GB1427488A - Ethylene copolymer dispersions as water repellent coatings - Google Patents
Ethylene copolymer dispersions as water repellent coatingsInfo
- Publication number
- GB1427488A GB1427488A GB1864974A GB1864974A GB1427488A GB 1427488 A GB1427488 A GB 1427488A GB 1864974 A GB1864974 A GB 1864974A GB 1864974 A GB1864974 A GB 1864974A GB 1427488 A GB1427488 A GB 1427488A
- Authority
- GB
- United Kingdom
- Prior art keywords
- wax
- ethylene
- per cent
- weight per
- cotton
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000576 coating method Methods 0.000 title abstract 3
- 239000006185 dispersion Substances 0.000 title abstract 3
- 229920001038 ethylene copolymer Polymers 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 2
- 230000002940 repellent Effects 0.000 title 1
- 239000005871 repellent Substances 0.000 title 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 4
- 239000005977 Ethylene Substances 0.000 abstract 4
- 239000001993 wax Substances 0.000 abstract 4
- 229920000742 Cotton Polymers 0.000 abstract 3
- 239000004744 fabric Substances 0.000 abstract 3
- 239000012188 paraffin wax Substances 0.000 abstract 3
- 229920000728 polyester Polymers 0.000 abstract 3
- 229920001897 terpolymer Polymers 0.000 abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000049 pigment Substances 0.000 abstract 2
- 229910001415 sodium ion Inorganic materials 0.000 abstract 2
- MKNJWAXSYGAMGJ-UHFFFAOYSA-N (2,3,4,5,6-pentachlorophenyl) dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl MKNJWAXSYGAMGJ-UHFFFAOYSA-N 0.000 abstract 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 241001553290 Euphorbia antisyphilitica Species 0.000 abstract 1
- 241000257303 Hymenoptera Species 0.000 abstract 1
- 235000009134 Myrica cerifera Nutrition 0.000 abstract 1
- 235000009421 Myristica fragrans Nutrition 0.000 abstract 1
- 240000005125 Myrtus communis Species 0.000 abstract 1
- 235000013418 Myrtus communis Nutrition 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 244000061457 Solanum nigrum Species 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 229910000410 antimony oxide Inorganic materials 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 229910052570 clay Inorganic materials 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- -1 defoamers Substances 0.000 abstract 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 abstract 1
- 239000001115 mace Substances 0.000 abstract 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract 1
- 239000012169 petroleum derived wax Substances 0.000 abstract 1
- 235000019381 petroleum wax Nutrition 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- WKEDVNSFRWHDNR-UHFFFAOYSA-N salicylanilide Chemical compound OC1=CC=CC=C1C(=O)NC1=CC=CC=C1 WKEDVNSFRWHDNR-UHFFFAOYSA-N 0.000 abstract 1
- 229950000975 salicylanilide Drugs 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
- PGNWIWKMXVDXHP-UHFFFAOYSA-L zinc;1,3-benzothiazole-2-thiolate Chemical compound [Zn+2].C1=CC=C2SC([S-])=NC2=C1.C1=CC=C2SC([S-])=NC2=C1 PGNWIWKMXVDXHP-UHFFFAOYSA-L 0.000 abstract 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
- C09D191/08—Mineral waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1427488 Fabric coating composition E I DU PONT DE NEMOURS & CO 29 April 1974 [30 April 1973] 18649/74 Heading B2E [Also in Division C3] Fabrics, e.g. of cotton, polyester, polyamide and cotton/polyester blends, may be rendered water repellant by coating on one or both sides with aqueous dispersions comprising (1) a copolymer of at least 30 weight per cent of ethylene with up to 70 weight per cent of an α-, #- ethylenically unsaturated carboxylic acid, (2) a wax and (3) a terpolymer of 64 to 77 weight per cent of vinyl acetate, 20 to 30 weight per cent of ethylene and 3 to 6 weight per cent of N-methylol acrylamide, the dry weight ratio of ethylene copolymer/wax to terpolymer being 70:30 to 20:80. The unsaturated acid may be acrylic, methacrylic, itaconic, maleic or fumaric, and the copolymer may be partially neutralised, e.g. with sodium ions. The wax may be paraffin or microcrystalline petroleum wax, or bees, wool, Japan, myrtle, mace, palm