TW413677B - 2-hydroxyphenyltriazines - Google Patents

Abstract

A compound of the formula I, in which E1 and E2, independently of one another, are each a group of the formula Ia or Ib, and in which in the case where R3' is -O-CR8R8'-(CH2)l-XA, R1 is C1-C12alkyl or C6-C18alkyl which is interrupted by -O-, -CO-O- or -O-CO-; and, in the case where E1 is a group of the formula Ib, R1 is -CH2-CH(XA)-CH2-O-R7; and in the case where E1 is a group of the formula Ia in which neither of the radicals R2 and R14 is hydrogen, R1 is -CH2-CH(XA)-CH2-O-R7, and -CR8R'8-(CH2)l-XA,; R2 is H, -CH3 or Cl; R2' is -OH; R3 is H, -CH3, C1-C4alkoxy, C3alkenoxy, F, Cl, phenyl, benzoxy or -CN; R3' is -OH-CH2-CH(XA)-CH2-O-R7, formula (II), -O-CH2-(CH2)l-XA, -O-CH2-CH(OA)-R9, -O-CH2-CH(OH)-CH2-XA or -OR131; R4, R14 and R15, independently of one another, are H, F, Cl, OCH3 or CH3; R4' and R4"" stand in meta-position to the triazine ring and, independently of one another, are H, -CH3, C3alkenyl, -OCH3, C3alkenoxy, F, Cl, phenyl-C3alkyl or -CN; R5 is H or -CH3; R6 is H; R7 is C1-C8alkyl, cyclohexyl, C3alkenyl, phenyl or benzyl; R8 and R8' are H; R9 is C1-C10alkyl; R12 is C1-C18alkyl, phenyl or cyclohexyl; R131 is C3-C18alkyl or C3-C18alkyl which is substituted by OH, C1-C18alkoxy, -NHCOR12 and/or -OCOR12; and A is -C(=O)-CR5=CH-R6; X is -NR8-, -O-, -NH-(CnH2n)-NH- or -C-(CkH2k)-NH; l is a number from 1 to 19; n is a number from 0 to 4; k is a number from 2 to 4. The novel compounds can be used as UV absorbers in or for organic materials.

Description

4i3677-Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (i) The present invention is based on a novel 2-hydroxybenzyltriazine, its preparation method, and its UV absorption as a radon substance_ ° ΕΡ-Α-0, 434,608 discloses a UV absorber in the form of a hydroxybenzyl group, particularly a combination with a stereogenic amine. Other compounds of this type are described in, for example, US-A-5, 1 89, 084, EP-A-0, 530, 135, US-A-5,364,749 and US-A-5 , 300,414. It is also known to use hydroxyphenyl-type UV absorbers, for example for surface coatings. US-3,423,360 describes polymerized hydroxybenzyltriazine acrylates and methacrylates and their use for surface coating. However, these conventional UV absorbers often have undesired properties, such as discomfort with respect to light, heat, or moisture, or mobility or volatility, or their resistance to emulsion * crystal formation, or baking. It has now been found that a group of 2-hydroxyphenyltriazine UV absorbers * surprisingly meets industrial needs to a considerable degree. The combination of this novel 2-hydroxyphenyltriazine and other types of UV absorbers, such as benzobenzyl * * benzyltriazole, sterically hindered amines, tincture of aniline, cyanoacrylate, salicylic acid, propylene Nitriles or thiazolines are also suitable for flooring organic substances. Therefore, the present invention is based on a 2-hydroxyphenyltriazine of formula I: < Please read the precautions on the reverse side before filling out this page) -pack., Vs. This paper size applies Chinese National Standard (CNS) A4 specifications ( 210X297 mm} 5. Description of the Invention (II (I) 413677-Λ

Ei N OH

OR, where: Ei and £; 2 are independent of the group basis of the formula I a or I b (la) R 14 Rd

(lb)

R4, where: A is -C (= 0) ~ CR 5 = CH-R 6; R ι is green (please read the precautions on the back before filling this page) Printed by the Central Consumers Bureau of the Ministry of Economic Affairs Consumer Cooperative 0A \ CH.

CH

CH 2 CH 2 ^ CH2) m

—CH 2 — C (= CH 2) — R i 〇 * 一 (CH ^) P- S i R ii R ii ^-CH-CH 2 -C (= 〇) _ (CH z) q- CH = CH z or this paper size is applicable to China National Standard (CNS) A4 specification (2ί297 × 297 mm) Printed by the Department of Economics, Central Standards Bureau, Ministry of Economic Affairs, Consumer Cooperation 413677 a7 B7 V. Description of Invention (々) -C (= 0)-0- CH2-c (= C Η 2) -Rio; and

In the case where R3 'is 10-CR8 Rs'-(CHZ) -XA, Ri can additionally be Ci-Ci 8 alkyl or C3-C2 0 alkyl group 1 which is composed of -0-, -C0- ◦—or —0—CO in a group of 蹯; and in the case where Ei is a group of formula I a, both R2 and Ri 4 groups are not hydrogen * R i can also be A, -C Η 2- C Η (XA)-C Η 2-0 — R7, —CR e R 8 '— (CH 2) 1 — XA * -CH 2-CH f 0 A)-R a-~ CH 2 — CH (OH) — CH 2 — XA > -CHR a-(CH 2) r- C (= 0)-CH z-CH (◦ H)-CH2-〇A and -CR a R δ y-(CH 2) 1- C (= 0)-XA; In the case where Ei is a group group of formula I b, Ri can be another -C Η 2-C Η (XA) — CH2-O — R · ?; R2 is not IS Respectively (： 1 —C! 8alkoxy > C3 —

Cis shop oxygen * —QH or -0_C〇_Riz ϊ R3 and R3 'are mutually independent Η, 〇H, -0-C Η 2-C Η (XA) -GHz-0-R 7 , -5- This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) --------- ¾ ------ IT ------ 0 (Please read the back first (Notes for filling in this page)

413677 V. Description of the invention (mountain) 0A A7 B7 Consumption cooperation between employees of the Central Bureau of Standards of the Ministry of Economic Affairs Du Yinzhuang '0-CH I 乂 "CH2) m CH2 〇-C Η 2 -C (= C Η-〇1 (C Η z) ps i 1 R i — 0 — C (= 0) — (C Η — 0 — C (= 0) — 0 — C — 0 — c R 8 RS — (— 0 — C Η 2 — C Η (0 A — 0 — C Η Z — C Η (0 Η 〇-C Η R 8 — (C Η 2 — c Η (0 H)-c Η ζ — — c R 8 R r 8 — (C Η ZZ C 1 -C 1 8 courtyards C 6 —alkenyl i — 0 R 1 3 1 9 halogen CI -C 4 courtyards> -C Ν t — or phenyl — S (= 0) t: R 4 t R 4 / and R 4 // each other C 1 8 heptyl C 3 -C 6 enofluorinated methyl t phenyl I phenyl — CC 1 -C 4 -mono substituted »_ tc 1-c X 8 Alkyl — S (j R is Η 9 C Η Z C 0

2) q-CH = CH2, Η 2-C (= C Η 2) R t 〇CH 2) 1-XA-) —R 9 1) —CH 2 — XA) rC (= ◦)-0 — CH2 0 A *) i-C (= O)-XA-Ci 2 cycloalkyl, C3 — Ci s, methyl trifluoride, phenyl, phenyl-C i-alkyl — S (0) t For Η, Ci- group, 〇Ri3 1, halogen, tri 1 _C4 compound, single to diyl group —Ci — C4 alkyl * — CN = 0) t-or phenyl-S (= ◦) t0 R i 3, Ci— Alkyl or i-wire (please read the notes on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 413677 A7 B7 V. Invention Note (r) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs-CN; R 6 is Η * — C 0 0 R 1 3 R 7 is C 1-C 1 6 Academic C 1 & alkenyl »Phenyl via — CS oxy, C 3 — C 8 instead of benzyl 9 phenyl — C 1 — C — interrupted C 3 — C 5 0 alkyl n-bornyl »2 — methyl n-R 1 2 t R 8 and R 8 / unrelated phenyl groups, phenyl — C 1-C 8 m courtyard 9 C 3 — C 8 alkenyloxy 9 CF 3 substituted phenyl 9 R 9 is C 1 — C 1 8 courtyard 1 »R 1 0 is Η or — C Η 3 f R ί 1 and R 1 1 / unrelated groups 9 or via one or two C 1 —C 3-C 8 alkenyloxy »halogen R Z is Η 9 C 1 — C 1 8 group t phenyl — C 1 a C 4 alkyl — c 1 2 ethoxy J phenoxy 9 2 — or 1 adamantyl> Ci—Ci 7 alkyl or phenyl; C5-Ci 2 cycloalkyl; C3 — to three Ci —Ce alkyl, Ci alkenyloxy, halogen or trifluoromethyl to be 4 alkyl; via one or more of a 0; 1 adamantyl; 1-adamantyl norbornyl or a C (= 0) _ Don't be Η, C 1 —C i S alkyl, radical, or one to three Ci _c4 Ci-Cs alkoxy, halogen or phenyl or phenyl-Ci-C4 alkyl are Cl-C4 alkane, respectively Or benzene C8 alkyl, Ci_C8 alkoxy or trifluoromethyl substituted phenyl; alkyl, C2-alkenyl, benzene, C5-cl2 cycloalkyl, Ci-bornyl-2-based, 5-bornyl Ene-I ginseng brocade (read the note on the back first) Please fill in this page again for this matter.) This paper size is applicable to the Chinese Family Standard (CMS) A4 specification (210X297 mm) 413677 A7 B7. 5. Description of the invention (printed by the Consumer Cooperative of the Central Bureau of Samples of the Ministry of Economic Affairs. -Oxygen, 2 or 4 alkanes are cleaved from c, l; alkanes I or C alkanes 21 C 2 or the group in the ring is fluorenyl, the groups S, _,, a halo 3RI group 2 of 12 Oxygen tablets 1 element ct group 10101 oxygen 11IR1 8 * to alkenyl C haloene C group RCC benzene CCOIR 1 group 涸 8 4 group I, N81 oxygen NΗ from it; 1 loo C alkane ICC methyl 1 group c (-11 Ene 幵; 2 or 6 代! ^ 0 _ 〇 by II 1C alkane, cc, col \ alkane C poly I ~ S 35 is 312, cyclic group-'CC * and prime ring OR 0; CC its CC or H2 alkane 3 I 1} group Halogen 2 generations or radicals, i,, and I radicals are C generations 3, 3 oxygen, or 1 Take an alkyl 3 base substrate type CC +, take C23 benzyl oxide CI from 04 C phenoxybenzene ice II II j The radical alkane-2 is a 1C 8 *., Alkane, and alkanoyl group, which is based on the group C of CC, "-3 ο oxygen ο 1 1CR, and the C-substituted alkane phase is broken through 1 C alkane, 101 from the alkane c} Rc., O group or CI in the ring I take the rigid group II C is the ring I CSIOI group C alkane I 1 2 and 1 arsenal benzene-its 2-3 c 1 0 ο 0-generation group C1IC group-S8, s; i, 3 1 o C 8 _ 5 take benzene, 00, methyl 211 group | 1C group CIRI, 1 or C via; HI I alkylation * RC phenyl 3 is an alkyl IRi- The radical c \ i is 5 alkylfluoro groups and I, and the alkane 118S0NN alkane I and 3 are benzene 3C 8 1 2nd courtyard 4 3 3 6 R 3 1 c ο o C 8 3 IC and ·, 1, or C Or ®; I c F 1 oic 1CCI [C group; R group of 1 I prime gold R-CCIRI group II-c is the generation of alkyl (read the notes on the back first and then fill out this (Page) This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 413677 A7 B7 V. Description of the invention (1)-S 0 2 R 1 2;

Ri 3 2 and Ri 3 3 are unrelated to each other Ci-Ci 2 alkyl, C3-Ci 2 alkoxyalkyl, C4 — Ci 6 dialkylaminoalkyl or C 5-Ci 2 cycloalkyl ;or

Ri 3 2 and only: 3 3 — starting from C3 — C3 alkylene, C3 — CS oxyalkylene or acrylylene; X is —NRs —, — 0 —, — N Η — (C η Η 2 η) — Ν Η one or -0- (CkHzlO-ΝΗ —; k is a number from 2 to 4; 1 is a number from 0 to 19; m is a number from 2 to 8; η is a Number from 0 to 4; P is a number from ◦ to 10; q is a number from 1 to 8; r is a number from 0 to 18; and t is 0, 1 or 2. In the formula (I) The alkyl group of the substituent in the compound may have up to 18 carbon atoms, examples are methyl, ethyl, propyl • butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl , Undecyl, + dialkyl, tetradecyl, hexadecyl or octadecyl · or equivalent branched isomers. Alkoxy of substituents in compounds of formula (I) The group can have up to 18 carbon atoms, examples are methoxy or ethoxy, or substituents similar to the above-mentioned alkyl groups. -9-This paper size applies to China National Standard (CNS) A4 (210X297 mm) ---------n _ _ _ n T If ____ _ 0¾,-" Business (Please read the notes on the back first Then fill page) A7 B7 V. invention is described in (f

The alkenyl group of the substituent in the compound of formula (ί) may have up to 18 carbon atoms, examples are vinyl, allyl 1-alkenyl (-CH = CH -C Η 3) or allyl 2 -alkenyl (A CH2 — CH = CH2) * or a group similar to the above alkyl group. The alkenyloxy group of the substituent in the compound of formula (I) may have up to 18 carbon atoms, examples are propane-1eneoxy (--0-CH = CH-CH3) or propane-2-eneoxy (—O-CHz —CH C Η or a group similar to the above-mentioned alkyl group. In the compound of formula (I), the substituent is phenyl-Ci-C4 fluorenyl or a single to tri-Ci_C4 alkyl-substituted phenyl For a Ci-C 4 alkyl group, an example is c (ch3) 2 -〇 · c (ch3) 2.

--------- Equipment -------- τ ------, ^ (Please read the notes on the back before filling this page) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs • OCK 2

Or -〇c2h4 In the compound of the formula (I), the substituent is phenyl-Ci-(: 4 alkoxy)> Examples are: -〇 · In the compound of the formula (I), the substituent is halogen, an example Fluorochloro | bromide or iodine. R i is preferably -ch2 -ch (oa) -ch2 -0-R7 or -1 ο- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 5 Description of the invention (1) A7 B7

R2 is preferably fluorene, Ci_C4 alkyl * C3 alkenyl, F, C1 or phenyl; particularly preferred is fluorene, -CH3 or C1; most preferred is fluorene or -C Η3. Rz 'is preferably -OH, C: -C4 alkoxy or C3 dilute oxy; particularly preferred is _0H, -Cz alkoxy or C3 alkenyloxy; most preferred is _0H. R 3 and R 3 'are preferably -O-CHz-CH (0 A)-CHz-〇- R7: OA Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

-0 one CR 8 R 8 / one (C Η z) 1--Ό A '-0 — C Η Z — c H (0 A) one R 9 y one 0 — C Η Z — c H (〇Η) -C Η 2-XA, Η, -0 Η t C 1-c 4 courtyard group »cyclohexyl 4 C 3 alkenyl, C 1 C 4 fluorenyl) c 3 m oxygen F» C 1. = 氤- · Yv \ methylated, -11- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) n.---I--I _ I 士 良 __ I _- \, __-------(Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Bureau of Samples of the Ministry of Economic Affairs 413677 at B7 V. Description of the invention (/ 〇, phenoxy , Benzyl, benzyloxy or -CN; particularly preferred is hydrazone,

—OH * ~ 0 — CH2 — CH (〇 A} — CHz — OR7 OA

—0 — C Η 2 ~ (C Η 2) 1— OA 1 — CH3 * C 1 — C4 alkoxy, C3 alkenoxy, F, Cl, phenyl, or stupid methoxy or mono CN; best Is Η,-OH, -0-C Η 2 — CH (0 A)-C Η 2-Ο-R 7, CH,

-Ο C Η 3, CI, phenyl or CN. R4 and R4 'and R4 " Preferred are hydrazone, Ci-C4 alkyl, C3 alkenyl, Ci-C4 alkoxy, C3 alkenoxy, F, C1, trifluoromethyl, phenyl, benzene A Ci-C3 alkyl group or -CN; particularly preferred is H, a CH3 * C3 alkenyl group, -0CH3 · C 3 alkenyloxy * F, C 1, benzyl_C3 alkyl group or a CN; most preferred Is Η or One C Η 3 ° -1 2-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)! ..... ^ 水 1 ^ I] ~ ^ {Please read first Note on the back then fill in this page) A7 B7 V. Description of the invention (, /)

Rs is preferably tritium or a CH3. Only 6 is preferably Η * —COORiS · -C Η 3, or phenyl * is particularly preferably Η or a CHs. R7 is preferably a 04-C3 alkyl group, a cyclohexyl group, a C3-Cs dilute group, a military group, a phenyl group substituted by one to three Ci_C4 integrators or Ci-C4 alkoxy groups, or benzyl, and particularly Preferred are (3i-Ce alkyl, cyclohexyl, C3 alkenyl, phenyl or benzyl.

Rs and R8 'are preferably fluorene or Ci_Cs alkyl, respectively. R 1 0 is preferably nitrogen. R 1 i and! ^: 1 'are preferably independent of each other (: 1-C4 alkyl or phenyl, especially methyl. X is preferably a 0- or a NRs-, especially an oxygen atom. Index 1 is preferred The number is 1-15. Examples of compounds of formula I that can be used in the present invention are compounds of formula IC: ^ This order line (please read the notes on the back before filling in this tile) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

-13- This paper size applies to China National Standard (CNS) A4 (210 X 29? Mm) 413677

OA

ch2

A7 B7 V. Description of the invention) Where: A is -C (= 0)-CR s = C Η-R 6 R i are not related to each other: -CH2 —C Η z — C (= C Η 2) --Ri〇,-(C Η 2) P- S i R 1 i R!! 7-CH = CH 2, -c (= 0)-t CH 2) q-CH = CH2 or -c (= 0) -0-CH z-c (= CH 2) -Rio; in the case where R2 'is OH or OA, Ri can be ~ C Η 2 — C Η (0 A) — C Η 2 — Ο — R 7;

Rz and R2 'are uncorrelated with Η, 10H, OA,

Ci —Ci 2 alkyl, cyclohexyl < C3 — alkenyl, Ci —

Ci β alkoxy, c 2-Ci 8 alkenyloxy, halogen, phenyl or methyl trifluoride; R3 and R3 'are unrelated to each other Η, -0H, -0A, the above-mentioned -0 R i- —0 — CHR 8 ~ (C Η 2) 1 — 0 A * —Ο — C Η 2 — C Η (0 A)-R 9, -〇-C Η 2-c H (OH)-C Η 2- 0 A * -1 4-This paper size is in accordance with Chinese National Standard (CNS) A4 (210x297 mm). __ Thread (please read the precautions on the back before filling out this page) Staff Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs Printed 413677 at B7 V. Description of the Invention (3) ~ 0-CHR a-(C Η 2) rC (= OJ-〇 C Η 2 -C Η (OH) ~ C Η 2 — 〇 A 1

Cl monoalkyl, cyclohexyl, C3-Cs alkenyl, Cj-c18 alkoxy, c3-cl8 alkenyloxy, halogen, methyl trifluoride, phenyl, phenoxy, benzyl-Cl_C4 alkyl , Phenyl-Ci_C4 alkoxy, —CN'Ci—Cl3 alkyl-S (= 0) t-or phenyl-S (= 0) t; R 4 * R 4, and R 4 " The relevant ones are Η, Ci-

Ci2 alkyl, C3—Cs alkenyl, Ci—018 alkoxy, C3—Ct 8 alkenyloxy, halogen, methyl trifluoride, phenyl, benzyloxy, benzyl—Cl—C4 alkyl, single To tri-Cl-C. *-Cyno-substituted phenyl-Ci-C4 alkyl, phenyl-Ci-C4 alkoxy, 010 ^, ^ 1 1018 alkyl-5 (= 0 ) t one or phenyl-S ί = 0) t-; R5 is H * -CH2 — CO〇l13, Ci_c4 alkyl or -CN;

Rs is H, —COORi 3, Ci —Ci 7 or base; printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) R ·? Is Ci ~ Cl8 alkyl Cyclohexyl, C3 — ClS alkenyl; Cage group; via one to three Ci — C.3 alkyl, Ci — C.8 alkyloxy, Cz -c3 alkenyloxy, halogen or trifluoromethyl substituted Phenyl; phenyl-Ci-C4 alkyl or -C (= 0)-R 1 z;

Rs is fluorene or Ci-CiS alkyl; R9 is Ci—Ci 8 alkyl, phenyl or phenyl-Ci—C4 -1 5-This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 413677 A7 B7 5. Description of the invention (★) Alkyl;

Ri. Is Η or --CH3;

Ri i and 1 ^: i 'are unrelated to each other Ci_C4 alkyl or phenyl, or via one to three Ci_C8 alkyl, Ci_C8 alkyloxy, C3-Ce alkenyloxy, halogen or trifluoride Methyl substituted phenyl,

Ri 2 is alas! — Ci 8 alkyl, — Ci 8 alkenyl or phenyl * Ri 3 is fluorene, Ci—Ci 8 courtyard, C3 — Ci 8 dilute or phenyl, 1 is a number from 0 to 19; P is a A number from 0 to 10; Q is a number from 1 to 8; r is a number from 0 to 18; and t is 0, 1 or 2. Preferred compounds of formula (I) are: where R2 is H-Ci-C4 alkyl, C3 alkenyl, F, C1 or phenyl 1 printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back first) Fill out this page again) R2 'is Ci -C4 alkoxy, C3 alkenyloxy, —0 — C0 — R ί 2 or a Q Η; ί? 3 and Rs' are mutually independent Η, _0H, —0-CHz _CH (XA) — CH 2 — 0 — R 7, -16- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Policy

R 10

V. Description of the invention (〆 • 〇 A 〇-O-CHz-CH (0 A)-R 9, -〇-C Η 2-C Η (OH)-C Η 2-XA-C i -alkyl, Cyclohexyl, C3 alkenyl, mono-ORi3 1, F, C1, methyl trifluoride, phenyl * benzyl or mono CN; R4 'and R4 " independently are Η, Ci-C4 alkyl, C3 alkenyl, Cl -C4 alkoxy > C3 alkenyl, F, Cl, tri-gasified methyl, phenyl, phenyl-Ci_C3 alkyl or one CN; fis is Η or —CH3;

Rs is H, _C00Ri3, a CH3 or a phenyl group; R7 is a Ci-C8 alkyl group, a cyclohexyl group, a C3-C8 alkenyl group * a phenyl group, which is substituted by one to three Ci-104 alkyl groups or a Ci_c4 alkoxy group Phenyl, or benzyl;

Rs is Ci-C! Alkyl, phenyl or benzyl;! And Ri i 'are unrelated to Ct-C4 alkyl or phenyl, respectively;

Rl2 is H'Ci-Ct8 alkyl, C2-C3 alkenyl, phenyl * phenyl-Ci-C4 alkyl or cyclohexyl;

Rl3 is 0; 1-C4 alkyl, C3 alkenyl * cyclohexyl, phenyl-Ci-Ci alkyl or phenyl; R 4 * Ri 4 and Ri s which are not related to each other are Η, Ci-C3 paper size Applicable Chinese National Standard {CNS) A4 specification (210X 297 mm) --------- ^ ------ IT ------, ^ (Please read the notes on the back before filling (This page)

41367V V. Description of the invention (, 〇 A7 B7 courtyard i F \ C 1 9 C 1 — CN 1 R 1 3 1 is C 1 — C 1 8 via 0 Η > C 1 — C 1 8 > C 0 〇 R 1 3 — — C t — C 0 Ν (RI 3 Zn) — N Η C 0 R 1 1 »— — C 9 or C 3 ene — C 5 0 0 Η or 0 C 0 R 1 所 So C 4 alkyl 1 — C 0 R 1 2 X Yes — 0 — or — NR 8 — 1 is a number from 1 to 1 9 »r is from 0 to 1 0 A particularly preferred formula (I) of the formula (I) is that the alkoxy groups, CFs, phenyl, or alkyl groups, C3-Ci 8 alkyl groups, which are unrelated to each other, are alkoxy groups * CS-Ci2 Fluoroalkoxy 0 N Η 2 *-C Ο Η NRI 3 2 f R 1 3 3) 1 N, a QCOR! 2 and / or phenoxy, Cs-Cl2 cycloalkyl, Cs or more-0 — Interrupted * or substituted; benzyl · phenyl—Ci — or —S 0 2 R 1 2; t and the compound is, wherein: the group group of the formula la or lb, which I-- ----- ^ ------ 1T ------. ^ (Please read the notes on the back before filling this page) Standards Agency employees consumer cooperatives R 1 is printed

This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 413677 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs CH 2

Five, description of the invention ()

Or in the case where R3 'is a 0 — CR3 Rs' (C Η Z) 1- X A, R! Can additionally be Ci-Ci 2 alkyl or C6 —

Ci 8 courtyards, which are interrupted by —0—, one C0 — 0 — or one 0 — C0 —; and in the case where Yau i is a group of type I b group, Rx can be -C Η 2- C Η (XA)-C Η 2-0-R 7; and in the case where it is a group of formula I a, where both R 2 and Ri 4 are not hydrogen, Ri can be ~ CR 8 R 8 y (C Η 2) 1-XA * -C Η 2-C Η (0 A)-R9 and -C Η 2-CH (OH)-C Η 2-XA;

Rz is H, one CHS or Ci; R2 'is -0H; R3 is H, one CH3 * Ci-C4 alkoxy, C3 alkenyloxy * F, C1, phenyl, benzoyloxy, or- CN; R 3 v is -0 Η, —0-C Η 2-C. Η (XA) — C Η 2 — 0 — R 7, 0 — -0 — CH 2 — CH (0 A) — R 9, -1 9- The paper ruler applies Chinese National Standard (CNS) A4 (210 X 297 mm) 1 Thread (please read the precautions on the back before filling out this page). Printed 413677 at B7 V. Description of the Invention (θ) -O-CHz-CH (OH)-CH2-XA, or ~ 0 R i 3 i; R 4 * Ri 4 · and Ri s which are not related to each other are H ， F ， C 1 ′ 0 CH 3 or CH 3; R4 ′ and R4 位于 are located in one position for the triazine ring, which are unrelated to each other are H, —CH3, C3 alkenyl, and OCH3 * C3 alkenyloxy , F, C 1, phenyl-C3 alkyl, or CN; R 5 is Η or —CH s; R 6 is Η; R7 is Ci — C8 alkyl, cyclohexyl, C3 alkenyl, phenyl or benzyl R 8 and R 8 'are Η; R9 is Cl — Ci 〇 courtyard;

Ri 2 is Ci — Ci e alkyl, phenyl or cyclohexyl; R 1 3 1 is 0 3 —Cl 8 alkyl or C 3 —ClS alkyl, which is via OH, Ci-Ci 8 alkoxy, NHCORi z and / or an OCORI 2 substitution; and 1 is a number from 1 to 19. The present invention also relates to a polymer compound obtained from the addition polymerization of at least one compound of formula (Id) or at least one compound of formula (Id) and at least one other ethylene-containing unsaturated compound: A4 size (210 X 297 mm) --------- ΐ 衣 -------- ΐτ ------, ^ (Please read the notes on the back before filling this page) Ministry of Economy Central Consumers ’Bureau Consumer Consumption Cooperation. Printed by the agency 413677 A7 B7 V. Description of Invention (1)

. And Chinese I mutually CH 1 1 is 1 1 C and E and AR * I

R 7 ordering (please read the precautions on the back before filling this page) This paper applies the Chinese National Standard (CNS) A4 specification (210 > < 297 mm). The Department of Economics, Central Standards Bureau, Consumer Consumption, Du printed A7 B7 V. Description of the invention (/) -C Η 2-C (= C Η 2)-R! 〇, ~ (C Η 2) ρ- S i R ι! R ι ι /-C Η = C Η ζ, -C (= 〇) — (C Η 2) q- C Η = C Η 2,

-C Η R 8-(C Η ζ) r- C (= Ο)-Ο-C Η 2 — C Η (0 Η)-C Η ζ-0 A > -CR 8 Re /-(C Η ζ ) 1- C (= Ο)-ΧΑ or -C (= 0)-O- CHz-C (= C Η ζ)-R! 〇; where R2 4 group is not hydrogen, Ri can be _Α or -C Η 2-C Η (OH)-C Η ζ-ΧΑ;

Rz is independent of fluorene, Ci — Ci 2 alkyl, Cs — Ci 2 cycloalkyl, C 3 — Cs alkenyl, halogen, phenyl or methyl trifluoride;

Irrelevant to Rz 'are Ci_Ci 8-oxyl, C2_Ce e dilute oxygen, —OH or —0 — COR12; R3 and R3' are uncorrelated to Η, OH, _0Ri · -〇R 1 3 1, (:! — Ci8 alkyl, C3 — Cl8 alkenyl * C6 — Ci2 cycloalkyl, halogen, tri-gasified methyl, phenyl, phenyl — Cl —C4 alkyl * — CN, Ci — Cl8 alkyl -S (= 0) t- or phenyl-s (= 0) t; R 4, R4 ′ and R4〃 are unrelated to each other, H, Cl—018 alkyl, C3—C6 alkenyl, —0Rl3 !, Halogen, trifluoromethyl * phenyl, phenyl-C! -C4 alkyl, single to tri-Cl-c4 alkyl-substituted phenyl-Ci-C4 alkyl, -CN, Ci-Paper size applicable China National Standard (CNS) A4 Specification (210 X 297 mm) ---------- # ------ IT ------. ^ (Please read the precautions on the back before (Fill this page) V. Description of invention (y |) A7 B7 Consumption cooperation between employees of the Central Standards Bureau of the Ministry of Economic Affairs C 1 8 焼 基 — S (~ 0) t--or--1 3 (= 0) tj R 5 is Η >-C Η Z — C 0 0 R 1 3 t C 1 — C 4 alkyl or-CNR 6 is Η t — C 0 0 R 1 3 * C 1 -C 丄 7 courtyard or phenyl IR 7 is C 1 — C 1 8 fluorenyl »C 5-C 1 Z cyclic courtyard j C 3 — C Ϊ 8 alkenyl passes through two C 1-C 8 alkyl radicals C 1 — C 8 alkyloxy t C 3 — C 8 alkenyloxy> halogen or difermated methyl substituted phenyl 9 phenyl — C 1 — C 4 C 3 —C 5 0 alkyl which is interrupted by one or more — 〇—; 1 — adamantyl »2 — adamantyl 9 n — norbornyl 2 — methylbenzyl — C (— 0 ) R 1 2 or — A 9 R a and R 8 不 are unrelated to each other Η > C 1 — C 1 8 alkylphenyl t phenyl-C 1 — C 4 or 9 or via 1-3 C 1 — C 8 alkyl group> C j — C e alkoxy group 9 C 3 — C 6 alkenyl group * halogen i CF 3 substituted aryl group »R 9 is C 1 — C 1 8 radical 9 phenyl Or phenyl-C 1 — C 4 courtyard 9 R 1 0 is Η or — C Η 3 R 1 1 and R i 1 / unrelated to each other is C丄 One C 4 acryl or phenyl i or via one to three C 1 —C 8 acryl * C 1 — C 8 alkoxy i C 3 -C 8 oxyhalogen or trifluoromethyl substituted benzene The group% RI 2 is C * C 1 —C 1 8 alkyl > phenyl > phenyl — C 1 — C 4 alkyl C — C 1 环 cycloalkyl C 1 C 1 Z oxy * -23- --------- ^ ------ 1T ------. ^ (Please read the notes on the back before filling this page) This paper is fully compliant with Chinese National Standard (CNS) A4 Present (210X297 mm) A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (1 I phenoxy > Borneol — Σ — base »5 — Borneene — 2 monoyl or 1 — adamane 1 1 radical * 1 1 Please [R 3 is Η »C 1 — C 1 8 Yuan C 3 — C 1 8 Alkenyl 1 Benzene First Reading II Reading 1 I radical C 5 —CI ZZ Circumferential» C 3 — C 0 courtyard base j It consists of one back 1 I Or more — 0 — interrupted > phenyl > which is composed of up to three C 1 -Cyan 1 radicals! C 8 alkane * C 1 — C 8 oxy C 3 -C 8 enoxyl Halogen and then 1 or trifluoromethyl substituted phenyl > phenyl — C 1 — C 4 courtyard 9 2 — Fill out this 1 pack of adamantylbornyl or 2 —methylbornyl t Page 1 [ R 1 4 and R 1 5 are unrelated to each other Η C 1 — C 1 8 courtyard 1 IC 3-C 1 8 alkenyl C 6 — C 1 Z cycloalkyl 1 halogen 9 CF 3 1 1) phenylbenzene — C i — C 4 Integrative CNC 1 — C 1 S Alkan 1 — — (S (= 0) t-Phenyl ™ -S (= 0) t One or 1 | — 0 R 1 3 1 t [R 1 3 1 is a C 1 — C 1 3 group consisting of 0 Η C 1 CI 8 I 1 oxygen C — C 1 Z cyclooxyl C 3 — C 6 alkenyl halide 1 line> — C 0 0 R 1 3-C 0 N Η Z — C 0 Η Ν R 1 3 Z 1 | »— C 0 Ν (R 1 3 Z) (R 1 3 3) 1 I — N Η C 0 R 1 2 * one CN * — 0 C 0 RX 2 phenoxy 1 1 and / or phenoxy substituted C 1 — C 1 8 photo group This phenoxy group is composed of 1 1 C 1 — C 1 8 group < C 1 — C 1 8 oxy or halogen-substituted t 1 I or C 3 — C 1 8 alkenyl t C 6 — C 1 Zn cyclosynthetic radical> C 1 — 1 1 C 4 radical — and / Or — 0 C 0 R 1 Z — replaced by C 6 — C 1 Z 1 1 ring comprehensive base> C 3-C 3 〇 courtyard base t which is composed of one or more — 0 — so [1-2 4 ink 1 1 This paper size applies to China National Standards (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 413677 A7 B7 5. The invention description is interrupted, or may be 0H or 1 O — CORi 2 substituted; benzyl, phenyl — Ci — C4 alkyl, one COri 2 or —S 0 2 R 1 2;

Unrelated to Ri 3 2 and only 1 3 3 are Ci — Ci 2 alkyl, C 3 — Ci 2 alkoxyalkyl, C 4 — Ci 6 dialkylamino alkyl, or — Ci 2 cycloalkyl; or

Ri 3 2 and 1 ?! 3 3 — starting from C3 — C9 alkylene, C3 _C9 oxaalkylene or monoacrylanthrium; X is-NR8-,-0-,-NH (C ηΗ Zn η)-Ν Η -Or -0- (CkH2k)-Ν Η-; k is a number from 2 to 4; 1 is a number from 0 to 19; m is a number from 2 to 8; η is a number from 0 to 4 P is a number from ◦ to 10; Q is a number from 1 to 8; r is a number from 0 to 18; t is 0, 1 or 2. The equivalent polymer under K is a stabilizer of formula (Id). An example of this group is as defined in the compound of formula (I) above. Among the polymerized UV absorbers of formula I d · Particularly advantageous compounds are those obtained from the polymerization of compounds of formula I d, -2 5-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) } I --------- ^ ------ 1T ------ # (Please read the notes on the back before filling out this page) A7 B7 V. Description of the invention (A) CH2 OA \ CH,

CH where R i is 2 CH I \ JCH2) m

CK 2 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs -C Η 2-C f = C Η 2) -Rio,-(CH 2) p- S i R ii R ii,-CH = CH 2, -C ( = 0}-(CH z) q-CH = CHz, -CHR a-(CH 2) r- C (= 0)-O-CH 2-CH (OH)-CH z-0 A * ~ CR 8 R ar ~ (CH 2) I-C (= ◦) — XA or -C (= 0)-0-CH 2-C (= CH z) -Ri〇, and if Ex or £: 2 is a form of Is s group (Derived from bis (2-hydroxyphenyl) triazine or tris (2-hydroxyphenyl) triazine), Ri also includes ~ C Η 2 — CH (XA) — C Η 2 — 0 — R 7,- CR8Rb /-(CHz) 1-XA > -CH2-CH (0 A)-R 9, -CH 2-CH (OH)-CH 2 — XA; and in the case where £! Is a group group of formula I f Where R2 and 4 are not hydrogen> R i also includes: -C Η 2-CH (XA)-CH 2-0-R 7 · ~ CR 8 R 8 7-(CH 2) 1-XA > -CH 2 -CH (0 A)-R 9, -2 6-Binding line (please read the precautions on the back before filling in this K) This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 413675 A7 B7 five 、 Explanation (彳)- C Η 2-C H (OH) — CHz-XA or A; especially those where

OA

-(c Η 2) p- S i R! 1 R t 1 '-CH = CH z, -CHR 8 — (CH z) r — C (= 0) — 0-CH z — CH (OH)-CH 2-0 A > —CRs R 8 — (CH 2) 1 — C (= 〇)-XA or -C (= 0)-0-CH 2-C (= CH 2) -Ri〇, and if E i or E2 is a group basis of the formula I g, Ri can additionally include: -C Η 2-C (= CH 2) -Ri〇, -c (= 0)-(CH 2) q- CH = CH 2,- CH 2-CH (XA)-CH 2-0-R 7, CRs R 8 r-(CH 2) 1- XA * -CH 2-CH {0 A)-R 9, -CH 2-CH (OH) — CH2-XA; and in the case where Ei is a formula I f, where R2 and Ri 4 are not hydrogen * R, it also includes ~ CH z ~ CH (XA) — CH 2 — 0 — R 7 1-CR 8 R 8 ,-(CH 2) 1- XA * -2 7- This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) --------- Approved clothing ------ IT- -----. ^ (Please read the notes on the back before filling out this page) Printed by the Consumers' Cooperation Department of the Central Bureau of Standards of the Ministry of Economic Affairs 413677 A7 B7 V. Description of the Invention (Long Time) — C Η 2 一 C Η (0 A) — R 9 *-C Η Zn — C Η (〇Η) C Η 2 —XA or —A. Among these compounds, t is particularly preferred in which E 1 is — a compound of formula I f and EZ is — 1 of a group of formula I g (derived white bis (2-hydroxyphenyl) azine ) C This novel polymeric compound is prepared by the addition polymerization of at least one compound of formula (Ih) or at least one compound of formula (Ih) and at least another ethylene-containing unsaturated compound:

I -------- install ------ order ------ m (Please read the precautions on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A Yes- C (= 0)-CRs = CH-R6, and R i is independent of -C Η 2-C Η (0 A)-C Η 2-0-R 7 -CHR 8-(CH 2) 1- 0 A * -CH 2-CH (0 A)-R 9,

-C H 2-C H (OH) ~ C E z-0 A _ 2 8 _ This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 413677 A7 B7

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs — C Η 2 a ct = C Η ZJ — R 1 0 > — (C Η 2) p -si 1 R]! JR 1 J /-) C] Λ: = C Η 2 »— C (= 0) — (C Η ζ) q--C Η: = C] Η 2» — C Η R δ — (c Η 2) r--C (= 0) -0- -C Η 2-C Η f 0 Η) — c Η ZO — 〇A or — C (= 0) — 0 — C Η ζ — C (= C Η 2) — R 1 0 y R 2 and R ζ / Irrelevant are Η 1-0 Η i-0 A * C 1-C 1 2 alkyl) cyclohexyl > C 3-C 6 alkenyl t C 1-C 1 η oxygen 4 C ζ — ci 8 alkenyloxy »halogen > phenyl or difluorinated methyl > R 3 and R 3 are mutually exclusive Η J — 0 Η 9 — 〇A * — 0 R 1 tc 1 — C 1 ζ Radical 9 cyclohexyl »C 3 — C 6 alkenyl C 1-c 1 8 alkoxy t C 3 — C 1 8 alkenyl y dentin t difluoromethylphenyl * phenoxy) benzyl — C 1 — C 4 Rhenylphenyl — C 1 —c 4 xe? WC oxygen 9 — C Ν, C 1-C 1 e Yuan Jiyi S (= 0) t--or phenyl--S (= 0) t 1 R 4 »R 4 / and R 4 ft are independent of each other Η C 1 CIZ Yuan Ji r C 3-c 6 Alkenyl) C 1 — C 1 8 Alkoxy i C 3 — C 1 3 Alkenyl halogen > Difluoromethyl 9 phenyl 1 phenoxy f phenyl — C 1-C 4 alkyl, mono — To two — CI — C 4 courtyard — substituted phenyl — C 1 — c 4 courtyard> phenyl one C 1 — C 4 oxygen 9 -29- j .: t ...... ^ Water order. ~ Line (please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 size (210X297 mm) Printed by A7 B7 of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Description of the invention (4) —CN'Ci-Ci; alkyl—S (= 0) t—or phenyl-S (= 0) t-;

Rs is Η '-CH2 — COORi 3, Ci-C4 courtyard or -C N;

Fie is H, —COORi 3, Ci — Ci 7 or a phenyl group; Ruler 7 is 〇1 — C, 8 alkyl, cyclohexyl, C3 — Ci s; alkenyl, phenyl, through one to three! A C3 alkyl, Ci — C6 alkoxy * C3 — C3 alkenyloxy, halogen or methyl trifluoride, phenyl — Ci — C4 alkyl or — C (= 0) ~ R12 substituted phenyl,

Rs is Η or Ci — Ci 6 焼;

Rs is <: 1-Ci 8 alkyl, benzyl or phenyl-Ci -C 4 alkyl j

Ri〇 is Η or · ~ CH3 >

Ri] and Ri: 'are unrelated to each other Ci—C4 alkyl or phenyl, or via one to three (: 1 — Cs alkyl * Ci — Ce alkyloxy, C3 — CS alkenyloxy, halogen or trifluoro Methyl substituted phenyl;

Rl 2 is Ci — Ci 3 complex, Cz _c! S dilute or phenyl; Ri3 is H, Ci monoalkyl, C3 — Ci3 alkenyl or phenyl; 1 is a number from 0 to 19; p is a Numbers from ◦ to 10; q is a number from 1 to 8; r is a number from 0 to 18; -30 ™ This paper size applies to China National Standard (CNS) A4 (210X297 mm) I batch This order line (read the precautions on the back before filling in this page) A7 B7 CH printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs,

V. Description of the invention (> ΐ

-CHRe-(C Η 2) rC (= 0)-0-C Η 2-CH (OH)-C Η 2 —OA; particularly preferred are: ~ CH z-CH (0 A) — CH z — 0 — R 7, —CHR a — (CH z) 1 — OA, -CHz-CH (OA)-R9 », -ch2 or —CHRs — (CH 2) r — C (= 〇) —0 — CH ^ CH (OH)-CH2 — 〇A; and the best are: -C Η 2-CH (OA)-CHz-O- R7, -31- The paper size is applicable to China National Standard (CNS) A4 (210X297 mm) ) Thread (please read the notes on the back before filling this page) 413677 A7 B7 V. Description of the invention (3C) -CHR 8-(C Η 2) 1-〇 A * -C Η 2-C Η (Ο AJ -Rs or

The R2 printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is preferably H'Ci_C4 alkyl, C3 alkenyl, F, C1 or phenyl; particularly preferred is H, _CH3 or C1; and the most preferred is Η Or —C Η 3. Rz 'is preferably mono-OH, Ci-c4 alkoxy or c3η-oxy; especially Ci-C2 alkoxy or mono-OH. R3 and R3 'are preferably H, 10H, 10Ri, -0Ri3 !, Ci-C4 alkyl, cyclohexyl, C3 alkenyl, F, C1, methyl trifluoride, benzene * Benzyl or _CN; particularly preferred is Η ·-0 Η--0 R i--C Η 3, C,-alkoxy, C2-Cs alkoxy, mono-substituted C2 _Ci s alkoxy Group, C3 alkenyloxy, F * C1, benzyl, benzyloxy or CM; and particularly preferred are fluorene, -0H, -ORi >-C Η3, Ci -Cl2 alkoxy, Cl , Phenyl or -CN. R3 'is often an OH, an OR; or an OR13 1 * and R 3 does not include _ 0 R i. R 4-R 4, and R4 " preferably fluorene, Ci-C4 alkyl, C3 alkenyl, Ci-04 alkoxy < C3 alkenoxy, F, C1 -32- (Please read the back first Note: Please fill in this page again.) This paper size is applicable to China National Standards (CNS) A4 (210X2W mm). Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Α7 Β7. 5. Description of the invention (y). Group, phenyl group, phenyl-Ci-C3 alkyl group, or CN; particularly preferred are H, a CH3, C3 alkenyl group, a 0CH3 · C3 alkenyloxy group, F, C1, and a benzyl-C3 alkyl group Or -CN; and particularly preferred is tritium or a CH3.

Rs is preferably tritium or a CH3. R6 is preferably H, -COORl3, -CHs or phenyl; and particularly preferably fluorene or -C C3. R7 is preferably a Ci-Cs alkyl group, a cyclohexyl group, a C3-Cs dilute group * phenyl group, and a phenyl group substituted through one to three C1-C4 alkyl groups or a C1-C4 alkoxy group or a benzyl group. And particularly preferred are: (i_c8 alkyl, cyclohexyl, C3 alkenyl, phenyl or benzyl.

Rs and Rs' are preferably (irrelevant to each other) fluorene, or Ci-C6 alkyl. R! 〇 is preferably hydrogen.

Ri 1 and Ri 1 'independently of each other are preferably Ci-C4 alkyl or phenyl, especially methyl. X is preferably a 0—or a NR3—particularly an oxygen atom. The value of the index 1 is preferably 1_15. Preferred compounds of the formula (Id) are: where R i is unrelated to -C Η 2-C Η {XA)-C Η z ~ Ο-R 7, -CR8R8 /-(CHz) 1-XA >- 3 3- This paper size applies to China National Standard (CNS) A4 (210X297 mm) --------- ¾ ------ IT! ---- ^ (Please read the note on the back first Please fill in this page for matters) __b7 V. Description of Invention (^) d

Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs or — C Η R a (C Η Z) r--C (= 0)-(D--C Η 2-C Η (0 Η)-C Η 2 — 0 A ϊ R Zn is Η ic 1 — C 4 alkenyl jc 3 alkenyl > F, C 1 t or phenyl% R ZZ t is c 1 — C 4 hexyloxy 3 alkenyl t — 0 A » — 0 — C 0 R 1 2 or — 0 Η IR 3 and R 3 t are unrelated to each other: Η 一 〇Η * — 〇R 1-〇R 1 3 1 9 C 1 — C 4 alkyl group »cyclohexyl C 3 Alkenyl JF y C 1) Methyl trifluoride 1 benzyl »benzyl» or — CN * R 4 / and R 4 // 相关 9 C 1 — C 4 alkenyl C 3 alkenyl $ C 1 — C 4 oxo> C 3 alkoxy 9 FC 1 »Digassed methylbenzyl» phenyl — C 1 — C 3 oxo or — C Ν 9 R 5 is Η or — C Η 3 9 R 6 is Η — C 0 0 R 1 3 τ — C Η 3 or phenyl 9 R 7 is C i — C 8 cyclohexyl t C 3 — C 3 alkenylbenzyl »via Benzyl or benzyl substituted by one to three C 1 —C 4 M groups or CI — C 4 alkoxy groups »R 8 and R 8 / unrelated to each other are fluorene or C 1 — C 1 8 group 4 R 9 Yes C 1 — C 1 0 Alkenyl phenyl or benzyl * RIZ Yes Η »C 1 — ™ CI 8 alkyl t phenyl J phenyl — C 1 — 34 — (Please read the notes on the back before filling (This page) This paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 413677 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (A) C 4 alkyl or cyclohexyl; Ri 3 is ^ :! —C4 alkyl, C3 alkenyl, cyclohexyl, phenyl—Ci—C4 alkyl or phenyl; R 4, 14 and 15 are unrelated to each other ^ 1, 卩, 〇1 ≪: 1-C4 alkoxy, CF3, phenyl, 01 ^ or 01-C8 alkyl; R 1 3 1 is <: 1- (318 alkyl, C3-Cl8 alkyl, which is via OH 'Ci — C! 8 alkoxy * Cs — (: 12 cycloalkoxy'-C 0 0 R 1 3--C 0 N Η 2 >-C 0 Η NR 1 3 ζ' —CON t R 1 3 2) (R i 3 3), -NH C 0 R 1 2, —CN, — OC〇R12 and / or phenoxy substituted I or C3 alkenyl, Cs-Ci 2 cycloalkyl; C3_C5 〇 alkyl * which is via one or more -0-interrupted * or substituted via 0Η or 0_C0Rl2; benzyl, phenyl-Ci_C4 alkyl, -CORl2 or -SOzRiz; X is _0- or-NRe —; 1 is a from 1 to 1 A number of 9; and r is a number from 0 to 1 ◦. A particularly preferred polymer is a polymer containing units of formula I d, where A is -C (= ◦)-CR 5 = C Η-R 6; R! The unrelated ones are: —C Η 2 — CH (0 A) — C Η 2 — Ο — R 7 * -C Η ζ-C Η (0 A)-R 9, -3 5-(Please read the precautions on the back before filling this page). Installation.,-° The size of this paper is in accordance with Chinese National Standard (CNS) A4 (210X297 mm > printed by Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs 413677 a? B7 V. Description of invention (祌)

Or -CHRs- (C H z) 1- 0 A;

Rz is _CH3 ·-0 CH 3, C3 alkenyloxy or Cl; R 2 'is H; R3 is H, — CH3' Ci-C4 alkoxy, C3 alkenoxy, F, C1, benzyl * benzyl Methoxy, or CN; only 3 'is _0 卩 1 or 〇Ri3 1; R 4, Ri 4 · and Ri 5 are mutually exclusive Η 1 F * C 1, phenyl, CH * 0CH3 Or CH3; R * 'and R4 不 are unrelated to each other, Η, a CH3 * C3 alkenyl, -0C Η3, alkenyloxy, F, C1, phenyl-C3 alkyl or -C Ν;

Rs is Η or --CHs >

Rs is fluorene or mono-CH3; only 7 is (: 1-C8 alkyl, cyclopentyl, cyclohexyl, C3 alkenyl, benzyl or benzyl; R8 is fluorene or Ci-CiS alkyl; only 9 is 〇1 — C10 alkyl or phenyl;

Ri 2 is (31-Ci 8 alkyl, phenyl or cyclohexyl;

Ri3! Is 〇3 — cl8 alkyl or alkyl, -3 6-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) --------- Disease --- --- 1T ------. ^ (Please read the notes on the back before filling out this page) 413677 A7 B7 V. Description of the Invention (8) 0H * Phenoxy, one NHCOR! 2 and / or one OCORI 2 substituted C3-Cl8 alkyl groups; and 1 is a number from 1 to 19; the most special is that: A is -C (= 0)-CR5 = CH-Re; R i are unrelated to each other: -CH z-C Η (0 A)-C Η 2-0-R 7, —C Η 2 — C Η (0 A) — R a, CH〇

Printed by the Employees 'Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs R 2 is H or c H 3; R 2' is-◦ H; R 3 is H, a CH3; C1 or phenyl; 1? 3 is _〇1? 1 or _0Ri3 1; R4 is Η or CH3; R 4 'R 4 ^' Rl4 and R1S are fi; R s is H or -C Η 3; R 6 is Η; R 7 is Ci-C 8 alkyl; Rg It is Ci-Ci 〇 Yuanji; -3 7-I Correction Thread (please read the precautions on the back before filling this page) This paper size adopts China National Standard (CNS) A4 specification (210X297 mm) 413677 5 Description of the invention

Ri 2 is Ci—C8 courtyard foundation;

Rl 3 i is a C3-Cl8 radical or a C3-CiS alkyl substituted by an OCORt 2; and 1 is a number from 1 to 10. Particularly preferred compounds of formula (Id) are those in which at least one of R3 and R3 'is -0R !. The invention further relates to a novel polymer comprising a unit of formula (I d), wherein E! Conforms to formula I f and E3 conforms to formula I g. Among these, particularly preferred compounds are compounds having mixed substituents, in which neither Rs nor Rs' is an ORi; in particular, where R2 'is 0H and R3' is Ci-Ci 8 焼 oxy or by a 0- Or-OCOR: 2 C2-Ci B alkoxy group interrupted, and / or it is substituted with -C, 8 alkoxy group or C5 -Ci 2 cycloalkoxy group, where Ri 2 is 匚! _Ci 8 alkyl, phenyl, benzyl ~ Ci _C4 alkyl or C5 —Ci 2 cycloalkyl, especially those in which 1 is —CR8 R8 '-(C Η 2) 1-XA. Printed by the Central Bureau of Standards, Ministry of Economic Affairs and Consumer Cooperatives (please read the notes on the back before filling out this page) Both homopolymers and copolymers are suitable, where the copolymer can be different from at least two formulas (Id) A compound (structural unit), or at least one compound of the formula I d) and another comonomer (containing an ethylene unsaturated compound) are established. The compounds of the formula I can also be used for the preparation of novel homopolymers and copolymers. 0 It is of particular technical interest to polymer compounds obtained from the copolymerization of at least two different compounds of the formula (Id). -38- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 4136V7 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (d) Other suitable comonomers (different from the formula (I d) compounds) of the common army), including acrylic acid, methacrylic acid, acrylates, methacrylates, acrylamide, methacrylamidine, ethylene_, styrene derivatives. Derivatives of methacrylonitrile, vinylpyrrolidine, vinylpyrrolidine, and derivatives containing vinyl unsaturated sterically hindered amines' 2 ~ (2 one-diameter basic group) Benzobier * 2 — Benzobenzene Moe and stereo phenol. Of particular importance is the use of other copolymerization stabilizers, such as derivatives containing vinyl unsaturated sterically hindered amines (HALS), 2- (2'-hydroxyphenyl) benzotriazole, 2-hydroxybenzobenzo Or sterically hindered phenol c- In addition to at least one unit of the compound of formula I d, this copolymer contains other comonomers, and it can be used as a light stabilizer. The ratio of these other comonomers: It is preferably as high as 10: 1, especially between 1: 1 and 5: 1. Relative HAL S that can be used as a comonomer is generally characterized by having the following formula where 3 free valences are saturated with fluorene or an organic substituent * and this molecule contains at least one polymerizable, ethylene unsaturated difluorene; relative The compounds are described in US-A-4, 942,238; 1154-4,983,737 and £? 4-0,634,399, and the references cited therein. 39- This paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm)- --------- ^ ------ 1Τ ------. ^ (Please read the notes on the back before filling this page)

Structural unit: 4i3bV7 A7 B7 V. Description of the invention (4 Relative 2 which can be used as a co-monomer 2 — (2 ^ monohydroxyphenyl) benzotriazole is generally a structural unit with the formula: where 4® free valence Is saturated by hydrazone or an organic substituent, and the molecule contains at least one polymerizable, ethylene unsaturated double bond; the relative compound is described in

US-A- 5, 0 9 9, 0 2 7; US-A-4,528,311; Research Disclosure 32,592, U S- A-4,8 9 2, 9 1 5; US-A-4, 611,061; EP-A -0, 5 0 8,7 4 4; US-A- 5, 2 3 4, 8 0 7; US-A- 5,3 7 2,92 2; JP-A- 03,85 4 7; EP- A-0,343,996; US-A-4, 7 1 6, 2 3 4; US-A-5,256,359; JP-A-03,139,590; GB-A-2,232,667; US-A-5 s 1 4 7, 9 0 2, US-A-4, 7 8 5, 0 6 3; EP-A- 0, 1 9 0, 0 0 3; US-A- 3, 4 9 3, 5 3 9; US-A- 5,385, 8 1 5; EP-A-0,431,868; EP-A-0,282,294; EP-A- 0, 1 3 3, 1 6 4; EP-A- 0,1 3 1, 4 68, J. IIIII i ϋ ί-^ (Please read the notes on the back before filling out this page) Printed by Shellfish Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs

among them

Hacromol. Sc i., Pure App1. Chen. A 3 0 (9-10), 7 4 1 (1993) and Polym. Bull · 12 (5), 375 (1984), and references cited therein. Relative 2-hydroxybenzophenones that can be used as comonomers are generally characterized by structural units of the following formula: -40 The size of the paper method is applicable to Chinese National Standard (CNS) A4 specifications (2! 0X297 mm) 413677 A7 B7 Five 2. Description of the invention (q Free q is saturated with Η or an organic substituent, and this molecule contains at least one polymerizable, ethylene unsaturated double bond; the relative compounds are described in dB_383,001 and CH-B-376,899, and their contents References. Relatively sterically hindered phenols that can be used as comonomers are generally characterized by structural units of the following formula

Among them, the 3 饱和 free bond is saturated by an organic substituent, and the molecule contains at least one polymerizable 'ethylene unsaturated double bond. Usually the substituent is in the opposite position to the hydroxyl group, and the compound is described in US-A-3,708, 52Q and references cited therein. Other comonomers (different from comonomers of compounds of formula (I d)) are better than (please read the notes on the back before filling out this page). The compounds of formula (II) (VII) below are: Printed by the Central Bureau of Work Consumer Cooperatives

H is H or Η Η C is 1 is X) 1x7C 8 9 R c〇-ί I _ 1 ί 1 its R-RRNRC 9, I 1 group} " alkane 7ν41 ί c R or _; (_ 1 Nc occ ο

X

2 R

2 Η C

Z Rοο C 3 c H 1 c 4i c or, 1 group 2 alkane R a0 c ◦ Ic 11 c c is substituted by 1 2 alkane 4c alkane ring Zn s c o

R 0 II / Vc 1 z Hc-z \ lf- 3 Hc

Η C The size of this paper is applicable to Chinese National Standard 隼 (CNS) A4 (2S0X297 mm) 413677 V. Description of the invention (π) 3 Η c / V c Ζ Η c

Μ 3ο S z H c or Μ 3ο s

c H. is o 2 R 2 c alkane 8 1 c '8 in the alkyl radical 1 original C ο-2 C poly' or alkane 8 by 1 is its c (please read the note on the back first Please fill in this page again) or H o and 2 H c

Substitute Μ 3 ο S

F z H c c2 H c Ν C Ζ cz ccz H c 2 H c Νc 2 Η c 2 Η c Printed by HR c (i Η 2 NC Yes 1-1 c 6 2; I-based CR-based 2

Naphthalene or Alkyl Alkyl Alkyl Fund Benzene, 1 Alkyl Alkane C 4 I C 7 i C 1 X R ◦ ο C I Z

之 8 of C is taken as J; C-based | 2 alkane 1 X) ring C C I Z C or aryl alkylene

R

R is X y C is

C

F

Phenylbenzene or alkane 4 C

C-based phenylalkane

X R 〇 I ο C

NC Amine 1 or Η is M and __ belongs to C 1 or this paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) where R2 3 is Η or a CH3; R24 is H, a CR23 = C Η 2, -C (0) -phenyl or -S 0 3 M; and M is Η or 鹸 metal. A7 B7 V. Description of the Invention (P) s is a number from 1 to 5. (III) R 2 2-C (= 0)-〇- CH = CHz * where R 2 2 is Ci — Ci 9 alkyl or phenyl. (Ilia) R2 2a-O-CH = CH2, where 1 ^ 22 3 is 〇1-〇18 alkyl. 1 Order (Please read the notes on the back before filling this page)

CH.

