JPS59169894A - Transfer material for thermal recording - Google Patents

Transfer material for thermal recording

Info

Publication number
JPS59169894A
JPS59169894A JP58043534A JP4353483A JPS59169894A JP S59169894 A JPS59169894 A JP S59169894A JP 58043534 A JP58043534 A JP 58043534A JP 4353483 A JP4353483 A JP 4353483A JP S59169894 A JPS59169894 A JP S59169894A
Authority
JP
Japan
Prior art keywords
cellulose
recording
high polymer
coloring material
thermal recording
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58043534A
Other languages
Japanese (ja)
Inventor
Osamu Hotta
収 堀田
Tokihiko Shimizu
清水 時彦
Nobuyoshi Taguchi
田口 信義
Akihiro Imai
章博 今井
Soichiro Mima
美間 総一郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP58043534A priority Critical patent/JPS59169894A/en
Publication of JPS59169894A publication Critical patent/JPS59169894A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/41Base layers supports or substrates

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Impression-Transfer Materials And Handling Thereof (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

PURPOSE:To obtain a high recording density and favorable image quality, by a method wherein a material consisting mainly of a cellulose base high polymer is used as a base, and a cellulose base high polymer is used as a binder for a coloring material, in the titled transfer material comprising a coloring material. CONSTITUTION:A coloring material layer 3 comprising a sublimable dye 4 and a cellulose base high polymer binder 6 is provided on a film base 2 consisting mainly of a cellulose base high polymer such as a cellulose ester (e.g., triacetyl cellulose) or cellophane to obtain a transfer material for thermal recording. The cellulose base high polymer binder 6 may be acetyl cellulose or nitrocellulose varying in degree of acidity or degree of nitrification. A body such as alumina or titanium oxide may be incorporated in the coloring material layer 3.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、熱印加により色材を転写する方式の記録に用
いられる感熱記録用転写体に関するものであり、とくに
サーマルヘッドやレーザービームなどの電子デバイスに
よる高速記録に利用し得るものである。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a heat-sensitive recording transfer body used for recording in which a coloring material is transferred by applying heat, and in particular to an electronic device such as a thermal head or a laser beam. It can be used for high-speed recording.

従来例の構成とその問題点 2ベ−二゛ 従来、高速記録に適用し得る。昇華性染料を含んだフル
カラー用の感熱記録用転写体が広く用いられている。と
ころが、一般には昇華性染料を用いた記録において十分
な記録濃度を得るには、大きな記録エネルギーが必要で
あり、昇華性染料が結着剤で転写体の基体に結着される
場合に、記録時の熱で染料が結着剤とともに転写されて
良好な画質をもつ記録が得られない場合がある。
Conventional structure and its problems The 2-base type conventional structure can be applied to high-speed recording. Full-color thermal recording transfer bodies containing sublimable dyes are widely used. However, in general, recording using sublimable dyes requires a large amount of recording energy to obtain sufficient recording density, and when the sublimable dyes are bound to the base of the transfer medium with a binder, recording Due to the heat of the process, the dye may be transferred together with the binder, making it impossible to obtain a record with good image quality.

発明の目的 本発明は、十分な記録濃度と良好な画質をもつ記録を与
える感熱記録用転写体を提供することを目的とする。
OBJECTS OF THE INVENTION An object of the present invention is to provide a transfer member for thermal recording that provides recording with sufficient recording density and good image quality.

発明の構成 本発明は、セルロース系高分子化合物またはこれを主体
とする組成物からなるフィルム基体に。
DESCRIPTION OF THE INVENTION The present invention relates to a film substrate made of a cellulose-based polymer compound or a composition mainly composed of the cellulose-based polymer compound.

昇華性染料とこれを結着するセルロース系高分子化合物
結着剤を含む色材層を設けた感熱記録用転写体である。
This is a heat-sensitive recording transfer body provided with a coloring material layer containing a sublimable dye and a cellulose-based polymer binder for binding the dye.

