GB1436245A - Catalysts for the oxidation of carbon monoxide and their pro duction - Google Patents
Catalysts for the oxidation of carbon monoxide and their pro ductionInfo
- Publication number
- GB1436245A GB1436245A GB4156373A GB4156373A GB1436245A GB 1436245 A GB1436245 A GB 1436245A GB 4156373 A GB4156373 A GB 4156373A GB 4156373 A GB4156373 A GB 4156373A GB 1436245 A GB1436245 A GB 1436245A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fibres
- activated
- carbon
- carbonized
- carbonizable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title abstract 4
- 229910002091 carbon monoxide Inorganic materials 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 229910052799 carbon Inorganic materials 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 229920003986 novolac Polymers 0.000 abstract 3
- 229910052763 palladium Inorganic materials 0.000 abstract 3
- 229910052697 platinum Inorganic materials 0.000 abstract 3
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 3
- 229910052703 rhodium Inorganic materials 0.000 abstract 3
- 239000010948 rhodium Substances 0.000 abstract 3
- 229910052707 ruthenium Inorganic materials 0.000 abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 239000005011 phenolic resin Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 230000004913 activation Effects 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 238000003763 carbonization Methods 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- -1 cellulosic Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000012299 nitrogen atmosphere Substances 0.000 abstract 1
- 238000006902 nitrogenation reaction Methods 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920003987 resole Polymers 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 238000009987 spinning Methods 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
- D01F11/127—Metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/58—Fabrics or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Inorganic Fibers (AREA)
- Catalysts (AREA)
Abstract
1436245 Carbon fibres KANEBO Ltd 4 Sept 1973 [8 Sept 1972 15 Nov 1972 (3)] 41563/73 Heading C1A [Also in Division B1] Activated carbon fibres able to catalyse the oxidation of carbon monoxide have a surface area of 800 to 3000 m<SP>2</SP>/g. and carry at least 0À05% by weight, preferably 0À05 to 30%, calculated as the metal and based on the weight of the fibres excluding the active catalyst ingredient, of one or more of palladium, ruthenium, rhodium and platinum, as the free metal or as a compound thereof, as an active catalyst ingredient. The carbon fibres may be derived from phenol resins, polyacrylonitrile, cellulosic, and pitch fibres, especially a novolac resin or a mixture of a novolac resin and a pitch, the novolac content being at least 30% by weight. In a preferred method a melt-spinnable carbonizable resin is mixed with elemental Pd, Pt, Rh or Ru or a compound thereof, the mixture meltspun to form fibres which are cured to make them infusible, carbonized, and the carbon fibres activated. Activation is effected using a mixture of steam and nitrogen, and carbonization at 900 C. in a nitrogen atmosphere. In another method a carbonizable infusible polymer, suitably polyacrylonitrile, cellulose or a resol, is dissolved to form a spinning dope, the catalyst incorporated therein and the dope spun into fibres which are carbonized and activated. Alternatively the catalyst may be applied to carbonizable and infusible fibres suitably phenol resin fibres, polyacrylonitrile fibres or cellulosic fibres which are then carbonized and activated. In a further method carbonizable and infusible fibres are carbonized and activated, at least one compound of Pd, Pt, Rh or Ru incorporated in the activated carbon fibres, and the fibres subjected to a reducing treatment, e.g. with hydrogen at 100 to 500 C., or to heat-treatment at not less than 500 C. in an inert gas or in air, or to treatment With formaldehyde or hydrazine to convert at least part of the metal compound to a metal element. In gas absorption tests, a gaseous mixture consisting of 400 p.p.m. carbon monoxide, 40 p.p.m. carbon dioxide, 20% oxygen and the remainder nitrogen is passed through a column of the fibres, and all the carbon monoxide is oxidized.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP47090778A JPS4947277A (en) | 1972-09-08 | 1972-09-08 | |
| JP47114541A JPS4971217A (en) | 1972-11-15 | 1972-11-15 | |
| JP47114543A JPS4973394A (en) | 1972-11-15 | 1972-11-15 | |
| JP47114542A JPS4973393A (en) | 1972-11-15 | 1972-11-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1436245A true GB1436245A (en) | 1976-05-19 |
Family
ID=27467816