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs where R 2 5 is Η or a C Η 3 0 (VI.) C Η 2 = CR 2 6-R ZZ 7 t where R 2 6 is Η > FI-C 1 Or -C Η 3 and R 2 7 are-C 1 >-Β Γ, -F or--C Ν. (V I I) -43- This paper size is applicable to China National Standard (CNS) A4 specification (210 × 297 mm) 413677 A7 B7 V. Description of invention (private)

Printed by the Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs, and the above polymerizable ethylene unsaturated sterically hindered amines (Η ALS) 2 — (2; —hydroxyphenyl) benzoxyl beer> 2-hydroxybenzobenone And sterically hindered phenol derivatives 0 Preferred comonomers of formula (II) — (VII) are: (II) R 1 8-C Η = C (R 1 7) — C f = 0) — X — R Z 0 where R 1 7 is Η »— C Η 3» — C Η 2 — C 0 0 R 2 1 or — CN, R 1 8 is Η t — C 0 0 R ZE 1 or — C Η 3 * R 1 9 is Η »C 1 — C 4 Comprehensive Foundation» — C (C Η 3) 2 — C Η 2-C (= 0) — C Η 3 »— C (C Η 3) Zn — C Η ZZ — S 0 3 Μ or — (C Η ζ) s--S 0 3 Μ; R 2 〇 is Η CJ-C 1 8 radical c 2 —C 3 0 alkyl which is interrupted by — · 0 or more 0 atoms I or — (C Η 2) S-S 0 3 Μ R 2 1 is Η t C 1 — C 1 3 Academic base »Phenyl or C 2 -C 1 8 alkenyl; M is fluorene or monobasic gold fluorene; -44- This paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm) ) Batch each order (please read the notes on the back before filling this page) 413677 A7 B7 V. Description of the invention (4) X is a 0-or —NRi 9 —; and s is a number from 1 to 5. (III) R z z ~ C (= 0)-0- CH = CHz, where 2 is 01-Ci s alkyl or phenyl. (II la) R2 2 a-0-CH = CH2, where R2 2 a is Ci-C8 alkyl. (I V) ch2

Where i? 2 3 is H or mono-CH3; R24 is H, -CR23 = C H 2 *-C (0) —phenyl or —S 0 3 Μ; and Μ is fluorene or an alkali metal. (V) --------- ¢ ------ 1T ------. ^ (Please read the precautions on the back before filling out this page} Staff Consumer Cooperatives, Central Procurement Bureau, Ministry of Economic Affairs Printed ch2

Where R2 5 is Η or — CH3. (VI) -4 5-This paper size applies to China National Standard (CNS) A4 ^ grid (2I0X297 mm) 4136V7 A7 B7 V. Description of the invention (4) CH2 = CRz 6-CN-where Rzs is Η or CH3. (VII)

Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economics. The possible definition of the substituents on formula (I I)-(VI I) is as defined in the compounds of formula (I) and (I d) above. When any of the substituents in the above formula is an alkyl group and contains up to 18 carbon atoms and is interrupted by one or more 0 atoms, an example of I is-(C Η 2 — C Η 2 — Ο) 1 _ 8 — C Η 3,-(C Η 2 — C Η 2 — 0) 1—8 — C 2 Η5 or one (CH2 — CHz-CH2 — 〇) 1 — s — C Η 3 0 When the group is alkali gold, it is Li > Na or K. Particularly preferred other comonomers (different from comonomers of compounds of formula (Id)) are compounds of formulae (I I)-(IV) and (VI I). The preferred copolymers are products obtained by polymerizing at least one compound of the preferred formula (I d) and at least one comonomer of the formula (I I)-(VI I). Particularly preferred are copolymers obtained by polymerizing at least one particularly preferred compound of formula (Id) and at least one comonomer of formula (I I)-(IV) or (VI I). The best is obtained by polymerizing at least one compound of the best formula (Id) 4 6 — --------- ^ ------ 1T ------. ^ (Please read first Note on the back, please fill out this page again) This paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) A7 B7 5. Description of invention (M) and at least formula (II) one (IV) or (VI I ) Co-monomer copolymer, where:

Ri ·? Is Η or a CH3;

Ri8 is Η or —CH3; Rule 19 is ^, 〇1_〇4 alkyl, -c (C Η 3) 2-C Η 2-S 0 3 Μ or-(C Η 2) s-S Ο 3 Μ ;

Rzo is H, Ci—C8 alkyl, or C2-Czo alkyl, which is interrupted by one or more 0 atoms; R2 2 is —CH3; only 2 2 3 is (31—04 alkyl; R23 and Rz4 are Η; Μ is H, Li, Na or K; X is —〇 一 or NRi g —; and s is a number of 2 or 3. Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs (Please Read the precautions on the back before filling this page) The compounds of formula (I) or (Id) are conventional or can be prepared by conventional methods. The reaction mechanism shown below shows two steps (a + b) from three Single resorcinol derivatization method for preparing compounds of formula (I) or (I d). Compounds derived from bis- or tris resorcinol can also be prepared in a similar manner. Other more detailed preparation methods See EP-A-0,4 3 4,6 0 8 〇a) Alkylation of resorcinol to mono-OH group (from, for example, cyclopropoxy ether or ω-bromo alcohol):- 4 7- This paper size is in accordance with China National Standard (CNS) A4 specification (210 × 2? 7 mm) 413677

V. Description of the invention (A A7 B7

Ar

+ RO-CH2-CH-CH,

OH

Ar

0-CHrCH (OH) -CH2-〇R (Ar = substituted or unsubstituted phenyl; R = as alkyl)

Μ

Br- (CH2) r〇H I binding yarn (Please read the precautions on the back before filling this page)

OH Central Cooperative Bureau of Ministry of Economic Affairs

Ar

〇- (CH2) -OH

Ar = substituted or unsubstituted phenyl; i = 1-2 0) -48- This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) A7 B7

+ CH2 = CRrC (= 0) Cl 413677 V. Description of the invention (β b) Fatty OH-based acrylic or methacrylated Ar

Ar

(Ar = substituted or unsubstituted phenyl; R = as alkyl; Ri Η or a C Η 3) I -------- 装 ------ ΪΤ ------ ^ (Please read the notes on the back before filling out this page)

+ CH2 = CRrC (= 0) Cl

0- (CH2): 0H

Ar

O ^ CH ^ O-Ci ^ -CR ^^ -4 9-

Ar

The size of the paper method is applicable to China National Standards (CNS) A4 (210X297 mm). Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. Phenyl; i = i_2C);] Ri = Η or -C Η 3) When triazineresorcinol of the formula is the starting compound:

Ar

It can be prepared by conventional methods or similar methods (EP-A-0,434,608; H. Brunetti and CE · Luthi, Helv. Chini. Acta 5 5, 1 5 6 6 (1 9 7 2); EP -A-0,577,559; GB-A-884,802) ° Polymerization reaction (addition polymerization) of monomer compounds of formula (Id) can be initiated by free radicals, cations, and anionic initiators. Preferred free radical initiators, which will decompose into free radicals when heated, such as organic peroxides or hydrogen peroxide, azo hydrazones or peroxidation catalysts. Polymerization can also be initiated by high energy irradiation. Polymerization can also be carried out in a solution, emulsion, dispersion or in the matrix. The method is familiar to those who are skilled in this skill. Suitable polymerization methods are described in EP-A-0, 577,122, page 9, line 46 to page 10, line 35. An example of a compound of formula (I) is shown below: -50- This paper applies the Chinese National Standard {CNS) A4 (210x297). II III Kunyi III Thread (please read the precautions on the back before filling This page) A7 Printed by the Shellfish Consumer Cooperative of the Central Bureau of Samples of the Ministry of Economic Affairs 413677 B7 V. Description of the invention (θ)

Number L i · L 3 -51- ---------- ^ ------ 1T ------ ^ (Please read the precautions on the back before filling this page) The paper size Use Chinese National Standard (CNS) A4 (210 X 297 mm) A7 B7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (π) (2 0 2) -CH2 -CHiCHz -0-n -C4 H9)-0-G (0) -CH = CH2 (207) Li = n-C6 Hi 3, L3 =-(CHz) ii -0-C (0) -C (CH3) = CH2 (208) Li =-(CH2),! -0-C (0) -CH3, L3 =-(CHz) i 1-OC (0) -C (CH3) = gh2

Number (3 0 0) -CHZ -CH (CH2 -0-n-C4 H9)-0-C (0) -CH = CHz (n-C4 H9; n-butyl) -52- This paper is for China National Standard (CNS) A4 specification (210X297 mm) I -------- installation ------ order ------ line (please read the precautions on the back before filling this page) 413677 V. Description of the invention (d A7 B7

CH number

H3C

L 3

ό (Please read the notes on the back before filling in this tile).

2 Η -c c

'1T Printed by the Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs 9

'L3 ό Line Tiger

L

3 L This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Description of the invention (η) (5 0 0) -CH2 -CH (CH2 -0-n-C4 H9)-0- C (0) -CH = CH2 (5 0 1)-CH of -CH (CH 2-0-n-C 4 H 9)-0-C (0)-C (CH 3) CHZ (5 0 2)-(CHz) ii -OC (0) -C (CH3) = CH2 (503) -CH2 -CH (Positive-C4 H9) -0-C (0) -C (Cfh) = CH2 (5G4) = Positive -Ce Hi 3, L3 =-(CHz i -0-C (0) -C (CH3) = CHz

CH (505) -ch2—CH2 (506) Li = positive -Ce Hi 3, L3 ^-(CHz) ii _〇-C (0) -CH = ch2 (507) -CH2 -CH (OH) -CH2- OC (0) -C (CH3) = CH2 In addition to the examples of comonomers of formula (Id), there are the following compounds: I -------- ^ ------ 1T- -----. ^ (Please read the notes on the back before filling this page)

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

-54- The size of this paper is applicable to China Solid Standard (CNS) A4 (210X297 mm). Printed by the Consumers' Cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs. CH (CH2 -0-n-C4 H9) -0-C (0) -CH = CH2 (n-c4 h9, n-butyl) π 01) -ch2 -ch (ch2 -ο-n-c4 η9) -0-C (0) -c (CK3) = ch2 (102)-(CHz) 1 1 -0-C (0) -CH = CH2 (103)-(CHz) 1 .-oc (0) -C (CH3) = CHz (104) -CH2 -CH (Positive-C4 H9) -0-C (0) -C (CH3) = CH2 (106) -CH2 -CH2 -0 ~ C (0) -C (CH3 ) = CH2

Cl

No. (200) -ch2 -ch2 -oc (0) -ch = ch2 -55- This paper size applies to Shen Guo National Ladder Standard (0 Yang) 6 4 specifications (210 father 297 mm) ------- --β ------ IT ------ 0 (Please read the precautions on the back before filling this page) V. Description of the invention (from) A7 B7

Number L 1, L 3 (201) -ch2 -CHz " 0 ™ C (0) ~ c (ch3) = ch2 (2 0 3)-(CHz) 1 1 -oc (0) -CH = CH2 (2 0 4)-(CHe) 1 1 -oc (0) -c (ch3) -ch2 (2 0 5) -C Η 2 -CH (positive-C4 H9) -0-C (0) -c (ch3) = chz (2 0 6) -CHz _CH (positive-C4 H9) -0-C (0) -ch = ch2 I -------- install --------- 1T ------ m (Please read the notes on the back before filling out this page)

Quick-use Chinese National Standard (CNS) A4 size (210X297 mm) of this paper scale 0 2)-(CHz) ι 1 -0-C {= 0) -C (CH3) = CH2 ch3