実施例の説明 以下に本発明の実施例を図面を参照して説明す3べ− る。図はサーマルヘッドを用いた記録の断面図でアリ、
サーマルヘッド1の熱はフィルム基体2をとおして色材
層3に伝導し、昇華性染料4id昇華によって受像体5
[転写される。
DESCRIPTION OF EMBODIMENTS Three embodiments of the present invention will be described below with reference to the drawings. The figure is a cross-sectional view of recording using a thermal head.
The heat from the thermal head 1 is conducted to the coloring material layer 3 through the film substrate 2, and is transferred to the image receptor 5 by sublimation of the sublimable dye 4id.
[transcribed.

フィルム基体2に用いられるセルロース系高分子化合物
捷たは組成物としては、例えば、 l−IJア°7ア7
Pすぐれた耐熱性をもち・良女子な結果を与える。捷だ
1色材層3のセルロース系高分子化合物結着剤6として
、さ捷さ1の酢化度または硝化[fもつアセチルセルロ
ースやニトロセルロースなどがある。これらの結着剤は
フィルム基体2に対する接着性が良好でかつ、耐熱性も
すぐれているので、記録時の熱によってもフィルム基体
2から剥離しない。1だ、この良好な接着性のために十
分な記録濃度が得られる。これは良好な接着性のために
サーマルヘッド1の熱がフィルム基体2全とおして円滑
にセルロース系高分子化合物結着剤6に伝導し、効率よ
く昇華性染料4に伝達されるためであると解釈される。
Examples of the cellulose polymer compound composition or composition used for the film substrate 2 include l-IJA°7A7
P Has excellent heat resistance and gives good results. Examples of the cellulose-based polymer binder 6 in the coloring material layer 3 include acetyl cellulose and nitrocellulose having a degree of acetylation or nitrification [f] with a degree of fragility of 1. Since these binders have good adhesion to the film base 2 and excellent heat resistance, they do not peel off from the film base 2 even when heated during recording. 1. Due to this good adhesion, sufficient recording density can be obtained. This is because the heat from the thermal head 1 is smoothly conducted to the cellulose polymer binder 6 through the entire film base 2 and efficiently transferred to the sublimable dye 4 for good adhesion. be interpreted.

さらに、これらのフィルム基体2はとくに厚みのむらが
少ないので、染料の均一な昇華による良好な画質を与え
る。
Furthermore, since these film substrates 2 have particularly little unevenness in thickness, they provide good image quality due to uniform sublimation of the dye.

なお1色材層3にアルミナ、酸化チタンなどの体質顔料
などを含寸せても良好な結果が得られる。
Note that good results can be obtained even if one color material layer 3 contains an extender pigment such as alumina or titanium oxide.

以下に具体例によって本発明をさらに詳しく説明する。The present invention will be explained in more detail below using specific examples.

下記の構造式Aで表される染料2重量部、結着剤3重量
部とを溶媒200重量部に溶解した液をそれぞれ15μ
mの厚みのセロファンフィルムに。
A solution prepared by dissolving 2 parts by weight of a dye represented by the following structural formula A and 3 parts by weight of a binder in 200 parts by weight of a solvent was mixed with 15μ of each solution.
m thick cellophane film.

3ミルのステンレス鋼線を1きつけたワイヤ・バーでキ
ャスティングして感熱記録用転写体とした。
A transfer material for thermal recording was made by casting with a wire bar attached with one 3 mil stainless steel wire.

次表に結着剤と溶媒の組み合わせを示す。The following table shows combinations of binders and solvents.

これらの転写体を用い、サーマルヘッドでポリプロピレ
ン製の合成紙に活性クレーを塗工した受像体に次の記録
条件で記録画像を描かせた。
Using these transfer bodies, a recorded image was drawn using a thermal head on a receiver made of polypropylene synthetic paper coated with activated clay under the following recording conditions.

主走査、副走査の線密度:4ドツト/朋記録電力   
      0.7W/ドツトヘツドの加熱時間   
 2〜8mB この結果、各転写体ともそれぞれの加熱時間でドツトに
対応した画素をもち、8mBにおける平均記録濃度(5
m+n径の異なる6カ所の記録部の濃度の平均値)が1
.6以上の均質なマゼンタの染料画像を得た。また、各
加熱時間で色材層の剥離は起こらなかった。
Linear density of main scanning and sub-scanning: 4 dots/ho Recording power
0.7W/dot head heating time
2 to 8 mB As a result, each transfer body has pixels corresponding to dots for each heating time, and the average recording density at 8 mB (5
The average value of the density of 6 recording areas with different m+n diameters) is 1
.. 6 or more homogeneous magenta dye images were obtained. Furthermore, no peeling of the coloring material layer occurred during each heating time.

6 、  ・・ 発明の効果 以上のように1本発明の感熱記録用転写体は。6,... Effect of the invention As described above, one of the transfer bodies for thermal recording of the present invention is provided.

十分な記録濃度と良好な画質をもつ記録を与えることが
でき、寸だ、シアン、マゼンタおよびイエロの記録画像
を与える三種類の感熱記録用転写体を用いてフルカラー
画像を得ることもできる。
Full-color images can also be obtained by using three types of thermal recording transfer bodies that can provide recordings with sufficient recording density and good image quality, and that can provide recorded images of cyan, magenta, and yellow.

【図面の簡単な説明】[Brief explanation of drawings]

図は本発明の一実施例における感熱記録用転写体の断面
図である。 2・・・・・・フィルム基体、3・・・・・・色材層、
4・・・・・・昇華性染料、6・・・・・・セルロース
系高分子化合物結着剤。
The figure is a sectional view of a transfer body for thermal recording in an embodiment of the present invention. 2...Film base, 3...Coloring material layer,
4... Sublimable dye, 6... Cellulose polymer compound binder.

Claims (2)

【特許請求の範囲】[Claims] (1)セルロース系高分子化合物捷たはこれを主体とす
る組成物からなるフィルム基体に昇華性染料とこれを結
着するセルロース系高分子化合物結着剤を含む電膜層を
設けたことを特徴とする感熱記録用転写体。
(1) An electrical film layer containing a sublimable dye and a cellulose polymer binder to bind it is provided on a film substrate made of a cellulose polymer compound or a composition mainly composed of this. Characteristic thermal recording transfer body.
(2)フィルム基体がセロファンまたはこれを主体とす
る組成物である特許請求の範囲第1項記載の感熱記録用
転写体。
(2) The transfer body for thermal recording according to claim 1, wherein the film substrate is cellophane or a composition mainly composed of cellophane.
JP58043534A 1983-03-16 1983-03-16 Transfer material for thermal recording Pending JPS59169894A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58043534A JPS59169894A (en) 1983-03-16 1983-03-16 Transfer material for thermal recording

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58043534A JPS59169894A (en) 1983-03-16 1983-03-16 Transfer material for thermal recording

Publications (1)

Publication Number Publication Date
JPS59169894A true JPS59169894A (en) 1984-09-25

Family

ID=12666400

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58043534A Pending JPS59169894A (en) 1983-03-16 1983-03-16 Transfer material for thermal recording

Country Status (1)

Country Link
JP (1) JPS59169894A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62122790A (en) * 1985-08-05 1987-06-04 Hitachi Ltd Color ink sheet for thermal transfer
EP0227093A2 (en) * 1985-12-24 1987-07-01 EASTMAN KODAK COMPANY (a New Jersey corporation) Cellulosic binder for dye-donor element used in thermal dye transfer
EP0334606A2 (en) * 1988-03-23 1989-09-27 Fuji Photo Film Co., Ltd. Heat-sensitive recording sheet materials
US5418210A (en) * 1990-03-15 1995-05-23 Dai Nippon Insatsu Kabushiki Kaisha Heat transfer sheet

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62122790A (en) * 1985-08-05 1987-06-04 Hitachi Ltd Color ink sheet for thermal transfer
JPH051760B2 (en) * 1985-08-05 1993-01-08 Hitachi Ltd
EP0227093A2 (en) * 1985-12-24 1987-07-01 EASTMAN KODAK COMPANY (a New Jersey corporation) Cellulosic binder for dye-donor element used in thermal dye transfer
EP0334606A2 (en) * 1988-03-23 1989-09-27 Fuji Photo Film Co., Ltd. Heat-sensitive recording sheet materials
US5418210A (en) * 1990-03-15 1995-05-23 Dai Nippon Insatsu Kabushiki Kaisha Heat transfer sheet

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