JPH05330252A - Thermal transfer image receiving sheet and production thereof - Google Patents
Thermal transfer image receiving sheet and production thereofInfo
- Publication number
- JPH05330252A JPH05330252A JP4165554A JP16555492A JPH05330252A JP H05330252 A JPH05330252 A JP H05330252A JP 4165554 A JP4165554 A JP 4165554A JP 16555492 A JP16555492 A JP 16555492A JP H05330252 A JPH05330252 A JP H05330252A
- Authority
- JP
- Japan
- Prior art keywords
- thermal transfer
- dye
- transfer image
- receiving layer
- receiving sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は熱転写受像シートに関
し、更に詳しくは発色濃度、鮮明性及び諸堅牢性、特に
耐指紋性、耐可塑剤性、耐擦過性等の耐久性に優れた記
録画像を形成することが出来る熱転写受像シートの提供
を目的とする。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a thermal transfer image-receiving sheet, and more particularly to a recorded image excellent in color density, vividness and various fastnesses, particularly fingerprint resistance, plasticizer resistance, scratch resistance and the like. It is an object of the present invention to provide a thermal transfer image-receiving sheet capable of forming a sheet.
【０００２】[0002]
【従来の技術】従来、種々の熱転写方法が公知である
が、それらの中で昇華性染料を記録剤とし、これをポリ
エステルフイルム等の基材シートに担持させて熱転写シ
ートとし、昇華性染料で染着可能な被転写材、例えば、
紙やプラスチックフイルム等に染料受容層を形成した熱
転写受像シート上に各種のフルカラー画像を形成する方
法が提案されている。この場合には加熱手段としてプリ
ンターのサーマルヘッドが使用され、極めて短時間の加
熱によって３色又は４色の多数の色ドットを熱転写受像
シートに転移させ、該多色の色ドットにより原稿のフル
カラー画像を再現するものである。この様に形成された
画像は、使用する色材が染料であることから非常に鮮明
であり、且つ透明性に優れている為、得られる画像は中
間色の再現性や階調性に優れ、従来のオフセット印刷や
グラビア印刷による画像と同様であり、且つフルカラー
写真画像に匹敵する高品質の画像が形成可能となってい
る。2. Description of the Related Art Conventionally, various thermal transfer methods are known. Among them, a sublimable dye is used as a recording agent, and a sublimable dye is used as a thermal transfer sheet by supporting it on a base material sheet such as polyester film. Transferable material that can be dyed, for example,
There has been proposed a method of forming various full-color images on a thermal transfer image-receiving sheet having a dye-receptive layer formed on paper, a plastic film or the like. In this case, the thermal head of the printer is used as the heating means, and a large number of three-color or four-color dots are transferred to the thermal transfer image-receiving sheet by heating for an extremely short time, and the full-color image of the original is formed by the multicolor dots. Is to be reproduced. The image formed in this way is extremely clear because the coloring material used is a dye and has excellent transparency, so the resulting image has excellent reproducibility of intermediate colors and gradation, and It is possible to form a high quality image which is similar to the image obtained by the offset printing or gravure printing and which is comparable to the full color photographic image.
【０００３】[0003]
【発明が解決しようとしている問題点】上記の如き熱転
写方法を有効に実施する為には、熱転写シートの構成は
勿論、画像を形成する為の熱転写受像シートの構成も同
様に重要である。熱転写受像シートの染料受容層は従来
多くの場合、ポリエステル樹脂やビニル樹脂等の熱可塑
性樹脂から形成されているが、該染料受容層に熱転写方
式で画像を形成した場合、染料は染料受容層の表層部分
に多く存在していることから、画像部に手で触れた際、
画像面に移行した汗や皮脂の影響で画像が変色したり、
更に染料受容層自体が膨潤やひび割れしたりするといっ
た問題、即ち耐指紋性の問題や、消しゴムや軟質塩化ビ
ニル樹脂製品の如く可塑剤を含む物質と接触した際の染
料の移行性、即ち耐可塑剤性の問題、更には染料受容層
が熱可塑性樹脂から形成されている為、表面が別の物体
に接触及び摩擦された場合、例えば、消しゴムで擦られ
た場合に表面に傷が付き易い、即ち耐擦過性に劣るとい
う問題がある。以上の如き問題は画像形成面に透明フイ
ルムをラミネートすることによって解消されるが、実際
にはかかるフイルムのラミネートは煩雑であり、工業的
には極めて用途が限定される為、汎用性の点で問題があ
る。従って本発明の目的は、昇華性染料を使用する熱転
写方法において、十分に濃度のある鮮明な画像を与え、
しかも形成された画像が優れた諸堅牢性、特に優れた耐
指紋性、耐可塑剤性、耐擦過性等を示す熱転写受像シー
トを提供することである。In order to effectively carry out the above-mentioned thermal transfer method, not only the structure of the thermal transfer sheet but also the structure of the thermal transfer image receiving sheet for forming an image are important. In many cases, the dye receiving layer of the thermal transfer image-receiving sheet is conventionally formed of a thermoplastic resin such as polyester resin or vinyl resin.However, when an image is formed on the dye receiving layer by a thermal transfer method, the dye is a dye of the dye receiving layer. There are many in the surface layer, so when you touch the image area with your hand,
The image may be discolored due to the effect of sweat or sebum transferred to the image surface,
Further, the dye receiving layer itself may swell or crack, that is, the fingerprint resistance, or the migration of the dye when contacted with a substance containing a plasticizer such as an eraser or a soft vinyl chloride resin product, that is, plastic resistance. The problem of formulation, and further because the dye receiving layer is formed of a thermoplastic resin, when the surface is contacted and rubbed with another object, for example, the surface is easily scratched when rubbed with an eraser, That is, there is a problem that the scratch resistance is poor. The above problems can be solved by laminating a transparent film on the image forming surface, but in reality, laminating such a film is complicated, and its application is extremely limited industrially. There's a problem. Therefore, an object of the present invention is to provide a clear image with sufficient density in a thermal transfer method using a sublimable dye,
Moreover, it is an object of the present invention to provide a thermal transfer image-receiving sheet in which an image formed has excellent various fastnesses, particularly excellent fingerprint resistance, plasticizer resistance, scratch resistance and the like.