--------- ¢ ------ IT ------. ^ (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (4 0 0) -ch2 -ch (ch2 -0-positive-c4) -0-C (0) -c (ch3) = ch2 (401)-(CHz) ii -OC (= 0) -CH = CHz (402)-(CHz) ii -0-C (= 0) -C (CHs) = CH2 (4 0 3) -CH2 -CH (Positive-C4 H9) -0-C (O) -C (CH3) = CH2 -57- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) Central Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Standards Bureau 413677 A7 B7 V. Description of the invention (0) (4 0 4) -CHz -CHz -0-C (0) -C (CH3) = CHz It is prepared from the compound of formula (I d) Examples of polymers are as follows: (600) Homopolymer of compound (204) (60 1) Copolymer of compound (204) and n-butyl acrylate, molar ratio of 1: 4 (602) compound (207) Homopolymer (603) Compound (207) and n-butyl acrylate copolymer, with a molar ratio of 1: 4 (604) Homopolymer (605) Compound (504) Compound ( Copolymer of 504) and n-butyl acrylic acid, with a molar ratio of 1 ·· 4 (606) Compound (204) and n-dodecyl methacrylic acid Copolymer of esters with a molar ratio of 1: 4 (607) Homopolymer (608) of compound (102) with a copolymer of compound (102) and n-butyl acrylate with a molar ratio of 1: 4 (609 ) Homopolymer (6 10) of compound (402) Copolymer of compound (402) and n-butyl acrylate, with a molar ratio of 1: 2 (61 1) Homopolymer (6 12 of compound) (103) ) Copolymerization of compound (103) and n-butyl acrylate -58- ---------------------------------. ^ (Please read the notes on the back before filling out this page) This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 413677 a7 B7 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Explanation () 1 1 1 Molar ratio is 1 2 [1 (6 1 3) homopolymer of ib compound (4 0 0) Please 1 1 (6 1 4) compound (4 0 0) and n-butyl Copolymerization of Acrylic Acrylic Ester 1 Read 1 I 1 I The ratio of ears is 1 2 Back 1 I 1 (6 1 5) Compound (1 0 5) and n-butyl acrylate copolymer 1 Matte ratio of I It is a copolymer of 4 1 (6 1 6) compound (4 0 5) and n-butyl acrylate. The content of mole ratio is 1 2 0 1 1 In addition to the above-mentioned novel copolymers, the formula ( I) The compound can be converted into 1 by copolymerization It is added to the polymer made from ethylene hydration and unsaturated carbohydrates. 1 1 1 This itb includes the following monomers such as acrylic acid, acrylic acid, acrylic acid, acrylic acid, and acrylic acid and acrylic acid. Amine t Acrylonitrile benzene 1 | Ethylene α — methylstyrene butadiene m isoprene maleic acid 1 I anhydride »maleic acid ester 9 m Amine and imine vinyl chloride ethylene chloride 1 1 substance, vinyl acetate, vinyl butyral vinyl ether and N-vinylpyridine, 1-ketoconone, 0 is preferably added to m or uglyamine styrene or acrylonitrile from acrylic methacrylic acid or 1 | methacrylic acid The prepared polymer 1 in I 0 These polymers can be prepared from one or more of these military bodies C unsaturated 1 1 and the addition of a compound of formula (I) can be carried out during polymerization such copolymerization 1 1 Happen together 1 | Polymerization can be initiated by a free radical cation or anionic initiator 1 | 〇 is preferably a free radical initiator 9 which decomposes after adding 1 1W to form a free radical t 1 I such as an organic peroxide or hydrogenation Peroxide azo compound or oxidation m 1 1-59-1 1 皋 Paper thickness is applicable to China Solid State Standard (CNS) A4 specification (210X297 mm) 413677 A7 B7 I 'V. Description of the invention (β) Media. Polymerization can also be initiated by high-energy rays, such as radiation-hardenable surface coatings (UV-hardenable or ESR-hardenable). In this case, the copolymerizable hydroxyphenyl ~ s-triazine is added to the coating substrate during film formation. Particularly suitable for this copolymerization reaction is group-transfer polymerization. One of the "living" polymers is formed using a specific initiator. A initiator suitable for this purpose is used. The gardenia is 1-trimethylsiloxy-1_alkoxy_2-methylpropene. Group-based transformation polymerization methods have been known for many years and have been described in, for example, U S-A-4, 6 9 5, 6 0 6 and U S-A-4, 4 1 4, 3 7 2. The polymerization can be carried out in solution, emulsion, dispersion or in a precursor. Compounds of formula (I) which are suitable for copolymerization condensation reaction or copolymerization multiplication reaction, especially those containing two fluorene functional groups. If only a small amount of the compound of formula (I) is added by means of polycondensation or polyaddition, suitable compounds of formula (I) are those compounds containing only one functional group: 0, functional, difunctional or trifunctional The compound of the formula (I) can be added to, for example, polyester, polyetherester, polyamide, polyurethane, polycarbonate, epoxy resin * phenol resin, melamine resin or alkyd resin. This person can prepare the gel using methods known to those skilled in the art. Wire or multiply polymer added. Addition reaction can also occur in oligomerization or polymerization intermediates, such as * • 6 0 * This paper size is applicable to China National Standard Car (CNS) A4 specification (210X297 mm)] | I 111 crack_ ^ 11 II Order n (Please read the notes on the back before filling this page) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Consumer Cooperation Du Yinye 413677 A7 B7 Printed by the Central Bureau of the Ministry of Economic Affairs of the Beihai Consumer Cooperatives V. Description of Invention () 1 1 1 Unsaturated compound of formula (I) and other ethylene compounds can be added to the unsaturated 1 1 I polyresin and its mixture after adding ms free radical initiator to harden the other. ) Functional group combination tree reaction * Read 1 1 Read 1 1 and this product is then hardened with an epoxy hardener 0 and formula (I) Back surface 1 | 1 of 0 Η A functional compound can react with melamine resin Then the result is injected into the hormone 1 lipid Matter 1 compound M added acrylic hardened 0 item and then 1 It is also possible to add a precursor to polyurethane before the final resin hardening Fill in this 1 Pack I ethyl phenol resin or alkyd resin 0 The TTrit of these resins is also May occur with acid or page 1 | m-type catalysts without affecting m triazine compounds 〇1 I Other additions may include the reaction of a compound of formula (I) and a polymer containing 1 [with appropriate functional groups. These can be, for example Polymer C containing hydroxy carboxyl 1-anhydride amine epoxy or isomethyl ester. Examples are copolymers of acrylic acid and methacrylic acid. A total of 1 1 polymer rings of hydroxyalkyl (meth) acrylate. The copolymer of oxypropyl (meth) acrylate is partially hydrogenated.  Poly \ 1 Ethylene Acetate or Ethylene-Ethylene Acetate Copolymer Partially esterified m-dimensional 1-rayon partially hydrogenated polyalkyl (meth) acrylate containing a reactive terminal 1 I group of polyester or poly Urethane maleic acid) maleic anhydride 1 I or maleic acid T m epoxy resin or copolymer or samaridine Λ 1 1 compound of formula (I) suitable for this reaction Are those compounds that contain ~ _ functional groups that can react with polymer 1 [% functional groups. This xtb can be > e.g. hydroxyl 1 I »carboxylate * amine 9 epoxide or isocyanate if 9 1 I is desired such as t Through, the method of the compound of formula (I) is modified-a 1 1 polymer containing 0 Η groups can be used, for example *-containing at least isoepoxide 1 1-6 1-1 1 This paper size applies Chinese national standards ( CNS) Regulation A4 (210 × 297 mm) Loss Bureau of Standards portion printed consumer cooperative staff A7 B7 V. invention described compound (In) thereof, carboxyl or ester group of the formula (I). The epoxy-containing polymer can react with, for example, a compound of formula (I) containing at least one hydroxyl, carboxyl or amine group. Copolymers of maleic anhydride can react with, for example, a compound of formula (I) containing a hydroxy, amine or epoxy group. These reactions can be carried out using a homogeneous reaction of a perylene polymer. This reaction is preferably carried out in a solution. It is also possible to react all functional groups of the polymer or some of its functional groups * depending on the child of the compound of formula (I) used. The following examples will further illustrate these reactions. One particular method of addition to polymers is the grafting of ethylene-containing unsaturated derivates of formula (I) onto hydrocarbon polymers. Compounds of formula (I) containing ethylene-containing unsaturated groups have been defined in detail. Hydrocarbon polymers can be saturated or unsaturated. The former include polyolefins, such as polyethylene * polypropylene, polybutene, and polyisobutylene. The latter include diene polymers and their copolymers with olefins * such as polybutadiene, polyisoprene, propylene-butadiene and ethylene-propylene-butadiene. It is preferred that the grafting is performed on polyolefin, especially on polyethylene. The grafting reaction can be performed in a solution or a precursor. The catalyst used is a radical-forming agent> homopolymerization of this unsaturated compound Reactions or copolymerizations are also useful. All these methods of adding formula (I) to polymers can be performed using a relatively small amount of triazine, for example, from 0.  0 5 to 5% by weight (based on modified polymer). These amounts make the polymer resistive to damage caused by light, gas, and heat, because of the migration or elution of the stabilizer -62- This paper size applies the Chinese National Standard (CNS) A4 standard (210X297 mm) I.  IH ^ 衣 n ^ I n, ^ (Please read the notes on the back before filling out this page) A7 413677 _ B7 V. Description of the invention (η >), so this cannot be missed. For this purpose, it is better to Add 0.1 · 3 to 3% by weight of the compound of formula (I). However, this method can also be used to add a large amount of triazine, for example, from 5 to 50% by weight (based on the modified polymer). If it is desired to use If the polymer modified in this way is used as a polymerization stabilizer, this amount is appropriate. These polymer spikes can be added to organic substances, especially S!] Are organic polymers. However, polymer stabilizers It can also be applied to plastic molds as a thin protective layer, such as by means of dissolution or co-extrusion, which is described in, for example, US-A-4,676,870. Other applications of this method are the addition formula (I ) Compounds into polymer microparticles. EP-A-0, 226,538 describes the addition of light spikes to microparticles via copolymerization and multiplication reactions or copolymerization condensation reactions. These particles can be used as a dispersion layer for coatings. In this case From 0 · 1 to 30% by weight A compound of formula (I), preferably from 0.5 to 10% by weight (calculated based on the modified polymer), is added to the microparticles. Adding humans to the microparticles can be advantageously performed by using a group-based conversion polymerization method As described in EP-A-0, 2 9 3, 8 7 1. The Central Government Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, printed the present invention is also limited to a polymer modified by the above method, which comprises a formula (I) Compounds are chemically bonded in amounts as described above * so that they can be set by spikes to resist damage from light, oxygen, and heat. The novel stabilizers of Formula I and Formula d, and polymers modified in accordance with the present invention can behave as though铳 Polymer technology can neutralize various additive mixtures. Jg Some additives can be scaler or processing co-ribs or colorants or other additives. -63- This paper size is applicable to China National Standard (CNS) A Vision grid (210 × 2ί »7mm) 413677 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the Invention (6 ^) 1 1 | Examples are the following additives 1 I 1 Elephant antioxidants 1 1 Please I 1 * 1 Synthesize monophenol 9 For example 2 > 6 — Di-tert-butyl — 4 Read 1 I Read II — Methyl 2 — Butyl 4 6 — Dimethyl m > 2 > 6 ~ two back 1 1 1 t-butyl- 4-n-butylphenol 2 6-di-tert-butyl 1 4 bet 1 thing 1 monoethylphenol 2 9 6-di-t Monobutyl-4 monoisobutylphenol * 2 r item and then 16 6-dicyclopentyl-4 methyl phenol 2 — (α-methylcyclohexyl) — fill in this 1 Pack I 4 > 6 Dimethyl Phenol 9 2 6 —octacosyl-4 monomethylphenol> Page 1 | 2 4 6 dicyclohexylphenol 2 6 —di-tert-butyl-4 4-II methoxymethyl m 2 ♦ 6 bis—nonyl — 4 monomethylphenol 2 4 1 1 dimethyl — 6 — (1 9 — methylundecane 1 — yl) m 2 1 order 4 dimethyl 6 — ( 1-A Heptadecane-1 -yl) phenol 2 1 I 4 -di-methyl-6-(1 f -methyldeca-Γ-1 t -yl) 1 | phenol and mixtures thereof 0 1 1 1 2 sulfur Methylmethylphenols such as 2 4 dioctylthiomethyl — 1-line 6 — tert-butylphenol 2 4 —dioctylthiomethyl — 6 * 1 methylphenol t 1! 2 4 — dioctylthio Methyl — 6 — ethylphenol 2 6 1212 1 | Nodhithiomethyl — 4 — Nonylphenol σ 1 1 1 3 Hydroquinone and its hydroquinone hydroquinone * For example 2 6 One 1 1 di-tert-butyl-1 4-methoxyphenol 2 5-di-tert-butyl hydroquinone j 2 > 5-di-tert-amyl hydroquinone 2 6- Di-1 1-phenyl-1, 4-octadecyloxy m 2 6-di-tert-butyl-terephthalene 1 i Phenol 9 2 P 5 — di-tert-butyl- 4-hydroxyanisole 3 t 5 — 1 1-64-1 1 paper iron Degree Applicable to China National Standard (CNS) A4 (210X297 mm) 413677 a? Β7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the Invention (d) Di-tert-butyl-1-4-hydroxyphenyl _ 4-Hydroxyphenyl) 1 * 4 · Tocopherol Tocopherol, 5-Hydroxy-1 · 5, Hydroxy-tert-butyl_ 4), 4, 4 * 4, 4 'Monothiobis (3,6 -Di-dimethyl-1 4-1 '6. Alkylbisbutyl 4-methyl-4 -ethylphenol) ct monomethylcyclohexyl 6 -cyclohexylphenol) based phenol), 2,2 * 2,2, -ethyl 2'-ethylidene bis ( 'Monomethylbis [6,2'_methylbisphenol], 4,4 * ^ β -methyl 4-hydroxyanisole y 3 stearate t bis-(3 adipate 0 t for example ta — Tocopherols tocopherols and mixtures of them (retinolide diphenyl ethers such as »-methylphenol)» 2 t 2 '-thiobis (6-tert-butyl (6-tert- 2 -methyl- sec-pentyl) Phenol) 1 4 Hydroxyphenyl) Disulfide 0 Phenol> For example »2 7 2 β Phenol) > 2» 2 * — Methyl 2 2 9 — Methylbis) Phenol> JS 2 t 2 9 — j 2 % 2 >-Methylene double, — Methyl double 4 »6 Fork double (4 t 6 — Di-6 — tert-butyl — 4 — — (α —methylthyl) r 6 — (a 9 α -Dimethylidene (2 S 6 bis (6-tert-butyl 65, 5-di-tert-butyl, 5-di-tert-butyl, / 5-tocopherol, 7-fat) Ε). 2,2'-thiobis (6'-thiobis (4-octyl-3-methylphenol), phenol), 4,4, -sulfur, 4'-bis (2,6--methyl Bis (6-tert-mono-bis (6-tert-butyl) [4-methyl-6- (methyl-bis (4-methyl- (6-nonyl-4-methyl-12-tert-butyl Phenol) tert-butyl phenol), 2 | isobutyl phenol), 2/2 — 4 —nonyl riding], 2 methyl benzyl) _4 monononyl 1,2 —butyl butyl — — 2 —methyl Base phenol), 1 (Please read the notes on the back before filling in this page} This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 413677 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Description of the invention (ψψ) I 1 | 4 1 — Jianbi (5 mono-tert-butyl — 4 — hydroxy — 2 —methylphenyl) butyl 1 1] 焼 »2 > 6 — bis (3 — tert-butyl — 5 — methyl — 2 monohydroxybenzyl 1 1 group) 4 methylphenol »1 1» 3 monoTT (5 monot-butyl_ 4 Read first 1 | read 1 | — hydroxyl — 2 — methylphenyl) butane * 1 1 — bis (5 — tert-butane 1 1 — 1 — hydroxy — 2 monomethylphenyl) — 3 — η — dodecanyl hydrogen Sulfur Attention 1 I butylated ethylene diether bis C 3 3 —bis (3 —tert-butyl — 4 matters again 1 1 > monohydroxyphenyl) butyrate bis (3 —tert-butyl — 4 — Hydroxy fill in this 1 Pack I — 5 — Methyl — phenyl) Dirutf m Pentylene C 2 mono (3 f — tert-butyl ^^ 1 | radical 2 t — hydroxy — 5 > — methylbenzyl ) — 6 — tert-butyl — 4 1 [— methylphenyl) p-ester 1 1 — bis — (3 5 — dimethyl 1 1 — 2 — hydroxybenzyl) butan 2 2 — bis — (3 5 — di-tert. 1 order — butyl — 4 — hydroxyphenyl) propane 2 2 — bis — f 5 — tert. — 1 I butyl — 4 — hydroxy — 2 — methylphenyl) — 4 — η — dodecanyl hydrogen 1 I thiobutane 1 1 5 5 Tetra- (5-tert-butyl-4-1 1 hydroxy 2-methylphenyl) pentylbenzene 1 line 1 7 0 — • Ν — and S — methyl compound 1 such as 3 5 t 1 | 3, 5 t — tetra-tert-butyl — 4 4 9 — dihydroxy-dibenzoyl 1 I-based ether octadecyl — 4 — hydroxy — 3 5 — dimethylbenzyl hydrogen sulfur t 1 based acetate Tris- (3 5 -di-tert-butyl- 4 -hydroxybenzyl 1 1 yl) amine bis (4 -tert-butyl- 3 -hydroxy- 2-6 »dimethyl 1 I -benzyl methyl) di Thio-p-peptide S bis (3 5 —di-tert-butyl 1 | 4-hydroxybenzyl) sulfide) isooctyl — 3 »5 di-tert-but 1 1 — 4 — Hydroxybenzyl hydrothioacetate 0 1 1-66-1 1 The paper size of the table is applicable to the Chinese National Standard (CNS) A4 (210X297 mm). Printed by the Consumer Cooperative of the Central Procurement Bureau of the Ministry of Economic Affairs 413677 at B7 5 ,invention Ming (β) 1 · 8 'hydroxybenzyl malonate * Example octacosyl-2 * 2 -bis (3,5-di-tert-butyl-2-hydroxybenzyl ) —Malonate * 218 octadecyl _2 — (3-sylobutyl-4 — hydroxy-5 —methylbenzyl) monomalonate, dodecyl hydrosulfide Ethyl-2,2-bis- (3,5-di-tert-butyl-1,4-benzylbenzyl) malonate, bis- [4-a (1 * 1, 3, 3_tetra Methylbutyl) phenyl] -2,2-bis (3,5-di-t-butyl-4-hydroxybenzyl) malonate. 1 · 9 · Aromatic hydroxybenzyl compounds · For example 1, 3, 5-tris- (3, 5-di-tert-butyl-4 4-hydroxybenzylmethyl) -2, 4, 6-trimethyl Phenylbenzene, 1,4-bis (3, di-tert-butyl_4-hydroxybenzyl) _2,3,5,6-tetramethylbenzene, 2,4 * 6-tris- (3,5 —Di-tert-butyl-4-hydroxybenzyl) phenol 0 1.  1 0 · Triazine compounds, such as 2,4-bis (octylhydrosulfanyl) -6-(3,5_di-tert-butyl-4-hydroxybenzylamino) -1,3,5-tris Azine, 2-octylhydrosulfanyl-4,6-bis (3,5-t-tert-butyl-4-hydroxy-aniline) -1,3,5-triazine, 2-octylhydrosulfide -4,6—bis (3,5-di-tert-butyl-4-hydroxybenzyloxy) -1,3,5-triazine, 2,4,6-di (3 * 5-di— Tert-butyl-4-benzylphenoxy) -1, 2,3-triazine, 1,3,5-tri- (3,5-di-tert-butyl-4-hydroxybenzyl) Isocyanurate, 1, 3, 5_ Trinity (-8 7-This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) I -------- ΐ 衣- ----- 1Τ ------ ^ (Please read the precautions on the back before filling out this page) 413677 A7 B7 Printed by the staff of the Central Bureau of Standards, Ministry of Economic Affairs, Consumer Consumption Du V. Invention Description () 1 1 I 4 — tert-butyl — 3 — hydroxy — 2, 6 — — — methylbenzyl) iso1 1 cyanuric acid m 2 »4 t 6 _ Di (3 > 5 — di-tert-butyl 4 1 | please 1 — hydroxyphenylethyl) — 1 3 5 — triazine 7 1 f 3% 5 — read first 1 1 read 1 1-(3 1 5 — Di-tert-butyl — 4 monohydroxybenzylpropanyl) — — Hydrogen on the back 1 I 1 — 1 3 5 — Diazine 1 3 5 — Tri — (3 5 — Bicyclic Note f: 1 thing 1 Hexyl — 4 — hydroxybenzyl) isocyanurate 0 item 1 1 * 1 1 ♦ benzyl phosphonates such as dimethyl — 2 5 — two one fill in this 1 I tert-butyl one 4 — Hydroxybenzylmethylphosphonic acid diethyl — 3 5 — di-page 1 I — tert-butyl — 4 — hydroxybenzyl phosphonate octadecyl 3 5 1 | -di-tert-butyl — 4 monohydroxybenzyl phosphonate octadecyl 1 1 5 — tert-butyl — 4 — hydroxy 3 — methylbenzyl — m acid m 3 1 order 5 — Di-tert-butyl-4 4-hydroxybenzyl-monoethyl ester of phosphonic acid 1 I Calcium 0 1 I 1 1 2 Aminoaminophenol 4-Hydroxystearate, aniline octyl — N — (3 5 — — 1 line — tert-butyl — 4 —hydroxyphenyl) carbamate 0 1 | 1 1 3 β — (3 * 5 — two — Tert-butyl — 4 —hydroxyphenyl 1 I) propanoic acid and mono- or poly-hydroalcohols m such as and methanol ethanol eighteen courtyard 1 1 alcohol 16 — hexanediol 1 »9 monononane di Ethylene dienzyme 1 1 1 2 — propanediol neopentyl glycol thiodiethylene diene diethylene 1 | endiol diethylene glycol f pentaerythritol tetrazolium i-tri- (hydroxyethyl) iso 1 cyanurate 9 Ν Ν t — bis (hydroxyethyl) ethylenediamine diamine 3 — thia 1 ί ten Jidrase 1 1 — thiopentadecanol 7 —.  Methylhexanediol __ · — Methyl alcohol 1 1-68-1 1 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 413677 at B7 Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Poly five, description of the invention (ι-Ί) 1 i I Bingyuan 4 — hydroxymethyl — 1 — m — 2 > 6 1 7 — —.  Oxybicyclo L 1 I 2 2 2 Octane 0 1 I Please I 1 1 4 β — (5 — tert-butyl — 4 — hydroxy — 3 — methylbenzene Read 1 1 Read 1 1 group) Propanoic acid and mono — Or esters of polyhydric alcohols such as »and methanol ethanol% eighteen back 1 of [alkanol 1, 6 — adipic acid J 1 9 mononon — diol ethylene two injection competition [事 1 alcohol 1 t 2 — Bingyuan Diol > neopentyl glycol thiodiethylene glycol, item I re j diethylene glycol, diethylene dienzyme t pentaerythritol tri- (hydroxyethyl filling 1 pack |) isocyanuric Ester N > N > — bis- (hydroxyethyl) ethylenediamine,-1 1 > 3-blind undecanol alcohol 3-thiopentadecanyl dimethyl hexanediase 1 I bis-methyl alcohol propionate 4 — hydroxymethyl — 1 monophosphate — 2 6 7 — 1 I-dioxodi Ring (2 2 2 J oct. 0 1 1 5 β 1 (3 5 —dicyclohexyl — 4- —hydroxyphenyl) propane 1 I acid and mono- or poly-hydrogenated 3CJ- esters such as and formazan Fermented ethanol stearyl alcohol »1 I 1 6 —Hexanediol 1 9-Nonanediol ethylene glycol 1 ♦ 1 1 2-Propanediol neopentyl di-fermentation thiodiethylene di-diethylenediol 1-line alcohol diethylmethane diol pentaerythritol di- (hydroxyethyl) isocyanurate 1 I acid ester N Ν t — bis (hydroxyethyl) ethylene diamine 3 — thiadecyl 1 | alcohol 3 — Warm pentadecanol dimethyl hexanedihalide dimethyl alcohol propion 1 1 ♦ 4-hydroxymethyl — 1 — m-2 6 9 7 — trioxodi rng ring Γ 2 1 1 • 2 * 2 Xinyuan 0 1 1 1 ♦ 1 6 * 3 5 — Di-tert-butyl — 4 monohydroxyphenylacetic acid 1 | and mono- or polyhydric alcohol esters such as and methanol ethanol stearyl alcohol 1 j 1 1 6 — hexanediase * 1 »9 — Nonanediol 1 Ethylene glycol t 1 2 — 1 1-63-1 1 This paper size applies to China National Standard (CNS) A4 (210X297 mm) Printed by A7, Consumer Cooperative of Central Standards Bureau, Ministry of Economic Affairs B7 V. Description of the invention (α) Propanediol * neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tetra-butyrate, tri- (hydroxyethyl) isocyanate Uric acid esters, N, N'-bis (hydroxy-ethyl) ethylenediaminediamine, 3-thiaundecanol, 3-thiopentadecanol, trimethylhexanediol, trimethyl fermentation Bingyuan, 4-hydroxymethyl- 1-phospho-2,6,7-trioxabicyclo [2,2 · 2] octane. 1 .  1-7, amines of reedi (3 * 5-di-tert-butyl-4-hydroxyphenyl) propanoic acid, such as N, bis (3,5-di-tert-butyl-4-hydroxy Phenyl propylene) hexamethylene diamine, N, Nf —bis (3,5-di-tert-butyl-4-hydroxyphenylpropanthionyl) trimethylenediamine * N * N * one bis (3,5 -Di-tert-butyl-4-hydroxy-phenylpropanyl) hydrazine · 1 · 18. Ascorbic acid (vitamin C) 1 ‘19. Amine antioxidants, for example, N, N'-di-isopropyl-P-phenylene diamine, N, N, -di-sec-butyl-p-phenylene diamine -N Ν, -bis (1 , 4-dimethylpentyl) -P-phenylenediamine> N, N'-bis (1-ethyl-3-methylpentyl) -ρ-phenylenediamine, N, Ny-bis (1-methylheptyl) _p —benzylidene diamine, NN / —dicyclohexyl —ρ —benzylidene diamine, N, -diphenyl — ρ —phenylene diamine, Ν, Ν′—bis ( 2-naphthyl) _ρ-phenylenediamine, N-isopropyl-N, monophenyl_ρ_benzylidene diamine, N- (1,3-dimethylbutyl) -N'-phenyl -ρ —Phenylenediamine, N — (1-methylheptyl) -N′-phenyl-E) —Phenylenediamine, N — -7 0-The paper size applies to Chinese National Standard (CNS) Μ Specifications (210 × 297 mm) ---------- Approval of clothes -------- Order ----- 0 (Please read the precautions on the back before filling this page) Central Standard of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperatives 413677 at B7 V. Description of the Invention (ti) Cyclohexyl-N'-phenyl-p-phenylenediamine, 4_ (p_toluenesulfonate) Dibenzylamine, N * Ν'-dimethyl-N, N'_di-sec-butyl-P-phenylene diamine, diphenylamine, N-allyl diphenylamine, 4 a Isopropoxydiphenylamine, N —phenyl — 1 pentylamine, N — (4-tert-octyl) — 1 —naphthylamine, N —phenyl — 2 —naphthylamine, Octylated diphenylamines, such as P, P'-di-tert-octyldiphenylamine, 4-n-butylaminophenol, 4-butylfluorenylaminophenol, 4-nononaminoaminophenol, 4-a Laurylaminophenol * 4 Octadecanylaminophenol * Bis (4-methoxyphenyl) amine, 2,6-di-tert-butyl_4-dimethylaminomethylphenol , 2,4'-diaminodiphenylmethane, 4,4'-diaminodiphenylmethane, N, N, N '* N'-tetramethyl-1 4 > 4'-diamine Diphenylmethane, 1,2-bis [(2-methylphenyl) amino] ethane, 1,2-bis (phenylamino) propane * (0-methylbenzyl) biguanide, Bis [4-mono (1 ', 3'-dimethylbutyl) phenyl] amine, tertiary mono-octylated N-benzyl_1-naphthylamine, mono- and dialkylated tertiary monobutyl Base / tert-octyl Mixtures of phenylamines, mixtures of mono- and dialkylated nonyldibenzylamines, mixtures of single and dialkylated dodecyldiphenylamines, mono- and dialkylated isopropyl groups / Isohexyldiphenylamine mixtures, single and dialkylated tert-butyldiphenylamine mixtures, 2 * 3-dihydro-3,3-dimethyl-4,4,1,4-benzyl Pyrazine * phenidazine, single and dialkylated tert-butyl / tert-octylphenothiazine mixture, mono- and dialkylated tert-octylphenothiazine mixture-allylphenoxazine * N, N, NV, N'— -7 1-This paper size applies to China National Standard (CNS) A4 (210X29 " 7 mm) I -------- ^ ------ ' Order ------ ^ (Please read the notes on the back before filling out this page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 413677 a7 B7 V. Description of the invention (π) Tetraphenyl_1, 4 12 Aminobutane-2, ene, N, N-bis (2,2,6,6-tetramethyl-piperidine-4-yl-hexamethylenediamine, bis (2,2,6,6-tetramethylene) Methylmorphine- 4-yl) sebacate, 2, 2 '6' 6 -tetramethyl Steep 4-fluorene, 2, 2, 6, 6, 6-tetramethyltonine-4-ferment 3 2-UV absorber and light stabilizer 2, 1 '2- (2, _hydroxyphenyl) benzotriazole Group, for example, 2- (2, -hydroxy-5'-methylbenzyl) -benzotriazolyl, 2_ (3 ', 5,1,2-tert-butyl-2'-hydroxyphenyl) benzene Benzotriazolyl, 2- (5, -tert-butyl- 2'-hydroxybenzyl) benzyltrisyl * 2 — (2, -hydroxy- 5 '-(1,1,3,3-tetra Methylbutyl) phenyl) benzotriazolyl, 2_ (3 *, 5'_di-tert-butyl- 2 'trimethylphenyl) -5-chloro-benzotritriyl, 2 -(3, 1-tert-butyl-2, 1-hydroxy-5'-methylphenyl) _5_chloro-benzotriazolyl, 2-(3'-sec-monobutyl-5, 1-tert-butyl Butyl- 2′-hydroxybenzyl) benzotriazolyl, 2- (2 J —hydroxy ~ 4′-octyloxyphenyl) benzotriazolyl, 2- (3′- 5′-di-tert-one Amyl-2'-hydroxyphenyl) benzotriazolyl, 2-(3 '* 5' one bis one (α, α -dimethylbenzyl) one 2, one hydroxyphenyl) benzotri Oxazolyl, 2_ (3'-tert-butyl-2'-hydroxy-5 '-(2-octyloxycarbonylethyl) phenyl) -5-chloro-benzotriazolyl, 2- (3, -tert-one Butyl-5,-[2-(2_ethylhexyloxy) -ethyl] _2 '—hydroxyphenyl)-5_ -7 2-This paper is in accordance with the Chinese National Standard (CNS) Α4 (210 X 297 mm) I -------- t ------ '1T ------' ^ (Please read the notes on the back before filling out this page) 413677 A7 B7 V. Description of the invention (7i) chloro-benzotriazolyl, 2- (3'-tert-butyl-2 -'- hydroxy-5 '-(2-methoxycarbonylethyl) phenyl)-5-chloro- Benzotriazolyl, 2- (3'-tert-butyl_2, monohydroxy-5 '-(2-methoxycarbonylethyl) phenyl) benzotriazolyl, 2-(3'- Tert-butyl- 2'-hydroxy-5 '-(2-octyl-oxycarbonylethyl) phenyl) benzotriazolyl, 2- (3'-tert-butyl-5'-[2 — ( 2-ethylhexyloxy) carbonylethyl] -2'-hydroxybenzyl) benzotriazolyl, 2-(3'dodecyl_2'_hydroxyl-5'monomethylbenzyl) benzyl And a triazolyl group, 2-(3, 1-tert-butyl-2'-hydroxy-5 '-(2-isooctyloxycarbonylethyl) phenylbenzotriazolyl 2,2 * ~ methylene-bis (4- ( 1,2,3,3 ~ tetramethylbutyl) -6-benzotriazolyl-2-ylphenol] mixture; 2-[3 * -tert-butyl-5 '-(2-methoxy Carbonylethyl) —2′-Hydroxymonophenyl] -2H —Bransylated product of benzotriazolyl and polyethylene glycol 300; [R — CH2 CHz — COO (CH 2) 3: where R = 3 'T-tert-butyl-4'-hydroxy-5'-2H-benzotriazolyl-2-ylphenyl. 2,2,2-Hydroxydibenone, for example, 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2,, 4'-trihydroxy and 2,1-hydroxy-4,4'-dimethoxy derivatives. 2 · 3 · Ester of substituted or unsubstituted benzoic acid, such as 4-tert-butyl-phenylsalicylate, phenylsalicylate | octylphenylsalicylate * -7 3- This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) --------- installation ----- 1T ------. ^ (Please read the notes on the reverse side before filling out this page) Printed by the Consumer Standards Department of the Central Bureau of Standards of the Ministry of Economic Affairs 413677 at Β7 Printed by the Consumer Standards of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China 5 、 Invention (lz) 1 1 | Dibenzidine metabenzidine * bis (4-tert-butylbenzidine) m-xylylene m 1 | t benzamidine m-phenylene m 9 2 i 4 _ di-tert-butylphenyl 3 5. . .  __.   1 I please I-tert-butyl-1-hydroxybenzoate > deca-alkyl3 > 5-di-read first 1 I read 1 I tert-butyl-4-hydroxybenzoate ten Octyl 3 t 5 —di-tert-back 1 I 1-butyl- 4-hydroxybenzylcarboxylic acid * 2 monomethyl — 4 i 6 —di-tertyl — butylphenyl 3 t 5 one two Mono-tert-butyl-4-hydroxy.  Benzoate matters 1 I refill 1 copy I 2 4 aromatic esters such as ethyl a — cyano — β β — diphenylpropanyl 1 I isooctyl aenoate — β β — two — Phenylacrylate * 1 I methyl a — 7 * W * carbomethoxycinnamate methyl α cyano — β 9 β — methyl 1 1 group — P monomethoxy — cinnamate butyl α — Cyano β β — methyl 1 order — P — methoxy — cinnamate methyl α — carbomethoxy — P — methoxy 1 i cinnamate and N — (β — carbomethoxy-1 β —cyanovinyl) —II 2 —methyl Q 1 1 2 5 Nickel compounds such as 2 2 t —thiomonobis — 4 — (1 line 1 1 3 * 3 — tetra-methylbutyl) phenol > M complex such as 1 1 1 1 or 1 2 with or without additional reactive groups like \ 1 I η —Butylamine * triethanolamine or η —cyclohexyldiethylamine —dibutyl 1 1 dithiocarbamate> 4 hydroxy — 3 * 5 — di-tert-butyl 1 1 butylphosphonic acid A single compound of nickel salt m such as methyl or ethyl T1M—mm oxime of nickel 1 1 complex 1 such as 2 —hydroxy — 4 —methylphenylundecylmoxime 1 — 1 1 phenyl — 4 — Laurel IC * r donkey — 5 — hydroxypyrazolyl nickel complex with or without 1 1 no additional reactive groups 0 1 1-7 4-1 1 This paper size applies to China National Standard (CNS) Α4 specifications (210 × 2? 7 mm) A7 413677 B7 V. Description of the invention (7¾) 2 · 6 · Sterically hindered amines, such as bis (2,2,6, S_tetramethyl-piperidinyl) decane Diesters, bis (2,2,6,6-tetramethyl-pyridinyl) succinate, bis (1,2,2,6 * 6-pentamethylimidinyl) sebacate , Bis (1,2,2,6,6-pentamethylmethylpyridinyl) η- Butyl-3, 5-di-tert-butyl-4 monohydroxybenzyl malonate, 1- (2-hydroxyethyl) -2, 2, 6, 6-tetramethyl-4 monohydroxy Concentrate of succinic acid * N, N 'a bis (2,2,6 * 6_tetramethyl-1,4-neosidyl) hexamethylene diamine and 4 a-tert-octylamino ~ 2, 6-dichloro-l, 3,5-triazine, tri- (2,2,6,6-tetramethyl-4-monomorphinyl) * four (2, 2, 6, 6-tetramethyl) —4 — # pyridyl) -1,2,3,4 monobutane-tetracarboxylic acid ester, 1,1 ′-(1,2-ethanediyl) bis (3,3,5,5 — Tetramethylapirazine hydrazone), 4-benzylhydrazone-2 * 2 * 6 * 6-tetramethylmethylpyridine, 4-stearylmethyloxy_2,2,6,6-tetramethylpiperidine , Bis (1,2,2,6,6—penta-methylbenzyl) —2—η—butyl—2— (2-hydroxy-1 3 * 5-di-tert-butylbenzyl) Malonate, 3-n-octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro [4,5] decane-2,4-di-2-, bis ( 1 — octyloxy-2, 2, 6, 6 Tetra-methyl # pyridyl) sebacate, bis (1-octyloxy-2,2,6,6-tetramethylpiperidinyl) succinate, N, N '— Bis (2,2 * 6,6 — tetramethyl-1_piperidinyl) hexamethylene diamine and 4_morpholino-2,6 -7 5- This paper size applies to Chinese National Standard (CNS) Α4 Specifications (210 × 297 mm) --------- ^ ------ 1T ------ 0 (Please read the precautions on the back before filling out this page) Employees of the Central Bureau of Standards, Ministry of Economic Affairs Printed by the cooperative 413677 A7 B7 V. Description of the invention (called)-Condensate of dichloro-1,3,5-triazine, 2-chloro-4, 6-bis (4-a-n-butyl-amino-a Concentrate of 2,2,6,6-tetramethylmethylpyridinyl) -1,3,5-triazine and 1,2-bis (3-aminopropylamino) -ethane, 2-chloro-1 4,6-Bis (4-n-butylhelyl-1 * 2,2,6,6-pentamethylnesanyl) _1,3 * 5-triazine and 1,2-bis- (3 —Aminopropylamino) ethane < 8-Ethylmethyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro [4 · 5] decane-2,4 -di 3-dodecyl- 1- (2,2,6,6-tetramethyl-4 4-ohidinyl) pyrrolidine-2,5-dihydrazone, 3-dodecyl-1- (1, 2,2,6,6-pentamethyl-4 imididinyl) pyrrolidine-2,5-di-4, hexadecyloxy and 4-octadecyloxy-2,2,6, A mixture of 6-tetramethylmorphine, N, N'-bis (2,2,6,6-tetramethyl-4-methylidinyl) hexamethylenediamine and 4-cyclohexylamino-2,6 —Dichloro-1,3 * 5-triamidine condensation product, 1,2-bis (3-aminopropylamino) ethane and 2, 4,6-trichloro-1,3,5— Condensation product of triazine and 4-butylamino-1,2,2,6,6-tetramethylnesine (C AS Reg. No. [136504-96-6]); N-(2, 2 * 6 , 6-tetramethyl-4 -pyridinyl) _n-dodecyl succinimide, N_ (1,2,2,6,6-pentamethyl_4 one ton) -n Dodecyl succinimide * 2 -undecyl_7 * 7,9,9_tetramethyl-1 2-ring eleven hospital base-1 1-oxa-3,8-di-p-Ya-4 4-oxospiro [4, 5: -7 6- This paper size applies Chinese National Standard i CNS) A4 specification (2I0X297 mm) gutter (please read the precautions on the back before filling this page) Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperation Du printed 413677 A7 B7 V. Description of invention (holes) Undecane and epichlorohydrin. 2 '7, ethylenedifluorenediamine, such as 4,4, -dioctyloxyoxoanilide, 2,2' -dioctyloxy-5,5 '-di-tert-butoxy-fluorene Tefaniline * 2,2,1,2 behenyloxy-1,5,5, _di_tert-butoxypanetilanilide, 2-ethoxy-2, _ethoxytinoline * N, N ' One bis (3-dimethylaminopropyl) ethylene diamine, 2-ethoxy-5-tert-butyl-1 2'_ethoxyfluorenil and its 2-ethoxy-2 ' -Ethyl-5,4'-di-tert-butoxyanilide aniline, and o- and m-methoxydisubstituted oxodianiline, and 0- and P-ethoxy One or two substituted oxotetanil. 2 8 · 2 — (2-alkylphenyl) -1,3.5-trichloro, such as 2,4,6-trione (2-hydroxy-4 4-octyloxy-phenyl) —1 * 3 * 5-triazine, 2_ (2-hydroxy-4 4-octyloxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2_ (2,4-dihydroxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2,4-bis (2-hydroxy-4_propane Phenyloxyphenyl) -6- (2,4-dimethylphenyl) -1,2,3,5-triazine, 2- (2-hydroxy-4-octyloxyphenyl) -4,6 —Bis (4-methylbenzyl) -1,3 * 5-triazine, 2- (2-hydroxy-1—dodecyl-oxyphenyl) —4,6-bis (2,4— Dimethylbenzyl) _1 * 3,5-triazine'2-[2-Hydroxy-4_ (2-Hydroxy-3 ~ butyloxy-propoxy) phenyl]-4 * 6-Bis (2, 4 —Dimethyl) —1, 3 * -7 7-The paper scale is applicable to China National Standard (CNS) A4 (210X 297 mm) I -------- ¢ ------ Order ------. ^ (Please read the back first Please fill in this note!) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 413677 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () 1 1 I 5 — hydrazine t 2 — r 2 — Hydroxy-4 — (2 — hydroxy — 3 -octyl 1 I oxy monopropyloxy) phenyl j — 4 > 6 bis (2 t 4 dimethyl 1 I please I) — 1 9 3 t 5 — hydrazine 2 — r 4 — (12 dodecyloxy / thirteen first read 1 I read 1 | oxydo 2 — hydroxypropoxy) — 2 — hydroxy — phenyl — 4 1 6 handle 1 r No. 1 Bis (2 > 4 Dimethylphenyl) — 1 1 3 > 5 — Triazine t 2 Yiyi 1 i < L 2 —Hydroxy-4 — (2 -Hydroxy — 3 Dodecanyloxy_propoxy matters 1 I then I) Phenyl] — 4 > 6 —Bis (2 $ 4 — Dimethylbenzyl Group) — 1 t 3 Fill in this 1 Pack II 5 — Triazine 2 — (2 —Hydroxy-4 monohexyloxy) Phenyl-4, Page 1 | 6 — Diphenyl — 1 9 3 * 5 Triazine i 2 — (2 -hydroxyl 4 — 1 I methoxybenzyl) — 4 t 6 —diphenyl-1 3 5 —triazine 2 1 1 ί 4 6 —diC 2 —hydroxyl — 4 — (3 — Butoxy — 2 — hydroxy 1 — — propoxy) benzyl] 1 1 3 5 monotriazine 2 — (2 ~ hydroxy 1 I benzyl) — 4 — (4 — methoxyphenyl) — 6 benzene — 1 3 > 1 I 5 —diazine 〇1 1 3 Au deactivator such as NN, —Diphenylethylenediamine diamine * 1 Line N —Salicyl — N f-Salicylhydrazine NN * — Bis (salicylamine 1 I group) hydrazine N »N * — bis (3 1 5 — two Tert-butyl- 4 -hydroxyl 1 phenylphenyl-propanium) hydrazone 3-salicylamino-1 9 2 t 4 — — 1 1 azole * bis (benzylidene) ethylene dihydrazine-m hydrazine 9 Dimethylhydrazine 1 Dimethylaniline 1 1 »Isopropylpyridinyl dihydrazine sebacic acid_diphenyl hydrazine f N 9 N 1 — 1 1 — ethylmethanehexamethylene dihydrazine t N > N f — Bis (salicylm * r-fluorenyl) ethyl 1 1 dim dihydrazine NN — Bis (salicyl) monothiopropylhydrazine 1 1 hydrazine 0 1 1-78-1 1 This paper is for China National Standards (CNS) A4 specifications (2 丨 0X297 mm) A7 B7 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention () 1 1 I 4 • Phosphorous acid m and phosphonic acid monitoring Example— ^ 1 · Phenylphosphonium phosphonium 9. Phenyl sulfonium 1 1 I methylene sulfite * Phenyl diammonium phosphite basket _ (Shinyphenyl) Methylene 1 I Please I Phosphate f Trilauryl m acid 馥 »rr — octadecyl phosphite union» two first read 1 1 read [I stearyl pentaerythritol tetramethylene diphosphite m 9 three — (2 4 one t-tert-back I 1 1 D Phenyl) phosphorous acid m 9 diisodecyl pentaerythritol tetraphosphite diphosphite mt 1 1 bis (2 t 4 —di-tert-butyl penyl) pentaerythritol diphosphite matter 1 [Re I Blue Bis (2 6 1-tert-butyl-4-methylbenzyl) — Wuchi fill in the book 1 pack 1 tetrabutyl alcohol diphosphite m »diisodecyloxy pentaerythritol di Phosphite M Page 1 1 1 Bis (2 4 12-tert-butyl-6-methylphenyl) Penta-butane 1 1 Tetraol diphosphine bis (2 4 6 — — — (tert-butyl Phenylbenzyl 1 1) pentaerythritol tetrabenzyl I ^ K m acid tristearate sorbitol triphosphite m 1 order > four (2 4 one two-tert-butyl Phenyl) 4 7 4 t —biphenylene 1 I diphosphonic acid m 6 —isooctyloxy— 2 4 8 ί 1 0—tetrayl 1 1 I monobutyl— 1 2 fluorene — diphenyl [dg ] — 1 3 2 —dioxophosphate 1 1 > 6 —fluoro — 2 1 4 8 1 0 — tetra —t-butyl — 1 2 methyl 1 linear — monobenzene Γ dg]-1 t 3 > 2 dioxo 9 bis (2 9 4 1 | — di-tert-butyl-6-methylphenyl) methyl phosphite bis (2 i 1 i 9 4 — di-tert-butyl-6 — Methylphenyl) Ethylphosphite 0 1 1 5 Hydroxylamines «For example» NN — Dibenzylhydroxylamine t NN — Di 1 1 Ethylhydroxylamine t N, N — Octylhydroxylamine > N * N-Dilauryl 1 I Hydroxylamine j Ν Ν C Di-C 14) Alkyl Hydroxylamine * N > N 1- (1 I | Deca-.L alkyl) Hydroxylamine »N * N — Di (De Octyl) Hydroxylamine »N 1 1 — Decadecyl — N Octadecyl Hydroxylamine> N — Heptadecyl — N — 1 1 7 9-1 1 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 413677 Α7 ____ Β7 V. Description of the Invention (Deng) 18 Alkylhydroxylamine, N-dialkylhydroxylamine from helium tallowamine, 6 'nitrone, for example, N-benzyl-α-phenylmononitrate, N-ethyl-ct_methylmononitrate Ketones, N—octyl-α ~ heptyl-nitrone, N—lauryl-ct-undecyl-nitridine, N—tetradecyl-α—tridecyl-nitro-, N—deca Hexadecyl — α — fifteen yards — nitrate, N — octadecyl — ct — heptadecyl — nitrate — hexadecyl — α — heptadecyl — nitrone, N — octadecyl Alkyl ~ α-pentadecyl mononitrazine, N-heptadecyl-α-heptadecyl-nitrone, N-octadecyl-ct hexadecyl-nitrone, derived from hydrogenation Nitrogen of tallowamine N, N ~ dialkylhydroxylamine. 7. Thio synergists, for example, dilaurylthiodipropionate or distearylthiopropionate. 8 Peroxide cleaners, such as esters of 0-thiodipropionic acid, such as lauryl, stearyl, tetradecyl or tridecyl. Hydrothiobenzimidazolyl or 2-hydrothiobenzene Zinc sulfonium of imidazole, zinc dibutyl dithiocarbamate, octacosyl disulfide, five erythridine tetrazolium four (0-dodecyl sulfanyl) propionate. 9. Polyamine stabilizers', e.g., net salts in combination with iodide and / or phosphorus compounds, and blues of divalent manganese. 10. Basic co-M agents, for example, melamine 'polyvinylpyrrolidone, dicyandiamide, tri-allyl hydrazone, urea derivatives, hydrazine derivatives, amine 1 polyamine, polyamine Urethane * higher fatty acid alkali metal or ochre gold tin toilet -80- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) ---------- pack ---- --Order ------ line (please read the precautions on the back before filling in this f) 413677 A7 B7_ V. Description of invention (rf), for example, calcium stearate, zinc stearate, adipic acid Magnesium, Magnesium Stearate, Sodium Metate and Potassium Hexadecite * Antimony pyrocatechuate or tin pyrocatechuate. 1 1 Nucleic acid agents, for example, inorganic substances * like talc, metal oxides, like titanium oxide or magnesium oxide, preferably alkaline earth metals, phosphates, 1 carbonate, or rhenium sulfate; organic compounds, such as mono- or polycarboxylic acids, and Toiletries, such as 4-butylated benzylmethyl, adipic acid, diphenylacetic acid, sodium succinate, or sodium benzoate; polymeric compounds, such as ionic copolymers (ionoiers). 1 2 · Fillers and reinforcements, such as calcium carbonate * silicic acid, glass fiber, asbestos • talc, high-sensitivity clay | mica, barium sulfate, gold oxides and hydroxides, carbon black, graphite, wood powder and or Powder or Tongwei of other natural products, synthetic fibers. 1 3 _Other additives, such as plasticizers, lubricants, emulsifiers, colorants, flow additives, catalysts, flow control agents, optical brighteners | fire retardants, antistatic agents and blowing agents (blowing agents) . 1 4 Benzofuranone and indole 例如 For example, described in ϋ S- A-4,3 2 5, 8 6 3; US-A- 4, 3 3 8, 2 4 4, ϋ S- A- 5, 1 7 5, 3 1 3; US-A- 5, 2 1 6, 0 5 2, US-A-5, 2 5 2, 6 4 3, DE-A-4, 3 1 6, B 1 1; DE-A- 4, 3 1 6,6 2 2; DE-A-4, 3 1 6,8 7 6; EP-A-0, 58 9,8 3 9 or EP-AG, 5 9 1 , 10 2 or 3- [4- (2-eth-oxyethoxy) phenyl] -5,7-di-tert-butyl-benzofuran-2-one, J3, 7-di- Tert-butyl-3-[4-mono (2-stearyloxyethoxy) benzyl] benzofuran 2-ketone, 3,3'-bis [5,7-di-δ 1 -benzyl Paper size applies Chinese National Standard {CNS) A4 specification (210X297 mm) I -------- 1 ------ 1T ------ ^ (Please read the notes on the back before filling Ben K) Printed by the Central Bureau of Standards, Ministry of Economic Affairs and Consumer Cooperatives 413677 at _ B7_ — V. Description of the Invention (π) — tert-butyl- 3_ (4-[2_hydroxyethoxy] phenyl) Furan-2 —one] '5' 7 ~ Di-tert-butyl-1 3- (4-ethoxyphenyl) benzofuran_2 ~ one. 3 — (4 —Ethyloxy-3, 5-dimethylphenyl) -5,7-di-tert-butyl-benzofuran-2-one, 3_ (3 '5 ~ dimethyl-4 4-trimethylacetoxy) -5 , 7-Di-tert-butyl-benzfurfuran_2_ 嗣. It is even better to add sterically hindered amines (the 2nd 6th additives mentioned above), as these provide the most effective photo-characterization for the modified polymer. 1: 1 If the additive is a spike stabilizer The amount added is from 0.05 to 5% by weight. In other embodiments of the invention, in addition to the compound of formula (I), other stabilizers are added to the polymer. It is particularly advantageous to add other sterically choline amines * Depending on whether the sterically hindered amine used contains an ethylene unsaturated group or other functional groups, the addition can occur in a co-condensation reaction or co-multiplication reaction, or with appropriate functionality Base polymer reaction. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back to fill in this note). The sterilization of sterilized amidine containing ethylene unsaturated groups and suitable for the copolymerization reaction of the present invention is 2, 2 Acrylic and methacrylic acid derivatives of 1,6,6-tetramethylimidine are described in US-A-3,7Q5,166 and their N-alkyl and N-alkoxy derivatives. Other tetramethylpiperidine copolymerizable derivatives are described in U S-A-4, 2 1 0, 6 1 2 and E P-A-0, 3 8 9, 4 2 0. Examples of sterically hindered amines capable of reacting with functional polymers are those compounds containing a diatomyl group, such as 2, 2 1 6, 6 -tetramethyl-1? 8 2-This paper is in accordance with China National Standards (CNS) ) A4 size (210X297mm) 413677 A7 B7 Printed by the Consumers' Cooperative Office of the Central Standards Bureau of the Ministry of Economic Affairs

