US2778742A - Method of impregnating a porous ferrous part with copper - Google Patents
Method of impregnating a porous ferrous part with copper Download PDFInfo
- Publication number
- US2778742A US2778742A US357338A US35733853A US2778742A US 2778742 A US2778742 A US 2778742A US 357338 A US357338 A US 357338A US 35733853 A US35733853 A US 35733853A US 2778742 A US2778742 A US 2778742A
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- United States
- Prior art keywords
- ferrous
- cupreous
- metal
- iron
- copper
- Prior art date
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- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical group [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims description 51
- 238000000034 method Methods 0.000 title claims description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title description 21
- 229910052802 copper Inorganic materials 0.000 title description 20
- 239000010949 copper Substances 0.000 title description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 75
- 229910052751 metal Inorganic materials 0.000 claims description 47
- 239000002184 metal Substances 0.000 claims description 47
- 229910052742 iron Inorganic materials 0.000 claims description 28
- 229910001018 Cast iron Inorganic materials 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 16
- 238000002844 melting Methods 0.000 claims description 13
- 230000008018 melting Effects 0.000 claims description 13
- 238000005470 impregnation Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 8
- 230000003628 erosive effect Effects 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 229910000881 Cu alloy Inorganic materials 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910001060 Gray iron Inorganic materials 0.000 description 1
- 241001387976 Pera Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910001037 White iron Inorganic materials 0.000 description 1
- 241000006770 Xenia Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- -1 ferrous metals Chemical class 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/24—After-treatment of workpieces or articles
- B22F3/26—Impregnating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/1216—Continuous interengaged phases of plural metals, or oriented fiber containing
Definitions
- This invention relates to impregnation processes and is particularly directed to the impregnation of porous ferrous parts with a cupreous material.
- suflicient ferrous metal with the cupreous metal used as the impregnant to satisfy the dissolving action of copper for iron prior to the time that said cupreous metal infiltrates the porous iron part and to also include suflicient non-metals in the impregnant material to prevent adhesion of excess ferrous metal to the surface of the ferrous part.
- This object is accomplished by utilizing iron in the form of cast iron powder, which cast iron includes graphitic carbon that acts as the non-metal and in mixed form with the cupreous metal acts as a retardenttoward flow of molten cupreous metal from the mixture until such time that full distribution of ferrous metal in the impregnant has occurred.
- cast iron includes graphitic carbon that acts as the non-metal and in mixed form with the cupreous metal acts as a retardenttoward flow of molten cupreous metal from the mixture until such time that full distribution of ferrous metal in the impregnant has occurred.
- the major portion of the erosive tendency can be controlled but in production processes, it is desirable to utilize a broad range of impregnation temperatures whereby the erosive tendencies are often aggravated.
- Another factor which causes difiiculty is the tendency of copper to dissolve more iron at the impregnating temperature than will remain in combination therewith at the freezing point. In other words, as the temperature rises, the erosive tendency of copper on iron increases. This condition obviously suggests that the most desirable infiltrating conditions can be promoted by actually dissolving iron in the cupreous metal at the impregnating tem- As previously explained, when cupreous 2,778,742 Patented Jan. 22, 1957 perature and prior to the time that the cupreous metal is drawn into the porous ferrous part.
- the magnesium oxide acts in this instance as a sponge to maintain this molten impregnant therein until such time that equilibrium temperature conditions are obtained between the impregnant and the ferrous part being impregnated, whereupon the molten impregnating metal is drawn into the porous fer rous part by capillarity.
- This invention attacks the same problem in a slightly different manner. I have found that a similar result can be obtained by mixing the cupreous impregnant with cast iron powder.
- This cast iron powder not only supplies the ferrous metal which is to be dissolved by the cupreous impregnant prior to infiltration thereof into the porous ferrous part, but likewise, supplies the nonmetallics required to act as. a sponge for holding the molten impregnant until equilibrium temperature conditions are obtained between the impregnant andthe part to be impregnated.
- These non-metallic materials normally found in cast iron are mainly graphitic carbon, silicon and its derivatives, etc.
- this powder will contain sufficient of the so called nonmetallics to create the desired condition.