【０００４】[0004]
【問題点を解決する為の手段】上記目的は以下の本発明
によって達成される。即ち、本発明は、基材シートの少
なくとも一方の面に染料受容層を形成してなる熱転写受
像シートにおいて、上記染料受容層が、有機フィラー及
びシリコーン化合物を含有することを特徴とする熱転写
受像シート及びその製造方法である。The above object can be achieved by the present invention described below. That is, the present invention is a thermal transfer image-receiving sheet comprising a base sheet and a dye-receiving layer formed on at least one surface thereof, wherein the dye-receiving layer contains an organic filler and a silicone compound. And its manufacturing method.
【０００５】[0005]
【作用】染料受容層に有機フィラー及びシリコーン化合
物を含有させることにより、形成される画像の耐指紋
性、耐可塑剤性、耐擦過性等の耐久性が向上する。By including the organic filler and the silicone compound in the dye receiving layer, the durability of the formed image such as fingerprint resistance, plasticizer resistance and scratch resistance is improved.
【０００６】[0006]
【好ましい実施態様】次に好ましい実施態様を挙げて本
発明を更に詳細に説明する。本発明の熱転写受像シート
は、基材シートの少なくとも一方の面に設けた染料受容
層とからなる。本発明で使用する基材シートとしては、
合成紙（ポリオレフィン系、ポリスチレン系等）、上質
紙、アート紙、コート紙、キャストコート紙、壁紙、裏
打用紙、合成樹脂又はエマルジョン含浸紙、合成ゴムラ
テックス含浸紙、合成樹脂内添紙、板紙等、セルロース
繊維紙、ポリオレフィン、ポリ塩化ビニル、ポリエチレ
ンテレフタレート、ポリスチレン、ポリメタクリレー
ト、ポリカーボネート等の各種のプラスチックのフイル
ム又はシート等が使用出来、又、これらの合成樹脂に白
色顔料や充填剤を加えて成膜した白色不透明フイルム或
いは発泡させた発泡シート等も使用することが出来、特
に限定されない。又、上記基材シートの任意の組み合わ
せによる積層体も使用出来る。代表的な積層体の例とし
て、セルロース繊維紙と合成紙或いはセルロース繊維紙
とプラスチックフイルム又はシートとの合成紙が挙げら
れる。これらの基材シートの厚みは任意でよく、例え
ば、１０〜３００μｍ程度の厚みが一般的である。上記
の如き基材シートは、その表面に形成する染料受容層と
の密着力が乏しい場合にはその表面にプライマー処理や
コロナ放電処理を施すのが好ましい。BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in more detail with reference to the following preferred embodiments. The thermal transfer image-receiving sheet of the present invention comprises a dye receiving layer provided on at least one surface of a substrate sheet. The base sheet used in the present invention,
Synthetic paper (polyolefin-based, polystyrene-based, etc.), high-quality paper, art paper, coated paper, cast-coated paper, wallpaper, backing paper, synthetic resin or emulsion-impregnated paper, synthetic rubber latex-impregnated paper, synthetic resin internal-added paper, paperboard, etc. Films or sheets of various plastics such as cellulose fiber paper, polyolefin, polyvinyl chloride, polyethylene terephthalate, polystyrene, polymethacrylate, and polycarbonate can be used, and white pigments and fillers are added to these synthetic resins. A white opaque film that has been formed into a film or a foamed sheet that has been foamed can also be used and is not particularly limited. Further, a laminated body made of any combination of the above-mentioned substrate sheets can also be used. As an example of a typical laminated body, a synthetic paper of cellulose fiber paper and synthetic paper or cellulose fiber paper and plastic film or sheet can be mentioned. The thickness of these base material sheets may be arbitrary, and for example, a thickness of about 10 to 300 μm is common. The substrate sheet as described above is preferably subjected to a primer treatment or a corona discharge treatment on the surface when the adhesion to the dye receiving layer formed on the surface is poor.
【０００７】上記基材シートの表面に形成する染料受容
層は、熱転写シートから移行してくる昇華性染料を受容
し、形成された画像を維持する為のものである。染料受
容層を形成する為の熱可塑性樹脂としては、例えば、ポ
リプロピレン等のポリオレフィン系樹脂、ポリ塩化ビニ
ル、ポリ塩化ビニリデン等のハロゲン化ポリマー、ポリ
酢酸ビニル、エチレン・酢酸ビニル共重合体、塩化ビニ
ル・酢酸ビニル共重合体、ポリアクリルエステル等のビ
ニル系樹脂、ポリエチレンテレフタレート、ポリブチレ
ンテレフタレート等のポリエステル系樹脂、ポリスチレ
ン系樹脂、ポリアミド系樹脂、エチレンやプロピレン等
のオレフィンと他のビニルモノマーとの共重合体系樹
脂、アイオノマー、セルロースジアセテート等のセルロ
ース系樹脂、ポリカーボネート系樹脂、ポリビニルアセ
タール系樹脂等を挙げることが出来る。The dye receiving layer formed on the surface of the base sheet is for receiving the sublimable dye transferred from the thermal transfer sheet and maintaining the formed image. Examples of the thermoplastic resin for forming the dye receiving layer include polyolefin resins such as polypropylene, halogenated polymers such as polyvinyl chloride and polyvinylidene chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, vinyl chloride. -Vinyl acetate copolymers, vinyl resins such as polyacrylic esters, polyester resins such as polyethylene terephthalate and polybutylene terephthalate, polystyrene resins, polyamide resins, olefins such as ethylene and propylene, and other vinyl monomers. Examples thereof include polymer resins, ionomers, cellulose resins such as cellulose diacetate, polycarbonate resins, polyvinyl acetal resins and the like.
【０００８】本発明の熱転写受像シートは、上記の如き
熱可塑性樹脂から染料受容層を形成するにあたり、該染
料受容層中に有機フィラー及びシリコーン化合物を包含
させることを特徴としている。使用する有機フィラーと
しては、融点が７０℃以上の有機フィラーであって、染
料受容層形成樹脂と非相溶性であり、微細な粉末状の有
機フィラーが好ましい。有機フィラーの融点が７０℃未
満であると、受像シートの保存時に有機フイラーが溶融
又は難化する場合があり、形成された画像に滲みが生じ
ると云う問題がある。この様な有機フィラーとしては、
例えば、平均粒径が２〜２０μｍ程度の微粉末状のポリ
エチレンワックス、ナイロン、ベンゾグアナミン樹脂、
コラーゲン、架橋ポリスチレン等の架橋樹脂、シリコー
ン変性樹脂、弗素樹脂等の微粉末が挙げられる。これら
の有機フィラーは、染料受容層形成用樹脂１００重量部
当たり１〜５０重量部の範囲で使用することが好まし
い。使用量が少なすぎると染料受容層表面における撥油
性、滑り性が不十分であって、所望の耐指紋性、耐可塑
剤性及び耐擦過性が得られない。一方、使用量が多すぎ
ると、染料の染着性が不十分となって高濃度の画像形成
が困難となり、又、染料受容層の被膜強度も低下するの
で好ましくない。The thermal transfer image-receiving sheet of the present invention is characterized by including an organic filler and a silicone compound in the dye-receiving layer when forming the dye-receiving layer from the above-mentioned thermoplastic resin. The organic filler to be used is preferably an organic filler having a melting point of 70 ° C. or higher, which is incompatible with the dye-receptive layer-forming resin and is in the form of fine powder. If the melting point of the organic filler is less than 70 ° C., the organic filler may be melted or difficult during storage of the image-receiving sheet, and there is a problem that the formed image has bleeding. As such an organic filler,
For example, finely powdered polyethylene wax having an average particle diameter of about 2 to 20 μm, nylon, benzoguanamine resin,
Examples thereof include crosslinked resins such as collagen and crosslinked polystyrene, and fine powders such as silicone-modified resins and fluororesins. These organic fillers are preferably used in the range of 1 to 50 parts by weight per 100 parts by weight of the resin for forming the dye receiving layer. If the amount used is too small, the oil repellency and slipperiness on the surface of the dye receiving layer are insufficient, and desired fingerprint resistance, plasticizer resistance and scratch resistance cannot be obtained. On the other hand, if the amount used is too large, the dyeing property of the dye becomes insufficient, and it becomes difficult to form a high-concentration image, and the film strength of the dye-receiving layer also decreases, which is not preferable.
【０００９】又、使用するシリコーン化合物としては、
アミノ基、水酸基、メルカプト基、エポキシ基、イソシ
アネート基、カルボキシル基、ビニル基等の反応性を有
する各種反応性シリコーンオイルと、これらの反応性基
と反応する基を有する熱可塑性樹脂とを反応させるか、
或はポリイソシアネート、ポリアミン等の架橋剤を用い
て両者を反応させたグラフトコポリマー、或はビニル変
性シリコーンオイルとビニル基やアクリロイル基を有す
る他の一般的なモノマーとを適当な比率で共重合させた
グラフトコポリマーが挙げられる。これらのシリコーン
化合物を染料受容層に添加混合することによって、グラ
フト化されているシリコーンセグメントが染料受容層の
表面に分配され、一方、幹ポリマーである熱可塑性樹脂
部分は染料受容層を形成している熱可塑性樹脂と相溶し
ているので、染料受容層表面に優れた撥油性及び滑り性
が付与される。The silicone compound used is
Reacting various reactive silicone oils having reactivity such as amino group, hydroxyl group, mercapto group, epoxy group, isocyanate group, carboxyl group and vinyl group with a thermoplastic resin having a group that reacts with these reactive groups Or
Alternatively, a graft copolymer obtained by reacting both of them with a cross-linking agent such as polyisocyanate or polyamine, or a vinyl-modified silicone oil and another general monomer having a vinyl group or an acryloyl group are copolymerized at an appropriate ratio. Graft copolymers. By adding and mixing these silicone compounds to the dye-receiving layer, the grafted silicone segment is distributed on the surface of the dye-receiving layer, while the thermoplastic resin portion, which is the trunk polymer, forms the dye-receiving layer. Since it is compatible with the existing thermoplastic resin, excellent oil repellency and slipperiness are imparted to the surface of the dye receiving layer.
【００１０】これらのシリコーン化合物は、染料受容層
形成用樹脂１００重量部当たり１〜５０重量部の範囲で
使用することが好ましい。使用量が少なすぎると染料受
容層表面における撥油性、滑り性が不十分であって、所
望の耐指紋性、耐可塑剤性及び耐擦過性が得られない。
一方、使用量が多すぎると、染料の染着性が不十分とな
って高濃度の画像形成が困難となり、又、染料受容層の
被膜強度も低下するので好ましくない。本発明では前記
有機フィラーと上記シリコーン化合物とを重量比１：９
〜９：１の割合で使用することが最も好ましく、この様
にすることによって最も優れた耐指紋性、耐可塑剤性及
び耐擦過性等を染料受容層に付与することが出来る。本
発明の熱転写受像シートは、前記の基材シートの少なく
とも一方の面に、前記の如き熱可塑性樹脂に有機フィラ
ー及びシリコーン化合物、更には他の必要な添加剤、例
えば、離型剤、架橋剤、硬化剤、触媒、熱離型剤、紫外
線吸収剤、酸化防止剤、光安定剤等を加えたものを、適
当な有機溶剤に溶解したり或いは有機溶剤や水に分散し
た分散体を、例えば、グラビア印刷法、スクリーン印刷
法、グラビア版を用いたリバースロールコーティング法
等の形成手段により塗布及び乾燥して染料受容層を形成
することによって得られる。These silicone compounds are preferably used in the range of 1 to 50 parts by weight per 100 parts by weight of the resin for forming the dye receiving layer. If the amount used is too small, the oil repellency and slipperiness on the surface of the dye receiving layer are insufficient, and desired fingerprint resistance, plasticizer resistance and scratch resistance cannot be obtained.
On the other hand, if the amount used is too large, the dyeing property of the dye becomes insufficient, and it becomes difficult to form a high-concentration image, and the film strength of the dye-receiving layer also decreases, which is not preferable. In the present invention, the weight ratio of the organic filler to the silicone compound is 1: 9.
It is most preferable to use it in a ratio of 9 to 9: 1, and by doing so, the best fingerprint resistance, plasticizer resistance, scratch resistance and the like can be imparted to the dye receiving layer. The thermal transfer image-receiving sheet of the present invention comprises, on at least one surface of the substrate sheet, an organic filler and a silicone compound in the thermoplastic resin as described above, and other necessary additives such as a release agent and a crosslinking agent. , A curing agent, a catalyst, a thermal release agent, an ultraviolet absorber, an antioxidant, a light stabilizer, etc., is dissolved in a suitable organic solvent, or a dispersion prepared by dispersing in an organic solvent or water, for example, , A gravure printing method, a screen printing method, a reverse roll coating method using a gravure plate, and the like.
【００１１】上記染料受容層の形成に際しては、染料受
容層の白色度を向上させて転写画像の鮮明度を更に高め
る目的で、酸化チタン、酸化亜鉛、カオリンクレー、炭
酸カルシウム、微粉末シリカ等の顔料や充填剤を添加す
ることが出来る。以上の如く形成される染料受容層は任
意の厚さでよいが、一般的には１〜５０μｍの厚さであ
る。又、この様な染料受容層は連続被覆であるのが好ま
しいが、樹脂エマルジョンや樹脂分散液を使用して、不
連続の被覆として形成してもよい。本発明では転写方法
で前記染料受容層を形成することも出来る。即ち、基材
シートとして、例えば、パルプ紙等を用いる場合には、
該基材は表面平滑性が不足する場合があり、この場合に
は上記塗工方法では形成される染料受容層に凹凸やピン
ホール等が発生する場合があるが、転写方法によれば、
この様な問題は発生しない。In the formation of the dye receiving layer, titanium oxide, zinc oxide, kaolin clay, calcium carbonate, fine powder silica, etc. are used for the purpose of improving the whiteness of the dye receiving layer to further improve the sharpness of the transferred image. Pigments and fillers can be added. The dye-receptive layer formed as described above may have any thickness, but generally has a thickness of 1 to 50 μm. Further, such a dye receiving layer is preferably a continuous coating, but it may be formed as a discontinuous coating by using a resin emulsion or resin dispersion. In the present invention, the dye receiving layer can be formed by a transfer method. That is, for example, when using pulp paper or the like as the substrate sheet,
The base material may lack surface smoothness, and in this case, the dye-receiving layer formed by the above coating method may have irregularities or pinholes. However, according to the transfer method,
Such a problem does not occur.
【００１２】転写方法は、例えば、ポリエステルフイル
ム等の離型性のよいフイルム面に上記の染料受容層を形
成し、更にその表面に適当な粘着剤層又は接着剤層を形
成しておき、この粘着剤層を前記パルプ紙等基材シート
面に対向させてラミネーター等で貼り合わせ、その後上
記ポリエステルフイルムを剥離する方法である。又、中
間層を形成する場合には予め基材シートの表面に中間層
を形成しておいてもよいし、染料受容層転写シートの染
料受容層表面に設けておいてもよい。又、本発明の熱転
写受像シートは、基材シートを適宜選択することによ
り、熱転写記録可能な枚葉或はロール状の熱転写受像シ
ート、カード類、透過型原稿作成用シート等の各種用途
に適用することも出来る。更に、本発明の熱転写受像シ
ートは必要に応じて基材シートと染料受容層との間にク
ッション層を設けることが出来、この様なクッション層
を設けることによって、印字時にノイズが少なく画像情
報に対応した画像を再現性良く転写記録することが出来
る。上記の如き本発明の熱転写受像シートを使用して熱
転写を行う際に使用する熱転写シートは、紙やポリエス
テルフイルム上に昇華性染料を含む染料層を設けたもの
であり、従来公知の熱転写シートはいずれも本発明でそ
のまま使用することが出来る。For the transfer method, for example, the above-mentioned dye receiving layer is formed on the surface of a film having a good releasing property such as polyester film, and further an appropriate pressure-sensitive adhesive layer or adhesive layer is formed on the surface, In this method, the pressure-sensitive adhesive layer is made to face the surface of the base material sheet such as pulp paper and bonded with a laminator or the like, and then the polyester film is peeled off. When the intermediate layer is formed, the intermediate layer may be previously formed on the surface of the base material sheet, or may be provided on the surface of the dye receiving layer of the dye receiving layer transfer sheet. Further, the thermal transfer image-receiving sheet of the present invention is applied to various applications such as a sheet or a roll-shaped thermal transfer image-receiving sheet capable of thermal transfer recording, cards, and a transmission type document preparation sheet by appropriately selecting a substrate sheet. You can also do it. Further, the thermal transfer image-receiving sheet of the present invention can be provided with a cushion layer between the substrate sheet and the dye receiving layer, if necessary, and by providing such a cushion layer, there is less noise during printing and the image information is displayed. Corresponding images can be transferred and recorded with good reproducibility. The thermal transfer sheet used when performing thermal transfer using the thermal transfer image-receiving sheet of the present invention as described above is a paper or polyester film provided with a dye layer containing a sublimable dye, and a conventionally known thermal transfer sheet is Any of them can be used as they are in the present invention.
【００１３】又、熱転写時の熱エネルギーの付与手段
は、従来公知の付与手段がいずれも使用することが出
来、例えば、サーマルプリンター（例えば、日立製作所
製、ビデオプリンターＶＹ−１００）等の記録装置によ
って、記録時間をコントロールすることにより、５〜１
００ｍＪ／ｍｍ2 程度の熱エネルギーを付与することに
よって所期の目的を十分に達成することが出来る。As the means for applying the heat energy during the thermal transfer, any conventionally known applying means can be used. For example, a recording device such as a thermal printer (for example, a video printer VY-100 manufactured by Hitachi, Ltd.). By controlling the recording time,
By applying thermal energy of about 00 mJ / mm 2 , the intended purpose can be sufficiently achieved.
【実施例】次に実施例及び比較例を挙げて本発明を更に
具体的に説明する。尚、文中、部又は％とあるのは特に
断りの無い限り重量基準である。 実施例１ 基材シートとして合成紙（ユポ ＦＰＧ＃１５０、王子
油化製、厚さ１５０μｍ）を用い、この一方の面に下記
の組成の塗工液をワイヤーバーにより乾燥時５．０ｇ／
ｍ2 になる割合で塗布及び乾燥させて本発明の熱転写受
像シートを得た。塗工液組成； ポリエステル樹脂（バイロン６００、東洋紡製） １００部 アミノ変性シリコーン（ＫＦ−３９３、信越化学工業製） ３部 エポキシ変性シリコーン（Ｘ−２２−３４３、信越化学工業製） ３部 ポリエチレンワックス（ＰＰＬＹＷＡＸ６５５、東洋インキ製、融点１０１． ７℃） １０部 シリコーンポリエステル（ＴＳＲ−１８７、東芝シリコーン製） １０部 メチルエチルケトン／トルエン（重量比１／１） ９００部EXAMPLES Next, the present invention will be described more specifically with reference to Examples and Comparative Examples. In the text, “part” or “%” is based on weight unless otherwise specified. Example 1 Synthetic paper (Yupo FPG # 150, manufactured by Oji Yuka, thickness 150 μm) was used as a base sheet, and a coating solution having the following composition was dried on one surface of the synthetic paper by a wire bar at a rate of 5.0 g /
The thermal transfer image-receiving sheet of the present invention was obtained by coating and drying at a ratio of m 2 . Coating liquid composition: Polyester resin (Vylon 600, Toyobo) 100 parts Amino-modified silicone (KF-393, Shin-Etsu Chemical Co., Ltd.) 3 parts Epoxy-modified silicone (X-22-343, Shin-Etsu Chemical Co., Ltd.) 3 parts Polyethylene wax (PPLYWAX655, Toyo Ink, melting point 101.7 ° C.) 10 parts Silicone polyester (TSR-187, Toshiba Silicone) 10 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 900 parts
【００１４】実施例２ 実施例１における塗工液に代えて下記の塗工液を使用
し、他は実施例１と同様にして本発明の熱転写受像シー
トを得た。塗工液組成； ポリエステル樹脂（バイロン６００、東洋紡製） １００部 アミノ変性シリコーン（ＫＦ−３９３、信越化学工業製） ３部 エポキシ変性シリコーン（Ｘ−２２−３４３、信越化学工業製） ３部 アクリルシリコーン（アロンＵＳ−１００） １０部 ポリエチレンワックス（ＰＰＬＹＷＡＸ６５５、東洋インキ製、融点１０１． ７℃） １０部 メチルエチルケトン／トルエン（重量比１／１） ９００部 実施例３ 実施例１における塗工液に代えて下記の塗工液を使用
し、他は実施例１と同様にして本発明の熱転写受像シー
トを得た。塗工液組成； 塩化ビニル・酢酸ビニル共重合体（＃１０００Ａ、電気化学製） １００部 アミノ変性シリコーン（ＫＦ−３９３、信越化学工業製） ３部 エポキシ変性シリコーン（Ｘ−２２−３４３、信越化学工業製） ３部 シリコーンポリエステル（ＴＳＲ−１８７、東芝シリコーン製） １０部 架橋ポリスチレン（ファインパール３０００ＳＰ、住友化学製、耐熱温度 ２００℃） １０部 メチルエチルケトン／トルエン（重量比１／１） ９００部Example 2 A thermal transfer image-receiving sheet of the present invention was obtained in the same manner as in Example 1 except that the following coating liquid was used in place of the coating liquid in Example 1. Coating solution composition: Polyester resin (Vylon 600, manufactured by Toyobo) 100 parts Amino-modified silicone (KF-393, manufactured by Shin-Etsu Chemical Co., Ltd.) 3 parts Epoxy-modified silicone (X-22-343, manufactured by Shin-Etsu Chemical Co., Ltd.) 3 parts Acrylic silicone (Aron US-100) 10 parts Polyethylene wax (PPLYWAX655, manufactured by Toyo Ink, melting point 101.7 ° C.) 10 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 900 parts Example 3 Instead of the coating liquid in Example 1, A thermal transfer image-receiving sheet of the present invention was obtained in the same manner as in Example 1 except that the following coating liquid was used. Coating liquid composition; vinyl chloride / vinyl acetate copolymer (# 1000A, manufactured by Electrochemical) 100 parts Amino-modified silicone (KF-393, manufactured by Shin-Etsu Chemical Co., Ltd.) 3 parts Epoxy-modified silicone (X-22-343, Shin-Etsu Chemical) Industrial) 3 parts Silicone polyester (TSR-187, Toshiba Silicone) 10 parts Crosslinked polystyrene (Fine Pearl 3000SP, Sumitomo Chemical, heat-resistant temperature 200 ° C) 10 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 900 parts
【００１５】実施例４ 実施例１における塗工液に代えて下記の塗工液を使用
し、他は実施例１と同様にして本発明の熱転写受像シー
トを得た。塗工液組成； ポリビニルブチラール（５０００−Ａ、電気化学製） １００部 アミノ変性シリコーン（ＫＦ−３９３、信越化学工業製） ３部 エポキシ変性シリコーン（Ｘ−２２−３４３、信越化学工業製） ３部 アクリルシリコーン（アロンＵＳ−１００） １０部 架橋ポリスチレン（ファインパール３０００ＳＰ、住友化学製、耐熱温度 ２００℃） １０部 メチルエチルケトン／トルエン（重量比１／１） ９０．０部Example 4 A thermal transfer image-receiving sheet of the present invention was obtained in the same manner as in Example 1 except that the following coating liquid was used in place of the coating liquid in Example 1. Composition of coating liquid: polyvinyl butyral (5000-A, manufactured by Electrochemical) 100 parts Amino-modified silicone (KF-393, manufactured by Shin-Etsu Chemical Co., Ltd.) 3 parts Epoxy-modified silicone (X-22-343, manufactured by Shin-Etsu Chemical Co., Ltd.) 3 parts Acrylic silicone (Aron US-100) 10 parts Crosslinked polystyrene (Finepearl 3000SP, Sumitomo Chemical, heat-resistant temperature 200 ° C) 10 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 90.0 parts
【００１６】実施例５ 厚さ１２μｍのポリエステルフイルム（商品名「ルミラ
ー」、東レ製）の表面に、実施例３の染料受容層用塗工
液をバーコーターにより乾燥時３．０ｇ／ｍ2になる割
合で塗布し、ドライヤーで仮乾燥後、１００℃のオーブ
ン中で３０分間乾燥して染料受容層を形成し、更に染料
受容層上に下記粘着剤溶液を同様にして乾燥時１５ｇ／
ｍ2 の割合で塗布及び乾燥して接着剤層を形成し、本発
明で使用する染料受容層転写フイルムを得た。粘着剤層用塗工液組成 ； エマルジョン系粘着剤（Ｅ−１０５４、綜研化学製） １００部 水 ３０部 上記の染料受容層転写フイルムをコピー用紙（ゼロック
スＭ紙、厚み９０μｍ）の表面に重ね、両者をラミネー
ター中に通して貼り合わせた後、基材フイルムを剥離し
て染料受容層を転写させ、本発明の熱転写受像シートを
得た。Example 5 The surface of a 12 μm-thick polyester film (trade name “Lumirror”, manufactured by Toray Industries, Inc.) was coated with the coating solution for dye-receptive layer of Example 3 by a bar coater to 3.0 g / m 2 when dried. The coating solution is applied at the following ratio, temporarily dried with a drier, and then dried in an oven at 100 ° C. for 30 minutes to form a dye receiving layer. Further, the following adhesive solution is similarly dried on the dye receiving layer at 15 g / dry.
An adhesive layer was formed by coating and drying at a ratio of m 2 to obtain a dye-receiving layer transfer film used in the present invention. Coating liquid composition for pressure-sensitive adhesive layer ; emulsion-type pressure-sensitive adhesive (E-1054, manufactured by Soken Chemical Co., Ltd.) 100 parts water 30 parts The above dye-receptive layer transfer film is superposed on the surface of copy paper (Xerox M paper, thickness 90 μm), Both were passed through a laminator and bonded, and then the substrate film was peeled off to transfer the dye receiving layer to obtain a thermal transfer image-receiving sheet of the present invention.
【００１７】比較例１ 実施例１における塗工液に代えて下記の塗工液を使用
し、他は実施例１と同様にして比較例の熱転写受像シー
トを得た。塗工液組成； ポリエステル樹脂（バイロン６００、東洋紡製） １００部 アミノ変性シリコーン（ＫＦ−３９３、信越化学工業製） ３部 エポキシ変性シリコーン（Ｘ−２２−３４３、信越化学工業製） ３部 メチルエチルケトン／トルエン（重量比１／１） ９００部 シリコーンポリエステル（ＴＳＲ−１８７、東芝シリコーン製） １０部 比較例２ 実施例１における塗工液に代えて下記の塗工液を使用
し、他は実施例１と同様にして比較例の熱転写受像シー
トを得た。塗工液組成； 塩化ビニル・酢酸ビニル共重合体（＃１０００Ａ、電気化学製） １００部 ポリエステル樹脂（バイロン６００、東洋紡製） １００部 アミノ変性シリコーン（ＫＦ−３９３、信越化学工業製） ３部 エポキシ変性シリコーン（Ｘ−２２−３４３、信越化学工業製） ３部 ポリエチレンワックス（ＰＰＬＹＷＡＸ６５５、東洋インキ製、融点１０１． ７℃） １０部 メチルエチルケトン／トルエン（重量比１／１） ９００部 比較例３ 実施例１における塗工液に代えて下記の塗工液を使用
し、他は実施例１と同様にして比較例の熱転写受像シー
トを得た。塗工液組成； ポリビニルブチラール（５０００−Ａ、電気化学製） １００部 アミノ変性シリコーン（ＫＦ−３９３、信越化学工業製） ３部 エポキシ変性シリコーン（Ｘ−２２−３４３、信越化学工業製） ３部 アクリルシリコーン（アロンＵＳ−１００） １０部 パラフィンワックス（ＨＮＰ−３、日本精蝋製、融点６６℃） １０部 メチルエチルケトン／トルエン（重量比１／１） ９０．０部 一方、下記組成の染料担持層形成用インキ組成物を調製
し、背面に耐熱処理を施した６μｍ厚のポリエチレンテ
レフタレートフイルムに、乾燥塗布量が１．０ｇ／ｍ2
になる様にワイヤーバーにより塗布及び乾燥して熱転写
シートを得た。 インキ組成； Ｃ．Ｉ．ディスパーズブルー２４ １．０部 ポリビニルブチラール樹脂 １０．０部 メチルエチルケトン／トルエン（重量比１／１） ９０．０部Comparative Example 1 The following coating liquid was used in place of the coating liquid used in Example 1.
In the same manner as in Example 1 except for the above, the thermal transfer image receiving sheet of the comparative example is used.
GotCoating liquid composition; Polyester resin (Vylon 600, manufactured by Toyobo) 100 parts Amino-modified silicone (KF-393, manufactured by Shin-Etsu Chemical Co., Ltd.) 3 parts Epoxy-modified silicone (X-22-343, manufactured by Shin-Etsu Chemical Co., Ltd.) 3 parts Methyl ethyl ketone / toluene (weight ratio 1 / 1) 900 parts Silicone polyester (TSR-187, manufactured by Toshiba Silicone) 10 parts Comparative Example 2 The following coating liquid is used instead of the coating liquid in Example 1.
In the same manner as in Example 1 except for the above, the thermal transfer image receiving sheet of the comparative example is used.
GotCoating liquid composition; Vinyl chloride / vinyl acetate copolymer (# 1000A, manufactured by Denki Kagaku) 100 parts Polyester resin (Vylon 600, manufactured by Toyobo) 100 parts Amino-modified silicone (KF-393, Shin-Etsu Chemical Co., Ltd.) 3 parts Epoxy-modified silicone (X- 22-343, manufactured by Shin-Etsu Chemical Co., Ltd. 3 parts Polyethylene wax (PPLYWAX655, manufactured by Toyo Ink, melting point 101.7 ° C.) 10 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 900 parts Comparative Example 3 Coating liquid in Example 1 Use the following coating liquid instead of
In the same manner as in Example 1 except for the above, the thermal transfer image receiving sheet of the comparative example is used.
GotCoating liquid composition; Polyvinyl butyral (5000-A, manufactured by Electrochemical) 100 parts Amino-modified silicone (KF-393, manufactured by Shin-Etsu Chemical Co., Ltd.) 3 parts Epoxy-modified silicone (X-22-343, manufactured by Shin-Etsu Chemical Co., Ltd.) 3 parts Acrylic silicone (Aron US -100) 10 parts Paraffin wax (HNP-3, manufactured by Nippon Seiro Co., Ltd., melting point 66 ° C.) 10 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 90.0 parts On the other hand, an ink composition for forming a dye carrying layer having the following composition Prepared
6 μm thick polyethylene tape with a heat-resistant back surface
A dry coating amount of 1.0 g / m on a rephthalate film.2
Coating with a wire bar and drying to achieve thermal transfer
Got the sheet. Ink composition; C. I. Disperse Blue 24 1.0 part Polyvinyl butyral resin 10.0 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 90.0 parts
【００１８】熱転写試験；上記の熱転写シートと前記の
本発明及び比較例の熱転写受像シートとを、夫々の染料
層と染料受容面とを対向させて重ね合せ、熱転写シート
の裏面からサーマルヘッドを用いて、ヘッド印加電圧１
１．０Ｖ、印加パルス幅１６ｍｓｅｃ．／ｌｉｎｅから
１ｍｓｅｃ．毎に順次減少させるステップパターン、副
走査方向６ｌｉｎｅ／ｍｍ（３３．３ｍｓｅｃ．／ｌｉ
ｎｅ）の条件でサーマルヘッドで記録を行ってシアン画
像を形成した後の両者の各種保存性等を調べ、下記表１
の結果を得た。 （１）耐指紋性評価方法 印字物表面に指紋を押捺し、室温に５日間放置した後、
指紋押捺部の変色及び濃度変化の度合いを目視にて評価
した。 Ａ：指紋押捺部と非押捺部の差が殆ど認められなかっ
た。 Ｂ：変色若しくは濃度変化が認められた。 Ｃ：指紋押捺部が白抜けし、指紋形状が明瞭に認められ
た。 Ｄ：指紋押捺部を中心として、白抜けが発生し、同時に
染料の凝集が認められた。 （２）耐可塑剤性及び耐擦過性評価方法 印字物表面の同一部分を、市販のプラスチック消しゴム
で５回軽く擦り、濃度変化の度合いを目視にて判定し
た。 ◎：濃度変化が全く認められなかった。 ○：濃度変化が殆ど認められなかった。 △：濃度変化が認められた。 ×：濃度が大きく変化し、低濃度部から中濃度部にかけ
ては白抜けとなった。 Thermal transfer test: The above-mentioned thermal transfer sheet and the above-mentioned thermal transfer image-receiving sheet of the present invention and the comparative example are superposed with their respective dye layers and dye-receiving surfaces facing each other, and a thermal head is used from the back surface of the thermal transfer sheet. Head applied voltage 1
1.0 V, applied pulse width 16 msec. / Line to 1 msec. Step pattern which is sequentially decreased every time, 6 line / mm (33.3 msec./li) in the sub scanning direction
After recording with a thermal head under the conditions of (ne) and forming a cyan image, various storability and the like of both are examined, and Table 1 below is shown.