V. Description of the invention (W) 1 1 I Pyridinol * 1 »2% 2 * 6 t 6 —Pentamethyl — 4 —piperidinol * 1 1 il Hydroxyethyl — 2 S 2 6 t 6 Tetramethyl — 4 Piperidinol and description t [Please refer to US-ί -4,087, i 04 and EF--(, 389 1 £ of compound 9 or those containing first read 1 1 read 1 t compound with amine 9 for example 4 —Amine — 2 > 2 > 6 »6 — Tetramethyl 1 1 1 1 morphine or described in US -ί, 9 04, 581 4 — Aminopyridine ° Note 1 I These steric hindrances The addition of amines can occur when triazine of formula (I) is added or matters 1 1 and 1 after the addition or after the addition. 0. This method can be the same as the addition of 1 and 1 human diazine. This section will be described in detail in the following example. Page I l Suppose that the compound of formula (I) is a hindered amine It is also added to the poly [I compound that the latter is preferably used in an amount from 0 * 1 to 15% by weight 1 1 ratio (calculated based on modified polymers) 0 This also applies to formula I d 1 The novel copolymer of the order unit 0 1 | Μ The polymer modified by the method of the present invention can be used for the traditional type of polymer 1 I 9 m, such as a model-like tubular layered film-like fibrous drip tree 1 1 Adhesive or coating Cover 0 is preferably an adhesive 1 (stained or unstained) for surface coating. 〇1 I Same as the above-mentioned compound of formula (I) or (I d) and modified polymer 1 I It can be used as a fixative for organic substances. 9 It is mainly a polymer. 0 For this purpose, the modified polymers used are preferably those containing at least 5% > such as 1 1-50%. I) or (I d) compounds. This novel formula I is preferred The amount is from 0 0 1 to 10% by weight »Special 1 1 is from 0 5 to 5% by weight (calculated based on the specified organic substance 1 1) C · This novel compound can be used to stabilize fluorene substances t For example Oil »Fat 1 1-83-1 I This paper size applies to the Chinese national standard (CNS> A4 is now (210X29 "? mm) 413677 a7 B7 Consumption cooperation between employees of the Central Standards Bureau of the Ministry of Economic Affairs. ) 1 1 1 S wax, cosmetics * Pigments or coatings 9 Especially stable organic polymers Γ-, 1 1 Energy M This example of a polymer determined as follows: Please 1 1 I 1 ♦ Monoolefin And diJijl m hydrocarbon polymers such as »polypropylene > polyisobutylene first read 1 I 1 |» polybut — 1 —ene > poly 4 —methylpent — 1 monoene polyisoprene back δ 1 I 1 or polybutadiene and cycloolefin Compound 9 such as cyclopentene or orbornene means 1 I (η 〇Γ b 〇Γ η e η e) polyethylene C which is a matter of selective crosslinking and then 1 1 I) r such as high density polyethylene (Η D Ρ Ε) High density and quotient molecular weight fill% of this pack 1 polyethylene (Η DP Ε — Η Μ W) High density and ultra high molecular weight polyethylene i 1 ene (Η D Ρ E-U Η Μ W) > Medium Density polyethylene (Μ D Ρ Ε) t 1 Low density polyethylene (LD Ρ Ε) Linear low density polyethylene (LL 1 i DP Ε) Branched low density polyethylene (Β LDPE) 1 Polyolefin is a monoolefin Polymers »Monoolefin polymers such as the 1 1 example given in the previous paragraph, especially polyethylene and polypropylene, can be prepared by different methods 1 1 especially the following method 1 1 I a) free reactive groups Polymerization (usually under high pressure and high temperature) 1 line b) catalyst polymerization reaction using a m catalyst i The catalyst usually contains one or more than one | IV — 1 on the periodic table IV b 1 V b, VI b or VI Ϊ Group I 1 I gold 靥 This lib metal usually has one or more types * typical oxidation 1 1 thing 9 Halides »Alcohol esters 9 ester ethers > amines > Alkylates f Alkenyls and 1 1 / or η alkylates * which may be π — or σ — covalent these metal complex 1 I compounds may be free or fixed On the substrate a is typically activated magnesium chloride 1 I titanium (III) chloride 1 aluminum or silicon oxide. These catalysts are soluble or 1 1 insoluble in the polymer matrix »and these catalysts can During the polymerization reaction 1 1-84-1 1 This paper size applies to Chinese national standards (CNS> A4 specification (210X297 mm) 413677 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () 1 1 1 The activator is or is typically gold tincture Alkyl compounds Gold metal hydride »Metal alkyl halides» Metal oxides or metal complexes t N Please 1 I The metal may be of Group I a II af and / or IIIA of the periodic table Read 1 1 Elemental 翏 activator can be advanced-* Ester 9 ether amine or silane ether can be used to easily change the quality of A 1 I 1 These catalyst systems are commonly called P hi I 1 i PSS ta η? 1 1 things [da Γ d 〇1 I η d 1 a η a Z ieg 1 er (item re 1 (fill in 1 N atta) TN ZO D Ρ 〇η t) meta 1 writing book I 1 〇C e η e Or single-sided catalyst (S ε c) 0 Page 1 1 2 The mixture of polymers mentioned in 1) such as a mixture of polypropylene and polyiso1 I butene. A mixture of polypropylene and polyethylene (for example PP / 1 i | Η DPEPP / LD PE) and different types of polyethylene mixed 1 Order (such as LD PE / Η DPE) 〇1 1 3 Copolymers of military olefins and diolefins and other ethylene military bodies such as f ethylene 1 I ene / propylene copolymer linear low density polyethylene (LLDPE) and its 1 1 t mixture and low density polymer Ethylene (LDPE) Propylene / Butene-1 Monoene [Linear Copolymers > Propylene / Isobutylene Copolymer * Ethylene / Butyl-1-m Copolymer 1 1 9 Ethylene / Hexene Copolymer Ethylene / Methylpentene Copolymer Ethylene / Heptane 1 olefin copolymer ene / octene copolymer propylene / butadiene copolymer 1 iso [1 I butene / isoprene copolymer * ethylene / hospital acrylate copolymer 1 1 and its carbon Military oxide-formed copolymer 9 or ethylene / acrylic acid copolymer 1 I t and its salts (ionized compounds) and t I terpolymers formed by ethylene and propylene and —diene like hexadiene dicyclopentadiene Or ethylenedi-orbornene and 1 1 1 the total Mixtures between polymers and the above 1) Examples of polymer mixtures 1 1-85-1 1 This paper size applies to China National Standards (CNS) A4 standard (210 X 297 mm) 413677 A7 B7 Central Ministry of Economic Affairs Printed by the Employees ’Cooperative of the Junction Bureau. 5. Description of the invention (η) 1 1 1 Such as» Polypropylene / Ethylene-propylene copolymer 9 LDPE / Ethylene-ethylene 1 I Acetate copolymer (EVA) * LD PE / Ethylene acrylic acid Copolymers please first 1 (EAA) »LLDP Ε / EVA» LLDPE / EAA reading 1 and interleaving (a 1 te Γ η at Ϊ η S) or scattered (Γ a η d 〇 back 1 1 1 tm) polymerization Olefin / carbon monooxide copolymers and other polymers formed by it / 玉 意 1 | 事 1 mixtures such as polyamines 0 and 1 I 4-hydrocarbon resins (such as C-C 9) including its Hydrogenation This 1 pack I quality (such as adhesives) »and the mixture of polyolefin and m powder page V_- · 1 1 5 polystyrene poly (P — methylstyrene) poly (α monomethylbenzene 1 I ethylene ) Λ \ I ί 6 stupid ethylene or a monomethylstyrene and diene copolymer or acrylic acid derivative 1 such as styrene / butadiene styrene / acrylonitrile styrene I 1 / alkyl methacrylate stupid Ethylene / Butadiene / Alkyl Acrylic Acid m Benzene [Ethylene / Butadiene / Academy Acrylic Copolymer Styrene / Maleic Anhydride 1 ti Styrene / Acrylonitrile / Methacrylate Styrene Copolymer Punch 1 linear strike strength mixture and another polymer such as polyacrylate-1 I diene polymer or -1 ethylene / propylene / diene dipolymer and styrene! I block copolymers like stupid ethylene / butadiene Diene / Styrene / Isoprene 1 1 I Diene / Styrene Styrene / Ethylene / Butene / Styrene or Styrene 1 1 / Ethylene / Propene / Styrene 0 1 1 7 Graft copolymers of styrene or a-methylstyrene such as in Styrene on poly 1 butadiene on polybutadiene-styrene or styrene on polybutadiene 1 1-acrylonitrile copolymer Styrene on polybutadiene and propylene 1 1- 86 1 1 This paper size applies to Chinese Standards (CNS) A4 specifications (2I0X297 mm) 413677 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () 1 1 I Acrylonitrile (or MAc ); Styrene on polybutadiene 9 propylene m and 1 1 1 methacrylic acid ester; styrene on polybutadiene and maleic anhydride 1 I please 1 1 9 on polybutadiene Styrene 9 on acrylonitrile and maleic acid Or cis-butene first 1 1-read 1 ene diimide; styrene on polybutadiene and cis butadiene diimine > back 1 ester 1 styrene on polybutadiene and Alkacrylic acid or methacrylic acid ester; styrene and acrylonitrile on t 1 ethylene η / propylene / diene terpolymer; on polyfluorene matters 1 | re 1 I acrylic acid or polyisopropyl methacrylate A mixture of ethylene and acrylonitrile on propylene filled with styrene and acryl on the acrylate / butadiene copolymer and the copolymer listed on page 6 1 I) 9 For example, the conventional ABS Μ Β SAS 1 ί A or AES polymer copolymer mixtures 0 [1 8 Halogen-containing polymers like polychlorinated pentadiene chloride ib rubber 9 1 Customized or vulcanized chlorinated polyethylene ethylene and chlorinated ethylene copolymer epichlorohydrin 1 I homo- * and copolymers, especially polymers containing halogenated vinyl compounds such as 1 1 I t polyethylene chloride polyvinyl chloride polyvinyl fluoride polyethylene 1 1 diene fluoride and its copolymers like ethylene Chloride / Ethylene Dichloride 1 line) Ethylene Chloride / Ethylene Acetate or Ethylene Chloride / Ethylene Acetate 1 1 Copolymer 0 1 1 9 * Prepared from α 9 β — unsaturated acids and their derivatives The resulting polymer 9 1 1 is like polyacrylate and polymethacrylate polymethacrylate 9 polypropylene 1 1 donkey amine and polyacrylonitrile t Μ butyl acetate into impact modifiers; · 1 I 1 〇 * 9) The total 1 1 I polymer formed between the army and other unsaturated monomers »For example, acrylonitrile / butadiene copolymer» acrylonitrile / fluorenyl acrylic acid 1 1 ester copolymer 9 acrylonitrile / compound Oxygen based acrylate or acrylic Acrylonitrile / vinyl halide 1 1-87-1 1 This paper size applies to the Chinese National Standard (CNS) A4 (210X297 mm) 413677 B7 Printed by the Shellfish Consumer Cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs 5. Description of the invention (to) 1 1 I compound copolymer or acrylonitrile / alkyl methacrylate / butadiene terpolymer C '1 1 I 1 1 * Polymer derived from unsaturated alcohol and amine or its rattan derivative please 1 1 or its acetal example > Polyvinyl alcohol poly / ^. 1 acetoacetic acid polyethylene stearin first read 1 1 read 1 I ester polyethylene benzoic acid m polyethylene maleate polybutylene 1 I of 1 aldehyde polyallylic acid m or polyallyl melamine; and its copolymer with the olefin mentioned in point 1 above Note 1 I Homopolymerization of cyclic ether Polyolefins Polyethylene oxide is filled in with this compound I polypropylene oxide or its copolymer with dioxoyl ether 0 pages 1 1 1 3 polym aldehydes like polyoxymethylene and those polyoxymethylenes which contain ethylene 1 | Po oxide as a comonomer thermoplastic polyurea acrylate or MB 1 1 S modified polyacetal 0 1 order 1 4 polybenzyl oxide and sulfide and polystyrene oxide and styrene 1 I Polymer or polyamine mixture 〇1 1 1 5 Polyurethane or polybutene 1 derived from hydroxyl-terminated polyether on one side and aliphatic or aromatic polyisocyanate on the other side and 1 Its precursors 0 1 I 1 6 polyS amine and copolymers derived from diamines and dicarboxylic acids and / or amine carboxylic acids or equivalent 1 1 I lactams such as polyamines 4 Amine 6 > 1 1 Polyamine 6/6 6/1 〇 6/9 6 / 1 2 4/6 t 1 1 1 2/1 2 Polyamine 1 1 Polyamine 1 2 Aromatic polyamines starting from m-xylylene 1 1 amine and adipic acid Polyamines derived from amines and isotitanates 1 1 I or / and peptidic acids, with or without elastomers 1 1 as modifiers such as poly-2 4 4 —trimethyl 1-methylene pairs Peptide 1 1 88 1 1 This paper size applies the Chinese National Standard (CMS) A4 specification (210X297 mm) A7 B7 Printed by the Consumer Cooperatives of the Central Standard Vehicle Bureau of the Ministry of Economic Affairs 5. Description of the invention (η) 1 1 1 — M monophenylene isophthalamide 9 and the aforementioned polyamides and polyolefins »1 I olefin copolymers * ionized or chemically bonded or grafted elastomers or and 1 1 I polyt as and polyethylene glycol» Polypropylene Glycol or Polytetramethylene Glycol Intermediate Read 1 1st Copolymer > and M E P D M or ABS modified polyamide or Copolymerization on the back 1 I amines »and polyamines concentrated in the preparation process {RI Μ polyamine system) Note 1 1 thing 1 item I again 1 I 1 7 Polyurea polyimide 9 Polyamine — Imidimide and polyoxazole. Fill in this package. I 1 8 Polyesters, such as polyethylene parapeptides, produced from diacids and glycols and / or from hydroxycarboxylic acids or their equivalents. Acid ester r polybutene terephthalate 1 I r poly 1 4 dimethyl alcohol cyclohexyl para-peptide and polyhydroxybenzoic acid m 1 1 »and block copolyether derived from hydroxyl terminated polyether m and Μ poly 1 order decarbonated or BS modified polyester 〇1 | 1 9 Polycarbonate and polyester carbonate 〇1 I 2 〇Polyether polyether mill and polymethyl ketone 〇1 f 2 1 phenol urea and honey by aldehyde on the side Derived from the other side-1-line cross-linked polymer 9 like phenol / formaldehyde resin »urea / formaldehyde resin and dense 1 I amine / formaldehyde resin 〇1 I 2 2 * dry and non-drying enzymatic resin 〇1 1 2 3 Unsaturated polyester resins derived from saturated and unsaturated dicarboxylic acids, polyhydrogenases, and K vinyl compounds as 1 1 cross-linking agents * and their low-methane-containing 1 I halogenated modifiers 0 1 1 2 4 • Cross-linked acrylic resins derived from substituted acrylates * 1 1 For example epoxy acrylic resins 9 Urethane acrylic resins or polyester acrylates 1 1-89-1 1 This paper size applies to China Standards (CNS > A4 size (210X297 mm) Printed by the Central Standards Bureau of the Ministry of Economy, Printed by Coopers Cooperative, 413677 A7 B7 V. Description of the invention (finding) 25 · Acrylic acid resin, polyester resin and melamine resin crosslinked acrylic acid Resin 'urea resin, Isocyanates or epoxy resins. 2 6 * A crosslinked epoxy resin derived from a polyepoxide, such as from a dioxoyl ether or from a cycloaliphatic diepoxide. 27 · Natural polymers, such as cellulose, margin, gelatin and their chemically modified homologous derivatives | such as cellulose acetate, cellulose propionate, and androgen butyrate, or Retinoids, like methyl pavidin; and turpentine and its derivatives. 28 · Blends (Polyblends) of the above polymers, such as PP / E PDM, Polyamide / EPDM or ABS, PVC / EVA * PVC / ABS · PVC / MBS > PC / ABS-PB TP / ABS, PC / ASA, PC / PBT, PVC / CPE, PVC / acrylate, POM / thermoplastic PUR, PC / thermoplastic PUR, POM / acrylate, POM / MBS * PPO / HIPS, PP0 / PA6. 6 and copolymers · PA / HDPE > PA / PP > PA / PPO-PBT / PC / ABS or PBT / PET / PC. Therefore, the present invention also provides a method for setting organic substances to resist damage caused by light, oxygen, and / or heat, including adding a compound of formula (I) or a monomer of formula (Id) > Essentially, polymers prepared from other monomers are used as stabilizers, and the use of these compounds to determine organic substances. -90- This paper size applies to China National Standard (CNS) A4 specification (210X297mm) t I order — f! I line {Please read the precautions on the back before filling out this page) Staff Consumption of the Central Government Bureau of the Ministry of Economic Affairs Printed by the cooperative 413677 a7 _B7_____ 5. Description of the invention (η) The amount of the bonding agent used is based on the stabilized organic substance 'and the intended use of the stabilized substance ° Generally speaking, the composition of this new particle contains ( For every 1 ◦ part of the anchoring material) from 0.001 to 15 parts by weight ', especially from 0.05 to 10 parts by weight, especially from 0.1 to 5 parts by weight of the spike fixing agent. Addition to organic polymers * For example synthetic organics, especially thermoplastic polymers, novel compounds can be added by methods known in the art ' and other additives can be added if needed. Addition can be conveniently added before molding, such as by mixing and pulverizing ingredients or adding stabilizers to the melt or solution of the polymer, or applying a compound that has been dissolved or dispersed in the polymer, if necessary * and then evaporate the solvent . In the case of elastomers, it can be determined as the type of latex. Other methods of adding this novel compound to the polymer include adding it to the monomer before or during polymerization, or adding it before crosslinking) The novel compound or its warm compound can be added to the substrate Sui Ding Plastic * These matrices include these compounds in concentrations, for example, from 2.5 to 25% by weight. The addition of novel compounds can be conveniently carried out as follows:-as an emulsion or dispersion (for example in a latex or polymer emulsion)-as a dry mixture when mixing other ingredients or polymer mixtures-directly into the processing equipment ( (Eg extruder, internal mixer, etc.)-as a solution or melt. -9 1-This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) ---------- t ------ IT ------. ^ (Please (Please read the notes on the back before filling this page) 413677 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () I 1 1 Μ The stable polymer composition obtained by this method can be converted into 1 by traditional methods 1 1-Shaped article »For example m-dimensional, film * laminates * sandwich laminates> capacity 1 I please 1 I device 9 traditional methods such as heat compression * textile first read 1 I read 1 1 Extrusion or injection molding 0 Back 1 1 1 Therefore, the present invention advances -1 step about the application of this novel polymer composition to the protection of 1 1 shaped articles 0 matters! I again I is also beneficial for multilayer board systems 0 here In the case of novel polymerization, fill in this 1-pack 1 composition containing a relatively high component of the stabilizer of formula (I) or containing formula (Page 1 | I d) monomer and if the concentration of the polymer that requires other monomers is 5 1 I to 15% by weight apply it to a shaped article into a thin film 1 1 I (100-1 100 Um) This shaped article is made of—contains a small amount or no 1 of the formula (I) or (Id) It is obtained by polymer preparation of the stabilizer. This application 1 1 can be performed at the same time as the article is formed, such as when co-extruded m, and this application can also be used when the article is ready to be formed, such as film into a thin layer. Or 1 1 solution coating. The outer layer or the layer of the finished article has the function of a UV filter. 1 The wire can protect the internal articles from damage by UV rays. 0 The outer layer is preferred. 1 I contains 5-15%. Weight percentage 9 especially 5 — 1 0% weight percentage 1 I Compared with at least one formula (I) or (I d) of the formula C 1 1 I This novel polymer composition is used to protect multiple layers. When the system is used, the outer layer 1 1 contains a novel polymer y with a thickness of 2 — 1 〇 0 U m The inner layer contains less 1 1 or no formula t I) or (I d) stabilizer 1 and therefore represents 0 1 1 of the other IS of the present invention. It is particularly advantageous that the component A of this novel polymer composition is a Polycarbon 1 1-92-1 1 This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) 413677 A7 B7_ V. Description of the invention (? /) An acid ester, which is used in the preparation of multilayered systems. (Please read the precautions on the back before filling out this page) The difference between polymers stabilized by this method is the high weather resistance * especially the high resistance to U V rays. Therefore, it can maintain its mechanical properties and its color and gloss even after long-term outdoor use: This stabilizer can also be a mixture of two or more new compounds, this novel composition (stable coating composition (Or organic matter) In addition to the spikes of formula (I) or (Id), other additives such as antioxidants, other light stabilizers, gold tincture deactivators, phosphites or phosphonates may also be included. Examples are the antioxidants (3-11), photopandin and other additives mentioned above. The examples under M will carefully describe the subject (non-limiting) of the present invention. In this example, parts are based on M by weight and% is by weight. If room temperature is mentioned in the examples, it means a temperature from 20 to 25, and these definitions apply in each case unless otherwise specified. The number directly after the chemical symbol represents the index of the ib formula even without the M subscript. The following abbreviations are: THF: azoisobutyronitrile abs' printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economics of Tetrahydrofuran: Absolute (anhydrous) m · P ·: Melting point or melting point range H mmHg: Torr (1 nnnHg = 133,322 Pa) MALD I: Matrix Assisted Laser Des〇rpti〇n