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4156373A Expired GB1436245A (en) | 1972-09-08 | 1973-09-04 | Catalysts for the oxidation of carbon monoxide and their pro duction |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR2198893B1 (en) |
| GB (1) | GB1436245A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2000489A (en) * | 1977-06-14 | 1979-01-10 | Kanebo Ltd | Carbon-carbon composite material and method for its production |
| FR2417329A1 (en) * | 1978-02-21 | 1979-09-14 | Siren Matti | FILTERING MATERIAL AND METHOD FOR MANUFACTURING AND USING SUCH MATERIAL |
| EP0779100A1 (en) * | 1995-06-28 | 1997-06-18 | Mitsubishi Jukogyo Kabushiki Kaisha | Flue-gas treatment system |
| US6106791A (en) * | 1995-06-28 | 2000-08-22 | Mitsubishi Jukogyo Kabushiki Kaisha | Exhaust gas treating systems |
| GB2346569B (en) * | 1998-12-30 | 2003-03-19 | Univ Montfort | Method for the production of fibrous catalysts |
| US6814948B1 (en) | 1995-06-28 | 2004-11-09 | Mitsubishi Jukogyo Kabushiki Kaisha | Exhaust gas treating systems |
| EP1726565A1 (en) * | 2003-12-05 | 2006-11-29 | Mitsubishi Heavy Industries, Ltd. | Carbon material and flue gas treatment apparatus |
| GB2452259A (en) * | 2007-08-25 | 2009-03-04 | Montford University De | Method of catalysing a chemical reaction and preparation of the catalyst used therein |
| WO2009027649A2 (en) | 2007-08-25 | 2009-03-05 | De Montfort University | Antimicrobial agent and/or catalyst for chemical reactions |
| US8410011B2 (en) | 2006-02-28 | 2013-04-02 | De Montfort University | Fibrous catalyst, its preparation and use thereof |
| CN113134357A (en) * | 2020-01-20 | 2021-07-20 | 中大汇智源创(北京)科技有限公司 | Water-resistant carbon monoxide catalyst and preparation method thereof |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5018878B1 (en) * | 1974-08-03 | 1975-07-02 | ||
| GB1573878A (en) * | 1977-03-18 | 1980-08-28 | Matsushita Electric Ind Co Ltd | Method for the purification of air containing carbon monoxide |
| US4491640A (en) * | 1980-12-09 | 1985-01-01 | Osaka Gas Company Limited | Catalyst for combustion at low temperatures and process for producing same |
| JPS58146446A (en) * | 1982-02-25 | 1983-09-01 | Asahi Chem Ind Co Ltd | Fixed bed catalyst |
| FR2587022B1 (en) * | 1985-09-10 | 1990-07-27 | Rhone Poulenc Spec Chim | PROCESS FOR THE PREPARATION OF LOW REDUCING METAL SOLUTIONS |
| DE10347673B4 (en) * | 2003-10-09 | 2012-01-12 | BLüCHER GMBH | Shoe, especially boots, with ABC protection |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3399979A (en) * | 1963-11-01 | 1968-09-03 | Union Carbide Corp | Process for producing metal nitride fibers, textiles and shapes |
-
1973
- 1973-09-04 GB GB4156373A patent/GB1436245A/en not_active Expired
- 1973-09-10 FR FR7332447A patent/FR2198893B1/fr not_active Expired
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2000489B (en) * | 1977-06-14 | 1982-02-24 | Kanebo Ltd | Carbon-carbon composite material and method for its production |
| GB2000489A (en) * | 1977-06-14 | 1979-01-10 | Kanebo Ltd | Carbon-carbon composite material and method for its production |
| FR2417329A1 (en) * | 1978-02-21 | 1979-09-14 | Siren Matti | FILTERING MATERIAL AND METHOD FOR MANUFACTURING AND USING SUCH MATERIAL |
| US6814948B1 (en) | 1995-06-28 | 2004-11-09 | Mitsubishi Jukogyo Kabushiki Kaisha | Exhaust gas treating systems |
| EP0779100A1 (en) * | 1995-06-28 | 1997-06-18 | Mitsubishi Jukogyo Kabushiki Kaisha | Flue-gas treatment system |
| EP0779100A4 (en) * | 1995-06-28 | 1999-02-24 | Mitsubishi Heavy Ind Ltd | Flue-gas treatment system |
| US6106791A (en) * | 1995-06-28 | 2000-08-22 | Mitsubishi Jukogyo Kabushiki Kaisha | Exhaust gas treating systems |
| GB2346569B (en) * | 1998-12-30 | 2003-03-19 | Univ Montfort | Method for the production of fibrous catalysts |
| EP1726565A1 (en) * | 2003-12-05 | 2006-11-29 | Mitsubishi Heavy Industries, Ltd. | Carbon material and flue gas treatment apparatus |
| EP1726565A4 (en) * | 2003-12-05 | 2010-03-31 | Mitsubishi Heavy Ind Ltd | Carbon material and flue gas treatment apparatus |
| US8410011B2 (en) | 2006-02-28 | 2013-04-02 | De Montfort University | Fibrous catalyst, its preparation and use thereof |
| GB2452259A (en) * | 2007-08-25 | 2009-03-04 | Montford University De | Method of catalysing a chemical reaction and preparation of the catalyst used therein |
| WO2009027649A2 (en) | 2007-08-25 | 2009-03-05 | De Montfort University | Antimicrobial agent and/or catalyst for chemical reactions |
| GB2452259B (en) * | 2007-08-25 | 2012-02-29 | Montford University De | Catalyst |
| CN113134357A (en) * | 2020-01-20 | 2021-07-20 | 中大汇智源创(北京)科技有限公司 | Water-resistant carbon monoxide catalyst and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2198893B1 (en) | 1977-02-25 |
| FR2198893A1 (en) | 1974-04-05 |
| DE2345297A1 (en) | 1974-03-21 |
| DE2345297B2 (en) | 1976-05-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19930903 |