kernel, spermacetic, carnuba, candelilla, bayberry, montan, polyolefin, chlorinated paraffin or Fischer-Tropich wax. The compositions may also contain fillers, pigments, thickeners, defoamers, fungicides, mildewicides and fire retardants; and may be applied by padding or blade coating. In examples cotton, polyester and nylon fabrics are blade coated with aqueous dispersions comprising ethylene/methacrylic acid copolymers 75% neutralised with sodium ions, paraffin wax, dimerised wood rosin, vinyl acetate/ethylene/N-methylol acrylamide terpolymers, clay, calcium carbonate, antimony oxide, titanium dioxide, chlorinated paraffins, defoamer, pigments, lauryl pentachlorophenate, salicyl anilide, copper 8-quinolate, zinc dimethyl dithiocarbamate/zinc mercaptobenzothiazole and ammonium polyacrylate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35550173A | 1973-04-30 | 1973-04-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1427488A true GB1427488A (en) | 1976-03-10 |
Family
ID=23397662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1864974A Expired GB1427488A (en) | 1973-04-30 | 1974-04-29 | Ethylene copolymer dispersions as water repellent coatings |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5014729A (en) |
| BE (1) | BE814440A (en) |
| CA (1) | CA1037177A (en) |
| DE (1) | DE2420971A1 (en) |
| FR (1) | FR2227286B3 (en) |
| GB (1) | GB1427488A (en) |
| IT (1) | IT1010231B (en) |
| NL (1) | NL7405770A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5164253A (en) * | 1990-01-31 | 1992-11-17 | Shell Oil Company | Water repellent fabrics |
| US5268004A (en) * | 1990-01-31 | 1993-12-07 | Shell Oil Company | Process to produce water repellent fabrics |
| WO2009046270A1 (en) * | 2007-10-06 | 2009-04-09 | E. I. Du Pont De Nemours And Company | Electrodepositable composition |
| WO2014031579A3 (en) * | 2012-08-21 | 2014-05-01 | Celanese International Corporation | Carpet coating compositions of vinyl acetate having improved wet and/or dry strength |
| WO2015015449A1 (en) * | 2013-07-31 | 2015-02-05 | Polyplex Corporation Ltd. | Coating composition for polyester film |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0965680A1 (en) * | 1998-06-18 | 1999-12-22 | Clariant International Ltd. | Aqueous dispersions, their preparation and use thereof |
| CN116285522B (en) * | 2023-02-24 | 2024-05-14 | 沪宝新材料科技（上海）股份有限公司 | High-temperature-resistant flame-retardant stone-like paint and preparation method thereof |
-
1974
- 1974-04-29 NL NL7405770A patent/NL7405770A/xx unknown
- 1974-04-29 FR FR7414894A patent/FR2227286B3/fr not_active Expired
- 1974-04-29 GB GB1864974A patent/GB1427488A/en not_active Expired
- 1974-04-29 IT IT2206774A patent/IT1010231B/en active
- 1974-04-29 CA CA198,609A patent/CA1037177A/en not_active Expired
- 1974-04-30 JP JP4781274A patent/JPS5014729A/ja active Pending
- 1974-04-30 DE DE19742420971 patent/DE2420971A1/en active Pending
- 1974-04-30 BE BE143828A patent/BE814440A/en unknown
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5164253A (en) * | 1990-01-31 | 1992-11-17 | Shell Oil Company | Water repellent fabrics |
| US5268004A (en) * | 1990-01-31 | 1993-12-07 | Shell Oil Company | Process to produce water repellent fabrics |
| WO2009046270A1 (en) * | 2007-10-06 | 2009-04-09 | E. I. Du Pont De Nemours And Company | Electrodepositable composition |
| CN101821344B (en) * | 2007-10-06 | 2013-02-06 | 纳幕尔杜邦公司 | Electrodepositable composition |
| WO2014031579A3 (en) * | 2012-08-21 | 2014-05-01 | Celanese International Corporation | Carpet coating compositions of vinyl acetate having improved wet and/or dry strength |
| WO2015015449A1 (en) * | 2013-07-31 | 2015-02-05 | Polyplex Corporation Ltd. | Coating composition for polyester film |
| US10683430B2 (en) | 2013-07-31 | 2020-06-16 | Polyplex Corporation Ltd. | Coating composition for polyester film |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5014729A (en) | 1975-02-17 |
| FR2227286B3 (en) | 1977-03-04 |
| BE814440A (en) | 1974-10-30 |
| IT1010231B (en) | 1977-01-10 |
| DE2420971A1 (en) | 1974-11-07 |
| NL7405770A (en) | 1974-11-01 |
| CA1037177A (en) | 1978-08-22 |
| FR2227286A1 (en) | 1974-11-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |
