JPS6463040A - Rhodium supported stainless steel catalyst for oxo reaction, production thereof and oxo reaction process using same - Google Patents
Rhodium supported stainless steel catalyst for oxo reaction, production thereof and oxo reaction process using sameInfo
- Publication number
- JPS6463040A JPS6463040A JP62221032A JP22103287A JPS6463040A JP S6463040 A JPS6463040 A JP S6463040A JP 62221032 A JP62221032 A JP 62221032A JP 22103287 A JP22103287 A JP 22103287A JP S6463040 A JPS6463040 A JP S6463040A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- stainless steel
- oxo reaction
- production
- synthesis gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE:To obtain a catalyst which is easily separated, recovered and recycled after a reaction and allows the production of aldehyde with high selectivity under mild conditions, by supporting rhodium on stainless steel. CONSTITUTION:Stainless steel is allowed to react with rhodium carbonyl in a hydrocarbon solvent under elevated pressure of synthesis gas to obtain a rhodium supported stainless steel catalyst. In the presence of the catalyst, olefin is allowed to react with synthesis gas while keeping the partial pressure of carbon monoxide under <=5kg/cm<2> gauge pressure and that of hydrogen under >=10kg/cm<2> gauge pressure. The catalyst can easily be produced, the loss of the metal catalyst in the oxo reaction is considerably reduced and the reaction is performed in a low pressure range of the synthesis gas. Useful straight chain aldehyde can be produced with high selectivity by adding triphenylphosphine.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62221032A JPS6463040A (en) | 1987-09-03 | 1987-09-03 | Rhodium supported stainless steel catalyst for oxo reaction, production thereof and oxo reaction process using same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62221032A JPS6463040A (en) | 1987-09-03 | 1987-09-03 | Rhodium supported stainless steel catalyst for oxo reaction, production thereof and oxo reaction process using same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6463040A true JPS6463040A (en) | 1989-03-09 |
JPH0364188B2 JPH0364188B2 (en) | 1991-10-04 |
Family
ID=16760415
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62221032A Granted JPS6463040A (en) | 1987-09-03 | 1987-09-03 | Rhodium supported stainless steel catalyst for oxo reaction, production thereof and oxo reaction process using same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6463040A (en) |
-
1987
- 1987-09-03 JP JP62221032A patent/JPS6463040A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPH0364188B2 (en) | 1991-10-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EXPY | Cancellation because of completion of term |