo dyes and laundry care compositions containing the same
US10655091B2 (en) 2010-11-12 2020-05-19 The Procter & Gamble Company Thiophene azo dyes and laundry care compositions containing the same
US8888865B2 (en) 2011-06-03 2014-11-18 The Procter & Gamble Company Thiophene azo carboxylate dyes and laundry care compositions containing the same
US9163146B2 (en) * 2011-06-03 2015-10-20 Milliken & Company Thiophene azo carboxylate dyes and laundry care compositions containing the same
US9752104B2 (en) 2011-06-03 2017-09-05 The Procter & Gamble Company Thiophene AZO carboxylate dyes and laundry care compositions containing the same
US20120309945A1 (en) * 2011-06-03 2012-12-06 Eduardo Torres Thiophene Azo Carboxylate Dyes and Laundry Care Compositions Containing the Same
CN115368339A (en) * 2022-09-05 2022-11-22 浙江迪邦化工有限公司 High-yield continuous synthesis method of 2-acetamido-3, 5-dinitrothiophene
CN115368339B (en) * 2022-09-05 2024-04-05 浙江迪邦化工有限公司 High-yield continuous synthesis method of 2-acetamido-3, 5-dinitrothiophene
CN116217542A (en) * 2023-03-21 2023-06-06 浙江万丰化工股份有限公司 Preparation method of dye intermediate 3, 5-binitro-2-acetamido thiophene

Also Published As

Publication number Publication date
BR7304847D0 (en) 1974-08-29
FR2236900B3 (en) 1976-06-18
AU5698673A (en) 1974-12-19
IT994896B (en) 1975-10-20
CH575981A5 (en) 1976-05-31
AU468842B2 (en) 1976-01-22
CA997754A (en) 1976-09-28
NL7309179A (en) 1974-01-07
BE801411A (en) 1973-12-26
ES416529A1 (en) 1976-02-16
FR2236900A1 (en) 1975-02-07
AR197409A1 (en) 1974-04-05
JPS4963736A (en) 1974-06-20
DE2333828A1 (en) 1974-01-17

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee