JP5241943B1 - Container-packed tomato-containing beverage and method for producing the same, and texture and taste improvement method for container-filled tomato-containing beverage - Google Patents
Container-packed tomato-containing beverage and method for producing the same, and texture and taste improvement method for container-filled tomato-containing beverage Download PDFInfo
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- JP5241943B1 JP5241943B1 JP2012173264A JP2012173264A JP5241943B1 JP 5241943 B1 JP5241943 B1 JP 5241943B1 JP 2012173264 A JP2012173264 A JP 2012173264A JP 2012173264 A JP2012173264 A JP 2012173264A JP 5241943 B1 JP5241943 B1 JP 5241943B1
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Abstract
【課題】青臭みが感じられない完熟した甘味及び旨みを強く感じることができ、且つ食感が滑らかで、さらっとしてより飲みやすい容器詰トマト含有飲料及び容器詰トマト含有飲料の酸味抑制方法並びに容器詰トマト含有飲料の食感及び呈味改善方法を提供する。
【解決手段】0.7〜2.2mg/100gの植物ステロールを含有し、飲料液中におけるグルタミン酸含有量(Glu)に対する、GABA含有量(Ga)の比[Ga/Glu]が0.30〜0.50であることを特徴とする容器詰トマト含有飲料、植物ステロール含有量を0.7〜2.2mg/100gに調整する工程と、飲料液中におけるグルタミン酸含有量(Glu)に対する、GABA含有量(Ga)の比[Ga/Glu]を0.30〜0.50に調整する工程とを含むことを特徴とする容器詰トマト含有飲料の製造方法、及び容器詰トマト含有飲料の食感及び呈味改善方法。
【選択図】なし[PROBLEMS] To provide a containerized tomato-containing beverage that can strongly feel a ripe sweet taste and umami that does not cause a blue odor, and that has a smooth texture and is easy to drink, and a method and a container for suppressing sourness of a containered tomato-containing beverage. Provided is a method for improving the texture and taste of a stuffed tomato-containing beverage.
A plant sterol is contained in an amount of 0.7 to 2.2 mg / 100 g, and a ratio [Ga / Glu] of GABA content (Ga) to glutamic acid content (Glu) in a beverage is 0.30 to 0.30. GABA content with respect to the glutamic acid content (Glu) in the beverage liquid, the step of adjusting the packaged tomato content beverage characterized by being 0.50, the step of adjusting the plant sterol content to 0.7-2.2 mg / 100 g Adjusting the ratio (Ga / Glu) of the amount (Ga) to 0.30 to 0.50, and a method for producing a containerized tomato-containing beverage, and the texture of the containerized tomato-containing beverage and Taste improvement method.
[Selection figure] None
Description
本発明は、トマト果汁、果肉等のトマトを原材料として含有する容器詰トマト含有飲料及びその製造方法、並びに容器詰トマト含有飲料の食感及び呈味改善方法に関する。 The present invention relates to a packaged tomato-containing beverage containing tomatoes such as tomato juice and pulp as a raw material, a method for producing the same, and a texture and taste improvement method for the packaged tomato-containing beverage.
近年、我が国においては、高齢化社会の急激な進行等に伴い、食を通じた健康確保への関心が高まっている。また、高齢者層のみならず、中高年から若年者層にあっても、健康志向の強まりから、食事における栄養バランスの確保等のため、野菜飲料への需要は今後も増大するものと考えられる。 In recent years, in Japan, with the rapid progress of an aging society, interest in securing health through food is increasing. In addition, not only for the elderly, but also for middle-aged and younger, the demand for vegetable drinks is expected to increase in the future in order to ensure nutritional balance in the diet, etc. due to the strengthening of health-consciousness.
各種野菜の中でもトマトは特に幅広い年齢層に親しまれており、生食の他、飲料、調味料、その他加工品に亘り、多種多様な形態の製品に利用されている。また、最近の研究においては、トマトに含有されるリコピン等のポリフェノールの生理活性機能にも着目されており、これらの有効成分を手軽に摂取したいという要望は確実に高まってきている。 Among various vegetables, tomatoes are particularly popular with a wide range of age groups, and are used in various forms of products, ranging from raw foods to beverages, seasonings and other processed products. In recent research, attention has been paid to the physiologically active functions of polyphenols such as lycopene contained in tomato, and the desire to easily ingest these active ingredients has been steadily increasing.
容器詰トマト含有飲料は、生食や加工品と比較して、一般的にトマトに含有されている有効成分を多量に、且つ手軽に摂取できるという特徴を有しており、トマト果実由来物100%のものの他、トマト以外の野菜汁及び/又は果汁を混合したもの、甘味料やフレーバーを添加したもの等、多種の形態の製品が既に上市されているが、トマトの有効成分をより多く一度に摂取するためには、少なくともトマトを主成分とした飲料であることが望ましい。 Container-packed tomato-containing beverages are characterized by being able to ingest large amounts and easily of active ingredients generally contained in tomatoes compared to raw foods and processed products, and 100% tomato fruit-derived products Products of various forms such as those mixed with vegetable juice and / or fruit juice other than tomatoes, those added with sweeteners and flavors, etc. are already on the market. In order to ingest, it is desirable that it is a drink which has at least tomato as a main component.
JAS規格で指定されたトマトジュース(トマトを破砕して搾汁し或いは裏ごしし、皮や種子等を除去したもの(以下「トマト搾汁」ともいう。)又はこれに食塩を加えたもの、及び、濃縮トマトを希釈して搾汁の状態に戻したもの又はこれに食塩を加えたもの)は、トマト本来の風味が再現されていることから、年齢層や性別を問わず、広く愛飲されているが、トマトには独特の風味があることから、個人の嗜好にも左右されやすく、果実飲料等と比較して、個人の好き嫌いが明確に分かれることも否めない。従って、より多くの消費者にトマト含有飲料を受け入れてもらうためには、広い嗜好要望を勘案し、風味、食感等の観点から、最適な製品展開を行う必要がある。 Tomato juice specified by the JAS standard (tomato crushed and squeezed or strained, skin and seeds removed (hereinafter also referred to as “tomato squeezed”), or salt added thereto, and , Which is obtained by diluting concentrated tomatoes and returning them to the juiced state or by adding salt to them), because the original flavor of tomatoes is reproduced, regardless of age group or gender. However, because tomatoes have a unique flavor, they tend to be influenced by individual tastes, and it is undeniable that individual likes and dislikes are clearly divided compared to fruit drinks. Therefore, in order to allow more consumers to accept tomato-containing beverages, it is necessary to develop an optimal product from the viewpoint of flavor, texture, etc., taking into account a wide range of preference requests.
一部の消費者においてトマト含有飲料が忌避される主な要因として、トマトの有するドロつきのある高い粘度とざらつきのある食感、及び酸味と青臭み等の風味の問題が挙げられるが、上述のとおり個人の嗜好にはばらつきがあり、これらを一律で軽減もしくは強化することで解決できる問題ではない。 The main factors for avoiding tomato-containing beverages in some consumers include tomato's high viscosity with stickiness and rough texture, and flavor problems such as acidity and blue odor. As can be seen, there are variations in individual preferences, and this is not a problem that can be solved by reducing or strengthening them uniformly.
例えば、トマト含有飲料の青臭みは、多くの消費者がトマト含有飲料を摂取したがらない理由の1つであり、種々の改良がなされてきた。例えば、青臭みを低減させるために、特許文献1ではエリスリトールを添加し、特許文献2では、茶抽出物を添加し、引用文献3ではワインポリフェノールを添加しているが、いずれも青臭みのみならずトマト本来の味からもかけ離れるものである。 For example, the blue odor of tomato-containing beverages is one reason why many consumers are reluctant to take tomato-containing beverages, and various improvements have been made. For example, in order to reduce the blue odor, erythritol is added in Patent Document 1, tea extract is added in Patent Document 2, and wine polyphenol is added in Cited Document 3, but each of them has only a blue odor. It is far from the original taste of tomato.
一方で、トマト含有飲料のドロドロとした食感が苦手な消費者も多く存在する。これに対しては、予め粘度を調整した原料トマトジュースに、植物組織崩壊酵素を添加した上で、せん断処理する技術が存在するが(特許文献4)、植物組織崩壊酵素の添加や長時間の剪断処理が必要であり、処理が煩雑であるうえ、トマト含有飲料を低粘度化させると、酸味が際立つ一方で、甘味を感じにくくなり、甘味料等の添加を行わずに甘味が強いトマト含有飲料を提供することは困難であった。 On the other hand, there are many consumers who are not good at the crisp texture of tomato-containing beverages. For this, there is a technique of shearing after adding a plant tissue-disrupting enzyme to a raw material tomato juice whose viscosity has been adjusted in advance (Patent Document 4). Shearing treatment is necessary, the treatment is complicated, and when the viscosity of tomato-containing beverages is reduced, the sourness stands out, but the sweetness becomes difficult to feel, and the tomato content is strong without adding sweeteners etc. It was difficult to provide a beverage.
以上の観点から、青臭みが感じられない完熟した甘味及び旨みを強く感じることができ、且つ食感が滑らかで、さらっとしてより飲みやすい容器詰トマト含有飲料が望まれていた。 In view of the above, there has been a demand for a containerized tomato-containing beverage that can give a strong sense of ripe sweetness and umami, in which no blue odor is felt, has a smooth texture, and is easier to drink.
本発明は、かかる実情に鑑みてなされたものであり、その目的は、低粘度でさらっとした食感を有しながらも、青臭みや酸味が抑制され、完熟したような旨み及び甘みが十分感じられる、呈味が良好で飲み易い容器詰トマト含有飲料及びその製造方法、並びに容器詰トマト含有飲料の食感及び呈味改善方法を提供することにある。 The present invention has been made in view of such circumstances, and its purpose is to have a low-viscosity and dry texture while suppressing the blue odor and sourness, and fully tasting and sweetness such as ripeness. Another object of the present invention is to provide a containerized tomato-containing beverage that has a good taste and is easy to drink, a method for producing the same, and a method for improving the texture and taste of a containered tomato-containing beverage.
本発明者らは、本課題を解決するために、鋭意研究を重ねた結果、トマト含有飲料中の植物ステロール濃度及び飲料液中におけるグルタミン酸含有量(Glu)に対するGABA含有量(Ga)の比を特定の範囲に調整し、かつ飲料中の粒子の大きさを特定範囲に調整することによって、青臭みが感じられない完熟した甘味及び旨みを強く感じることができ、且つ食感が滑らかで、さらっとしてより飲みやすい容器詰トマト含有飲料が得られることが明らかとなった。 In order to solve this problem, the present inventors have conducted intensive research, and as a result, determined the ratio of GABA content (Ga) to plant sterol concentration in tomato-containing beverages and glutamic acid content (Glu) in beverages. By adjusting to a specific range and adjusting the size of the particles in the beverage to a specific range, you can strongly feel the ripe sweetness and umami that you can not feel the blue odor, and the texture is smooth and smooth. As a result, it was clarified that a tomato-containing beverage that is easier to drink was obtained.
具体的には、本発明は、以下(1)〜(6)のとおりである。
(1)0.7〜2.2mg/100gの植物ステロールを含有し、飲料液中におけるグルタミン酸含有量(Glu)に対する、GABA含有量(Ga)の比[Ga/Glu]が0.30〜0.50であることを特徴とする容器詰トマト含有飲料。
(2)前記容器詰トマト含有飲料は粒子を含有するものであって、該粒子の累積50%粒子径が270μm以下であり、且つ累積90%粒子径が480μm以下であることを特徴とする(1)に記載の容器詰トマト含有飲料。
(3)植物ステロール含有量を0.7〜2.2mg/100gに調整する工程と、飲料液中におけるグルタミン酸含有量(Glu)に対する、GABA含有量(Ga)の比Ga/Gluを0.30〜0.50に調整する工程と、を含むことを特徴とする容器詰トマト含有飲料の製造方法。
(4)さらに、前記容器詰トマト含有飲料に含まれる粒子の累積50%粒子径を270μm以下、且つ累積90%粒子径を480μm以下となるように調整する工程を含むことを特徴とする(3)に記載の容器詰トマト含有飲料の製造方法。
(5)植物ステロール含有量を0.7〜2.2mg/Lに調整し、かつ飲料液中におけるグルタミン酸含有量(Glu)に対する、GABA含有量(Ga)の比Ga/Gluを0.30〜0.50に調整することを特徴とする容器詰トマト含有飲料の食感及び呈味改善方法。
(6)さらに、前記容器詰トマト含有飲料に含まれる粒子の累積50%粒子径を270μm以下、且つ累積90%粒子径を480μm以下となるように調整する工程を含むことを特徴とする(5)に記載の容器詰トマト含有飲料の食感及び呈味改善方法。
Specifically, the present invention is as follows (1) to (6).
(1) It contains 0.7-2.2 mg / 100 g of plant sterol, and the ratio [Ga / Glu] of GABA content (Ga) to glutamic acid content (Glu) in the beverage is 0.30-0. A tomato-containing beverage containing a container, characterized in that the beverage is .50.
(2) The container-packed tomato-containing beverage contains particles, wherein the cumulative 50% particle size of the particles is 270 μm or less, and the cumulative 90% particle size is 480 μm or less ( Container-packed tomato-containing beverage according to 1).
(3) Adjusting the plant sterol content to 0.7-2.2 mg / 100 g and the GABA content (Ga) ratio Ga / Glu to the glutamic acid content (Glu) in the beverage liquid is 0.30. The process of adjusting to -0.50, The manufacturing method of the container-packed tomato containing drink characterized by the above-mentioned.
(4) The method further comprises a step of adjusting the cumulative 50% particle size of the particles contained in the container-packed tomato-containing beverage to be 270 μm or less and the cumulative 90% particle size to be 480 μm or less (3) The manufacturing method of the container-packed tomato containing drink as described in.
(5) The plant sterol content is adjusted to 0.7 to 2.2 mg / L, and the GABA content (Ga) ratio Ga / Glu to the glutamic acid content (Glu) in the beverage is 0.30 to 0.30. The texture and taste improvement method of the container-packed tomato content drink characterized by adjusting to 0.50.
(6) The method further comprises a step of adjusting the cumulative 50% particle size of the particles contained in the container-packed tomato-containing beverage to be 270 μm or less and the cumulative 90% particle size to be 480 μm or less (5). ) The texture and taste improvement method of the container-packed tomato-containing beverage according to (1).
本発明によれば、トマト含有飲料中の植物ステロール濃度及び飲料液中におけるグルタミン酸含有量(Glu)に対するGABA含有量(Ga)の比を特定の範囲に調整し、かつ飲料中の粒子の大きさを特定範囲に調整することによって、さらっとして飲みやすいながらも青臭み及び酸味が抑制されると共に、完熟したような甘み及び旨みが感じられる、呈味が良好で飲み易い容器詰トマト含有飲料及びその製造方法、並びに容器詰トマト含有飲料の食感及び呈味改善方法を提供することができる。 According to the present invention, the ratio of the GABA content (Ga) to the concentration of plant sterol in the tomato-containing beverage and the glutamic acid content (Glu) in the beverage is adjusted to a specific range, and the size of the particles in the beverage By adjusting the amount to a specific range, it is easy to drink, but the blue odor and sourness are suppressed, and the taste and taste of sweetness and taste that are fully ripe are felt. The manufacturing method and the texture and taste improvement method of a container-packed tomato-containing beverage can be provided.
以下、本発明の実施の形態について説明する。なお、以下の実施の形態は、本発明を説明するための例示であり、本発明はその実施の形態のみに限定されるものではない。
以下、本実施形態のトマト含有飲料について説明する。
Embodiments of the present invention will be described below. In addition, the following embodiment is an illustration for demonstrating this invention, and this invention is not limited only to the embodiment.
Hereinafter, the tomato-containing beverage of this embodiment will be described.
本発明においてトマト含有飲料とは、トマトジュースのみならず、これらトマトジュースと果汁や野菜汁を混合した所謂ミックスジュース、あるいはトマトジュースを配合した炭酸飲料等、トマト搾汁を主体とした飲料を意味するものであり、原料としてトマトの破断物、より具体的にはトマトを破砕して搾汁し、或いは裏ごしし、皮や種子等を除去して得られるトマト搾汁、及び、これらを濃縮したもの(濃縮トマト)を意味し(これらを希釈還元したものが含まれる)、JAS規格で指定されたトマトジュース、トマトピューレ、トマトペースト及び濃縮トマト等を含むものである。これらは、さらに他の成分(例えば、少量の食塩や香辛料、食品添加物等)を含有していてもよい。かかるトマト加工物の性状は、特に限定されず、例えば、液状、ゲル状、ペースト状(擬固体状)、半固体状、固体状のいずれであってもよい。なお、主原料とは、トマト含有飲料の総量に対して50重量%以上を占めるものをいう。
本発明の容器詰トマト含有飲料は、0.7〜2.2mg/100gの植物ステロールを含有し、飲料液中におけるグルタミン酸含有量(Glu)に対する、GABA含有量(Ga)の比Ga/Gluが0.30〜0.50であることを特徴とする。
本発明において、飲みやすいトマト含有飲料とは、さらさらしてとても喉越しが良いながらも、飲み応えがあり、後味のキレも良好なトマト含有飲料である。
In the present invention, the tomato-containing beverage means not only tomato juice, but also a so-called mixed juice obtained by mixing these tomato juice and fruit juice and vegetable juice, or a beverage mainly composed of tomato juice such as a carbonated beverage containing tomato juice. Tomato juice obtained by crushing and squeezing tomato as a raw material, more specifically crushing or squeezing the tomato as a raw material, removing the skin and seeds, etc., and concentrating these Means (concentrated tomatoes) (including those obtained by diluting and reducing them) and includes tomato juice, tomato puree, tomato paste, concentrated tomatoes and the like specified by the JAS standard. These may further contain other components (for example, a small amount of salt, spices, food additives, etc.). The properties of such processed tomato products are not particularly limited, and may be any of liquid, gel, paste (pseudo-solid), semi-solid, and solid. In addition, a main raw material means what occupies 50 weight% or more with respect to the total amount of a tomato containing drink.
The container-packed tomato-containing beverage of the present invention contains 0.7 to 2.2 mg / 100 g of plant sterol, and the ratio of GABA content (Ga) to the glutamic acid content (Glu) in the beverage liquid is Ga / Glu. It is 0.30 to 0.50.
In the present invention, the easy-to-drink tomato-containing beverage is a tomato-containing beverage that is smooth and very throaty, yet has a drinking response and has a good aftertaste.
(トマト含有飲料の植物ステロール含有量)
植物ステロール(phytosterol)とは、植物中に存在するステロール類の総称であり、植物の細胞膜中に細胞膜構成成分として広く存在している。例えば、β−シトステロール、スティグマステロール、カンペステロール、ブラシカステロールなど、及びこれらのエステルや配糖体などの誘導体を含むものであり、天然または合成物を挙げることができる。これらは1種単品であっても、また2以上の混合物であってもよい。天然由来の植物ステロールは、例えば大豆、菜種、綿実、小麦胚芽、米糠、胡麻などの植物油脂から得ることができる。
本願発明においては、トマト含有飲料中に含まれる植物ステロール量を、0.7〜2.2mg/100gに調整することにより、酸味が前面に出るのを抑える分甘みが感じられ、さらっとした飲み心地となる傾向がある。一方で植物ステロールを2.2mg/100gを上回る量含有すると、さらっとした性状が薄れ、重たい印象の飲料となる。また植物ステロールが0.7mg/100g未満である場合は、飲料が水っぽく感じ、酸味が前面に出ることになり、甘みが感じられなくなる。したがって、飲料の食感と味のバランスとを考慮して、植物ステロール量は、特定範囲量含むことが重要であり、好ましくは0.8〜2.1mg/100g、さらに好ましくは0.9〜1.7mg/100g、最も好ましくは1.0〜1.4mg/100gに調整することとする。植物ステロール含有量の調整は、種々の植物ステロール含有量を有する原材料を適宜選択することにより、調整することができる。
(Plant sterol content in tomato-containing beverages)
Plant sterol is a general term for sterols present in plants, and is widely present as a cell membrane constituent in plant cell membranes. For example, it includes β-sitosterol, stigmasterol, campesterol, brassicasterol and the like, and derivatives such as esters and glycosides thereof, and examples thereof include natural or synthetic products. These may be a single type or a mixture of two or more. Naturally derived plant sterols can be obtained from vegetable oils and fats such as soybean, rapeseed, cottonseed, wheat germ, rice bran, and sesame.
In the present invention, by adjusting the amount of plant sterol contained in the tomato-containing beverage to 0.7 to 2.2 mg / 100 g, sweetness is felt to suppress the acidity from appearing on the front, and it is a dry drink Tend to be comfortable. On the other hand, when plant sterol is contained in an amount of more than 2.2 mg / 100 g, the dull nature is reduced and a heavy impression beverage is obtained. When the plant sterol is less than 0.7 mg / 100 g, the beverage feels watery, sourness comes to the front, and sweetness is not felt. Therefore, considering the beverage texture and the balance of taste, it is important that the amount of plant sterol includes a specific range amount, preferably 0.8 to 2.1 mg / 100 g, more preferably 0.9 to The amount is adjusted to 1.7 mg / 100 g, most preferably 1.0 to 1.4 mg / 100 g. Adjustment of plant sterol content can be adjusted by selecting suitably the raw material which has various plant sterol content.
([Ga/Glu]比)
グルタミン酸は、トマトに含まれる主要なアミノ酸の1つである。GABAもまた、トマトに含まれるアミノ酸の一種であり、化学合成の他、GABAの生成酵素であるグルタミン酸デカルボキシラーゼにより、グルタミン酸のα位カルボキシル基が除かれることによって生成される。
本発明者らは、重量基準において、トマト含有飲料におけるグルタミン酸含有量(Glu)に対する、GABA含有量(Ga)の比[Ga/Glu]が特定の範囲内にある場合には、トマト飲料の青臭みが低減され、熟した香り立ちをコクのある後味が生じることを見出した。即ち、飲料液中のGABAの含有量:(Ga)(mg/100g)とグルタミン酸の含有量:(Glu)(mg/100g)の含有比率がトマト含有飲料の呈味と重要な相関関係があることを見出し、この数値によりトマト含有飲料における、完熟した甘み及び旨みを具現することが可能である。
本発明にあっては,[Ga/Glu]比は、0.30〜0.50、望ましくは0.32〜0.43、更に望ましくは0.34〜0.4である。(Ga)/(Glu)比の調整は、種々の[Ga/Glu]比を有する原材料を適宜選択したり、熱履歴を調整することによって適宜調整可能である。
([Ga / Glu] ratio)
Glutamic acid is one of the main amino acids contained in tomato. GABA is also a kind of amino acid contained in tomato, and is produced not only by chemical synthesis but also by removing the α-carboxyl group of glutamic acid by glutamic acid decarboxylase which is a GABA producing enzyme.
When the ratio [Ga / Glu] of the GABA content (Ga) to the glutamic acid content (Glu) in the tomato-containing beverage is within a specific range on a weight basis, the present inventors It was found that the odor was reduced and a rich aftertaste with a ripe scent. That is, the content ratio of GABA content in beverages: (Ga) (mg / 100 g) and glutamic acid content: (Glu) (mg / 100 g) has an important correlation with the taste of tomato-containing beverages. It is possible to embody the ripe sweetness and umami in the tomato-containing beverage.
In the present invention, the [Ga / Glu] ratio is 0.30 to 0.50, preferably 0.32 to 0.43, and more preferably 0.34 to 0.4. The adjustment of the (Ga) / (Glu) ratio can be appropriately adjusted by appropriately selecting raw materials having various [Ga / Glu] ratios or adjusting the thermal history.
また、飲料液中のGABA含有量(Ga)は、40mg/100g以上であるのが好ましく、45〜250mg/100gがより好ましく、48〜200mg/100gがより好ましく、50〜180mg/100gがさらに好ましく、52〜170mg/100gが最も好ましい。
グルタミン酸量の調整方法は、トマト搾汁液若しくはその処理液又はこれらの濃縮液などの原料におけるグルタミン酸量やこれらの配合割合などを考慮して組み合わせたり、原料の熱履歴を調節することにより実施できる。
また、グルタミン酸量を高める他の方法としては、グルタミン酸や、これを含有する天然由来原料などを別途添加する方法もあるが、製造コスト抑制の観点から添加を極力控えるのが好ましく、可能であればこれらを全く添加しないのが最も好ましい。
The GABA content (Ga) in the beverage is preferably 40 mg / 100 g or more, more preferably 45 to 250 mg / 100 g, more preferably 48 to 200 mg / 100 g, and even more preferably 50 to 180 mg / 100 g. Most preferred is 52-170 mg / 100 g.
The method for adjusting the amount of glutamic acid can be carried out by combining the amount of glutamic acid in the raw materials such as tomato juice or its treated liquid or their concentrated liquid, the blending ratio thereof, etc., or by adjusting the heat history of the raw materials.
In addition, as another method for increasing the amount of glutamic acid, there is a method of separately adding glutamic acid or a naturally-derived raw material containing the same, but it is preferable to refrain from addition as much as possible from the viewpoint of manufacturing cost suppression. Most preferably, these are not added at all.
(トマト含有飲料の含有粒子径)
本発明に係るトマト含有飲料は、含有粒子径が600μm以下、好ましくは500μm以下、更に好ましくは350μm以下、最も好ましくは120μm以下である。このように、飲料中の粒子径を特定サイズ以下にすることにより、さらりとしてのど越しが良く、飲みやすい性状のトマト含有飲料になるだけでなく、飲料自体酸味が抑制され、その分低粘度であっても甘みを感じやすくなることがわかった。含有粒子径は、より小さい粒子径に限定するほど滑らかできめ細かい性状のトマト含有飲料となり、好ましい。
ここで、含有粒子径が600μm以下とは、粒子の全て(100%)が600μm以下であることを要求するものではなく、トマト含有飲料中に含有される粒子の90%以上、好ましくは95%以上の粒子の粒子径が600μm以下であればよい。
ここで、粒子の粒子径は、粒子の長径を測定したものであり、具体的には島津製作所社製のレーザ解析式粒度分布測定装置SALD−2100によって測定した値である。粒子としては、トマト由来の粒子、野菜由来の粒子、果物由来の粒子又はそれらの混合物が挙げられる。粒子には、繊維状のものも含まれるものとする。
(Contained particle size of tomato-containing beverage)
The tomato-containing beverage according to the present invention has a particle size of 600 μm or less, preferably 500 μm or less, more preferably 350 μm or less, and most preferably 120 μm or less. In this way, by making the particle size in the beverage not more than a specific size, not only does it become a tomato-containing beverage that is easy to drink and is easy to drink, but also the beverage itself is suppressed in acidity, and accordingly the viscosity is low. I found that it would be easier to feel sweetness. The contained particle size is preferably smoother and finer tomato-containing beverage as it is limited to a smaller particle size.
Here, the content particle size of 600 μm or less does not require that all (100%) of the particles are 600 μm or less, and 90% or more, preferably 95% of the particles contained in the tomato-containing beverage. The particle diameter of the above particles should just be 600 micrometers or less.
Here, the particle diameter of the particle is a value obtained by measuring the major axis of the particle, and is specifically a value measured by a laser analysis type particle size distribution analyzer SALD-2100 manufactured by Shimadzu Corporation. Examples of the particles include tomato-derived particles, vegetable-derived particles, fruit-derived particles, or a mixture thereof. The particles include fibrous ones.
(トマト含有飲料の累積頻度径)
本発明に係るトマト含有飲料が含有する粒子径は、粒度分布を測定したときに、粒度分布積算値の50%累積頻度径が270μm以下、好ましくは260μm以下、更に好ましくは255μm以下である。また、90%累積頻度径は、480μm以下、好ましくは470μm以下、更に好ましくは460μm以下である。
トマト含有飲料の粒子径の調整は、特に限定されるものではないが、代表的かつ簡便な手段はろ過である。用いる篩は、24メッシュ以上、好ましくは30〜300メッシュ、さらに好ましくは40〜250メッシュであるが、その果実の粉砕状況や繊維の硬さなどの質的なものにより、また処理時の圧力によっても変わるため、これに限定されるものではない。ろ過処理は、数段階に分けて、最初は目の粗いろ紙でろ過し、徐々に目の細かいろ紙を用いて段階的に行ってもよい。また、優位にはそれ自体大きな粒子を含まない透明トマト汁を使用することができる。
ここで、「a%累積頻度径」とは、累積粒子数が全粒子のa%に達したときの粒子径をいう。なお、粒度分布の測定は、粒度分布計を使用して行うことができ、具体的には、島津製作所社製のレーザ解析式粒度分布測定装置SALD−2100によって測定した値である。50%累積頻度径及び90%累積頻度径が上記範囲にあることで、よりさらっとしたテクスチャーが得られながらも、酸味が低減され、甘みが感じられ、完熟したトマト感のある、のどごしがより良いトマト含有飲料となる。このような粒度分布を有する粒子は、破砕又は磨砕、裏ごし、濾過等を適宜行うことにより得ることができる。また、このような粒子径調整のためには透明トマト汁を用いることも効果的である。
(Cumulative frequency of tomato-containing beverages)
When the particle size distribution of the tomato-containing beverage according to the present invention is measured, the 50% cumulative frequency diameter of the particle size distribution integrated value is 270 μm or less, preferably 260 μm or less, more preferably 255 μm or less. The 90% cumulative frequency diameter is 480 μm or less, preferably 470 μm or less, and more preferably 460 μm or less.
The adjustment of the particle size of the tomato-containing beverage is not particularly limited, but a representative and simple means is filtration. The sieve to be used is 24 mesh or more, preferably 30 to 300 mesh, more preferably 40 to 250 mesh, but depending on qualitative things such as the pulverization status of the fruit and the hardness of the fiber, and depending on the pressure during processing However, it is not limited to this. The filtration treatment may be performed in several stages, first by filtration with a coarse filter paper, and gradually using a fine filter paper. In addition, a clear tomato juice that does not itself contain large particles can be used.
Here, “a% cumulative frequency diameter” refers to the particle diameter when the cumulative number of particles reaches a% of all particles. The particle size distribution can be measured using a particle size distribution meter. Specifically, the particle size distribution is a value measured by a laser analysis type particle size distribution analyzer SALD-2100 manufactured by Shimadzu Corporation. The 50% cumulative frequency diameter and the 90% cumulative frequency diameter are within the above range, so that a smoother texture is obtained, but the sourness is reduced, the sweetness is felt, and the ripening tomato feels more. A good tomato-containing beverage. The particles having such a particle size distribution can be obtained by appropriately performing crushing or grinding, scouring, filtration and the like. It is also effective to use transparent tomato juice for such particle size adjustment.
トマト含有飲料は、トマト以外の野菜汁を含有してもよく、これら原料となる野菜の種類としては、特に限定されることなく、例えば、ナス、カボチャ、ピーマン、ゴーヤ、ナーベラ、トウガン、オクラ、エダマメ、サヤエンドウ、サヤインゲン、ソラマメ、トウガラシ、トウモロコシ、キュウリ等の果菜類、ニンジン、ゴボウ、タマネギ、タケノコ、レンコン、カブ、ダイコン、ジャガイモ、サツマイモ、サトイモ、ラッキョウ、ニンニク、ショウガ等の根菜類、モロヘイヤ、アスパラガス、セロリ、ケール、チンゲンサイ、ホウレンソウ、コマツナ、キャベツ、レタス、ハクサイ、ブロッコリー、カリフラワー、ミツバ、パセリ、ネギ、シュンギク、ニラ等の葉茎類等が挙げられる。上記の野菜は、1種を単独で又は2種以上を混合して使用することができる。 Tomato-containing beverages may contain vegetable juices other than tomatoes, and the types of vegetables used as these raw materials are not particularly limited, for example, eggplant, pumpkin, bell pepper, bitter gourd, nerbera, tougan, okra, Fruit vegetables such as green soybeans, green peas, green beans, broad beans, peppers, corn, cucumbers, carrots, burdock, onions, bamboo shoots, lotus roots, turnips, radish, potatoes, sweet potatoes, taros, red peppers, garlics, ginger, root vegetables, Moroyai Examples include leaf and stems such as asparagus, celery, kale, spinach, spinach, komatsuna, cabbage, lettuce, Chinese cabbage, broccoli, cauliflower, beeswax, parsley, leek, garlic, and leek. Said vegetables can be used individually by 1 type or in mixture of 2 or more types.
また、本トマト含有飲料は、果実汁を含んでもよく、これら果実の種類としては、本発明の効果が発揮される限りにおいて特に限定されることなく、例えば、イチゴ、キウイフルーツ、ブドウ、モモ、パイナップル、グアバ、バナナ、マンゴー、アセロラ、プルーン、パパイヤ、パッションフルーツ、ウメ、ナシ、アンズ、ライチ、メロン、西洋ナシ、スモモ類、柑橘類果実類(オレンジ、温州ミカン、レモン、グレープフルーツ、ライム、マンダリン、ユズ、シークワーサー、タンジェリン、テンプルオレンジ、タンジェロ、カラマンシー等)等が挙げられる。上記の果実は、1種を単独で又は2種以上を混合して使用することができる。なお、リンゴは、上記粒子径を有する粒子範囲に調整した場合、パルプの苦渋味が炭酸ガスの刺激と重なり、エグ味が強く感じるようになり、良質な果実感を得ることができなかったため、使用しないことが好ましい。 Further, the tomato-containing beverage may contain fruit juice, and the type of these fruits is not particularly limited as long as the effect of the present invention is exhibited, for example, strawberry, kiwi fruit, grape, peach, Pineapple, guava, banana, mango, acerola, prunes, papaya, passion fruit, plum, pear, apricot, lychee, melon, pear, plum, citrus fruit (orange, citrus fruit, lemon, grapefruit, lime, mandarin, Yuzu, Sikhwasa, Tangerine, Temple Orange, Tangero, Karamanshi, etc.). Said fruit can be used individually by 1 type or in mixture of 2 or more types. In addition, when apple is adjusted to the particle range having the above particle diameter, the bitter and astringent taste of the pulp overlaps with the stimulation of carbon dioxide gas, and the taste becomes strong, and it was not possible to obtain a good fruit feeling, It is preferable not to use it.
本発明のトマト含有飲料は、トマト本来の風味維持し、トマト本来の風味をより一層際立たせる観点から、トマト以外の野菜汁及び/又は果汁を一定比率以上含まないことが好ましい。即ち、飲料の総量に対するトマト以外の野菜汁及び果汁の総含有量が0〜10.0重量%、好ましくは0〜8.0重量%、さらに好ましくは0〜5.0重量%であることを意味する。トマト以外の野菜汁及び/又は果汁を一定以上含まないものは、トマト本来の甘みが際立ち、飲料形態としておいしく飲めるトマト含有飲料という、消費者への訴求力に優れた飲料となる。 The tomato-containing beverage of the present invention preferably contains no vegetable juice and / or fruit juice other than tomatoes in a certain ratio or more from the viewpoint of maintaining the original flavor of tomatoes and making the original flavor of tomatoes more distinctive. That is, the total content of vegetable juice and fruit juice other than tomato is 0 to 10.0% by weight, preferably 0 to 8.0% by weight, and more preferably 0 to 5.0% by weight with respect to the total amount of beverage. means. What does not contain more than a certain amount of vegetable juice and / or fruit juice other than tomato is a beverage excellent in appealing to consumers, which is a tomato-containing beverage that stands out from the original sweetness of tomato and can be drunk deliciously as a beverage form.
(トマト含有飲料の製造方法)
本発明のトマト含有飲料は、主原料としてトマトを搾汁して得られるトマト汁を含有するものであって、トマト汁はトマト搾汁又はその濃縮物(これらの希釈還元物が含まれる。)であってもよいが、さらさら感等の観点から好ましくは透明トマト汁を優位に使用することができる。また、1又は複数のトマト汁をブレンドすることにより得ることが可能である。好ましくは、トマト搾汁又はその濃縮物(これらの希釈還元物が含まれる。)などのトマト汁及び脱酸処理したトマト汁(脱酸トマト汁)を含有しても良い。本発明者らは、それらのトマト原料を適宜ブレンドして、植物ステロール量、Ga/Glu比率及び含有粒子径を所定の範囲に調整したトマト含有飲料を作製したところ、完熟したように青臭みが感じられず、旨み及び甘みがあり、且つトマトの酸味が抑制されているにも関わらず、さらっとした喉越しを有しながらも飲み応えがある、後味のキレが良好な飲み易いトマト含有飲料が、再現性よく簡便に実現されることを見出した。
本実施形態のトマト含有飲料の製造方法を説明するにあたり、まず原料として特に好適なトマト汁、透明トマト汁及び脱酸トマト汁などについて以下に説明することとする。
(Method for producing tomato-containing beverage)
The tomato-containing beverage of the present invention contains tomato juice obtained by squeezing tomato as a main ingredient, and the tomato juice is squeezed tomato juice or a concentrate thereof (including these diluted reduced products). However, a transparent tomato juice can be preferably used from the viewpoint of a smooth feeling. It can also be obtained by blending one or more tomato juices. Preferably, it may contain tomato juice such as tomato juice or concentrates thereof (including these diluted reduced products) and deacidified tomato juice (deoxidized tomato juice). The inventors of the present invention appropriately blended these tomato ingredients to produce a tomato-containing beverage in which the amount of plant sterol, the Ga / Glu ratio, and the contained particle diameter were adjusted to a predetermined range. A tomato-containing beverage that has a good aftertaste and is easy to drink, with a refreshing throat but a refreshing sensation even though it is not felt, has a umami and sweetness, and the sourness of the tomato is suppressed Has been found to be easily realized with good reproducibility.
In describing the method for producing a tomato-containing beverage of this embodiment, first, tomato juice, transparent tomato juice, deacidified tomato juice, and the like that are particularly suitable as raw materials will be described below.
(トマト汁)
本発明において、トマト汁とは、トマトを破砕して搾汁し或いは裏ごしし、皮や種子等を除去して得られるトマト搾汁、及び、これらを濃縮したもの(濃縮トマト)を意味し(これらを希釈還元したものが含まれる)、JAS規格で指定されたトマトジュース、トマトピューレ、トマトペースト及び濃縮トマト等を包含する概念である。なお、トマトペーストとは、上記の濃縮トマトのうち、無塩可溶性固形分が24%以上のものを意味する。トマトペーストは、必要に応じて濃縮或いは希釈して用いることができ、特に限定されないが、飲料製造時の扱いやすさの観点から、無塩可溶性固形分が24〜40%のものが好ましい。一方、本明細書において、トマトピューレとは、上記の濃縮トマトのうち、無塩可溶性固形分が8%以上24%未満のものを意味する。これらは、さらに他の成分(例えば、少量の食塩や香辛料、食品添加物等)を含有していてもよい。かかるトマト加工物の性状は、特に限定されず、例えば、液状、ゲル状、ペースト状(擬固体状)、半固体状、固体状のいずれであってもよい。なお、主原料とは、容器詰トマト含有飲料の総量に対して50重量%以上を占めるものをいう。
(Tomato juice)
In the present invention, the tomato juice means tomato juice obtained by crushing and squeezing or squeezing the tomato and removing the skin and seeds, etc., and those concentrated (concentrated tomato) ( These include a product obtained by diluting and reducing these), tomato juice, tomato puree, tomato paste, concentrated tomato and the like specified by the JAS standard. In addition, a tomato paste means a thing with a salt-free soluble solid content of 24% or more among said concentrated tomatoes. The tomato paste can be concentrated or diluted as necessary and is not particularly limited. However, from the viewpoint of ease of handling at the time of beverage production, a tomato paste having a salt-free soluble solid content of 24 to 40% is preferable. On the other hand, in this specification, tomato puree means a salt-free soluble solid content of 8% or more and less than 24% among the concentrated tomatoes. These may further contain other components (for example, a small amount of salt, spices, food additives, etc.). The properties of such processed tomato products are not particularly limited, and may be any of liquid, gel, paste (pseudo-solid), semi-solid, and solid. In addition, a main raw material means what occupies 50 weight% or more with respect to the total amount of a container-packed tomato containing drink.
なお、トマト汁の搾汁方法としては、リーマ等を用いて搾り取る方法、油圧プレス機、ローラー圧搾機やインライン搾汁機を用いて圧搾し搾汁する方法、パルパー・フィニッシャー等を用いて破砕し搾汁する方法、並びにクラッシャー等を用いて破砕し、エクストラクター等を用いて搾汁する方法が知られている。好ましくは、搾汁時の温度は、ペクチナーゼの失活温度以下の所謂コールドブレイク処理とする。
さらに、これらの方法に従って圧搾(搾汁)されたものを、所望により、ジューサーにかけてもよい。さらに、これらの方法に従って圧搾(搾汁)されたものを、所望により、ペクチナーゼやセルラーゼといった酵素処理、ジューサーにかけてもよい。
また、上記における濃縮方法としては、本願においては減圧濃縮、低温濃縮、真空濃縮、凍結濃縮、及び逆浸透濃縮等、加熱濃縮以外の手段が適用できる。
In addition, as a squeezing method of tomato juice, a method of squeezing using a reamer or the like, a method of squeezing and squeezing using a hydraulic press machine, a roller squeezing machine or an inline squeezing machine, a pulper finisher or the like A method of squeezing and crushing using a crusher or the like and a method of squeezing using an extractor or the like are known. Preferably, the temperature at the time of squeezing is a so-called cold break treatment having a pectinase inactivation temperature or lower.
Furthermore, what is squeezed (squeezed) according to these methods may be applied to a juicer as desired. Furthermore, what is squeezed (squeezed) according to these methods may be subjected to an enzyme treatment such as pectinase or cellulase or a juicer, if desired.
As the concentration method described above, means other than heat concentration, such as reduced pressure concentration, low temperature concentration, vacuum concentration, freeze concentration, and reverse osmosis concentration, can be applied in the present application.
(透明トマト汁)
透明トマト汁は本発明の容器詰トマト含有飲料を製造するに当たって特に好適である。本明細書において、透明トマト汁とは、濁度の指標であるT%(660nmでの透過率)が10%以上のものを意味する。かかる透明トマト汁としては、上述したトマト搾汁或いは濃縮トマトを遠心分離等して得た上清を濃縮したもの(言い換えれば、トマト搾汁或いは濃縮トマトに含まれる水不溶性固形分の一部を除去した濃縮トマト)及びこれらを希釈還元したものが包含される。また、「透明」とは、Brix4.5において、Brix4.5を超えるものに対して、透明度に優れることを意味する。なお、透明トマト汁は、必要に応じて濃縮或いは希釈して用いることができ、特に限定されないが、飲料製造時の扱いやすさの観点から、無塩可溶性固形分が4〜70%のものが好ましい。
(Clear tomato juice)
Transparent tomato juice is particularly suitable for producing the containerized tomato-containing beverage of the present invention. In the present specification, the transparent tomato juice means one having a turbidity index T% (transmittance at 660 nm) of 10% or more. As such transparent tomato juice, a concentrated supernatant obtained by centrifuging the above-described tomato juice or concentrated tomato (in other words, a part of the water-insoluble solid contained in the tomato juice or concentrated tomato Removed concentrated tomato) and those obtained by diluting and reducing them. Further, “transparent” means that, in Brix 4.5, the transparency exceeds that of Brix 4.5. In addition, transparent tomato juice can be used by concentrating or diluting as necessary, and is not particularly limited. However, from the viewpoint of ease of handling during beverage production, the transparent tomato juice has a salt-free soluble solid content of 4 to 70%. preferable.
上記の透明トマト汁の調製は、当業界で公知の手法により適宜行うことができ、特に限定されない。例えば、常法に従い、上述したトマト搾汁、或いは濃縮トマトを遠心分離する等して得た上清を濃縮して濁度を10%以上とすることにより得ることができ、また、市販のトマト搾汁或いは濃縮トマトを濃縮することにより得ることもでき、さらには、市販の透明トマト汁を用いることもできる。市販品の透明トマト汁としては、特に限定されないが、例えば、三栄源エフ・エフ・アイ社のクリアトマト濃縮汁等が挙げられる。
なお、透明トマト汁は、1種のみを単独で、或いは2種以上を組み合わせて用いることができる。
Preparation of said transparent tomato juice can be suitably performed by a well-known method in this industry, and is not specifically limited. For example, according to a conventional method, it can be obtained by concentrating a supernatant obtained by squeezing the above-described tomato juice or concentrated tomato to obtain a turbidity of 10% or more. It can also be obtained by concentrating squeezed juice or concentrated tomato, and furthermore, commercially available transparent tomato juice can also be used. Although it does not specifically limit as a transparent tomato juice of a commercial item, For example, the clear tomato concentrate of San-Eigen FFI Corporation etc. are mentioned.
In addition, transparent tomato juice can be used individually by 1 type or in combination of 2 or more types.
(脱酸トマト汁)
脱酸トマト汁は、トマト汁、好ましくは透明トマト汁を、脱酸処理することにより得られる。酸味を抑え、甘味を引き出したトマト含有飲料を作製するには、脱酸処理を行い、酸成分を低減させた1または2種類以上脱酸トマト汁を、一部含有することが好ましい。脱酸処理の手法に関しては、吸着剤処理や膜処理など、一般に用いられる脱酸処理を採用することができるが、好ましくはカルシウム又はその塩を配合することにより脱酸処理する「カルシウム脱酸」、及び重炭酸置換又は炭酸置換された陰イオン交換樹脂に通液することにより脱酸処理する「陰イオン交換樹脂脱酸」が採用される。
(Deacidized tomato juice)
Deacidified tomato juice is obtained by deoxidizing tomato juice, preferably transparent tomato juice. In order to produce a tomato-containing beverage that suppresses acidity and brings out sweetness, it is preferable to partially contain one or two or more kinds of deacidified tomato juice that has been subjected to deoxidation treatment and reduced acid components. Regarding deoxidation treatment techniques, commonly used deoxidation treatments such as adsorbent treatment and membrane treatment can be adopted, but preferably "calcium deoxidation" for deoxidation treatment by adding calcium or a salt thereof. In addition, “anion exchange resin deoxidation” in which deoxidation treatment is performed by passing through a bicarbonate-substituted or carbonate-substituted anion exchange resin is employed.
脱酸トマト汁の原料として用いる透明トマト汁は、必要に応じて濃縮或いは希釈して用いることができる。高糖度の脱酸トマト汁を得たい場合は、Brixが8〜80であることが好ましいが、特に限定するものではない。なお、本明細書において、糖度とはBrix値を意味する。ここで、Brix値とは、溶液100g中に含まれる可溶性固形分(糖類など)のグラム量を計測する単位である。Brix値は、市販の屈折率計又は糖度計を用いて測定することができる。 Transparent tomato juice used as a raw material for deacidified tomato juice can be used after being concentrated or diluted as necessary. When it is desired to obtain deacidified tomato juice having a high sugar content, Brix is preferably 8 to 80, but is not particularly limited. In addition, in this specification, sugar content means a Brix value. Here, the Brix value is a unit for measuring the gram amount of soluble solids (such as sugars) contained in 100 g of a solution. The Brix value can be measured using a commercially available refractometer or saccharimeter.
また、本発明の脱酸トマト汁の原料として用いる透明トマト汁等は、特に限定されないが、Brix4.5調整時の酸度が0.1〜0.5であることが好ましい。酸度が低い透明トマト汁を用いることで得られる脱酸トマト汁の酸度が低くなる傾向にある。一方、透明トマト汁の酸度が高いほど、カルシウム又はその塩の配合による酸度の低減効果が顕著に発揮され易い傾向にある。なお、本明細書において、酸度は、0.1mol/L水酸化ナトリウム標準液を用いた電位差滴定法により算出される、クエン酸換算での濃度(%)を意味する。 Moreover, although the transparent tomato juice etc. which are used as a raw material of the deoxidized tomato juice of this invention are not specifically limited, It is preferable that the acidity at the time of Brix4.5 adjustment is 0.1-0.5. There exists a tendency for the acidity of the deoxidized tomato juice obtained by using transparent tomato juice with low acidity to become low. On the other hand, the higher the acidity of the transparent tomato juice, the more easily the effect of reducing the acidity due to the blending of calcium or a salt thereof tends to be exhibited. In the present specification, the acidity means a concentration (%) in terms of citric acid calculated by a potentiometric titration method using a 0.1 mol / L sodium hydroxide standard solution.
また、本発明の脱酸トマト汁の原料として用いる透明トマト汁等は、特に限定されないが、pHが3.7〜4.6であることが好ましい。pHが中性側に偏ると、カルシウム又はその塩の配合による効果が低くなり、得られる脱酸トマト汁のクエン酸の低減率が低くなる傾向にある。 Moreover, although transparent tomato juice etc. which are used as a raw material of the deoxidized tomato juice of this invention are not specifically limited, It is preferable that pH is 3.7-4.6. When the pH is biased to the neutral side, the effect of the calcium or salt combination tends to be low, and the citric acid reduction rate of the resulting deacidified tomato juice tends to be low.
(カルシウム脱酸トマト汁)
カルシウム脱酸とは、上記のトマト汁等、好ましくは透明トマト汁に、カルシウム又はその塩を配合することにより、トマト汁中の酸成分を除去することであり、処理後の透明トマト汁(脱酸トマト汁)において酸味が低減するものである。これは、透明トマト汁等に含まれる酸味成分、例えばクエン酸等のヒドロキシ酸及とカルシウムとが反応してカルシウム生成物(塩、水和物、又はキレート等)を形成することによるものと推定される。脱酸トマト汁の酸味を低減させるために配合されるカルシウム又はその塩の具体例としては、例えば、カルシウム、炭酸カルシウム、硫酸カルシウム、乳酸カルシウム、グルコン酸カルシウム、コハク酸カルシウム、塩化カルシウム等が挙げられるが、これらに特に限定されない。これらの中でも、炭酸カルシウム、硫酸カルシウム及び乳酸カルシウムが好ましく、脱酸処理後トマト加工物の香味へ与える影響を極力抑える観点から、炭酸カルシウムがより好ましい。上記のカルシウム又はその塩の配合量は、脱酸トマト汁の所望する酸味に応じて適宜設定することができ、特に限定されない。カルシウム又はその塩を配合することにより生成するカルシウム生成物(塩、水和物、又はキレート等)を脱酸トマト汁から除去すると、脱酸トマト汁の酸味が一段と低減する。また、未反応のカルシウム又はその塩及びカルシウム生成物は白色の固形物が多く、かかる白色沈殿物の存在により飲料の見栄えが損なわれ得るとともに、他の飲料と混合した際に所望しない色変化を生じ得る。したがって、透明トマト汁にカルシウム又はその塩を配合した後、上記カルシウム生成物の少なくとも一部を除去することが好ましい。その際、未反応のカルシウム又はその塩を除去することがより好ましい。カルシウム生成物の除去方法は、濾過、遠心分離等の公知の手法を適宜適用して行うことができ、特に限定されない。とりわけ、脱酸トマト汁中に沈殿・析出・分散しているカルシウム生成物は、濾過法によって簡易且つ低コストで除去することができる。かかる濾過法を適用する場合、安価に透明性の高い脱酸トマト汁を得る観点から、珪藻土或いはフィルターを用いた濾過等を用いることが好ましい。
(Calcium deoxidized tomato juice)
Calcium deoxidation is to remove acid components in tomato juice by adding calcium or a salt thereof to the above-mentioned tomato juice, preferably transparent tomato juice. Acidity in acid tomato juice). This is presumed to be due to the formation of calcium products (salts, hydrates, chelates, etc.) by the reaction of sour components contained in clear tomato juice etc., for example, hydroxy acids such as citric acid and calcium. Is done. Specific examples of calcium or a salt thereof blended to reduce the acidity of deacidified tomato juice include, for example, calcium, calcium carbonate, calcium sulfate, calcium lactate, calcium gluconate, calcium succinate, calcium chloride and the like. However, it is not particularly limited to these. Among these, calcium carbonate, calcium sulfate, and calcium lactate are preferable, and calcium carbonate is more preferable from the viewpoint of suppressing the influence on the flavor of the processed tomato product after deoxidation as much as possible. The compounding quantity of said calcium or its salt can be suitably set according to the acidity which deacidified tomato juice desires, and is not specifically limited. When the calcium product (salt, hydrate, chelate, etc.) produced | generated by mix | blending calcium or its salt is removed from deoxidized tomato juice, the acidity of deacidified tomato juice will reduce further. In addition, unreacted calcium or a salt thereof and a calcium product are often white solids, and the presence of such white precipitates may impair the appearance of the beverage, and may cause an undesirable color change when mixed with other beverages. Can occur. Therefore, it is preferable to remove at least a part of the calcium product after adding calcium or a salt thereof to the transparent tomato juice. At that time, it is more preferable to remove unreacted calcium or a salt thereof. The method for removing the calcium product can be performed by appropriately applying known methods such as filtration and centrifugation, and is not particularly limited. In particular, the calcium product precipitated, precipitated and dispersed in the deacidified tomato juice can be removed easily and at low cost by the filtration method. When such a filtration method is applied, it is preferable to use diatomaceous earth or filtration using a filter from the viewpoint of obtaining inexpensive and highly transparent deacidified tomato juice.
かくして得られる濾過、遠心分離等の処理を施した脱酸トマト汁は、不要な水不溶性固形分の少なくとも一部が除去され、且つ、カルシウム生成物が必要に応じて除去されることにより、そうでないものと比較して、低粘度であり、且つ、酸度が低減されたものとなる。そのため、かかる脱酸トマト汁を用いて、トマト含有飲料を調製することにより、得られるトマト含有飲料の粘度の低減、及び、酸度或いは酸味の低減が、再現性よく簡便に行われる。 The deacidified tomato juice that has been subjected to the treatment such as filtration and centrifugation thus obtained is freed of at least a part of unnecessary water-insoluble solids, and the calcium product is removed as necessary. Compared to those not having a low viscosity, the acidity is reduced. Therefore, by preparing a tomato-containing beverage using such deacidified tomato juice, the viscosity of the obtained tomato-containing beverage and the acidity or acidity are easily reduced with good reproducibility.
(陰イオン交換樹脂脱酸トマト汁)
脱酸のもう1つの方法は陰イオン交換樹脂脱酸法であり、前述の透明トマト汁等を重炭酸置換又は炭酸置換された陰イオン交換樹脂に通液することにより、処理後の透明トマト汁(脱酸トマト汁)においてクエン酸等に由来する酸味を低減させるものである。これは、透明トマト汁等に含まれるクエン酸等の酸味成分が重炭酸置換又は炭酸置換することで除去され、また、置換した重炭酸が炭酸ガスとなって抜け出ることによるものと推定される。ここで、透明トマト汁等に含まれる酸味成分のなかでも、比較的に透明トマト汁中の含有量が多く、また比較的に酸味を強く感じさせる成分はクエン酸である。上述した酸味低減効果は、透明トマト汁等中のクエン酸の除去によるところが大きいと考えられる。陰イオン交換樹脂脱酸法によって得られた脱酸トマト汁は、カルシウム脱酸法によって得られた脱酸トマト汁に混合して使用することができる。
(Anion exchange resin deoxidized tomato juice)
Another method of deoxidation is an anion exchange resin deoxidation method, and the transparent tomato juice after treatment is passed by passing the above-mentioned transparent tomato juice or the like through an anion exchange resin substituted with bicarbonate or carbonate. In (deacidified tomato juice), acidity derived from citric acid or the like is reduced. This is presumed to be due to removal of sour components such as citric acid contained in transparent tomato juice etc. by bicarbonate substitution or carbonation substitution, and substitution of bicarbonate to escape as carbon dioxide gas. Here, among the sour components contained in transparent tomato juice and the like, citric acid is a component that has a relatively large content in transparent tomato juice and that makes it feel relatively sour. It is considered that the acidity reduction effect described above is largely due to the removal of citric acid in transparent tomato juice and the like. The deoxidized tomato juice obtained by the anion exchange resin deoxidation method can be used by mixing with the deacidified tomato juice obtained by the calcium deoxidation method.
透明トマト汁等を脱酸処理するために用いる重炭酸置換又は炭酸置換された陰イオン交換樹脂は、重炭酸イオン又は炭酸イオンがイオン結合した陰イオン交換樹脂であることが必要とされる。その母材となる陰イオン交換樹脂は、強塩基性イオン交換樹脂又は弱塩基性イオン交換樹脂であることが好ましい。かかる強塩基性イオン交換樹脂又は弱塩基性イオン交換樹脂中に含まれるClイオン或いは水酸基等のイオン交換基を、重炭酸イオン又は炭酸イオンにイオン交換させることにより、重炭酸置換又は炭酸置換された陰イオン交換樹脂を簡易に得ることができる。 A bicarbonate-substituted or carbonate-substituted anion exchange resin used for deoxidizing transparent tomato juice or the like is required to be an anion exchange resin in which bicarbonate ions or carbonate ions are ion-bonded. The anion exchange resin as the base material is preferably a strong basic ion exchange resin or a weak basic ion exchange resin. By replacing the ion exchange group such as Cl ion or hydroxyl group contained in the strong basic ion exchange resin or weak basic ion exchange resin with bicarbonate ion or carbonate ion, the bicarbonate substitution or carbonate substitution was performed. An anion exchange resin can be easily obtained.
陰イオン交換樹脂脱酸法における透明トマト汁等の通液方法は、特に限定されず、上向流方式或いは下向流方式のいずれであっても構わないが、生産性の観点から、上向流方式が好ましい。重炭酸イオン又は炭酸イオンへの置換に伴い炭酸ガスが発生し得るが、上向流方式を採用すると炭酸ガスが通液方向に沿って抜けやすくなるので、陰イオン交換樹脂中或いはこれが配置されたカラム内の炭酸ガスの滞留による生産性の低下が抑制され得る。 The liquid passing method such as transparent tomato juice in the anion exchange resin deoxidation method is not particularly limited, and may be either an upward flow method or a downward flow method. The flow system is preferred. Carbon dioxide may be generated with the substitution to bicarbonate ion or carbonate ion, but if the upward flow method is adopted, carbon dioxide is easily removed along the liquid passing direction, so that it is disposed in the anion exchange resin or this. A decrease in productivity due to the stay of carbon dioxide in the column can be suppressed.
このようにして得られる脱酸トマト汁は、透明トマト汁に含まれるクエン酸等の酸味成分が重炭酸置換又は炭酸置換することで除去されるばかりでなく、ろ過等の処理を施すことにより不要な水不溶性固形分の少なくとも一部が除去され、更には置換した重炭酸又は炭酸が炭酸ガスとなって抜け出ることにより、そうでないものと比較して、低粘度であり、且つ、酸度が低減されたものとなる。そのため、このような脱酸トマト汁を用いて、トマト含有飲料を調製することにより、得られるトマト含有飲料の粘度の低減、及び酸度或いは酸味の低減が、再現性よく簡便に行われる。 The deacidified tomato juice obtained in this way is not only removed by replacing the sour components such as citric acid contained in the transparent tomato juice with bicarbonate or carbonate, but is not necessary by applying a treatment such as filtration. As a result, at least a part of the water-insoluble solid content is removed, and the substituted bicarbonate or carbonic acid escapes as carbon dioxide gas, thereby lowering the viscosity and reducing the acidity. It will be. Therefore, by preparing a tomato-containing beverage using such a deacidified tomato juice, the viscosity of the obtained tomato-containing beverage and the acidity or acidity can be easily reduced with good reproducibility.
なお、脱酸トマト汁は、必要に応じて濃縮或いは希釈して用いることができるため、特に限定されないが、容器詰トマト含有飲料の低粘度化をより一層高める観点から、粘度が0〜100cPであることが好ましい。ここで、脱酸トマト汁の粘度は、トマトストレートBrix4.5換算で算出したものとする。また、粘度が0とは、粘度が0.5未満のもの、及び、検出限界以下のものを含む含意である。粘度の下限は、特に限定されないが、0.01cP以上であることが好ましい。 In addition, since deacidified tomato juice can be concentrated or diluted as necessary and used, it is not particularly limited, but the viscosity is 0 to 100 cP from the viewpoint of further increasing the viscosity of the container-containing tomato-containing beverage. Preferably there is. Here, the viscosity of the deoxidized tomato juice is calculated in terms of tomato straight Brix 4.5. Moreover, the viscosity of 0 means that the viscosity is less than 0.5 and includes those below the detection limit. Although the minimum of a viscosity is not specifically limited, It is preferable that it is 0.01 cP or more.
本発明のトマト含有飲料は、上述の加工処理した1又は複数のトマト加工物をブレンドすることにより製造することができ、好ましくは、トマト搾汁又はその濃縮物(これらの希釈還元物が含まれる。)などのトマト汁、カルシウム脱酸トマト汁及び陰イオン交換樹脂脱酸トマト汁の3種類を少なくとも含有するものである。 The tomato-containing beverage of the present invention can be produced by blending one or more processed tomato products processed as described above, and preferably a tomato juice or a concentrate thereof (including these dilute reduced products). .) And the like, and at least three kinds of calcium deoxidized tomato juice and anion exchange resin deoxidized tomato juice.
トマト含有飲料中に含まれるカルシウム量を前述のとおりの範囲に調整するには、カルシウム又はその塩を単独で添加することでも調整可能であるが、カルシウム又はその塩を配合することにより脱酸処理した脱酸トマト汁を、カルシウム添加処理がなされていないトマト汁と適宜ブレンドすることによっても調整可能である。カルシウム添加処理がなされていないトマト汁は、重炭酸置換又は炭酸置換された陰イオン交換樹脂に通液することにより脱酸処理した陰イオン交換樹脂脱酸トマト汁を使用すると、酸味が抑えられる一方で甘みが引き出された、呈味の改善されたトマト含有飲料を得ることが可能となる。 In order to adjust the amount of calcium contained in the tomato-containing beverage to the range as described above, it can be adjusted by adding calcium or a salt thereof alone, but deoxidation treatment is performed by adding calcium or a salt thereof. It can also be adjusted by appropriately blending the deacidified tomato juice with the tomato juice not subjected to the calcium addition treatment. Tomato juice that has not undergone calcium addition treatment can be reduced in acidity by using an anion exchange resin deacidified tomato juice that has been deacidified by passing through an anion exchange resin that has undergone bicarbonate substitution or carbonate substitution. Thus, it is possible to obtain a tomato-containing beverage with an improved taste and a sweet taste.
また、本発明のトマト含有飲料において、トマト汁と脱酸トマト汁(カルシウム脱酸トマト汁と陰イオン交換樹脂脱酸処理した脱酸トマト汁の混合物)との重量割合は、特に限定されないが、1.5〜4.5であることが好ましい。ここで、本明細書において、かかる重量割合は、トマトストレートBrix4.5換算で算出したものとする。トマトペーストと脱酸トマト汁とを上記の重量割合で含ませることにより、フルーツトマトのような甘みがあり且つトマトの酸味が抑制されたトマト含有飲料を再現性よく簡易に得ることができる。トマトの甘み及び酸味のバランスをより一層高める観点から、トマトペーストと透明トマト汁との重量割合は、2.5〜3.5であることが好ましい。 Moreover, in the tomato-containing beverage of the present invention, the weight ratio of tomato juice and deacidified tomato juice (a mixture of calcium deoxidized tomato juice and deoxidized tomato juice subjected to anion exchange resin deoxidation treatment) is not particularly limited, It is preferable that it is 1.5-4.5. Here, in this specification, the weight ratio is calculated in terms of tomato straight Brix 4.5. By including tomato paste and deacidified tomato juice in the above weight ratio, a tomato-containing beverage having a sweet taste like fruit tomatoes and suppressing the acidity of tomatoes can be easily obtained with good reproducibility. From the viewpoint of further increasing the balance between sweetness and sourness of tomato, the weight ratio of tomato paste and transparent tomato juice is preferably 2.5 to 3.5.
本発明に係るトマト含有飲料は、前述のように含有粒子径が600μm以下、好ましくは含有粒子径が500μm以下、更に好ましくは350μm以下、最も好ましくは120μm以下に調整される。この調整は、既に篩等によってろ過処理した調整済みのトマト汁、あるいは透明トマト汁を用いてもよいが、これらをブレンドした後に調整を行ってもよい。 As described above, the tomato-containing beverage according to the present invention has a particle size of 600 μm or less, preferably a particle size of 500 μm or less, more preferably 350 μm or less, and most preferably 120 μm or less. For this adjustment, adjusted tomato juice that has already been filtered through a sieve or the like, or transparent tomato juice may be used, but adjustment may be performed after blending these.
本発明に係るトマト含有飲料は、前述のように果実汁又は野菜汁を含有してもよく、それにより、飲用したときに得られる果実感又は野菜感を、味、香り等の点から、より向上させることができる。それらは常法によって得ることが可能である。例えば、破砕、磨砕等の処理により、さらに所望により裏ごしすることにより得ることができる。さらに、ふるい等を使用して濾過することが好ましい。 The tomato-containing beverage according to the present invention may contain fruit juice or vegetable juice as described above, thereby giving a fruit feeling or vegetable feeling obtained when drinking from the point of taste, aroma, etc. Can be improved. They can be obtained by conventional methods. For example, it can be obtained by crushing, grinding, or the like, and further lining it as desired. Furthermore, it is preferable to filter using a sieve or the like.
破砕又は磨砕する場合には、例えば、原料としての果実又は野菜に対して、温める、煮る、蒸す等の加熱処理や、十分な水洗い、水にさらす、薬品処理する等の非加熱処理を施してから、ラインミキサー、エマルダー、カッターミル、ディスパー、ジューサーミキサー、マイルダー、ホモミキサー、高圧ホモジナイザー等の装置を使用して、破砕又は磨砕する。裏ごしは、裏ごし機等を使用して行うことができる。また、含有粒子径を600μm以下、好ましくは500μm以下、更に好ましくは350μm以下、最も好ましくは120μm以下にするために使用するふるいとしては、通常は、24〜60メッシュ、特に40メッシュのふるいが好ましいが、その果実の粉砕状況や繊維の硬さなどの質的なものにより、また処理時の圧力によっても変わるため、これに限定されるものではない。 When crushing or grinding, for example, the fruit or vegetable as a raw material is subjected to heat treatment such as warming, boiling, steaming, etc., sufficient washing with water, exposure to water, chemical treatment, etc. Then, it is crushed or ground using a device such as a line mixer, emulder, cutter mill, disper, juicer mixer, milder, homomixer, high pressure homogenizer. Backing can be performed by using a backside machine or the like. In addition, as a sieve used for making the contained particle size 600 μm or less, preferably 500 μm or less, more preferably 350 μm or less, and most preferably 120 μm or less, usually a sieve of 24 to 60 mesh, particularly 40 mesh is preferable. However, it is not limited to this because it varies depending on qualitative things such as the pulverization state of the fruit and the hardness of the fiber, and also depending on the pressure during the treatment.
また、本発明に係るトマト含有飲料は、上記成分の他、水や、公知の飲料に含まれる材料(成分)、例えば、糖類や甘味料などからなる甘味付与剤、酸味料、香料、ミネラル分、ビタミン類、色素成分、栄養成分、酸化防止剤等を含有してもよい。
水は、飲用に適した水であればよく、例えば、純水、硬水、軟水、イオン交換水等のほか、これらの水を脱気処理した脱気水等が挙げられる。
甘味付与剤としては、糖類又は甘味料を使用することができ、糖類としては、例えば、ブドウ糖、果糖、ショ糖、還元麦芽糖等が挙げられる。甘味料としては、例えば、砂糖、異性化糖、フラクトース、グルコース、キシリトール、ステビア抽出物、パラチノース、アスパルテーム、アセスルファムカリウム、ステビア、サッカリン、サッカリンナトリウム等が挙げられる。また、シュガーレスバルク甘味料、バルク砂糖甘味料、高甘味度甘味料等を含んでいてもよいし、ソルビトール等の糖アルコールを含んでいてもよい。
In addition, the tomato-containing beverage according to the present invention includes, in addition to the above-mentioned components, water and materials (components) contained in known beverages, for example, sweeteners such as sugars and sweeteners, acidulants, flavorings, and mineral content. , Vitamins, pigment components, nutritional components, antioxidants, and the like.
The water may be water that is suitable for drinking, and examples thereof include pure water, hard water, soft water, ion exchange water, and deaerated water obtained by deaeration of these waters.
As the sweetener, saccharides or sweeteners can be used. Examples of the saccharide include glucose, fructose, sucrose, and reduced maltose. Examples of the sweetener include sugar, isomerized sugar, fructose, glucose, xylitol, stevia extract, palatinose, aspartame, acesulfame potassium, stevia, saccharin, saccharin sodium and the like. Moreover, a sugarless bulk sweetener, a bulk sugar sweetener, a high sweetness degree sweetener, etc. may be included, and sugar alcohols, such as sorbitol, may be included.
酸味料としては、例えば、クエン酸、クエン酸三ナトリウム、アジピン酸、グルコン酸、コハク酸、酒石酸、乳酸、フマル酸、リンゴ酸、又はそれらの塩類が挙げられ、中でも、クエン酸、乳酸、リンゴ酸、酒石酸、アジピン酸等が好ましい。 Examples of the acidulant include citric acid, trisodium citrate, adipic acid, gluconic acid, succinic acid, tartaric acid, lactic acid, fumaric acid, malic acid, or salts thereof, among which citric acid, lactic acid, apple Acid, tartaric acid, adipic acid and the like are preferable.
香料としては、例えば、柑橘その他果実から抽出した香料、果汁又は果実ピューレ、植物の種実、根茎、木皮、葉等又はこれらの抽出物、乳又は乳製品、合成香料等が挙げられる。 Examples of the fragrances include fragrances extracted from citrus and other fruits, fruit juices or fruit purees, plant seeds, rhizomes, bark, leaves and the like or extracts thereof, milk or dairy products, synthetic fragrances and the like.
ビタミン類としては、例えば、ビタミンA、ビタミンC、ビタミンE、ビタミンD及びビタミンB等が挙げられる。 Examples of vitamins include vitamin A, vitamin C, vitamin E, vitamin D, and vitamin B.
ミネラル分としては、例えば、カルシウム、クロム、銅、フッ素、ヨウ素、鉄、マグネシウム、マンガン、リン、セレン、ケイ素、モリブデン及び亜鉛等が挙げられる。 Examples of the mineral component include calcium, chromium, copper, fluorine, iodine, iron, magnesium, manganese, phosphorus, selenium, silicon, molybdenum, and zinc.
色素成分としては、例えば、クロレラ、葉緑素等が挙げられる。
栄養成分としては、例えば、L−アスコルビン酸やそのナトリウム塩等が挙げられる。
Examples of the pigment component include chlorella and chlorophyll.
Examples of nutritional components include L-ascorbic acid and its sodium salt.
機能性成分としては、例えば、コラーゲン、鮫軟骨、牡蛎エキス、キトサン、プロポリス、オクタコサノール、トコフェロール、カロチン、ポリフェノール、梅エキス、アロエ、乳酸菌、霊芝、アガリクス等が挙げられる。 Examples of the functional component include collagen, salmon cartilage, oyster extract, chitosan, propolis, octacosanol, tocopherol, carotene, polyphenol, plum extract, aloe, lactic acid bacteria, ganoderma, agaricus and the like.
また、本発明に係るトマト含有飲料は、その他、各種エステル類、乳化剤、保存料、調味料、ガム、油、pH調整剤、品質安定剤等を含有してもよい。 In addition, the tomato-containing beverage according to the present invention may contain various esters, emulsifiers, preservatives, seasonings, gums, oils, pH adjusters, quality stabilizers and the like.
本発明に係るトマト含有飲料のpHは、3.7〜4.8であることが好ましく、4.2〜4.6であることがより好ましい。粒子含有炭酸飲料のpHが上記範囲内にあると、果実感又は野菜感を損なうことなく、ほどよい酸味が得られる。pHの調整は、一般的に用いられるpH調整剤を配合することにより行われる。pH調整剤としては、重曹が好ましい。pH調整剤として重曹を採用することにより、上述したpH調整機能に加えて、さらにトマトのエグ味(青臭さ、生臭さ等)が緩和されてトマト含有飲料の飲み易さが向上する傾向にある。 The pH of the tomato-containing beverage according to the present invention is preferably 3.7 to 4.8, and more preferably 4.2 to 4.6. When the pH of the particle-containing carbonated beverage is within the above range, a moderate acidity can be obtained without impairing the fruity feeling or vegetable feeling. Adjustment of pH is performed by mix | blending the pH adjuster generally used. As the pH adjuster, sodium bicarbonate is preferable. By adopting baking soda as a pH adjuster, in addition to the pH adjusting function described above, the tomato taste (blue odor, fresh odor, etc.) is further relaxed and the ease of drinking tomato-containing beverages tends to improve. .
本発明のトマト含有飲料は、粘度が100〜400cP、より好ましくは200〜300cPに調整されていることが好ましい。この程度の低粘度であることにより、殊にさらっとして、飲み易さが高められる傾向にある。 The tomato-containing beverage of the present invention preferably has a viscosity adjusted to 100 to 400 cP, more preferably 200 to 300 cP. This low viscosity tends to increase the ease of drinking, especially.
本発明のトマト含有飲料は、糖度が7.0〜13.0であり、且つ、糖酸比が19.0〜30.0であることが好ましい。また、トマトの甘み、酸味、及び濃厚な味わいのバランスをより一層高める観点から、糖度が9.0〜13.0であり、且つ、糖酸比が19.0〜30.0であることがより好ましい。 The tomato-containing beverage of the present invention preferably has a sugar content of 7.0 to 13.0 and a sugar acid ratio of 19.0 to 30.0. In addition, from the viewpoint of further increasing the balance of sweetness, sourness, and rich taste of tomato, the sugar content is 9.0 to 13.0, and the sugar acid ratio is 19.0 to 30.0. More preferred.
本発明に係るトマト含有飲料は、容器に充填した形態で提供することができる。当該容器としては、紙容器、金属缶、PETボトル等のプラスチック製ボトル、瓶などの通常の野菜果汁飲料に用いられる容器を使用可能である。 The tomato-containing beverage according to the present invention can be provided in a form filled in a container. As the said container, the container used for normal vegetable fruit juice drinks, such as a paper container, a metal can, plastic bottles, such as a PET bottle, and a bottle can be used.
本発明に係るトマト含有飲料は、特定の粒子を特定量使用する以外、従来公知の方法により製造することができる。例えば、水に、前述した方法によって得られた野菜由来の粒子及び/又は果実由来の粒子、そして所望により野菜汁及び/又は果汁、さらに所望により前述した他の成分を添加して攪拌し、飲料原液を調製する。そして、必要に応じてpHの調整及び/又は加熱殺菌をしてから冷却した後、容器に充填して、殺菌する工程により製造することができる。 The tomato-containing beverage according to the present invention can be produced by a conventionally known method except that a specific amount of specific particles is used. For example, the vegetable-derived particles and / or the fruit-derived particles obtained by the above-described method, and if necessary, the vegetable juice and / or fruit juice, and optionally the other components described above are added to the water and stirred, Prepare stock solution. And after adjusting after pH adjustment and / or heat sterilization as needed, it can manufacture by the process of filling a container and sterilizing.
以下、実施例及び比較例を挙げて、本発明を詳細に説明するが、本発明は限定されるものではない。 EXAMPLES Hereinafter, although an Example and a comparative example are given and this invention is demonstrated in detail, this invention is not limited.
(トマトペースト1〜4)
70℃以下でトマトを破砕(コールドブレイク)して搾汁後、裏ごしし、皮や種子等を除去して濃縮したトマト加工物を、それぞれ目開き1000μm(16メッシュ)、106μm(150メッシュ)、63μm(250メッシュ)の篩により大気圧下で濾過することによって、含有粒子径が限定された以下の粒子組成のトマトペースト1〜3とし、濾過処理を行わなかったものをトマトペースト4とした(表1)。
(Tomato paste 1-4)
Tomato is crushed at 70 ° C. or lower (cold break), squeezed, strained, and processed tomato products concentrated by removing the skin and seeds are 1000 μm (16 mesh) and 106 μm (150 mesh), respectively. By filtering it under atmospheric pressure through a 63 μm (250 mesh) sieve, tomato pastes 1 to 3 having the following particle compositions with limited particle diameters were prepared, and tomato paste 4 was obtained without filtration treatment ( Table 1).
(脱酸トマト汁試料A)
本実施例において使用するカルシウム脱酸トマト汁は以下の手順で調製されたものである。
まず、市販の透明濃縮トマト加工物(Clear Tomato Concentrate 60°Brix、LYCORED社製、Brix:60、酸度:3.64、pH:4.15)をイオン交換水で約4倍に希釈還元して、透明トマト汁(Brix:17.5、酸度:1.06、pH:4.2、Brix4.5調整時の粘度:1.36cP)を準備した。次に、得られた透明トマト汁1500kgをタンク内に仕込み、80℃まで加温した後、タンク上部から炭酸カルシウム12.75kgを投入し、60分間撹拌して、発生する炭酸ガスを排出した。タンクを20℃まで冷却した後、遠心分離し、市販の珪藻土を用いて濾過し、さらに5μmのフィルターで濾過することで固形分を除去した。
(Deacidified tomato juice sample A)
The calcium deoxidized tomato juice used in this example was prepared by the following procedure.
First, a commercially available transparent concentrated tomato product (Clear Tomato Concentrate 60 ° Brix, manufactured by LYCORED, Brix: 60, acidity: 3.64, pH: 4.15) was diluted and reduced about 4 times with ion-exchanged water. A transparent tomato juice (Brix: 17.5, acidity: 1.06, pH: 4.2, viscosity at the time of adjusting Brix 4.5: 1.36 cP) was prepared. Next, 1500 kg of the obtained transparent tomato juice was charged into the tank and heated to 80 ° C., and then 12.75 kg of calcium carbonate was added from the upper part of the tank, stirred for 60 minutes, and the generated carbon dioxide gas was discharged. The tank was cooled to 20 ° C., centrifuged, filtered using commercially available diatomaceous earth, and further solids were removed by filtering with a 5 μm filter.
(脱酸トマト汁試料B)
本実施例において使用する陰イオン交換脱酸トマト汁は以下の手順で調製されたものである。
即ち、強塩基性陰イオン交換樹脂(三菱化学株式会社製、PA316)をタンクに充填し、これに3%NaOH水溶液を通液した後、イオン交換水、3%NaHCO3水溶液、イオン交換水を順次通液して、重炭酸置換を行った。
次に、市販の透明濃縮トマト加工物(Clear Tomato Concentrate 60°Brix、LYCORED社製、Brix:60、酸度:3.64、pH:4.15)をイオン交換水で約4倍に希釈還元して、透明トマト汁(Brix:14.6、酸度:0.86、pH:4.2、Brix4.5調整時の粘度:1.36cP)を準備し、これを重炭酸置換した陰イオン交換樹脂に上向流方式で複数回通液した後、100メッシュのフィルターで濾過することにより、本実施例の脱酸トマト汁を得た。
(Deacidified tomato juice sample B)
The anion exchange deacidified tomato juice used in this example was prepared by the following procedure.
That is, after filling a tank with a strongly basic anion exchange resin (manufactured by Mitsubishi Chemical Corporation, PA316) and passing a 3% NaOH aqueous solution therethrough, ion exchange water, 3% NaHCO 3 aqueous solution, and ion exchange water were added. The solution was sequentially passed through to replace with bicarbonate.
Next, a commercially available transparent concentrated tomato product (Clear Tomato Concentrate 60 ° Brix, manufactured by LYCORED, Brix: 60, acidity: 3.64, pH: 4.15) is diluted and reduced by about 4 times with ion-exchanged water. An anion exchange resin prepared by preparing transparent tomato juice (Brix: 14.6, acidity: 0.86, pH: 4.2, viscosity at the time of Brix 4.5 adjustment: 1.36 cP), and replacing this with bicarbonate Then, the solution was passed through an upward flow system several times, and then filtered through a 100 mesh filter to obtain a deacidified tomato juice of this example.
(サンプル調製)
上記のトマトペースト1〜4、市販の混濁トマト汁及び脱酸トマト汁試料A,Bを、Bx.5.0に換算した際に表2の割合となるように配合し(小数点第三位を四捨五入)、その後、目標のBx.になるよう加水調整を行い、pHを4.4に調整後、試験例1〜11を得た。
(Sample preparation)
The above-mentioned tomato pastes 1 to 4, commercially available cloudy tomato juice and deacidified tomato juice samples A and B were mixed with Bx. When converted to 5.0, it is blended so as to have the ratio of Table 2 (rounded to the second decimal place), and then the target Bx. The water was adjusted so that the pH was adjusted to 4.4, and Test Examples 1 to 11 were obtained.
上記試験例1〜11において、各種含有成分の種測定方法は、例えば以下の方法によって行うことができる。
なお、測定方法については、以下に示す方法以外であっても、公知方法から適宜選択することができる。
また、本願発明の評価にあって特に必須ではない数値項目については、適宜測定を省略することができる。
In the said Test Examples 1-11, the seed | species measuring method of various content components can be performed with the following method, for example.
In addition, about a measuring method, even if it is except the method shown below, it can select from a well-known method suitably.
In addition, for numerical items that are not particularly essential in the evaluation of the present invention, measurement can be omitted as appropriate.