Ionization This paper size is applicable to China Gujia Standard {CNS) A4 specification (210X297 mm) 413677 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (P) 1 1 | Μ s; R; Nuclear Resonance 1 1 Please read IGC ϊ Gas Chromatography First Read 1 I Read 1 IG PG C Permeation Chromatography Back 1 1 of 1 DSC Differential Scanning Calorimeter Note 1 I Μ η * Number average molecular weight ( Unit g / mol (g / i οο)) Matter 1 1 MW w Weight average molecular weight (g / mol (g / N 0))) Fill in this 1 Pack I T S Two glass transition temperature page 1 1 Example 1: Under nitrogen, L contains 14 2 g (30 mmol 1 I ears) of 2 1 4 —dibenzyl — 6 — r 2 — hydroxy — 4 — (3 — positive 1 I — butoxy — 2 — hydroxypropoxy) phenyl — 1 3 5 triazine 1 order) 3 5 g (38 mmol) of propylene sulfonium chloride and 0 4 g (1] 5 mmol) of ttt In 100 ml of a mixture of toluene, heat 1 1 at 70 ° C. for 24 hours and add 4 5 g (4 4 mmole of J 1 1-ethylamine and reheat at a temperature of 70 ° C. 6 Hour 0 Allow the mixture to cool 1 Line 9 Excessive solid residue ((C Η 3 C Zn) 3 N Η C 1) i | Evaporate the m solution to obtain 175 g of a crude resinous product chromatography (silica 1 I gum 6 〇 2 3 0 — 4 〇 0 me sh eluent C Η 2 C 1/1 1 C Η 3 0 Η 9 5/5) can get 1 2 5 grams (79% yield) 1! 2 i 4-dibenzyl — 6 — Γ 2 — hydroxy — 4 — (3 — n-butoxy 1 I-based-2-propylene methoxypropoxy) phenyl — 1 »3 > 5 diazine 1 I (Compound 1 0 0 J 9 which is a yellow resin ° 1 1 丄 Η — N MR spectrum (CDC 1 3 1 3 〇 〇 Η) and desired 1 1 94 1 1 This paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) A7 413677 B7 V. Description of the invention (β) The product agrees with C 3 1 Elemental analysis of Η 3 1 Ν 3 0 5 (5 2 5 · 60): theoretical value: C: 7 0 · 8 4 Η: 5 · 9 4 Ν: 7 · 9 9% found value: C: 7 0 · 8 0 Η: 5 · 8 5 Ν: 8 · 0 2% Example 2: Under a nitrogen atmosphere |-2, 4 -diphenyl-6-containing 24.2 g (30 mmol) ~ 4 — (3-n-butoxy-2-hydroxypropoxy) benzyl] _1,3,5-triamidine, 8.0 g (76 mmol) of methacrylium chloride and 0 · A mixture of 4 g (5 mmol) of pyridine dissolved in 100 ml of toluene, heated at 80 3C for 48 hours, excess methyl propylene chloride and methylbenzene on a rotary evaporator Remove. Add 100 ml of toluene and 4.5 g (44 mmol) of triethylamine and heat at a temperature of 75 = 5 hours. The mixture was allowed to cool and the solid residue ((C Η 3 C Η 2) 3 N H C 1) was decanted off. The filtrate was evaporated to obtain 18.4 g of crude product. Chromatography (silica gel 60; 230-400 mesh; diameter 8 cm, length = 30 cm; eluent CHz Cl2) yielded 8 '5 g of 2 * 4--2 Phenyl-6 — [2-hydroxy-4 (3-n-butoxy-2_methacryloxypropoxy) phenyl] _1,3,5-triazine (Compound 101) * It is Yellow resin. -9 5-The size of this paper is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) --------- Installation ------ Order ------ ^ (please first Read the notes on the back and fill in this page) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 413677 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () 1 1 1 Η-N MR spectrum (CDC 1 3, 3 00M Η Z) and the desired 11 1 product agree 1 I Please 1 IC 3 Z Η 3 3 N 3 0 t (5 3 9 6 3) elemental analysis read first 1 I read 1 I rational m value On the back I 1 1 C j 7 1 2 2 Η; 6 * 1 6 Ν * 7 7 9% Note 1 I found value matters 1 I then 1 IC: 7 0 4 2 Η 6 2 8 Ν * 7 5 7% Fill in Intermediate 2 of Example 3 of this Example 2 — f 2 -hydroxyl 4-(1 1 —hydroxyl — page, 1 | undecyloxy) —phenyl] — 4 6 — diphenyl — 1 »3 5 — 1 I — 'hydrazine 1 1 This inverse ephemeris is carried out under nitrogen protection. 0-contains 1 7 〇7 g (L order 0 5 mol) 2 1 (2 4- Dihydroxybenzyl) — 4 6 — 1 | Diphenyl- 1 3 5 —Diazine Σ 8 1 g (0 * 5 mole) 1 I powdered potassium hydroxide (F1 uk a, > 85¾) soluble Heat 1 1 digl y id e (F 1 uk a, 99¾) in 1 C 0 ◦ml to 80 t. Add 1 5 5 4 g (〇6 mol) of 1 yellow bromide to this yellow solution 1 1 liquid bromine — 1 1 I ten-L yeast (Fluk a, 97¾) heat the mixture under ί 0 0 υ 4 0 1 II hours t Mixture when heated * and cooling solution 0 V over m Out of knot 1 1 Crystal solids * K Washed, rinsed and dried (50 V / 70 mm Η g) C. 1 1 Yes 2 1 9 * 5 g (8 5 8 4% yield of 2 — L 2 monohydroxy 1 1 group — 4 — (1 1 — hydroxy — undecyloxy) phenyl — 4 * 6 — 1 1 2 Benzy — 1 9 3 5 — hydrazine »It is a light yellow solid 〇1 1 F-1 3 1 — 1 3 2 V 〇1 1-96-1 1 This paper size applies to Chinese National Standard {CNS) A4 specification (210X297 (Mm) 413677 A7 B7 V. Analysis of the invention (C32H3 7Ν3 0 3 (511 · 6 7): Calculated value: C: 7 6 · 12 Η: 7 * 2 9 Ν: 8.21 Found value: C: 7 5 · 0 6 Η: 7 · 4 6 Ν: 8 · 1 3 (Please read the precautions on the back before filling in this page)

Printed by the Consumer Sample Cooperative of the Central Procurement Bureau of the Ministry of Economic Affairs Example 3: 2-[2-Hydroxy-4 — (1 1-acrylofluorenyl-11-oxyl) -phenyl] _4, 6_diphenyl-1 1, 3, 5-triazine This reaction is carried out under the protection of nitrogen. In 1-2-[2-hydroxy-4-(1 1-hydroxy-undecanoyloxy) -phenyl] -4, S-di-cryl) containing 5 1.2 g (0.1 mole) _1,3,5-triazine, a mixture of 22.2 g (0.22 mol) of triethylamine, 500 ml of toluene (Merck, 99.5¾), added in the form of K droplets -97- Paper size Applicable to China National Standard (CNS) A4 specification (21 × 297 mm) A7 B7 413677 V. Description of invention (shirt) 13 _ 3 grams (0 · 105 mol) of 3_ chloropropionic acid chloride: Addition time: In 20 minutes, the temperature was 15 to 20 υ. The mixture turned into a white suspension. The solid was decanted, the solvent was washed with water, dried (Na 2 S 0 4), and evaporated. The solids were filtered through a Kieselgel 60 plate and eluted with toluene. 48.8 g (79. 2% yield) of 2-[2-hydroxy-1-4- (1 1-propenyloxy-undecyloxy) -phenyl] -4,6-diphenyl One 1,3,5-triazine (chemical

Compound No. 102) * This is a white solid, analysis of F123-125 CC 3 ε Η 3 9 Ν 3 0 4 (565, 71): Calculated: C 7 4 · 3 1 Β 6 · 9 5 Ν7.43 Found Value: C 7 4 · 2 2 Η 7 · 0 8 Ν 7 · 4 5 (Please read the notes on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

-98 This paper size applies to China National Standards (CNS) A4 specifications (210X297 mm) A7 413677 B7 V. Description of the invention (called) (Please read the precautions on the back before filling this page) Fact 4: 2 — 〔 2-Hydroxy-4— (11-methylpropenyloxy-deca-oxy) phenyl] -4,6-diphenyl-1,3,5-triazole The title compound (Compound 103) can be described by Prepared by the method of Example 3 | The melting point is 94-96. Example 4b: 2— [2-Hydroxy-4- (3-vinylbenzyloxy) benzyl] -4,6_bis (2,4-dimethylphenyl) -1,3,5-triazine And 2— [2-hydroxy-4 (4-vinylbenzyloxy) phenyl] -4 * 6-bis (2,4-dimethylphenyl) -1,3,5-triazine mixture This title compound (Compound 105) was prepared by the method described in Example 8b, with a melting point of 1 58-1 60 ° C. Example 4c: 2— [2_Hydroxy_4_ (2-methylpropenyloxyethoxy) phenyl] -4,6-dibenzyl-1,3,5-triazine The title compound (Compound 10 6 ) Can be prepared by the method of Example 3, which is a white solid. Analysis of C 2 7 Η 2 3 Ν 3 0 4 (4 5 3 · 50): Calculated value printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs: C 7 1 · 57 Η 5 · 1 1 Ν 9 · 2. 7% Found values: C 7 0 · 7 0 Η 5 · 3 8 Ν 9 · 0 0% Example 5: 2, 4—Bis (2,4-dimethylbenzyl) -6- [2 1-hydroxyl 4 — ( 3 —n-butoxy—2 —methacryloxypropoxy-99- This paper size applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 413677 at B7 Printed by the Consumer Cooperative of the Central Standards Bureau, Ministry of Economic Affairs V. Description of the invention () 1 1 | group) phenyl — 1 f 3 5 — triazine 1 1 The title compound (compound 4 0 0) can be prepared by the method of Example 2 y — 'v 1 | Melting point 3 〇 First M 1 I Read 1 1 Intermediate of Example 6: 2 — 2 — hydroxy — 4 — (1 1 — hydroxy — back δ 1 I 1 undecyloxy) — phenyl — 4 6 — Double (2 4 — Dimethylbenzene Note 1 matter 1 base) — 1 3 5 — Triazine term | Re I This reaction is performed under nitrogen protection. The mixture contains this 1 pack | 7 9 5 g (0 2 mole) 2 — (2 4 — Dihydroxybenzyl 1 |) — 4 6 — (2 4 — Dimethylphenyl) — 1 3 5 — 1 I hydrazine 1 12 g (0 2 mol) of powdery hydroxide Potassium (F 1 uk a, 1 1 > 855!) Is dissolved in 5000 ml of dig 1 y id e (F 1 uka, 99¾) and heated to 80 volts. 〇 In this yellow solution Add 5 9 6 g (1 | 〇 2 3 mol) of 1 1 -bromo-1-undecanol (F 1 uk a, 97¾) 1 I 0 heat the m compound at a temperature of 100 volts 4 6 When the solution is hot, pass 1 1 m to produce solids and cold SP m to 0 ° CC. Excessive sediments ♦ Wash with 1 line and dry (50 ° C / 7 mm) C to get 8 1 0 Gram (1 | 7 1 4% yield) 2 r 2 — hydroxy — 4 — (1 1 — hydroxy 1 I undecyloxy) benzyl] — 4 6 — bis — (2 4 — dimethyl 1 1 phenyl) — 1 ♦ 3 4 5 — three It is a light-colored solid 1 1 F such as 9 5 — 9 6 V 0 1 IC 3 Θ Η 4 5 Ν 3 0 3 (5 6 7 * 7 8) Analysis 1 I Calculated value 1 t C 7 6 * 1 6 Η 7 9 9 N 7 4 0 1 1-10 0 '1 1 The size of this paper is in accordance with the Chinese National Standard (CMS) A4 (210 X 2 to 7 mm) 413677 A7 B7 V. Description of the invention (na) Hair value: C 7 5 · 42 Η 7 · 9 2 Ν 7 · 3 9

Printed Example 6: Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs: 2_ [2_Hydroxy-4- (1 1-propenyloxy-10-alkoxy) phenyl] -4,6-bis (2,4- Dimethylbenzyl) 1 * 3,5-triazine (Compound 401) This reaction is carried out under the protection of nitrogen. A mixture containing 56 ′ 8 grams (0 ′ 1 mole) of 2_ [2-hydroxy-1 4-((1 1-hydroxy-undecyloxy) benzyl] -4,6-bis- (2, 4-dimethylphenyl) -1,3,5-triazine, 12.4 g (0.133 mol) of propylene hydrazone chloride (Fluka, 97¾), 0-4 g of hydrogen hydrazone ("11 ^ &, 98%), 2 'ml of pyridine was dissolved in 50 ml of toluene (Merck, 99.5%), and heated at 80 ° C for 30 hours. Cool the solution to 50 ° C, and add 21 · 3 ml (-1 0 1-order (please read the precautions on the back before filling out this page) This paper size applies Chinese National Standard (CNS) A4 specification {210X297 mm ) The Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, Consumer Cooperative A7 B7 V. Invention Description (/ iT17) 0 · 154 mol) of triethylamine, then heated at 70C for 6 hours. Filter off the solids, remove the solvent, and pass! The iieselgel 60 pad filtered off a yellow solid and eluted with K toluene. The product was recrystallized from isopropanol. 47,0 g (75.5% yield) of 2- [2-hydroxy-4- (11_propenyloxy-undecyloxy) benzyl was obtained. ] 1,2,4-bis (2,4-dimethylphenyl) -1 * 3,5-triazine (compound 4 0 1), which is a white solid; F81-83 ° C. Analysis of C 3 9 Η 4 7 N a 0 4 (621 * 82): Calculated value: C 7 5 · 3 3 Η 7 · 6 2 Ν 6 · 7 6 Hair value: C 7 4 · 18 Η 7 7 5 Ν 6 · 5 4

Example 7: 2,4-bis (2,4-dimethylbenzyl) -6- [2-hydroxy-1-4- (11_methacryloxyundecyloxy) -phenyl-1 0 2 -This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) gutter (please read the notes on the back before filling this page) Printed by the Consumers' Cooperative of Central Bureau of Standards, Ministry of Economic Affairs DESCRIPTION OF THE INVENTION (1!)] _1,3,5-trimethylsulfonamide The title compound (Compound 4 0 2) can be prepared by the method of Example 6, melting point 7 1-73T :. Example 8a: 2,4-bis (2,4-dimethylphenyl) -6- [2-hydroxy-1-4- (2-methylpropenyloxyethoxy) phenyl] -1,3,5 —Triazine The title compound (Compound 404) can be prepared by the method of Example 3 and has a melting point of 132-133¾. Example 8b: 2-[2-Hydroxy-4 4- (3-vinylbenzyloxy) -phenyl] 4 :, 6-bis- (2,4 · -dimethylpenyl) -1, 3 , 5-triazine and 2- [2-hydroxy-1 4- (4-vinylbenzyloxy) -phenyl] -4 * 6-bis- (2,4-dimethylphenyl) -1,3 , 5-Triazine (Compound 405).

This reaction was carried out under nitrogen. A mixture containing -10 3 ™ This paper is sized for China National Standard (CNS) A4 (2 丨 0 X 297 mm) ----------- batch clothes ----- 1T- ----- # (Please read the notes on the back before filling out this page) 413677 A7 B7 Printed by the Consumer Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs V. Invention Description (1 1 | 1 9 • 9 g (0 * 〇 5 mole) 2 — f 2 4 — dihydroxy 1 I phenyl] 1 4 ί 6 1 bis (2 t 4 _ dimethylphenyl) _ 1 3 1 | please I 9 5 — ~ *-azine r 8-4 grams (0 * 0 5 5 mol) of vinyl benzyl chloride first read 1 I read 1 1 compound (F3 Uii a, 98¾, isomer mixture-· 70% meta position, 30% pair Back 1 bit of 1 I) * 3 * 1 gram (0 • 0 5 5 mol) of potassium hydroxide and 1 〇〇Note 1 ml Dig 1 y me * heat it at 1 t 0 t Cool the suspension for 3 hours and add 1 liquid and 1 liter of water * After m, the solid product i and Isolate again in isopropanol ▲ Pack 1 Pack | Crystal 0 can get 1 9-6 g t 7 6 3% Yield) 2 — r 2 — hydroxyl page 1 | base — 4 — (3 — / or 4 — ethylene Benzyloxy) monophenyl-2j 1 | 4 —bis — (2 t 4 monodimethylbenzyl) — 1 3 5 — — ^. Azine (1 1 compound 4 0 5) * it is light yellow Solid F 1 1 0 — 1 1 4 1 Order: 0 1 IC 3 4 Η 3 1 N 3 0 Z (5 1 3 6 4) Analysis 1 | Calculated value 1 1 C 7 9 5 1 Η 6 0 8 N 8 1 8 1 Line found value 1 IC 7 9 5 3 Η 5 * 9 8 N 7 • 9 8 0 1 I Example 9 Under a nitrogen atmosphere a mixture includes 5 μg (1 1 1 1 millimolar) 2 — phenyl — 4 6 — bis r 2 — hydroxy — 4 — 1 1 (2 — hydroxyethoxy) phenyl> — 1 y 3 »5 — diazine 3 * 4 1 I g (3 3 mmol Ear) of methacrylidine chloride and 1 1 g (14 mmol 1 mole) of pyridine Dissolve in 35 ml of toluene, add it at 80 ° C for 1 1 heat 16 hours C excess methyl propylene chloride and toluene at 60 ° C / 1 1-10 4- 1 1 This paper size is applicable China National Standard (CNS) A4 specification (2 丨 0X297 mm) 413677 at B7 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of invention (w) 60mmHg is removed. Add 4 ml of toluene and 3.8 g (38 mmol) of triethylamine, and heat the mixture at 80 ° C for 4 hours. The mixture was allowed to cool and the solid residue was filtered off. Next, column chromatography was performed (silica gel 60; 230-400 mesh; diameter 8 cm; length = 30 cm; eluent methylbenzyl acetate / ethyl acetate 1/1) to obtain 1.64 g of 2-phenyl-1 4,6-bis [2-hydroxyl-4 mono (2-methylpropenyloxyethoxy) benzyl] -1 * 3 * 5-triazine (Compound 201) as a yellow solid (melting point 1 54 —1 59) ° 1 H — NMR spectrum (CDCI3 * 300MHz) and elemental analysis that agrees with the desired product C 3 3 Η 3 i Ν 3 〇s (597_ 62): Theoretical value: C: 6 6 · 3 2 Η: 5 · 2 3 Ν: 7 · 0 3% hair value: C: 6 6 · 0 4 Η: 5.37 Ν: 7.03%. Example 10: Under a nitrogen atmosphere, a mixture containing 12.7 g (2 ◦mmol) of 2-phenyl-4,6-bis [2-hydroxy-4-(3 ~ n-butoxy -2 -hydroxypropoxy) phenyl] ~ 1,3,5-triazine * 4.3 grams (46 millimoles) of propylene sulfonium chloride and 0.4 grams (5 millimoles) of pyridine Dissolve in 80 ml of toluene and heat it at 70 ° C for 16 hours. After cooling to 50 ^, add 8.0 g (80 mmol) of triethylamine, and heat and mix at 80 t. -1 0 5-(Please read the notes on the back before filling out this page} Binding. The size of the paper for this guideline applies the Chinese National Standard (CNS) Α4 specification (2iOX297 mm) 413677 A7 B7 Printed by the Central Consumers Bureau of the Ministry of Economic Affairs Preparation of the invention 5. Description of the invention (1 4) 1 1 | Product 6 hours 0 Allow the mixture to cool 1 and over m to give a solid residue (1 1 | ((C Η 3 C Η ZO) 2 Ν-Η CI) Evaporate the filtrate 9 And I will ask the residue of I 1 in 200 ml of methylene chloride 9 solution K 1 of the silicon first read 1 I Read 1 I gel over m (silicone 6 0 2 3 0-4 0 0 mesh) »and K 4 50 0 1 I 1 ml of methylene chloride on the back 1 wash and remove the solvent» and dry (8 0 η ： ) Yi i I can get 8 8 grams (59% of theoretical value) 2 — Benzy — 4 6 — Double matter 1 1 Can 2 — Hydroxy — 4-(3 — n-butoxy — 2 — propylene Filled with oxypropyl 1 (Ioxy) BenzoΊ Ί J — 1 3 t 5 monotriazine (compound 2 0 2) Page 1 I is orange resin 0 ί t 1 Η — NM MR spectrum (CDC 1 3 3 〇〇Μ Η Z) and the desired 1 1 product 1 order C 4 1 Η 4 7 Ν 3 0 1 0 (7 4 1 8 4) elemental analysis * 1 I theoretical value 1 1 C 6 6 3 8 Η 6 3 9 N 5 6 6% 1 1. Found value 1 line C 6 6 0 9 Η: 6 50 0 N; 5 • 4 〇% 1! Example 1 1 and 1 2 Preparation of starting compounds * Under nitrogen Under the atmosphere and 8 〇r 1 under 9 will add 3 2 4 grams (128 mol) 1 1-bromo-1-1! Undecanol to one containing 20 * 0 g (54 4 mol) ) 2 — Benzyl 1 1 4 »6 — Bis (2 $ 4 dihydroxyphenyl.) — 1 3 i 5 — 1 I hydrazine t 6 * 6 g (109 mmol) potassium hydroxide And 150 ml of a solution of 1 1 in Dig 1 y in e. The mixture was heated at .0 0 ° C for 14 hours. At the same time, the SP m solution was heated and cooled to 〇V 〇ί..ΙΠ m while it was hot 1 1-10 6-1 1 Paper size applies Chinese National Standard (CNS) A4 now (210X297 mm) 413677 at Β7 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention () 1 1 1 crystalline solid Drying (60 mm Η g 1 [6 〇) to obtain 27.6 g (72% yield) 2 __ benzyl 1 j please 1 I 4 »6 — hetero [2 — hydroxy — 4 — ( 1 1 — hydroxyl eleven φΰ? Gas group) read 1 I ik 1 I phenylΊ J — 1 i 3 »5 —: =: hydrazine» it is a light yellow solid > melting point on the back 1 r 1 1 2 6 — 1 3 5 V 〇 Note 1 1 Η Ν Μ R light m (CDC 1 3 9 3 0 0 Μ Η Z) and desired 1 I then 1 I Material matching book 1 Spring case 1 1 Under a nitrogen atmosphere 9 Will — · Contains 1 0 * 8 g (15 pages, 1 I ml) 2 — Benzy — 4 6 — ia.tu double r 2 — Hydroxy — 4 — (1 1 1 I — hydroxyundecyloxy) phenyl > ~ 1 3 5 —diazine 3 1 1 6 g (40 mmol) of propylene chloride 0.22 g of hydrogen m and 1 order 0 3 g (38 mmol) of Eft pyridine dissolved in 80 ml of toluene 1 I The mixture was heated at 78 ° C for 16 hours. Benzene was removed on a rotary evaporator, and the residue was dissolved in 100 ml of toluene 1 t. 16 2 g (16 mmol) was added-ethylamine and 埶 j,% at 8 ί line 0. 5. Mix the mixture for 5 hours. Allow the mixture to cool down. I will leave a solid residue 1 I retentate ((C Η 3 C Η 2) 3 N Η C 1) 0 Evaporate liquid 9 and dissolve 1 1 I in 50 ml of methyl chloride. C in compounds Silicone (Silicone 6 0 9 2 3 1 1 0—4.0 0 hi esh; diameter 6 cm—length 4 cm) Pass m solution 1 1 and rinse with 4,000 ml of methylene chloride »Strip solvent and dry 1 1 Residue after 2 hours (80 V / 0 • 1 mm Η g) * 1 10 1! I * 7 g (86% yield) 2 —phenyl — 4 t 6 — bis C 2 Monohydroxy 1 1 group — 4 — t 1 1 — propylene fluorenyl undecyloxy) phenyl] — 1 1 «1 0 7 * 1 1 This paper size applies to China National Standard (CNS) Α4 size (2! 0 × 297 mm} 413677 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention {1 ") 1 1 | 3 > 5-hydrazine (compound 2 0 3) It is a light yellow solid (melting point 1 1 9 3 3 V is determined by DSC) 0 1 I Please I 1 Η — Ν Μ 光 议 (CDC 1 3 3 〇 0 Μ Η) and the first read 1 I read 1 | the product agrees Back 1 I 1 Example 1 2 Under a nitrogen atmosphere, a solution containing 10 g (1 5 ml 1 side) 2 yl — 4 6 — double 2 — hydroxy — 4 — (1 1 Item I then I — hydroxydeca —- alkoxy) phenyl — 1 3 5 — triazine »4 0 Fill in this 1 pack of 1 gram (38 mmol) of methacrylium chloride chloride 02 gram of hydrogen stick and Page 1 I 0 3 g (38 mmol) of pyridine dissolved in 80 ml of methylbenzyl 1 I mixture heated at 800 volts for 16 hours 〇 excess of methacrylidine chloride 1 1 and toluene in — spin Remove the residue from the evaporator and dissolve it in 100 ml of 1 stylus pen. Add 81 g (80 mmol) of diethylamine and 0 1 1 g of hydrogen roller »and heat the mixture at 70. 4 Let the mixture cool for 1 h but decanted off the solid residue ((C Η 3 C Η Z) 3 Ν Η C 1) 1 I 〇 Evaporate m liquid and dissolve in 500 ml of methylene chloride 0 through silicone 1 line (silicone 6 〇t 2 3 0 — 4 0 〇me sh * diameter 6 cm length = 1 I 4 After centimeter solution and washing with 400 ml of methylene chloride 9 1 | After stripping the solvent and drying the residue for 2 hours (8 〇υ / 〇1 1 1 mm Η g)) 1 〇 * 9 Gram (85% yield) 2—benzyl 1 1 radical— 4 6—C 2 —hydroxyl 4 — (1 1 —methacryloxy 1 I undecyloxy) phenyl] 1 1 * 3 > 5-Diazine (compound 2 0 4 1 1) which is a pale yellow solid (melting point 6 8 * 3, determined by DSC) 1 1 1 Η -N MR spectrum (CDC 1 3 > 3 〇〇Μ Η) and 1 1-10 8- 1 1 This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) 413677 A7 B7 V. Description of the invention (μ) The product agrees. Get it

The actual evidence is based on the method of 502 compound 3 1X

4 C analysis. «—V 4 8 9 〇7 / V 0 8 V ο 7 3 1 N = 7 g 4 τ 算 Calculate iJ-Ia% 2 9 5 N 7 6 6 Η 7 3 9 6 c value According to the law, there are 3 cases of% 1 ο buttercup. According to 6 according to N is 7 6 6 ο, 2 ο 6 (p Η 物 5 口 口 1 3 化 = 5: g * 4 T 00---6 cases obtained C Real and 9 7 1X 8 6 «IV S ο 3 N 3 4 Η: 5 values Γ〇 Calculate C score --------- install — (Please read the precautions on the back before filling this page ) 'η 6 Ν 6 3 6 Η 1Χ 7 8 Value 6 Now C% 6

5 6 8 6 C 5 group 1 oxygen group hexamethylene-% 9 4 6 Ν 4 4 6; 的 phenyl group in the compound 1 hydroxyl <-I 2 4 (--group 4 hydroxyl 1 I group 2 benzene -I 2 6

Zhengji i Hydroxy 4 I line Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

OK, advance one --- ^ ΚΙ i protects-D stilbenzyl phenylbenzyl nitrogen I 4 6 hydroxy hydroxy bis-containing 4 oxazine 2 triad (-mixed-5-diazine tri F t I (bromine 5 Η I * ο 1—_ 3 κ 1, the last 1 powder grams I 9} grams · 6 benzene. 2 _ 6. 〇 耳 莫 ο ο

U IX a Fermented ear ο ο This paper is again applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 413677 A7 B7 V. Description of the invention (4) 0.03 Moore, and 0.6 grams (3 · 6 millimolar) of potassium iodide (Merck, 99.5¾) was dissolved in 160 ml of diethylene glycol-dimethyl ether (Diglyme, Fluka, 39¾), and it was heated under mixing for 10 minutes under 10 ¾. After cooling to 5〇υ, 6.6 grams (Q '1 mole) of powder K0Η (Fluka, >855;) and 17.0 grams (0' 103 mole) of normal monobromide were added. Hexane (Fluka, 98¾). The mixture was heated at 105 ° C for 14 hours with stirring. After the mixture was hot, it was filtered and the mash was evaporated (rotary evaporator). The product was subjected to column chromatography [Kieselgel 60, 230-400 mesh; l 0 cm diameter; length 30 cm; eluent CH2 C 12] The first elution was the dihexyl derivative, and the second elution was The desired title product, the third product is dried from two 1 1-hydroxy-undecyl dialkylated products (60C / 60mmHg, 24 hours), 22 5 g (35 ' 8% yield) 2-phenyl_4_ (2-hydroxy-4 4-n-hexyloxy-phenyl) _6_ [2-hydroxy-4 — (11-hydroxy-undecyloxy) -phenyl ] ~ 1, 3 * 5-triazine, which is a pale yellow solid, F · 96-99%. 1 Η — NMR spectrum (CDC 13, 300M3ζ) and analysis of the desired product C 3 s Η 4 9 N 3 0 5 (627 · 83): Calculated value: C 7 2 · 7 Ο Η 7 · 8 7 Ν 6 · 6 9 96 Issued value: -110- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm). Second = Square line (please read the precautions on the back before filling this page) Economy Printed by the Consumer Standards Cooperative of the Ministry of Standards of the People's Republic of China Printed by the Consumer Standards Cooperative of the Ministry of Economy of the People's Republic of China Printed at 413677 at B7 V. Description of the Invention (,. 1) C 7 2 · 1 9 Η 8 · 0 1 Ν 6 · 8 8% Example 15 : 2-phenyl-1, 4- (2-hydroxy-4, 4-n-hexyloxy_phenyl), 6- [2-meryl-4— (1 1_methylpropionyloxy-undecyloxy] Phenyl) phenyl] _1,3,5-triazine (compound 207). This reaction was carried out under nitrogen. A mixture including 22.0 grams (35.0 millimoles) of 2-phenyl-4- (2-hydroxy-4-n-hexyloxy-phenyl) -6- [2-hydroxy-4 — ( 1 1-Hydroxy-1 + -alkoxy) phenyl] -1,3 * 5-triazine, 4,4 g < 42.0 millimoles) of methylene propene trioxide (Fluka, 97%) 0.5 g (6,3 mmol) of pyridine was dissolved in 100 ml of toluene (Merck, 99.5¾) * It was heated at 80-85 ° C for 2 hours and cooled to 55t : Later * 8.9 g (87. 5 mmol) of triethylamine (Fluka, 99.5¾) was added. The mixture was heated at 80 ° C for another 7 hours and then filtered when it was hot. The filtrate was evaporated, and the crude product (25'7 g) was dissolved in 120 ml of CH2CI2, and extinguished with Kieselgel 60 pad (2 3 0-4 0 0 mesh; 6 · 5 cm diameter; length = 5 cm) and K 380 ml CH2 C 12 elution. Remove the solvent and dry it at 80 ° C / 0 · ImmHg for 2 hours and 30 minutes to obtain 22 * 3 g (91. 4% yield) of 2-phenyl-4-(2-hydroxy-4 -hexyloxy) Phenyl) -S— [2-Hydroxy-4— (11-Methacryloxy-undecyloxy) -phenyl] -1,3,5-triazine, which is tangerine-1 1 1- This paper size is applicable to China National Cricket (CNS) A4 specification (2 [0 X 297 mm) ---------- Approval of clothes ------, order ------ # ( Please read the notes on the back before filling in this f) 413677 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (CDC 13, 300MHz) and analysis of the desired product C 4 2 Η Ξ, 3 N 3 0 6 (6 9 5 · 90): Calculated value: C 7 2 · 49 Η 7 · 6 8 Ν 6 · 04% Found values: C 7 2 · 14 Η 7 · 4 8 Ν 5-9 8 96 Example 16: 2-phenyl-1, 4-L2, hydroxyl-1, 4- (1 1-ethoxyl-undecyloxy) Benzyl] _6-[2_Hydroxy-4_ (1 1_methacryloxy-undecyloxy) phenyl] -1,3,5-triazine (combined 2 0 8). The reaction was carried out under a nitrogen blanket. A mixture including 20 · ◦ g (28.0 mmol) of 2-phenyl-4,6-bis- [2-hydroxy-4— ( 11 mono-hydroxy-undecyloxy) phenyl] -1,3,5-triazine (intermediate compound of Examples 1 and 12) * 3.1 g (29 '4 mmol) of methacrylium chloride Compound (Fluka, 97¾), 0.2 g of hydrogen hydrazone (Fluka, 98¾), 3 g (3.8 mmol) of pyridine was dissolved in 115 ml of toluene in the first reaction step Heat at 80 ° C with stirring for 5 hours, then cool to 60T :, and add 4.62 g (58.8 millimoles) of acetic acid chloride and heat at 6 ° C for another 18 hours. At After separating the solvent and excess acetic acid chloride ib (rotary evaporator), the residue was dissolved in 100 ml of formazan-1 1 2- (please read the precautions on the back before filling this page). Loading ·-• Thread paper Standards are applicable to China National Standard (CNS) A4 (210X297 mm). Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 413677 A7 B7 V. Description of the invention (, 〆) in benzene. 7.1 g (70 mmol) of triethylamine was added, followed by heating at 70 ° C with stirring for 6 hours. After cooling, the solid ([Hs C2j 3 N-HC1) was filtered off, and the filtrate was concentrated to dryness. The crude product was dissolved in 100 ml of CH2Clz * and filtered through Kieselgel 60 (230-400 mes h) over a period of time and eluted with 1,000 ml of a CΗ2C12 / methanol mixture (95: 5). The solvent was separated and dried (40 ° C // 60mmHg, 48 hours, to obtain 20 '8g (90, 1%) of the ib compound (208), which is a yellow solid, F · 70-76Ϊ; 17: Under a nitrogen atmosphere, a monovalent compound containing 70 g (141 mol) of 2- (4-chlorophenyl) -4,6-bis [2-hydroxy-1 4- ( 2-hydroxyethoxy) phenyl] _1 * 3, 5-triazine, 8.52 grams (94.1 millimoles) of propylene sulfonium chloride and 0.3 grams (3.8 millimoles) of Iftidine is dissolved in 180 ml of toluene, and it is heated at 75 ° C for 14 hours. The excess propylene oxide and toluene are removed on a rotary evaporator = after adding 10 ml of toluene and 5 · After 0 g (48 mmol) of triethylamine, the warm mixture was heated at 90 ° C for 14 hours. The mixture was cooled and the solid residue ((CH3 CH2) 3 N-HC1) was filtered. The filtrate was evaporated * And recrystallized from ethyl acetate to obtain 4'4 g (52% yield) of 2_ (4-monochlorophenyl) -4,6_bis [2_hydroxy-4_ (2-propanehydrazone) Ethoxy) phenyl] _1 * 3 * 5-triazine (compound 2 0 0), which is yellow Color solid (melting point 115 ~ 120). -11 3-This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) I -------- batch clothes ------ iT ------ ^ (Please read the precautions on the back before filling in this tile) 413 Grab 77 Printed by the Central Government Bureau of the Ministry of Economic Affairs, Consumption Cooperation by Employees 5. Printed Description of the Invention (π) iH — NMR spectra (300MHz) and the desired product agree with the theoretical value of elemental analysis of C 3 1 H z 6 C 1 Ν 3 0 8 (6 0 4 · 02): C: 6 1 · 64 Η: 4 · 3 4 Ν: 6 · 9 6 Cl: 5- 87% found: C: 6 1 · 36 Η: 4 · 4 9 Ν: 6 · 9 8 Cl: 6-02¾ Example 1 Intermediate (I) 2 to 22b-Mesitryl- 4,6-dichloro-1,3,5-triazine-one solution * containing 1 09. 5 g (0.55 mol) of 2-bromomesitylene (98% purity) in 150 ml of anhydrous In THF (purity 99.5%), it was added to a stirred suspension under nitrogen atmosphere within 1 1/2 hours, this suspension contains 14.6 g (0.660 mol) of magnesium ( (Purity: 99, 8%) is dissolved in 1 ◦ ml of anhydrous THF, the temperature is maintained at 60 ° C, and added to it Iodine crystals. It was then maintained at the reflux temperature (6 8 3C) for 30 minutes. After cooling the SP, transfer the resulting Grignard reagent to a dropper funnel | and add K drops to a solution containing 96.0 g (0.52 mol) of cyanuric acid chloride (98%) in 270 ml Solution in THF-11 4-(Please read the precautions on the back before filling in this!)-The paper size of the '1T line' paper is applicable to the Chinese National Standard (CNS) A4 specifications (210X297 mm) w). During the addition (takes 1 and 2 hours), the temperature is maintained at ′%, and the temperature of 2 small and 3 2 parts is increased to milliliter. Mix 8 and find V with 5 and 2 and mix with water at medium temperature. \ ICE B ° c liter 2 3 into 5 after pouring 1 and then after the time-minutes ο small 3 1 mixing materials-mixed with water mixed with C liter} milli ο ο ο 1— -ο 8 1 • In ◦ Floating Hang 1 cake cm Η. When filtering, the younger 4 σ 2) cake; isa dry P dry ο 5 〇〇〇 2 8 P (MS ο Η times m two m to do ο exercise 6 this force covers the weight-ο Ρ 0 5 over 2 泸 outdated 'track m Dryness and mildness are the same at the same time., V in ο Benzene to methyl SP} in cold i dissolved ί products, producing the rough crystal title knot gram of hexane. into 8 1 plus' 7 DEK from 2 1 and 8 (Please read the notes on the back before filling this page)

, 1T

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economics of the People's Republic of China) 3 3 3, M s ο ί ο 2 3 3,, · 4 3 2 I hydrazine. 1 ., . Radical tri pc}} benzene-1 D Η H methyl 5 9 c 6 2 tri *-('both 3 5 R ss _ »8 M ((2 1. N 2 5) -ρ I 2 9-1) • H * i-based m 2 6 Benzene 6 bis 2 δ-based hydroxydi I 4 The paper size applies to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 413b77 at B7 5. Description of the invention (^) 148 · 7 grams ( 1 '21 mol) of anhydrous aluminum trichloride (98% purity) was added to a 2-mesityl-tolyl_4, 6_dichloro-1 1 * 3 containing 130 · 0 g (0.485 mol). , 5-triamidine (丨) is suspended in a suspension of 300 ml of petroleum ether (boiling point range 1 10-1 40 Ό) and 385 ml of sulfane. The addition is under stirring. While adding, the temperature of the mixture rises to 4, and within 45 minutes add a solution containing 133.5 g (1.21 mol) of resorcinol (98% purity) dissolved in 155 ml of sulfane to the mixture. Between 8 and 8 Heat the mixture at 5 ° C for 5 hours and 30 minutes to evaporate HC1. Remove the upper layer (petroleum) * and transfer the lower viscous phase (while it is still hot) to a mixture containing 2 '1 liter of methanol and 2 · 1 liter of water in the mixing mixture. After stirring the mixture for 14 hours, the solids were filtered off, and searched for 1 hour in 22 liters of 1 mol HC1, and then eliminated. The cake was suspended in 1,000 ml of water, searched for 30 minutes, and then filtered. . Repeat this operation twice and dry the filter cake for 24 hours (80C, pressure 60mmHg (8 0 0 0 P a)) * You can get 17 0 · 5 g of the following title product (ii): ^ This order (please first (Please read the notes on the back and fill in this page) Printed by the Staff Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs

H3C

OH This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 413677 A7 B7 V. Description of the invention (π) m'p-23〇-234C = Actual 洌 18: Compound (500) is based on Example 10 Prepared by the method, which is a yellow resin; Tg: 9TC. Analysis for C 4 4 Η 5 3 Ν 3 0 1 0 (7 8 3-9 2): Calculated: C67-42 Η 6 · 8 1 Ν 5 · 3 6% Found: C 6 7 · 2 7 Η 6 · 9 1 Ν 5 · 6 6 96 Example 19: Compound (50 1) was prepared according to the method of Example 10 * It is a yellow resin, Tg: _2C. Analysis of C 4 6 Η 5 7 N 3 0 1 〇 (811.98): Calculated value: C 6 8 · 0 1 Η 7 · 0 8 Ν 5 · 1 8% Found value: C 6 8 · 0 1 Η 7 · 1 0 Ν 4 · 9 2% = Example 20: Compound (502) can be prepared by the method of Example 12 * which is resinous. Analysis of C s 4 Η 7 3 Ν 3 〇8 (8 9 2 · 19): Calculated value: C 7 2 · 7 Ο Η 8 · 2 5 Ν 4 7 1% Found value: -1 1 7- Standard of this paper Applicable to Chinese National Standard (CNS) A4B (210 × 297 mm) I -------- Meal -------- ΐτ ------ m (Please read the precautions on the back before filling this page ) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 413677 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Description (Γ ry) \ 1 | C 7 1 6 9 Η 8 0 9 N 4 • 7 5% 1 1 1 寊 例 2 1 Compound (5 〇 3) can be prepared by the method of m 9 and 1 1 Please prepare 1 1 * The result is -L yellow resin 9 TS 2 2 C First! I read 1 | C 4 4 Η 5 3 N 3 0 8 (7 5 1 9 2) Analysis of the back 1 | of 1 Calculated value Note 1 1 C 7 0, 2 8 Η 7 1 1 N 5 5 9% Matter 1 I Reissue the value 1 IC 6 9 8 1 Η 6 8 7 N 5 6 7% Page 1 | Examples 2 2 and 2 2 b Intermediate 2 — mesitylene — 4 — (2 — 1 I hydroxy — 4 — n-hexyloxy — phenyl) — 6-2 — hydroxy — 4 — 1 1 ( 1 1 —Hydroxyundecyloxy) benzyl] — 1 3 5 —triazine 1 This reaction is carried out under a nitrogen blanket a mixture including i I 8 3 〇g diazine (〇 * 2 〇 Mor) No. 2 — Mesitryl — 1 I 4 i 6 — Bi — (2 i 4 — Dihydroxy — phenyl) — 1 3 * 5 — 1 1 Diazine »1 3 • 2 g (〇 2 〇〇〇〇mol ) Powder K 〇Η (1 line F 1 uk a, > 85¾), 5 1 8 g (0 2 0 6 mol) of 1 1 — 1 I bromo — 1-deca —- alcohol (F 1 uk a, 97%), and 12 grams (72 milliliters of I 萁) of potassium iodide (Me Γ C k, 9 9 .5¾) dissolved in 300 milliliters of bis: ethylene 1 1 ene-diol-di Methyl ether (Dig 1 y in e, Fiukat 99¾) was heated for 3 hours with stirring at 1 1 and 120 volts. After cooling to 60 volts r Add 1 1 1 3 2 gram fraction K 0 Η and 3 4 0 gram positive — Bromide House 1 | (0 * 2 0 6 tt F1 uk a, 98¾) 0 During mixing and 1 1 〇 At 1 ° C, the mixture is heated for 1 to 6 hours. When the mixture is hot, the mixture is filtered and the filtrate is evaporated. 1 1-118- 1 1 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) Description of the invention (/) (rotary evaporator). The product (152 · 1 g) was subjected to column chromatography [

Kieselge 1 60; 2 3 0-4 0 mesh); 10 cm diameter; length = 30 cm; eluent: toluene / methanol 98: 2], the product was separated from the second product part. The first elution product is a di-hexyl derivative, and the second elution product is a desired product. The third product is a dialkylated product of two 1 1-hydroxyl-11 alkyl groups. After drying (1 l0 ° C / 0 · 1mm H g) for 2 hours, 55 ′ 2 g (41.2% yield) of 2-mesityl-tolyl-4_ (2-hydroxy-1—4-n-hexane) was obtained. Oxymonophenyl) -6-[2-hydroxy-4-(1 1 monohydroxy-undecyloxy) -phenyl] -1,3,5-triazine, which is a yellow resin, 25 ° C Will slowly crystallize. Analysis of the 1 H-NMR spectrum (CDC13-3 0 0 Μ Η z) and the desired product C 4 I Η 5 5 Ν 3 Ο s (6 6 9 * 9 1): Calculated value: C 7 3 · 5 1 Η 8 · 2 7 Ν 6 · Zn 7% found: C 7 3 5 5 Η 8 · 4 7 Ν 6 · 2 9% Example 22: 2 —Mesitylenyl-1 4— (4 —Hydroxy-4—n Monohexyloxyphenyl) -6- [2-hydroxy-1-4- (1 1-methylpropanyloxy-undecyloxy) -benzyl] -1,3,5-triazine (compound 5 0 4). This reaction is performed under the protection of nitrogen | including -1 1 9- This paper size applies to China National Standard (CNS) Α4 specification (210X297 mm) --------- ¢ ------ ΐτ ------. ^ (Please read the notes on the back before filling out this page) Printed by the Consumers 'Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 Printed by the Zhengong Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (uS) \ \ | 1 0 * 9 g (1 60 0 mol) 2 — mesityl-4 — 1 1 | (2 1-hydroxy-1 4 —n-hexyloxyphenyl) — 6 1 2 hydroxyl_ 1 | Please I 4 — (1 1 monohydroxy — decadecyloxy) — phenyl j — 1 3 »5 Read 1 I Read 1 1 — hydrazine 1 2 0 g t 1 9 2 millimoles) The back of methacrylic acid chloride 1 1 1 (F1 uk a, 9 7¾), and 0.4 g (50 mmol) of pyrimidine solution Note 1 I in 70 ml of toluene (Merck, 99. 5¾) in 8 0-Boxing 1 I After heating at I 8 5 V for 16 hours, cool SP to 5 5 ° C, and then add 4 * 1 g of triethylamine (F 1 uk a, 99. 5¾) filled in this package (4 0 * 0 mmol): Heat the mixture at 80 ° C for 1 hour at 1 ° C and then pass m 0 when it is hot. Evaporate the solution t I. Dissolve the crude product (136 grams) in 1000 ml of 1 1 C Η 2 C 1 In Z via Ki es el ge 1 6 0 (2 30 -4 0 0 mesh) pad 1 order filter (65 cm diameter 9 length = 4 cm) and C of 3 8 0 1 1 liter Η ZZ C 1 Z Elution 0 Remove the solvent > and dry it at 80 volts / 〇1 1 I ΓΤΠ Η g for 2 hours and 30 minutes i can obtain 2 2 3 g (1 1 9 1 4% yield of 2-homo-toluene — 4 — (2 monohydroxy — 1-line 4-hexyloxyphenyl) — 6 — r 2 — hydroxy — 4 — (1 1 —methylpropanyl 1 I ethenyloxy-undecyloxy) — benzene 1 1 > 5-azine (1 I compound 5 0 4) 1 which is a yellow resin T g — 1 〇V ( 1! DSC) C 1 1 1 Η — N MR spectrum (CDC 1 3 1 3 0 0 Μ Η AZ) agrees with the desired 1 I product 1 1 IC 4 5 Η Η 9 N 3 0 ς. (7 3 7 9 8) Analysis: 1 1 Calculated value 1 1-12 0- 1 t This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 413677 A7 B7 V. Description of invention (4) C 7 3 · 2 4 Η 8 · 0 6 Ν 5 · 6 9 96 Hair value: C 7 3 · 0 1 Η 7? 6 Ν 5 * 6 1% Example 22a: Compound (505) was prepared according to the method of Example 8b. Orange tallow fat; T g: 1 3 · 3 t (DSS) = C 4 2 Η 3 7 N 3 〇4 (647-78) analysis: Calculated value: C 7 7 · 8 8 Η 5 · 7 6 Ν 6 · 4 9% Found: C 7 7 · 6 4 Η 5 · 7 6 Ν 5 · 6 6 96 Example 22b: 2 -Mesityl- 4-(2 -Hydroxy-4 -n-hexyloxy Benzyl) -6- [2-Hydroxy-4 (11-propenyloxy-undecyloxy) -benzyl] -1,3,5-triazine (compound 5 0 6)] This reaction is Under nitrogen Be under guard. A single-mixed mixture including 27 '3 g (40 8 mmol) of 2-mesityl-tolyl-4— (2-hydroxy ~ 4—n-hexyloxyphenyl) -6— [2_hydroxyl 4-(11-Hydroxy-undecyloxy) monophenyl] -1, 3 * 5 monotriazine, 4.4 g (49,0 mmol) of propylene sulfonium chloride (Fluka, 9 7¾) , 0 1 g (0 '9 millimoles) of hydrogen plutonium (

Fluka, 99%), and 0.75 g (9.5 mmol) of pyridine was dissolved in 170 ml of toluene (Merck, 99.5%), and heated at 70-7 5 C for 17 hours, at After cooling to 5 ◦ ° C, add -1 2 1-This paper size applies to China National Building Standard (CNS) A4 specification (2 [0X297mm) I i (Please read the precautions on the back before filling this page) Economy Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 413677 at B7 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Description () 1 1 | 2 〇 * 0 grams (1966 millimoles) of triethylamine (FI τι ka, 1 1 99.5¾) * Heat the mixture at 6 5 Β at 8 5 TC, and then pass y—V 1 when it is hot. 1 Filter 1 and evaporate the liquid. * The crude product is dissolved in 100 ml. Toluene / formazan (read 1 I read 1 1 9 8 * 2), and filter through the Kiese 1 ge 1 6 0 (2 30 -400 ir e E h) pad on the back 1 | 1 f 6 * 5 cm Diameter 9 length = 5 cm) and 4 〇〇 Note: 1 ml of benzene / methanol (98: 2), remove the solvent and dry (80 ° C / item 1 I then I 〇 • 1 mm Η SJ 3 hours to get 2 4 3 g (8 2 3 Fill out this 1 i. I 96 yield) 2 — mesityl — 4 — (2 — mesityl — 4 — hexyl 1 1 | phenyl) — 6 — guang 2 — hydroxy — 4 — ( 1 1 —propenyloxy — 1 I decadecyl) Benzoj — 1 3 5 — Diazine (compound 5 0 6 1 1) It is a yellow resin TS — 1 4 • 2 υ (DSC) 1 Order 1 Η — N MR spectrum (CDCI 3 9 3 0 0 Μ Η Z) is in agreement with the desired 1 I product 1 IC 4 4 Η t 7 Ν 3 0 6 (7 2 3 9 6) analysis 1 1 calculated value 1 line C 7 3 〇〇Η 7 9 4 N 5 8 0% 1 I Found value 1 1 | C? 2 8 1 Η 7 7 0 N 5 5 3% 1 1 Example 2 3 Under nitrogen atmosphere »A mixture f includes 1 5 • 9 grams of 1 1 (2 0 mmol) 2 1 4 6 — tri r 2 — hydroxy — 4 a (3 1 I — n-butoxy — 2 — hydroxypropoxy) phenyl > — 1 9 3 »5 — 1 1 diazine, 7 • 3 g (80 mmol) of propylene sulfonium chloride and 0 * 4 1 1 g (5 mmol) of pyridine dissolved in 120 mL of toluene 1 Apply it at 1 1-12 2-1 1 This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 413677 A7 B7 V. Description of the invention (θ) Temperature 7 5 f and heating under stirring for 2 4 hours The propylene chloride and toluene were removed on a rotary evaporator. The residue was dissolved in 1 Q 0 ml of toluene, 10 ′ 1 g (100 mmol) of triethylamine was added, and The mixture was stirred at 0 ° C for 6 hours. The mixture was cooled and the solid residue ((CH3 C Η 2) 3 N · H C 1) was filtered off. The filtrate was evaporated and then dissolved in 1 ml of methylene chloride. The solution was filtered through a layer of sand glue (silicone 60; 230-4 00 mesh; diameter 10 cm, length = 5 cm), washed with 2000 ml of methylene chloride, stripped of solvent and dried (90X: / 0 _ 5mmHg), we can obtain 12.0 g (63% yield) of 2, 4, 6-tri [2 _ diameter group — 4 ((3_n-butoxy_2 —propane) oxygen (Propylpropoxy) benzyl: -1,3,5-triazine (compound 300), which is a pale yellow resin. 1H — NMR spectrum (CDCI3, 300MHz) and element analysis of C 5 1 Η 6 3 N 3 0 1 5 (958.07): Theoretical value: C: 6 3 · 9 4 Η: 6 * 6 3 Ν: 4 · 3 9% found: C: 6 3 · 2 4 Η: 6 * 5 7 Ν: 4 · 0 2% Examples 24 and 25 5 Preparation of starting compounds: Under nitrogen atmosphere, 42 '9 g (170 millimolar) of 1 1 monobromo-1-undecanol to one containing 203 grams (5 ◦ millimolar) of 2, 4, 3 (-1 2 3-this paper size applies to the Chinese national ladder隼 （CNS） A4B (210 × 297mm) --------- Approve clothes ------, π ------ @ (Please read the precautions on the back before filling this page) Economy Printed by the Consumer Standards Cooperative of the Ministry of Standards and Technology of the Ministry of Foreign Affairs 413677 A7 B7 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the Invention (1 1 | 2 I 4-Dihydroxybenzyl 1 * 3 ♦ 5 — Diazine > 9 * 3 grams (1 1 1 4 1 mmol) of potassium hydroxide and 150 ml D 1 g 1 y π in solution of e 1 1 Please heat the mixture at 100 6 hours 9 Then pass m when it is hot. Read 1 read 1 | »and cool the m liquid to 0 ° C 0. Pass m to produce a crystalline solid. Compress and decompress the back I | 1 (6 0 ΠΊ m Η g 7 〇) Drying for 4 8 hours can be obtained 2 4-3 Responsibility 1 Gram 1 (53% yield) 2 4 6 one three 2 — hydroxy — 4 — (item I then I 1 1 — hydroxy eleven Alkyl) Benzoyl J 1 t 3 t 5 — Diazine It is filled in. 1 Pack I is a pale yellow fat-like solid 0 I _ · »1 I 1 Η — N MR spectrum (CDC 1 3 3 0 0 Μ Η Z) and the desired 1 1 product 1 1 Example 2 4 Under a nitrogen atmosphere a mixture of 1 0 1 g 1 order (1 1 mmol) 2 4 6 — three L 2 — hydroxyl — 4 — (1 I 1 1 —hydroxyundecaloxy) phenyl hydrazone — 1 3 5 —diazine 1 j 3 6 g (40 mmol) propylene醯 Chloride 〇2 grams of hydrogen 1 m and 0 3 grams (38 mmol) of pyridine dissolved in 80 ml of chloroform 1 wire sterilized and heated at 80 for 18 hours M, m amount of propylene醯 Cl 1 | Toluene and toluene were removed on a rotary evaporator and dissolved in 100 ml of 1 | of methylbenzylbenzene > Added 16 * 2 g (160 mmol) of diethylamine And 1 1 0 1 g of hydrogen and mix the mixture at 7 8 ° cm for 5 hours 0 Let the mixture 1 1 cool down over m to produce a solid residue ((C Η 3 C Η ZO) 3 N 1 I Η C]) 1 Evaporate m Solution »then dissolved in 100 ml of methylene chloride 1 1 1 > via a layer of silicone (silicone 60 0) 2 3 0-4 〇〇1 ί me S h diameter 6 cm i length = 4 cm) Filtration solution and M 1 1-12 4- 1 1 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 413677 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Description (ιθ) 1 1 I 4 00 ml of methylene chloride washes and rinsed after stripping the solvent and drying the residual 1 I (2 hours * 7 0 ° C / 0 1 mm Η) to get 7. 7 1 Please I gram (65% yield) of 2 4 6 one three [2 — hydroxy — 4 — (Xian Ge 1 I read 1 | 1 1 — propylene fluorenyl undecyloxy J pen base) — 1 3 ί 5 One triple back [1 hydrazine (Compound 3 〇1) t It is a light yellow solid f Melting point 1 7 2 • 8 Note 1 I »Determined by DSC) 〇 Chapter 1 I then I 1 Η — Ν Μ The R spectrum (CDC 1 3 t 3 0 0 Μ Η 2) is consistent with the product you want to fill out. Page 1 1 Example 2 4 Under nitrogen atmosphere j — mixture containing 1 0 * 1 gram 1 I (1 1 Mil) 2 4 6 — trif 2 — hydroxy — 4 — (1 1 1 1 — hydroxyundecyloxy J benzene — 1 3 5 — — ^ hydrazine 1 order 4 2 g (40 mmol) of methacrylium chloride 0 2 g of 1 | Hydromill and 0 3 g (38 mmol) of pyridine dissolved in 8 0 ml of toluene was heated at 80 ° C for 18 hours. An excess of methacrylidine 1 1 chloride and toluene were removed on a rotary evaporator. The residue was dissolved in 1000 ml of toluene. T was added. 8 1 g (80 millitorles) of triethylamine and 1 I 0 1 g of hydrogen and stirred the mixture at 70 for 5 hours. The mixed 1 1 I product was cooled to eliminate the solid residue. The filtrate was evaporated and dissolved in m. 1 〇0 1 1 ml of methyl chloride fb ♦ through the layer of silicone (silicone 6 〇> 2 3 I 1 0 — 4 〇 0 me S hi diameter 6 cm> length 4 cm ί [) After washing with 1 and 400 ml of methylene chloride, strip the solvent and dry residue after stripping 1 1 (2 hours 9 7 〇 / 0 * 1 mm Η 1 1 g) > 2 of 7 7 g (65% yield) can be obtained »4 > 6-_: 1 1 12 5- 1 1 This paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) 41367? V. Description of invention ()