- This cast iron powder is then thoroughly mixed with copper powder, or copper alloy powder in a desired quantity to provide suflicient cupreous metal to impregnate the porous ferrous part as desired.
- the mixture of the cast iron powder and the cupreous metal powder is briquetted into a self-sustaining mass.
- the cast iron powder should be in quantities ranging from 1 to 5% by weight of the total impregnant used which may be copper or copper alloy or may be copper, for example, with some zinc, tin or other alloying ingredient.
- the cast iron powder supplies, sufiicient iron to satisfy the dissolving action of copper or iron and simultaneously, due to the nonmetallics, acts as a retardent toward the immediate flow of the molten constituent.
- the residue of the impregnant material may be brushed 01f the surface of the part due to the fact that the graphitic carbon, silicon, etc., prevents any firm adhesion of the residue to the surface of the porous ferrous part. In this manner,-an excess of cast iron powder maybe utilized with no deleterious results such as sticking to the surface of said part and thereby marring said surface due to the removal of the adhered parts.
- impregnation is carried out at temperatures above the melting point of copper and below the melting point of iron and preferably within the range of 2000 F. and 2150 'F.
- the -heating may be carried out by induction if selective impregnation is comprehended, but preferably is carried out by standard furnace heating. Usual non-oxidizing atmospheres should be .used n all cases to facilitate the impregnation.
- cast iron powder as referred to herein may be powder from white cast iron, gray cast iron or any of the conventional cast irons as known commercially.
- a method for impregnating a porous ferrous part with a cupreous metal wherein the ferrous part, after impregnation, is substantially free from pits, channels and .the like, the steps comprising; mixing a desired quan .tity of cupreous metal with from 1 to 5% by weight thereof of cast iron powder, placing said mixture upon said ferrous part to be impregnated in a desired position relative thereto, heating the ferrous part with the mixture .of cupreous metal and cast iron powder thereon toa temperature above the melting point of .the cupreous metal.
- a method for selectively impregnating predetermined portions of a porous ferrous part witha cuprctous metal while maintaining the ferrous part substantially free from pits, channels and the like .at the surface thereof comprising; providing a compact including a predetermined quantity of cupreous metal together with from 1 to 5% by weight thereof of cast iron powder having a particle size of at least minus mesh said compact having a shape substantially similar to the shape of the area to be impregnated of said ferrous part, pla ng he compa urea h e o pa ti the e r d Pos t n nd o tiguou o t a ea t b mp gna selectively heating the ferrous part at that portion only .to be impregnated to a temperature above the vmelting point f he unre u m ta an be t m l n po n of iron While simu a e u y he
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Powder Metallurgy (AREA)
Description
United States Patent M METHOD OF IMPREGNATING A POROUS FERROUS PART WITH COPPER Paul I. Shipe, Xenia, Ohio, assignor to General Motors Corporation, Detroit, Mich., a corporation of Delaware No Drawing. Application May 25, 1953, Serial No. 357,338
6 Claims. (Cl. 117-37) This invention relates to impregnation processes and is particularly directed to the impregnation of porous ferrous parts with a cupreous material.
. It is one of the objects of the invention to provide a method for impregnating porous ferrous parts with copper or other cupreous metals wherein the impregnated ferrous part is free from channels, pits or other surface imperfections due to the impregnation process.
In carrying out this object, it is a further object to supply suflicient ferrous metal with the cupreous metal used as the impregnant to satisfy the dissolving action of copper for iron prior to the time that said cupreous metal infiltrates the porous iron part and to also include suflicient non-metals in the impregnant material to prevent adhesion of excess ferrous metal to the surface of the ferrous part.
This object is accomplished by utilizing iron in the form of cast iron powder, which cast iron includes graphitic carbon that acts as the non-metal and in mixed form with the cupreous metal acts as a retardenttoward flow of molten cupreous metal from the mixture until such time that full distribution of ferrous metal in the impregnant has occurred. In this manner, when the cupreous metal actually infiltrates the ferrous part, cupreous metal has had its dissolving action fully satisfied whereby no further erosion occurs.
Numerous methods have been proposed for preventing erosion of porous ferrous materials by copper and copper alloys when said ferrous metals are infiltrated with copper. This infiltration process is one of high utility since a copper or copper alloy impregnated into a porous ferrous part adds strength to the part, reduces its porosity and thereby generally improves the physical characteristics of the part. metals are infiltrated into porous ferrous parts, there is a tendency toward erosion at the surface due to the dissolving tendencies of copper on iron. Past processes for controlling this tendency are disclosed in Bourne Patent No. 2,401,221, assigned to the assignee here, wherein iron powder is added directly to the copper impregnant, which procedure reduces the erosion tendency considerably. However, when large quantities of copper or copper alloys are desired to be impregnated into a selected area of a porous ferrous part, there is still some erosive tendency due to the concentration of copper at the point of entry.
The major portion of the erosive tendency can be controlled but in production processes, it is desirable to utilize a broad range of impregnation temperatures whereby the erosive tendencies are often aggravated. Another factor which causes difiiculty, is the tendency of copper to dissolve more iron at the impregnating temperature than will remain in combination therewith at the freezing point. In other words, as the temperature rises, the erosive tendency of copper on iron increases. This condition obviously suggests that the most desirable infiltrating conditions can be promoted by actually dissolving iron in the cupreous metal at the impregnating tem- As previously explained, when cupreous 2,778,742 Patented Jan. 22, 1957 perature and prior to the time that the cupreous metal is drawn into the porous ferrous part. In order to accomplish this end, Shigley applications, Serial Nos. 357,181 and 357,182, filed concurrently herewith (MP-157 and MP-2l3) and assigned to the assignee of the present invention suggest the use of compacts of cupreous metal, ferrous metal and a non-metallic material, such as magnesium oxide, which mixture with an excess of ferrous metal therein is briquetted into a compact of the shape and size desired and is placed on the porous ferrous part and heated therewith. When the temperature exceeds the melting point of the cupreous metal, melting occurs and simultaneously the molten cupreous metal commences to dissolve the associated ferrous material. This condition continues until the dissolving action of copper for iron'is fully satisfied. The magnesium oxide acts in this instance as a sponge to maintain this molten impregnant therein until such time that equilibrium temperature conditions are obtained between the impregnant and the ferrous part being impregnated, whereupon the molten impregnating metal is drawn into the porous fer rous part by capillarity.
This invention attacks the same problem in a slightly different manner. I have found that a similar result can be obtained by mixing the cupreous impregnant with cast iron powder. This cast iron powder not only supplies the ferrous metal which is to be dissolved by the cupreous impregnant prior to infiltration thereof into the porous ferrous part, but likewise, supplies the nonmetallics required to act as. a sponge for holding the molten impregnant until equilibrium temperature conditions are obtained between the impregnant andthe part to be impregnated. These non-metallic materials normally found in cast iron are mainly graphitic carbon, silicon and its derivatives, etc.
Thus if cast iron turnings or powder for example, are properly graded, preferably to a -l00 mesh powder, this powder will contain sufficient of the so called nonmetallics to create the desired condition. This cast iron powder is then thoroughly mixed with copper powder, or copper alloy powder in a desired quantity to provide suflicient cupreous metal to impregnate the porous ferrous part as desired. Preferably, the mixture of the cast iron powder and the cupreous metal powder is briquetted into a self-sustaining mass.
I have found that the cast iron powder should be in quantities ranging from 1 to 5% by weight of the total impregnant used which may be copper or copper alloy or may be copper, for example, with some zinc, tin or other alloying ingredient. In any case, the cast iron powder supplies, sufiicient iron to satisfy the dissolving action of copper or iron and simultaneously, due to the nonmetallics, acts as a retardent toward the immediate flow of the molten constituent. After the porous ferrous part has been impregnated, the residue of the impregnant material may be brushed 01f the surface of the part due to the fact that the graphitic carbon, silicon, etc., prevents any firm adhesion of the residue to the surface of the porous ferrous part. In this manner,-an excess of cast iron powder maybe utilized with no deleterious results such as sticking to the surface of said part and thereby marring said surface due to the removal of the adhered parts.
In practice, it is desirable to briquet the impregnant material into a shape and size approximating the shape of the surface of the part to be impregnated particularly where selective impregnation is required. Sufiicient metal is supplied to the compact to provide the adequate and desired quantities of the cupreous metal in the porous part.
impregnation is carried out at temperatures above the melting point of copper and below the melting point of iron and preferably within the range of 2000 F. and 2150 'F. The -heating may be carried out by induction if selective impregnation is comprehended, but preferably is carried out by standard furnace heating. Usual non-oxidizing atmospheres should be .used n all cases to facilitate the impregnation.
It is to be understood that cast iron powder as referred to herein may be powder from white cast iron, gray cast iron or any of the conventional cast irons as known commercially.
While the embodiments of the present invention as herein disclosed, constitute preferred foims, it is to be understood that other forms might be adopted.
What is claimed is as follows:
1. In a method for impregnating a porous ferrous part with a cupreous metal wherein the ferrous part, after impregnation, is substantially free from pits, channels and .the like, the steps comprising; mixing a desired quan .tity of cupreous metal with from 1 to 5% by weight thereof of cast iron powder, placing said mixture upon said ferrous part to be impregnated in a desired position relative thereto, heating the ferrous part with the mixture .of cupreous metal and cast iron powder thereon toa temperature above the melting point of .the cupreous metal. and below the melting point of iron fora time sufficient to obtain equilibrium temperature conditions in said mixture and said part whereupon sa-id cupreous metal dissolves a desired portion .of the iron in lthe cast ,iron and then infiltrates said ferrous part, and finally removing any .residueof said mixture from-said infiltrated part.
2. In .a method for impregnating a porous ferrous part with a cupreous metal wherein the ferrous part, after impregnationjis substantially .free from pits, channels and the like, .the steps comprising; mixi gfi desired quantity of .cupreous metal with :from 1 to 5% by weight thereof of .castiron powder, briquetting said mixture into aselfsustainingcompact of ,a .desired shape, placing said compact upon the ferrous part .to .be impregnated and in a desired position relative thereto, .heatingdhe ferrous part and the compact 'to a temperature above the meltingpoint of the cupreous metal and below the melting pointof iron .for a .time sufficient to obtain equilibrium temperature .conditions betweensaidco-mpactrand said part whereupon said .cupreousmetal dissolves .a portion of the iron in the cast iron and lthen'infiltrates said ferrous part, and finally removing anyresiduetof saidcompactfromsaid infiltrated :part.
3. In a method for impregnating aporous ferrous part with acupreousmetal wherein the ferrous ,part,,after impregnation, is substantially free from pits, channels .and .the like, the st pscomprising; mixinga cupreous metal .in a predetermined quantity with cast iron powder in- ..cluding sufficient iron to.fully satisfy the dissolving action of copper or ironatthe impregnating temperature, placing said :mixtureupon ,thesferrouspart .in proxirnityto the area thereof to be impregnated, dissolving at .least aportion .of ,the iron in :said cast, iron into said ,cupreous metal by heating the mixture and .the -part simultaneously to a temperature above the .melting point of the cupreous .metal-and'below-t-he melting point of iron fora time suf- .ficient .to obtain equilibrium temperature conditions between the mixture and the part, causing said 'cupreous metal to then infiltrate-said part only after said equilibrium is obtained by drawing said molten impregnant by capillarity into the pores of said part and finally removing any residue of said mixture from said part.
4. In a method for impregnating a porous ferrous part with a cupreous metal wherein the ferrous part, after impregnation, is substantially free from pits, channels and the like, the steps comprising; mixing a predetermined quant y o upr ous m ta Po de w th cas iron powder in amounts to provide suflieient iron to fully satisfy the dissolving action of copper for iron at the imp es s pera ur hr que t n sa d ix u e into a compact, placing said compact upon said part and in proximity to the area thereof to be impregnated, dissolving at least a portion of the iron in said cast iron powder into said cupreous metal by heating the mixture and the part simultaneously to a temperature above the melting point of the cuprcous metal and below the melting point of iron for a time sulficient to obtain eguilibrium temperature conditions between the part and the compact, then causing said cupreous metal to infiltrate the ports of said porous ferrous part only after said equilibrium is obtained by drawing the molten impregnant by capillarity into the pores of the part and finally removing any residue of said compact from said part.
5. In a method for selectively impregnating predetermined portions of a porous ferrous part witha cuprctous metal while maintaining the ferrous part substantially free from pits, channels and the like .at the surface thereof, the steps comprising; providing a compact including a predetermined quantity of cupreous metal together with from 1 to 5% by weight thereof of cast iron powder having a particle size of at least minus mesh said compact having a shape substantially similar to the shape of the area to be impregnated of said ferrous part, pla ng he compa urea h e o pa ti the e r d Pos t n nd o tiguou o t a ea t b mp gna selectively heating the ferrous part at that portion only .to be impregnated to a temperature above the vmelting point f he unre u m ta an be t m l n po n of iron While simu a e u y he tin d mpa t e ntinu ng said heat fo u a t me tha qui riumtemperature eonditions are obtained between the part and the compact while progressively dissolving sufiicient iron from said cast iron by said cupreous metal to fully satisfy h dis o v n act o coppe on iron an the when equilibrium temperature conditions have been obtained, causing said cupreous metal to infiltrate the selected heated portion of said porous ferrous part for imp e at n e sa e and fin y m ng ny r sidue of said compact framsa dpar The me hod as c ai e in .c aim 5, whe e the s l ct ve heating is ac omp ishe y i du v y h ting a partion only of theferrous part.
References Cited in the file of thispatent UNI ED TATE E 1? 2,401,221 {Bourne May '28, 19.46 2,422,439 Schwarzkopf June 117, :1947 2,481,962 Whitfield Sept. :13, .1949 2,561,579 Lenel July '24, 1951 2715589 Smith Aug. :16, 1:955
Claims (1)
1. IN A METHOD FOR IMPREGNATING A POROUS FERROUS PART WITH A CUPREOUS METAL WHEREIN THE FERROUS PART, AFTER IMPREGNATION, IS SUBSTANTIALLY FREE FROM PITS, CHANNELS AND THE LIKE, THE STEPS COMPRISNING; MIXING A DESIRED QUANTITY OF CUPREOUS METAL WITH FROM 1 TO 5% BY WEIGHT THEREOF OF CAST IRON POWDER, PLACING SAID MIXTURE UPON SAID FERROUS PART TO BE IMPREGNATED IN A DESIRED POSITION RELATIVE THERTO, HEATING THE FERROUS PART WITH THE MIXTURE OF CUPREOUS METAL AND CAST IRON POWDER THEREON TO A TEMPERATURE ABOVE THE MELTING POINT OF THE CUPREOUS METAL AND BELOW THE MELTING POINT OF IRON FOR A TIME SUFFICIENT TO OBTAIN EQUILIBRIUM TEMPERATURE CONDITIONS IN SAID MIXTURE AND SAID PART WHEREUPON SAID CUPREOUS METLA DISSOLVES A DESIRED PORTION OF THE IRON IN THE CAST IRON AND THEN INFILTRATES SAID FERROUS PART, AND FINALLY REMOVING ANY RESIDUE OF SAID MIXTURE FROM SAID INFILTRATED PART.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US357338A US2778742A (en) | 1953-05-25 | 1953-05-25 | Method of impregnating a porous ferrous part with copper |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US357338A US2778742A (en) | 1953-05-25 | 1953-05-25 | Method of impregnating a porous ferrous part with copper |
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US2778742A true US2778742A (en) | 1957-01-22 |
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US357338A Expired - Lifetime US2778742A (en) | 1953-05-25 | 1953-05-25 | Method of impregnating a porous ferrous part with copper |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2902747A (en) * | 1959-09-08 | Reiter | ||
US2903611A (en) * | 1955-05-06 | 1959-09-08 | Vickers Electrical Co Ltd | X-ray tube comprising a cast copper anode sealed with a copper-silver electric alloy |
US3120436A (en) * | 1961-03-23 | 1964-02-04 | Presmet Corp | Powdered metal article and method of making |
US3326678A (en) * | 1964-02-03 | 1967-06-20 | Talmage Charles Robert | Method of infiltrating a metal powder compact |