<Brix(糖度)>
光学屈折率計(アタゴ社製、Digital Refractometers、RX5000α−Bev)を用いて、Brixを測定した。
<植物ステロール量>
内部標準物質(5α−コレスタン)を100 g添加し、窒素気流下で有機溶媒を乾固させた後、試料を約2gサンプリング した。これに50%(w/w)水酸化カリウム溶液を1mL添加し、沸騰湯浴中で20〜30分煮沸することでアルカリ融解を行った。その後エタノール6mLを加え、70℃で1時間、時々混和しながら、抽出及びケン化を同時に行った。室温まで冷却後、ヘキサン5mLを加え植物ステロールの分配抽出を行った。1000rpmで5分遠心分離後、ヘキサン層を回収した。このヘキサン抽出を計3回繰り返した。窒素気流下でヘキサンを乾固させた後、誘導体化試薬(ピリジン:ヘキサメチルジシラザン:トリメチルクロロシラン=9:3:1(v/v/v))によるヒドロキシル基のトリメチルシリル化後、下記の条件のガスクロマトグラフィーにて植物ステロールの定量を行った。なお、植物ステロール総量はカンペステロール、スティグマステロール、β-シトステロールおよびβ−シトスタノールの総和として求めた。
分析条件
使用機器:GC14A(島津製作所)
記録計:CR−8A(島津製作所)
カラム:SPBTM−1(0.25mm×60mm)(Supelco)
キャリアーガス:He
検出器:FID(H2:0.6Kg/cm2、Air:0.6Kg/cm2、Make upガス(He):0.7Kg/cm2)
カラム温度:280℃
注入口温度:300℃
検出器温度:300℃
スプリット比:50:1
<アミノ酸類>
Allianceシステム(Waters株式会社製)を用いて、HPLC法(蛍光検出)に基づいてアミノ酸の含有量を求めた。
サンプル調整法:
サンプルを適量はかりとり、蒸留水に懸濁後、フィルターろ過して分析に供した。
HPLC測定条件:
カラム :XBridge Shield RP18 3.0×100mm
温度 :40℃
注入量 :5μL
移動相A:50mM酢酸ナトリウムバッファー(pH6.0)
移動相B:アセトニトリル
検出器 :Waters 2475マルチ波長蛍光検出器
検出波長:励起335nm エミッション450nm
<粒子径測定>
レーザー解析粒度分布測定装置(島津製作所製「SALD−2100」を用い、10積算質量%の粒子径(D10)、50積算質量%の粒子径(D50)及び90積算質量%の粒子径(D90)を測定した。
<Brix (sugar content)>
Brix was measured using an optical refractometer (Atago Co., Ltd., Digital Refractometers, RX5000α-Bev).
<Plant sterol amount>
After adding 100 g of internal standard substance (5α-cholestane) and drying the organic solvent under a nitrogen stream, about 2 g of the sample was sampled. 1 mL of 50% (w / w) potassium hydroxide solution was added thereto, and the alkali was melted by boiling in a boiling water bath for 20 to 30 minutes. Thereafter, 6 mL of ethanol was added, and extraction and saponification were simultaneously performed at 70 ° C. for 1 hour with occasional mixing. After cooling to room temperature, 5 mL of hexane was added to perform partition extraction of plant sterols. After centrifuging at 1000 rpm for 5 minutes, the hexane layer was recovered. This hexane extraction was repeated a total of 3 times. After drying hexane under a nitrogen stream, trimethylsilylation of the hydroxyl group with a derivatization reagent (pyridine: hexamethyldisilazane: trimethylchlorosilane = 9: 3: 1 (v / v / v)) followed by the following conditions Plant sterols were quantified by gas chromatography. The total amount of plant sterol was determined as the sum of campesterol, stigmasterol, β-sitosterol and β-sitostanol.
Analytical condition equipment: GC14A (Shimadzu Corporation)
Recorder: CR-8A (Shimadzu Corporation)
Column: SPB ™ -1 (0.25 mm x 60 mm) (Supelco)
Carrier gas: He
Detector: FID (H 2 : 0.6 Kg / cm 2 , Air: 0.6 Kg / cm 2 , Make up gas (He): 0.7 Kg / cm 2 )
Column temperature: 280 ° C
Inlet temperature: 300 ° C
Detector temperature: 300 ° C
Split ratio: 50: 1
<Amino acids>
The content of amino acids was determined based on the HPLC method (fluorescence detection) using an Alliance system (Waters Co., Ltd.).
Sample adjustment method:
An appropriate amount of the sample was weighed, suspended in distilled water, filtered and used for analysis.
HPLC measurement conditions:
Column: XBridge Shield RP18 3.0 × 100 mm
Temperature: 40 ° C
Injection volume: 5 μL
Mobile phase A: 50 mM sodium acetate buffer (pH 6.0)
Mobile phase B: Acetonitrile Detector: Waters 2475 Multi-wavelength fluorescence detector Detection wavelength: Excitation 335 nm Emission 450 nm
<Particle size measurement>
Laser analysis particle size distribution measuring apparatus (“SALD-2100” manufactured by Shimadzu Corporation) 10 cumulative mass% particle diameter (D10), 50 cumulative mass% particle diameter (D50) and 90 cumulative mass% particle diameter (D90) Was measured.
<官能評価試験>
トマト含有飲料の官能評価試験は、7人のパネラーに委託して行い、各項目を以下に示す基準で評価したものである。ここで、表中の数値は、7人のパネラーの評価の平均値である。
<青臭み>
◎:感じられない
○:わずかに感じる
△:感じる
×:強く感じる
<完熟したような甘み>
◎:十分に感じる
○:感じる
△:わずかに感じる
×:あまり感じられない
<酸味>
◎:気にならない
○:わずかに感じる
△:感じる
×:強く感じる
<さらさらした喉越し>
◎:さらさらしてとても喉越しが良い
○:比較的さらさらして喉越しが良い
△:普通の喉越しである
×:喉越しが良くない
<飲み応え>
◎:飲み応えが十分ある
○:比較的飲み応えがある
△:普通の飲み応えである
×:飲み応えがない
<後味のキレ>
◎:後味のキレが十分ある
○:比較的後味のキレがある
△:普通の後味である
×:後味のキレがない
<Sensory evaluation test>
The sensory evaluation test for tomato-containing beverages was conducted by entrusting 7 panelists to evaluate each item according to the criteria shown below. Here, the numerical values in the table are average values of the evaluations of the seven panelists.
<Blue odor>
◎: Not felt ○: Slightly felt △: Feeled ×: Strongly felt <Ripe sweetness>
◎: Feeling enough ○: Feeling △: Feeling slightly ×: Not much felt <acidity>
◎: Not concerned ○: Feeling slightly △: Feeling ×: Feeling strongly <Feeling over the throat>
◎: Smooth and very good over throat ○: Relatively smooth and good over throat △: Normal over throat ×: Not good over throat <Drinking response>
◎: Sufficient drinking response ○: Relatively comfortable drinking △: Normal drinking response ×: No drinking response <Finished aftertaste>
◎: There is a sufficient aftertaste ○: There is a relatively aftertaste △: A normal aftertaste ×: There is no aftertaste
<総合評価>
各評価項目を総合的に勘案して、商品としての適性を評価した。
◎:商品としての適性に非常に優れている
○:商品としての適性に優れている
△:商品としての適性は標準的である
×:商品としての適性に劣っている
<Comprehensive evaluation>
The suitability as a product was evaluated by comprehensively considering each evaluation item.
◎: very good suitability as a product ○: good suitability as a product △: good suitability as a product ×: poor suitability as a product
以下に、実施例及び比較例についての各種測定結果及び官能評価結果を示す。 The various measurement results and sensory evaluation results for the examples and comparative examples are shown below.
(考察)
実施例1〜7(試験例1〜5及び10〜11)は、青臭みが感じられないか、気にならない程度であり、酸味も抑えられ、完熟したような甘み・旨みがあり、喉越しも良好で、飲み応えがあり、後味のキレもあるため、総合評価において、試験例6〜9と比較して高い官能評価結果を得られた。特に本試験例10〜11は、甘みがより強く感じられ、全体的に評価が高かった。
一方、比較例1(試験例6)は青臭みが気になり、後味のキレも悪く、比較例2(試験例7)は全体として味が薄く水っぽい印象があり、飲み応えがなく、比較例3(試験例8)は加熱し過ぎたような焼け臭がし、比較例4(試験例9)はドロドロまとわりつくような飲料で後味の切れがよくなかったため、実施例より商品適性が劣っているものと判断された。
このことから、飲料中のステロール量を特定範囲含有させ、[Ga/Glu]比率を特定範囲に調整することによって、さらっとした食感を有しながらも、酸味が抑制され、完熟したような甘みが十分感じられる、呈味が良好で飲み易いトマト含有飲料を提供することができる。
これによって、トマト含有飲料に対する消費者の幅広い嗜好に応えられる、サラッとした食感を有しながらも、甘みが感じられるトマト含有飲料及びその製造方法を提供することができる。
また、本願に係る方法は、トマトの酸味を抑制する方法としても、広く一般的に適用できるものであり、その応用範囲は広い。
(Discussion)
In Examples 1 to 7 (Test Examples 1 to 5 and 10 to 11), the blue odor is not felt or is not worrisome, the acidity is also suppressed, and there is a sweetness and umami that seems to be ripe, and it goes over the throat. In addition, the sensory evaluation was good, and there was a response to drinking. In particular, in Test Examples 10 to 11, the sweetness was felt stronger and the overall evaluation was high.
On the other hand, Comparative Example 1 (Test Example 6) was concerned about the blue odor and the sharpness of the aftertaste was poor, and Comparative Example 2 (Test Example 7) had a light and watery impression as a whole. 3 (Test Example 8) had a burning odor as if it was overheated, and Comparative Example 4 (Test Example 9) was a beverage that clung to muddy, and its aftertaste was not good. It was judged.
From this, the amount of sterols in the beverage is included in a specific range, and the [Ga / Glu] ratio is adjusted to a specific range, so that the acidity is suppressed and the product is completely ripe while having a light texture. It is possible to provide a tomato-containing beverage that is sufficiently sweet and has a good taste and is easy to drink.
Thus, it is possible to provide a tomato-containing beverage that can satisfy a wide range of consumer preferences for tomato-containing beverages and that has a smooth texture and can be sweetened, and a method for producing the same.
In addition, the method according to the present application can be widely and generally applied as a method for suppressing the sourness of tomato, and its application range is wide.
本発明によれば、青臭みが感じられない完熟した甘味及び旨みを強く感じることができ、且つ食感が滑らかで、呈味が良好で飲み易い容器詰トマト含有飲料並びに容器詰トマト含有飲料の食感及び呈味改善方法を提供することができる。 According to the present invention, a containerized tomato-containing beverage and a containerized tomato-containing beverage that can strongly feel ripe sweetness and umami that does not feel blue odor, have a smooth texture, have a good taste, and are easy to drink. A texture and taste improvement method can be provided.
Claims (3)
飲料液中におけるグルタミン酸含有量(Glu)に対する、GABA含有量(Ga)の比Ga/Gluを0.30〜0.50に調整する工程と、
粒子の累積50%粒子径を270μm以下、且つ累積90%粒子径を480μm以下となるように調整する工程を含むことを特徴とする容器詰トマト含有飲料の製造方法。 Adjusting the plant sterol content to 0.7-2.2 mg / 100 g;
Adjusting the ratio Ga / Glu of the GABA content (Ga) to 0.30 to 0.50 to the glutamic acid content (Glu) in the beverage liquid;
A method for producing a packaged tomato-containing beverage, comprising a step of adjusting a cumulative 50% particle size of particles to 270 μm or less and a cumulative 90% particle size to 480 μm or less .
粒子の累積50%粒子径を270μm以下、且つ累積90%粒子径を480μm以下となるように調整することを特徴とする容器詰トマト含有飲料の食感及び呈味改善方法。 The plant sterol content is adjusted to 0.7 to 2.2 mg / L, and the GABA content (Ga) ratio Ga / Glu to the glutamic acid content (Glu) in the beverage is 0.30 to 0.50. Adjust to
A method for improving the texture and taste of a packaged tomato-containing beverage, characterized by adjusting the cumulative 50% particle size of particles to 270 μm or less and the cumulative 90% particle size to 480 μm or less .
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