Got the result. (1) Fingerprint resistance evaluation method After fingerprints were imprinted on the surface of the printed matter and left at room temperature for 5 days,
The degree of discoloration and density change of the fingerprint imprinted portion was visually evaluated. A: Almost no difference between the fingerprint imprinted part and the non-imprinted part was recognized. B: Discoloration or change in density was observed. C: The imprinted part of the fingerprint was blank, and the fingerprint shape was clearly recognized. D: White spots occurred around the fingerprint imprinted portion, and at the same time, dye aggregation was observed. (2) Evaluation method of plasticizer resistance and scratch resistance The same portion of the surface of the printed material was lightly rubbed with a commercially available plastic eraser 5 times, and the degree of density change was visually determined. A: No change in density was observed. ◯: Almost no change in density was observed. Δ: A change in density was recognized. X: The density changed greatly, and white spots were seen from the low density area to the medium density area.
【００１９】[0019]
【表１】 尚、比較例３で得られた画像は滲みが発生した。[Table 1] Bleeding occurred in the image obtained in Comparative Example 3.
【００２０】[0020]
【効果】以上の如き本発明によれば、染料受容層に有機
フィラー及びシリコーン化合物を含有させることによ
り、形成される画像の耐指紋性、耐可塑剤性、耐擦過性
等の耐久性が向上する。[Effect] According to the present invention as described above, by containing an organic filler and a silicone compound in the dye receiving layer, the durability of the formed image such as fingerprint resistance, plasticizer resistance, and scratch resistance is improved. To do.
フロントページの続き (72)発明者 山口 桂 東京都新宿区市谷加賀町１丁目１番１号 大日本印刷株式会社内Front page continuation (72) Inventor Katsura Yamaguchi 1-1-1 Ichigayaka-cho, Shinjuku-ku, Tokyo Inside Dai Nippon Printing Co., Ltd.
Claims (8)
受容層を形成してなる熱転写受像シートにおいて、上記
染料受容層が、有機フィラー及びシリコーン化合物を含
有することを特徴とする熱転写受像シート。1. A thermal transfer image-receiving sheet comprising a substrate sheet and a dye-receiving layer formed on at least one surface of the substrate sheet, wherein the dye-receiving layer contains an organic filler and a silicone compound.
ィラーである請求項１に記載の熱転写受像シート。2. The thermal transfer image-receiving sheet according to claim 1, wherein the organic filler is an organic filler having a melting point of 70 ° C. or higher.
請求項１に記載の熱転写受像シート。3. The thermal transfer image-receiving sheet according to claim 1, wherein the organic filler is a fine powder wax.
塑性樹脂である請求項１に記載の熱転写受像シート。4. The thermal transfer image-receiving sheet according to claim 1, wherein the silicone compound is a silicone-modified thermoplastic resin.
形成してなる染料受容層転写フイルムを、熱転写受像シ
ートの基材シートに張り合せ、しかる後に基材フイルム
を剥離することからなり、上記染料受容層が、有機フィ
ラー及びシリコーン化合物を含有することを特徴とする
熱転写受像シートの製造方法。5. A dye receiving layer transfer film having a transferable dye receiving layer formed on the surface of a base film, is stuck to a base sheet of a thermal transfer image-receiving sheet, and then the base film is peeled off. A method for producing a thermal transfer image-receiving sheet, wherein the dye receiving layer contains an organic filler and a silicone compound.
フィラーである請求項５に記載の熱転写受像シートの製
造方法。6. The method for producing a thermal transfer image-receiving sheet according to claim 5, wherein the organic filler is an organic filler having a melting point of 100 ° C. or higher.
請求項５に記載の熱転写受像シートの製造方法。7. The method for producing a thermal transfer image-receiving sheet according to claim 5, wherein the organic filler is a fine powder wax.
塑性樹脂である請求項５に記載の熱転写受像シートの製
造方法。8. The method for producing a thermal transfer image-receiving sheet according to claim 5, wherein the silicone compound is a silicone-modified thermoplastic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16555492A JP3256278B2 (en) | 1992-06-02 | 1992-06-02 | Thermal transfer image receiving sheet and method of manufacturing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16555492A JP3256278B2 (en) | 1992-06-02 | 1992-06-02 | Thermal transfer image receiving sheet and method of manufacturing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05330252A true JPH05330252A (en) | 1993-12-14 |
| JP3256278B2 JP3256278B2 (en) | 2002-02-12 |
Family
ID=15814576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16555492A Expired - Fee Related JP3256278B2 (en) | 1992-06-02 | 1992-06-02 | Thermal transfer image receiving sheet and method of manufacturing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3256278B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009190383A (en) * | 2008-02-18 | 2009-08-27 | Dainippon Printing Co Ltd | Heat transfer image receiving sheet |
| JP2013208854A (en) * | 2012-03-30 | 2013-10-10 | Dainippon Printing Co Ltd | Thermal transfer image receiving sheet and method of manufacturing the same |
| JP2013208865A (en) * | 2012-03-30 | 2013-10-10 | Dainippon Printing Co Ltd | Thermal transfer image receiving sheet and method of manufacturing the same |
| JP2014198396A (en) * | 2013-03-29 | 2014-10-23 | 大日本印刷株式会社 | Thermal transfer image receiving sheet and manufacturing method thereof |
| JP2016068562A (en) * | 2014-09-30 | 2016-05-09 | 大日本印刷株式会社 | Transfer sheet |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62264994A (en) * | 1986-05-13 | 1987-11-17 | Dainippon Printing Co Ltd | Manufacture of heat transfer sheet |
| JPS6395990A (en) * | 1986-10-13 | 1988-04-26 | Nec Corp | Thermal transfer recording material |
| JPS63170087A (en) * | 1987-01-09 | 1988-07-13 | Taiho Ind Co Ltd | Material to be recorded for thermal transfer |
| JPH01160682A (en) * | 1987-12-18 | 1989-06-23 | Dainippon Printing Co Ltd | Image receiving layer transfer sheet |
| JPH0225393A (en) * | 1988-07-15 | 1990-01-26 | Kanzaki Paper Mfg Co Ltd | Image-receiving sheet for thermal transfer recording |
| JPH02277694A (en) * | 1989-04-20 | 1990-11-14 | Fuji Photo Film Co Ltd | Thermal transfer image receiving material |
| JPH04113893A (en) * | 1990-09-04 | 1992-04-15 | Konica Corp | Image-receiving sheet for thermal transfer recording |
| JPH0558062A (en) * | 1991-08-31 | 1993-03-09 | Kanzaki Paper Mfg Co Ltd | Image receiving sheet for thermal transfer recording |
| JPH05139058A (en) * | 1991-11-18 | 1993-06-08 | Mitsubishi Paper Mills Ltd | Image receptor for thermal transfer and method for producing the same |
| JPH05330263A (en) * | 1992-05-29 | 1993-12-14 | Victor Co Of Japan Ltd | Transparent image receiving sheet |
-
1992
- 1992-06-02 JP JP16555492A patent/JP3256278B2/en not_active Expired - Fee Related
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62264994A (en) * | 1986-05-13 | 1987-11-17 | Dainippon Printing Co Ltd | Manufacture of heat transfer sheet |
| JPS6395990A (en) * | 1986-10-13 | 1988-04-26 | Nec Corp | Thermal transfer recording material |
| JPS63170087A (en) * | 1987-01-09 | 1988-07-13 | Taiho Ind Co Ltd | Material to be recorded for thermal transfer |
| JPH01160682A (en) * | 1987-12-18 | 1989-06-23 | Dainippon Printing Co Ltd | Image receiving layer transfer sheet |
| JPH0225393A (en) * | 1988-07-15 | 1990-01-26 | Kanzaki Paper Mfg Co Ltd | Image-receiving sheet for thermal transfer recording |
| JPH02277694A (en) * | 1989-04-20 | 1990-11-14 | Fuji Photo Film Co Ltd | Thermal transfer image receiving material |
| JPH04113893A (en) * | 1990-09-04 | 1992-04-15 | Konica Corp | Image-receiving sheet for thermal transfer recording |
| JPH0558062A (en) * | 1991-08-31 | 1993-03-09 | Kanzaki Paper Mfg Co Ltd | Image receiving sheet for thermal transfer recording |
| JPH05139058A (en) * | 1991-11-18 | 1993-06-08 | Mitsubishi Paper Mills Ltd | Image receptor for thermal transfer and method for producing the same |
| JPH05330263A (en) * | 1992-05-29 | 1993-12-14 | Victor Co Of Japan Ltd | Transparent image receiving sheet |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009190383A (en) * | 2008-02-18 | 2009-08-27 | Dainippon Printing Co Ltd | Heat transfer image receiving sheet |
| JP2013208854A (en) * | 2012-03-30 | 2013-10-10 | Dainippon Printing Co Ltd | Thermal transfer image receiving sheet and method of manufacturing the same |
| JP2013208865A (en) * | 2012-03-30 | 2013-10-10 | Dainippon Printing Co Ltd | Thermal transfer image receiving sheet and method of manufacturing the same |
| JP2014198396A (en) * | 2013-03-29 | 2014-10-23 | 大日本印刷株式会社 | Thermal transfer image receiving sheet and manufacturing method thereof |
| JP2016068562A (en) * | 2014-09-30 | 2016-05-09 | 大日本印刷株式会社 | Transfer sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3256278B2 (en) | 2002-02-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3256278B2 (en) | Thermal transfer image receiving sheet and method of manufacturing the same | |
| JP3058279B2 (en) | Thermal transfer image receiving sheet | |
| JP3493023B2 (en) | Manufacturing method of thermal transfer image receiving sheet | |
| JP2975416B2 (en) | Thermal transfer image forming method | |
| JP3181972B2 (en) | Thermal transfer image receiving sheet | |
| JP3088780B2 (en) | Thermal transfer image receiving sheet | |
| JPH05229265A (en) | Thermal transfer image receiving sheet | |
| JP3210070B2 (en) | Thermal transfer image receiving sheet | |
| JP4163928B2 (en) | Dye-receiving layer transfer sheet | |
| JP2872781B2 (en) | Thermal transfer image receiving sheet | |
| JP2571752B2 (en) | Thermal transfer sheet | |
| JP3150725B2 (en) | Receiving layer transfer sheet | |
| JP2993972B2 (en) | Thermal transfer image receiving sheet | |
| JPH0564978A (en) | Thermal transfer image-receiving sheet | |
| JPH0550774A (en) | Accepting layer transfer sheet | |
| JP3274884B2 (en) | Thermal transfer image receiving sheet | |
| JP3172573B2 (en) | Thermal transfer image receiving sheet | |
| JPH08230337A (en) | Thermal transfer image receiving sheet | |
| JPH05330248A (en) | Thermal transfer image receiving sheet | |
| JPH068646A (en) | Thermal transfer image receiving sheet | |
| JPH061085A (en) | Dye accepting layer transfer sheet and composite thermal transfer sheet | |
| JPS6342892A (en) | Thermal transfer recording sheet | |
| JPH0717150A (en) | Thermal transfer image receiving sheet | |
| JPH05330251A (en) | Receiving layer transfer sheet | |
| JPH05246151A (en) | Heat transfer image receiving sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20071130 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20081130 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20081130 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20091130 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20091130 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20101130 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20101130 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111130 Year of fee payment: 10 |
|
| LAPS | Cancellation because of no payment of annual fees |