US3343954A (en) * | 1963-12-13 | 1967-09-26 | Porter Prec Products Inc | Article and process of forming the article from powdered metal |
US3343927A (en) * | 1963-12-18 | 1967-09-26 | Motor Wheel Corp | Sintered metal brake drum |
US3429696A (en) * | 1966-08-05 | 1969-02-25 | New Jersey Zinc Co | Iron powder infiltrant |
US3459547A (en) * | 1967-06-28 | 1969-08-05 | Burgess Norton Mfg Co | Method of making a structural alloy steel containing copper and other alloy elements |
US3803687A (en) * | 1970-11-27 | 1974-04-16 | Gen Signal Corp | Bonded bronze-iron valve plate for steel cylinder barrel and method of making same |
US3808659A (en) * | 1972-07-27 | 1974-05-07 | Gen Signal Corp | Bonded bronze-iron liners for steel cylinder barrel and method of making same |
US4769071A (en) * | 1987-08-21 | 1988-09-06 | Scm Metal Products, Inc | Two-step infiltration in a single furnace run |
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US2401221A (en) * | 1943-06-24 | 1946-05-28 | Gen Motors Corp | Method of impregnating porous metal parts |
US2422439A (en) * | 1943-01-29 | 1947-06-17 | American Electro Metal Corp | Method of manufacturing composite structural materials |
US2481962A (en) * | 1944-02-29 | 1949-09-13 | Fairchild Engie And Airplane C | Manufacture of laminated articles |
US2561579A (en) * | 1947-10-02 | 1951-07-24 | Gen Motors Corp | Impregnated ferrous gear |
US2715589A (en) * | 1951-10-26 | 1955-08-16 | Ferro Powdered Metals Inc | Metallic impregnation of porous metal |
-
1953
- 1953-05-25 US US357338A patent/US2778742A/en not_active Expired - Lifetime
Patent Citations (5)
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US2422439A (en) * | 1943-01-29 | 1947-06-17 | American Electro Metal Corp | Method of manufacturing composite structural materials |
US2401221A (en) * | 1943-06-24 | 1946-05-28 | Gen Motors Corp | Method of impregnating porous metal parts |
US2481962A (en) * | 1944-02-29 | 1949-09-13 | Fairchild Engie And Airplane C | Manufacture of laminated articles |
US2561579A (en) * | 1947-10-02 | 1951-07-24 | Gen Motors Corp | Impregnated ferrous gear |
US2715589A (en) * | 1951-10-26 | 1955-08-16 | Ferro Powdered Metals Inc | Metallic impregnation of porous metal |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2902747A (en) * | 1959-09-08 | Reiter | ||
US2903611A (en) * | 1955-05-06 | 1959-09-08 | Vickers Electrical Co Ltd | X-ray tube comprising a cast copper anode sealed with a copper-silver electric alloy |
US3120436A (en) * | 1961-03-23 | 1964-02-04 | Presmet Corp | Powdered metal article and method of making |
US3343954A (en) * | 1963-12-13 | 1967-09-26 | Porter Prec Products Inc | Article and process of forming the article from powdered metal |
US3343927A (en) * | 1963-12-18 | 1967-09-26 | Motor Wheel Corp | Sintered metal brake drum |
US3326678A (en) * | 1964-02-03 | 1967-06-20 | Talmage Charles Robert | Method of infiltrating a metal powder compact |
US3429696A (en) * | 1966-08-05 | 1969-02-25 | New Jersey Zinc Co | Iron powder infiltrant |
US3459547A (en) * | 1967-06-28 | 1969-08-05 | Burgess Norton Mfg Co | Method of making a structural alloy steel containing copper and other alloy elements |
US3803687A (en) * | 1970-11-27 | 1974-04-16 | Gen Signal Corp | Bonded bronze-iron valve plate for steel cylinder barrel and method of making same |
US3808659A (en) * | 1972-07-27 | 1974-05-07 | Gen Signal Corp | Bonded bronze-iron liners for steel cylinder barrel and method of making same |
US4769071A (en) * | 1987-08-21 | 1988-09-06 | Scm Metal Products, Inc | Two-step infiltration in a single furnace run |
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