2_Hydroxy ~ 4 3, 5-Methacryloxy undecyloxy) benzyl hydrazine

2 TC

Η-NMR, measured by DSC) Spectrum (CD c product fit example 28: 2 ~ phenyl) -6- [2 1 棊 oxy) phenyl]-丄, 2) 〇300MHz) and desired 4-2- Hydroxyl-4_hexyloxyphenyl 1 1 -methacryloxy undecanetriazine homopolymer (compound 60 (please read the notes on the back before filling in this f) -¾. Central Standard of the Ministry of Economic Affairs Bureau employee consumer cooperative prints a solution, including 5.2-based), 4-one (2 ~ hydroxyhydroxy-1 1 ~ methacrylofluorenyloxy | 5-triazine (compound 207)), and puts it under argon. In a 100 ml three-necked flask, milligrams (..22 millimoles) of α, monoacryl isobutyronitrile (AI β N »F 1 uk fi qq ν λ 38¾) and mg (〇 · 75 millimolar) of n-butyl mercaptan (Fluka, 9 U) treatment: keep the mixture at 8 ° C for 16 hours under cooling. After cooling down, this solution is stimulated by droplets under agitation. It was added to 400 ml (Fluka, 99.5¾) of the solution. The precipitate was decanted and dissolved in toluene, and the solvent was stripped and dried for 2 hours (80o / 0.1mmHg) to obtain 3 '3 5 g (64%) of the title compound (Compound 602); Tg: 2 9 · 9 υ. G (7.5 mmol) of 2- (benzene4-hexyloxyphenyl) -6- (2 — Undecyloxyphenyl) -1,3,) dissolved in 4 ◦ ml of methylbenzyl (Fluka, -126- This paper size applies to China National Standard (CNS) M specifications (210X297 mm) -9 Γ i 413677 at B7 Printed by the Consumer Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs 5. Description of the invention () 1 1 I 1 Η — N MR spectrum (CDC 1 3 > 3 0 0 Μ Η ζ) and desired 1 1 ί 1 The product agrees (without a signal of ethylene) G 1 I Please \ 1 Μ ALDI Μ S Μ η 1 6 9 8 Read first [Read 1 1 Μ w = 3 2 5 1 Back Λ 1 I Example 1 2 9 2 1 Phenyl — 4 — (2 — hydroxy — 4 — hexyloxybenzyl 1 1) — 6 — Γ 2 — hydroxy — 4 1 (1 1 — methacryloxy 1 deoxygenated matter 1 I then 1 I oxygen Base) BenQ > — 1 3 5 — Triazine-n-butyl acrylate is filled out in the contents of this 1 (mole ratio 1: 4) 〇 pages s ··· 1 I A solution includes 5 2 grams (7 5 millimoles) 2- (Benzene \ 1 I group) — 4 a (2 — hydroxy — 4 monohexyloxyphenyl) — 6-(2 — 1 1 hydroxy — 1 1 methacryl undecyloxyphenyl) — 1 »3 t 1 t 5-triazine (compound 207) and 38 g (30 mmol) of 1 I n-butyl acrylate (F 1 uk a, 99¾) dissolved in 40 ml of toluene ( \ 1 IF 1 uk a, 99-5¾) Place it in--L 0 0 ml three-neck 1 1 flask under argon > x 2 0 0 mg (1 1 2 mmol) α α 〆 一 1-line acryl bisisobutyronitrile (AIBNF lu ka 98¾) and 300 mg (1 I 37 55% mole) of n-butyl mercaptan (F 1 uka, 97¾) treatment 1! IC in m Keep the mixture under stirring for 8 5 1 7 hours after cooling the SP, and then stir this clear yellow by means of stirring 1 M droplets. The color solution was added to 400 奄 liters (1 1 F 1 uk a 3 99 · 5¾) of the solution. C was precipitated and dissolved in 30 ml of 1 I toluene. 4 The solid impurities were removed by distillation. The solvent was stripped. And dry 2 hours 1 1 1 (80 0 X: / 0 • 1 ΪΏ m Η > 660 g (7 3 1 1%) of the title compound (compound 6 0 3)} T g -3 · 5 X: 1 i-127- 1 1 This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) A7 4136V7 B7 V. Description of the invention (4) MALDI-MS Μ η = 2 9 0 5 M w = 4 1 9 9 Example 30: Compound (604) was prepared according to the method of Example 28, and an orange-yellow resin was obtained, Tg: 4 9, 8 t :. CC45H59N3O6] (737-98) Calculated: C 7 3 · 2 4 Η 8 · 0 6 Ν 5 · 6 9% Found: C 7 2 · 5 6 Η 8.43 Ν 5 · 4 9% Μ η = 1 9 2 0 M w = 4 1 9 8 (MALDI-MS) Example 3 1: Compound (605) was prepared according to the method of Example 29 to obtain an orange resin, T g:-4 · 2 Ό. [C4sHs9N3〇ej 1 [C7 H12 O2] 4 Calculated value: C 7 0 · 1 1 Η 8 · 6 2 Ν 3 · 3 6 96 Found value: C 7 0 · 7 1 Η 8 · 7 4 Ν 3 · 6 7¾ Μ η = 3 2 3 8 Μ w = 4 9 2 3 (MALDI-MS) ^ Example 31a: Compound (606) was prepared according to the method of Example 29, but M3 0 n-dodecyl Methacrylic acid is intended to replace -1 Z8- This paper size applies to Chinese national standards (CNS M4 specification (210X297 mm) I batch of water line (please read the precautions on the back before filling this page) Printed by the cooperative 413677 A7 B7 V. Description of the invention (ί 4) Printed n-butyl acrylate T g by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs;-3 3 * 4 ° c Μ Δ LDI-Μ S Μ η = 2 〇 2 3 MW = 3 6 6 1 Example 3 2; Compound (6 〇 7) was prepared according to the method of Example 2 8 to obtain a white solid C- C 3 Η 3 9 Ν 3 0 4 Ί (5 6 5 • 7 1) Calculated C 7 4 3 1 Η 6 • 9 5 Ν 7 • 4 3% found value; C 7 4 • 1 3 Η 7 1 6 Ν 7 • 2 7% Μ η-1 9 3 8 Μ W = 3 〇 5 4 (Μ ALDI — Μ S) Example 3 3 * Compound (6 0 8) can be prepared by the method of Example 2 9 to obtain ir C 3 £ Η 3 9 N 3 〇 4 di 1 C 7 丄 丄 Z 〇 〇 > 4 Calculated value: C 7 〇1 7 Η 8 • 1 3 Ν 3 * 9 ％ found value C 7 0 * 7 0 Η 8 • 3 3 Ν 4 6 0% Μ η-2 3 1 〇 W-3 3 4 1 (Μ ALDI — Μ S) Example 3 4 Compound (6 0 9) can be prepared according to the method of Example 2 8 It is a color recognition resin 0 C 4 0 0 4 9 Ν 3 0 4 J (6 3 5 8 5) -129- I Line {Please read the precautions on the back before filling this page) This paper size applies to China National Standards (CNS) Α4 size (210 × 297 mm) 413677 A7 B7 Ministry of Economic Affairs Central Standards Bureau Offset Consumer Cooperatives Description of the invention ('4) 1 1 I Calculated value 1 1 IC 7 5 5 6 Η 7 7 7 N 6 f 6 1% 1 | Please find the value to read first 1 I Read 1 IC 7 4 0 2 Η 8 • 〇6 N 6 * 〇6% Back 1 1 1 Μ η — 1 7 8 1 Note 1 MW — 3 6 6 9 (Μ ALDI _ Μ S) Item 1 I then \ I Example 3 5; Compound (6 1 0 ) It can be prepared according to the method of Example 2 9 and filled in this paper. It is obtained by using only 1—only half of the amount is normal—butyl acrylate ° i, r1 1 r C 4 0 Η 4 9 Ν 3 0 4 JC 7 Η 1 Z 〇Z Ί 1 Z 1 | Calculated value 1 1 C 7 2 7 0 Η 8 2 5 N 4 7 1% 1 Order found value 1 IC 7 1 8 1 Η 8 4 1 N 4 6 8% 1 1 Μ η — 1 9 〇8 I 1 MW = 3 1 1 1 (GPC) 1 Example 3 6; Compound (6 1 1) was prepared according to the method of Example 2 8 to obtain 其 1! It is obtained by the formula-»m. Colored solid ί melting point 8 5 7 V f DSC) 1 1 | C 3 6 Η 4 1 Ν 3 0 4 〆 (5 7 9 7 4) 1 1 Calculated value: 1 1 C 7 4 * 5 8 Η 7 1 3 N 7 2 5% 1 I found value; 1 1 IC 7 3 * 9 0 Η 7 1 5 N 7 • 〇3% 1 1 Μ η = 2 4 0 5 1 1-13 0- 1 1 This paper size applies to China National Standard (CNS) Μ specification (2 丨 0X2? 7 mm) A7 B7 Consumption Cooperation of Employees of the Central Bureau of Standards of the Ministry of Economic Affairs Du Yin 褽 5. Description of the Invention (\ 21) 1 1 | Μ W = 3 7 〇1 (Μ ALDI — M s) 1 i | Example 37: Compound (6 1 2) Yes Prepared according to the method of Example 3 5 and it is a yellow resin 1 T s J 1 5. 8 o Read first [I 1 1 r C 3 b Η 4 1 Ν 3 0 4 J c 7 HL z 0 Z back 1 I 1 Calculated value * Note 1 IC 7 1 8 3 Η 7 * 8 4 N 5 • 0 3% Matter 1 1 Re 1 Find the value to fill in this I. IC 7 1 7 1 Η 7-6 1 N 5 1 9% page 、 W · 1 1 Μ η 3 2 4 1 1 | Μ W = 4 9 2 0 (Μ ALDI — M s) 1 1 Spring Example 3 8 Compound (6 1 3) can be prepared by the method of Example 2 and 1 can be ordered It is-yellow solid Tg: 5 9 1 X: 0 1 ILC 3 6 Η 4 1 Ν 3 0 «J f 5 9 5 7 4) 1 | calculated value 1 1 C 7 2 5 8 Η 6 * 9 4 N 7 0 5% 1 line found value; 1 IC 7 2 ♦ 2 5 Η 6 ♦ 9 5 N 6 6 3% 1 1 I Μ η ZO 2 4 〇5 1 1 Μ W — 5 5 3 3 (Μ ALDI — MS) 1 1 Example 3 9 Compound (6 1 4) can be prepared by the method of Example 3 5 and 1 I is obtained. It is an orange butter fat i T g: 3 5 7 ° C 1 1 ί C 3 6 Η 4 1 Ν 3 〇 & 1 r C 7 H l 2 0 ZJZ 1 1 Calculated value: i 1-13 1-1 1 This paper size applies to China National Standard (CNS) A4 specifications (210X297 (Mm) A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (f points) 1 1! C 7 0 4 8 Η 7 6 9 N 4 9 3% 1 I Found value: 1 I Please IC 7 〇6 1 Η 7 7 6 N 5 • 3 5% Read I 1 Read 1 I Μ η = 3 6 1 2 Back 1 1 1 Μ W 2 5 2 6 4 (Μ ALDI-Μ S) Note 1 贲Example 4 〇 Compound (6 1 5) can be prepared according to the method of Example 3 5 and the matter 1 I is then 1 to obtain t T g 6 6 * 5 υ ο Fill in 1 Pack I Μ η — 2 1 1 1 Page '· 1 I Μ w = 3 1 7 4 (Μ ALDI-Μ S) 1 I Example 4 1 Compound (6 1 6) It can be prepared by the method of Example 3 5 and 1 1 to obtain T g 5 9 8 υ 0 1 order 〆c 3 4 Η 3 1 Ν 3 0 2] 1 C 7 Η i Z 0 2 Ί j Z 1 | Μ η = 2 2 2 3 1 Μ w = 3 6 3 4 (Μ ALDI-Μ S) 1 1 Example 4 2 Copolymer of methacrylic acid ester and compound (1 0 3) 1 Linear methyl methacrylate at 1% by weight Compound 1 0 3 was polymerized by the method described below for VX 1 I. 1 — — The mixture includes 7000 g of methyl methacrylate 0 7 i 1 g of compound (1 0 3) and 0 7 g of laurel peroxide VX f 1 6 0 r Heated pre-polymerized into a syrup-like shape> still m moldable material mold! I made a prepolymer into a model (2 glass separator * 1 6 0 X 2 1 〇X 6 millimeters 1 PVC 1 — Wire r diameter 15 mm 6 metal clips) t next 1 1 polymerization in a water bath for 6 hours 1 temperature 6 0 ri last cycle gas roasting 1 I -13 2- 1 1 This paper size applies to China National Standard (CNS) A4 (2) 〇 X 297 mm 413677 at Β7 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the Invention (θ) Box Hardened for 3 hours (120 t :). The resulting plate was approximately 1.5 m m -1. 3 g of the modified polymethylmethacrylate (PMMA) was dissolved in CHCI3 (solution I; 0. 06 g of PMMA / 1), and the UV spectrum was measured. The polymer was then precipitated by the addition of methanol, filtered, dried, and then redissolved in CHCls (solution I I; 0.04 g PMMA / 1). Record the UV spectrum of Solution II. Calculate the molar extinction coefficient of 3 4 2 nm based on the molar weight of the monomer: Solution I: ε3 4 2 = 20700 Solution ΙΙ: ε342 = 222〇〇 In these two solutions, the extinction coefficient shows the monomer (1 0 3) has been incorporated into the polymer. Example 43: Copolymer of methyl methacrylate and compound (402) methyl methacrylate K1% by weight of compound 402 using the method described in Example 4 2 Polymer: Sample K of the resulting polymer is described in Example 4 2 The method detects monomers, and the following information is calculated from the UV spectrum: Solution I: ε 3 3 9 = 2 1 6 0 0 Solution II: ε 3 3 s = 22200 In these two solutions, the extinction coefficient shows that the monomer (402) has And in the polymer. Β) Application Example-1 3 3-(Please read the notes on the back before filling in this page) Gutter-This paper size applies to China National Standard (CNS) Α4 specification (210 × 297 mm) Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Printing A7 413677 B7 V. Description of Invention (π)

Β1: 5 g of modified polymethyl methacrylate, prepared from Examples 42 and 43 (containing 1% copolymerization stabilizers [103] and [402], respectively), were dissolved in 30 g of formazan Pyrochloride (room temperature). This solution was drawn into a thin film on glass > The thickness was 30 wm after evaporation of the solvent and drying in a vacuum. For comparison, a similar film of an unstabilized polymethyl methacrylate product was prepared (Plex (R) 8704, Rohm & Haas, AG). The film was scraped off the glass plate and clipped onto a cardboard frame (6 X 3 cm). The sample was irradiated with UV rays (5TL / 09 halogen lamp and 5 TL / 12 lamp), which was fixed 20 cm above the sample (wavelength range 2 9 5-4 0 0 n m). Periodically check the fading index of the sample with the yellowing index (YI, Method ASTMD 1925): Table 1 shows the results: Table 1: ΥΙ of PMMA with 1% stabilizer (K copolymerization type exists): YI did not have a 0 · 8 compound (1 ◦ 3) 3 · 8 compound (4 0 2) 3 · 2 The stabilizer of the present invention makes the base plate not fade. Example B6: This novel UV absorber [Compound (202), (-1 3 4-The size of this paper is applicable to China National Standards (CNS) (2I0XM7mm) ) Packing. 54.δ 16.3 1 9 A7 413677_B7_ 5. Description of the invention (w) 6 ◦◦ 丨 and (601)] are pre-dissolved in about 5-1 gram of xylene, and incorporated into a composition containing K U racr ο n ® 2 2 6 3 X Β (5 0 35) 1

Cyme 丨 ㊣ 327 (90¾) 2 butyl glycol acetate dimethylbenz n-butanol

Baysilon® A (U in xylene) 3 10 0.0 1 Acrylic resin (DSH, NL) 2 Melamine resin (American Cyanamid, USA) 3 Flow control agent (Bayer, D) The varnish prepared by this method uses Ding Glycol glycol acetate / n-butanol / dimethylbenzyl (1/6/13) thin and uniformly sprayed on a prepared base board (coil-coated aluminum plate, automotive filler, silver-metal Base paint). After drying for about 15 minutes, the coating is baked at 130 for about 30 minutes to obtain a dry film with a thickness of about 40_45wm-using the same method to prepare a comparative sample, but without UV collector. C Sample Put in a UVC 0 N ® unit for weathering test (A t 1 as Cop.) (U Ο-3 1 3 lamp, cycle 8 hours, UV, 70 ° C; 4 hours, 5 G): Measurement 2 ◦ ° Gloss (DIN 6 7 5 3 0), stable sample ratio is not stable -1 3 5-This paper wave standard is applicable to Chinese national standard (CNS M4 specification (210X2 ~ 7mm) I ------- --Equipment ------ IT ------ ^ (Please read the notes on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 413677 V. Description of Invention (μ) -Uil Xiong Zeguang's best has a better quality than b LU (please read the precautions on the back before filling out this page) -Pack.

Line -1T Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

Claims (1)

413677 A8 B8 C8 D8 Patent application scope a A compound of formula i: J-4 public N The basic group's b Tti or a Ti formula is ^ ϋ points, and the relationship is incompatible with each other. Ε: and Chinese i and E g (please read the precautions on the back before filling this page) -If f It Printed by Employee Consumer Cooperatives (Tb VR * --------- line. The paper size in this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 413677 A8 B8 C8 D8 Patent application scope a Formula i ib compound J-4 sue N The basic group's b Tti or a Ti formula is ^ ϋ points, and the relationship is incompatible with each other. Ε: and Chinese i and E g (please read the precautions on the back before filling this page) -If f It Printed by Employee Consumer Cooperatives (Tb VR * --------- line. The paper size in this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 413677 6. The scope of patent application is R 3 is 0 CR 8 R f — / ◦ Η 2 λ} 1 — In the case of XA, t R i is c I — i Z Yuanji or C 6 — CL free alkyl which is interrupted by 0 c 0 0 or 0 c 0 E3J 1 and in When Η 1 is a τ τb group group, f R 1 is a Η 2_ — C Η (XA \ — c H 1 — — R 7; When both z and RL 4 are not hydrogen) R 1 can additionally be: — C Η — c H (X Λ) H 2 — 0 — R 7 9 and — CR a π / 8 — (◦ Η 2) 1 --XA > f R 2 is Η, — c H 3 or C τ * t R 2 / is 〇HR 3 is Η i — H 3 Τ cl — ◦ 4 alkoxy jc 3 alkoxy ί F j C 1 S phenyl i phenoxy or — c N > R 3 / yes — 0 H 3 — 0 — C Η 2 — Η XA) — Η 2 — 0 — R 7 ------------- I -------- order i I- nn DI _ II 1 (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-0-C Η 2-(C Η 2) 1— ΧΑ, -O-CHz-CH (0 A)-R 9 A4 specification (210 X 297 mm) 413677 AS B8 C8 D8 VI. Application scope-0-C Η 2-CH (OH)-CH2-XA, or-0 R i 3 i; R 4, R t 4 and R ts are H, F * C i, 0 CH 3 or CH 3 respectively; R 4 'and R 4 " are in eta-positi ο n)' S relative to the triazine ring Phases II are H, -CHs, C3 alkenyl, -0C -3, 03 alkenyloxy,? , (: 1, phenyl_03 alkyl or -C NR; Rs is Η Rong Yi CHs; R is Η; Rv is Ci-C8 alkyl, cyclohexyl = Cs alkenyl, phenyl or benzyl 9 R 8 and RS ′ are Η; Rs is Ci — Ci. Courtyard; Ri 2 is Ci-Cis alkyl, phenyl or cyclohexyl; R 1 3 iiCs — CiS.C3 — C1S alkyl 1 which is composed of OH , Ci —Ci 3 alkylchloro, —NHCORi z and / or —0 C 0 R i 2 substituted; and A is -C (= ◦)-CRs = CH-R0; X is, — 0 —, —ΝΗ — (C η Η ζ η) — ΝΗ —or -Ο-(C k Η 2 k)-ΝΗ, 1 is a number from i to 19, -3- This paper standard applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) ----- — — — —---- I. ^, I ------ * ------ II > 1 (Please read the notes on the back first (Fill in this page again.) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives. 413677 A8 B8 C8 D8 The number of patent applications ranges from 44 to 0 2 from 1! Yes is nk Physicochemical fh and d are not 1 ene (B. Contains 1 one less and at least from to * Desserts and species are combined into one. Compound 2} I of poly d (Please read the precautions on the back before filling this page) Order --------, the basic group _—, or f I — _ in the line, which is divided into two phases: 2 E and印 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs§ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 413677 83 88 A0CD Among them: R L is not related to -C Η 2 C Η (0 A)-C Η 2-〇-R 7 ~ C Η 2-CH (0 A) — R y, CHa is only 1G Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs or — Η 2 / C T_T z) i- -0 A j A Yes — C / = 〇) — R c = CH — R s R 2 Yes Τ or Τ_Γ s IR 2 fp = t 疋 — 0 Η »R 3 is Η 5 — c H 3 > CI or phenyl t 3 / Μ. ~ " 0 R ί or — 0 R i 3 1 > R 4 R_ Η or Η 3 4) R 4 t, R 4 f R 1 4 and R i ^ are hydrogen; R 5 is Η or — CH! '≪ b F = T λΕ Η ί -δ-u ii. ^ 1. ^ 1. ^ 1 nn · ^-*-0.--UJ n I -1 III (Please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 413677 as B8 C8 D8 VI. The scope of patent application R 7 is C — 0 base 1 R 9 is C i — 1 0 alkane »R Z is L 1 £ m base» R ί 3 1 疋 C 3 —c 1 8 alkyl or C 3-C 1 S alkyl, which is substituted by td-0 0 R 1 2; and i is 1 to 1 0 fishing number 3 >聚合 Aggregation of Patent Application Scope 2 It is obtained by polymerizing at least one compound of formula (I d) and at least one other comonomer in the second patent claim, and other comonomers are selected from the group consisting of: acrylic acid, meproic acid, Acrylic acid esters, methacrylic acid methacrylamide *, methacrylamidine, vinyl ether, vinyl ether, styrene derivatives, vinylpyridine, propylene glycol, methylpropene, vinylpyrrolidone, vinylpyrrolidine fluorene derivatives, and derivatives containing Derivatives of vinyl unsaturated Z-sterically hindered amines, 2- (2'-hydroxyphenyl) benzotriazole, 2-hydroxybenzobenzylbenzene and stereo-sterically hindered phenols 4, such as the polymerized compound of item 3 of the scope of patent application锪, where the other comonomers conform to one of the group groups of formula (II) — (VII): ii ί) R i 6-C Η = C ί R ί 7;-C {= 0)-X,-R 2 〇Where X 'is _0 —or a NRi g —; Ri 7 is H, Cl ·-c4 alkyl, a CH2-COORz i This paper size applies to China National Standard (CNS) A4 specification (2 丨 0 x 297 mm Li) -------------- hit ----- order .-------- line. I (Please read the notes on the back before filling this page) A8 B8 C8 D8 6. Scope of patent application 1 or-CM; H · LS is Η · -CO 0 R · 2 1 or -CH 3; R t 9 Η, C 1-a alkyl, C 4 -Cl 2 ring N ( 1ΐ · χ) 2 ~ substituted C i _ C 4 alkyl, — S (= 0) -R χ f — / ί C Η 3) 2-H 2 -c (= 0)-CH — C (c Η 3) 1-HZ -s 0 3 M j — (C nz) s-S Ο 3 M or Rz 0 is H, Ci—Cis fluorenyl, C3—C is alkenyl, Cz—Cs. Alkyl, which is interrupted by one or more 涸 〇 atoms; and can be substituted by m G Η, or one (C Η 2) s — S 0 3 Μ; ~ CH2F--CH2Ci > -CH2CN > -C Η £ C Κ 2 Ci--C Η 2 C Η 2 CN -7 'This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) It — — — — — — — — — — ^ — — — — — ------- ill II (Please read the notes on the back before filling out this page) Printed by the Employees ’Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Employees’ Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed 413077 Rhyme C8 D8 VI. Application scope -CH2 CHa -COORs > C7-Ci t phenylalkyl, Czeki, _ N i R x) 2 _ substituted C! -C 4 alkyl, gold alkyl or Ci _Ct z Cyclocyclyl; R2 1 is H, Ci-CiS alkyl, phenyl or Cs-Ct3 alkenyl; Rx is C · -C4 alkyl or phenyl; '' 'is only, 001- (12 alkyl , Phenyl, -00-0 ft. \, —CN, —F, or —C i; M is rhenium or an alkali metal; and s is a number from 1 to 5; (III) R 2 z-C (= 0)-〇- CH = CH2, where R2 2 Ci - Ci 3 alkyl group or stupid; (Ilia) Rz 2 a-0-CH = CH2, wherein R2 2 a is a Ci - Ct s Hospital group; (IV) Wherein R2 3 is H or a CH3; Rz 4 is Η, a CR2 3 = C Η 2, a C (0) -phenyl or the paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) / r, nnn ϋ nnnnnl .1 · 々-. ^ 1. ^ 1 ^ ^ nf— I— / t 1 (Please read the precautions on the back before filling out this page) 413677 I D8 6. Scope of patent application and 鼷;金 Μ 基 3 or ο Η} S is VI Μ ί 3 Η c 1 or Η is 5 2 R and V 2 HR is ce I 91 2 RH c is c 2 7 2 R 2, r RFB 7 and 3, Η Ν c. C-one or or- -FCIV ^^ 1 ^^ 1 ^^ 1 ^^ 1 ^^ 1 ^^ 1 1 ^ ^^ 1 ^^ 1 ^^ 1 ^^ 1 n VE tF fell ·. It- «I 1 ^ 1 J {Please read first (Notes on the back, please fill in this page again.) Consumer cooperation of the Intellectual Property Bureau of the Ministry of Economy Shen 'J gathers like I and other ^ —_ items of its V4 一 ί9- No. and _ 圔 to} Fan and V benefits 1 special (please apply _ Φ J) such as Hri This paper size applies Chinese national standards (CNS ) A4 specification (210 X 297 mm) 413677 A8 B8 C8 D8 Six, its RRR alkane in the scope of patent application;; 4 3 3 C Η Η Ic ci I _ c or or, Η Η Η yes yes 7 Β 3 Ηc // Vc or Μ 3ο s I z Hc z Hc M 3o sc H is o 2 R 2 c or alkane u] c 2c its alkane (please read the precautions on the back before filling this page)中 ι · 了 子 原 ο more than one or 1 free is 2 R Η C £ RC alkane 4 C Η is 4 2 R and L Κ or a NR 〇N number I or 3 I or ο 2 and the wisdom of the Ministry of Economic Affairs Printed by the Property Agency Staff Consumer Cooperatives 6 '' A method for penetrating 2-hydroxyphenyltriazine to a polymerizable polymer, including a copolymerization condensation reaction or copolymerization of a compound of formula (I) as described in the first patent scope It is added during the reaction, or the reaction is the same as the compound of formula (I) in the first patent application scope and a polymer 锪 containing an appropriate functional group. This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) A8 B8 C8 D8 6. Patent applications range from 0 · 0 5 to 5 ◦% wt. Formula (ί) Compound s, a Organic substances containing compounds of formula (丨) as described in item 1 of the scope of patent application, or polymerized compounds I as claimed in item 2 of patent application (I) as an S-fixant to resist light, oxygen, and / or heat Harmful effects. 9 * If the organic substance of item 8 in the patent claims is an organic polymer, it is an organic polymer. 1 10 * As the lining substance of the item 8 in the patent application, it is the adhesion of the coating composition. 1 1 * A stable substance with resistance to light, oxygen and / or heat The method of harming W includes adding as a definite agent such as ® the formula (I) of the patent scope of the patent application (I) or Hewei or the application of the patented patent painting 2nd polymerization combination * i 2 as application (1) The compound of formula (I) in the first item of the patent scope is used to stabilize organic substances against the harmful effects of light, oxygen, and / or heat. 1 3 * If the polymerized compound in item 2 of the patent application is under review, it is used to stabilize organic substances against the harmful effects of light, oxygen and / or heat. This paper size applies to Chinese national standard (CNS > A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) ----- I--Order --------- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Online Economy