US3326834A - Paraffin wax polybutene-1 resin blends - Google Patents

Paraffin wax polybutene-1 resin blends Download PDF

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US3326834A
US3326834A US395204A US39520464A US3326834A US 3326834 A US3326834 A US 3326834A US 395204 A US395204 A US 395204A US 39520464 A US39520464 A US 39520464A US 3326834 A US3326834 A US 3326834A
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wax
polybutene
resin
creased
molecular weight
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Richard A Signorelli
Joseph I Wrozina
John J Kaufman
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Honeywell International Inc
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Allied Chemical Corp
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Priority to GB38424/65A priority patent/GB1060196A/en
Priority to GB38429/65A priority patent/GB1062855A/en
Priority to FR30963A priority patent/FR1446710A/en
Priority to DE19651570065 priority patent/DE1570065A1/en
Priority to NL6511754A priority patent/NL6511754A/xx
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
    • F16B43/00—Washers or equivalent devices; Other devices for supporting bolt-heads or nuts
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C09D191/06—Waxes
    • C09D191/08—Mineral waxes

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  • This invention relates to petroleum wax compositions and, more particularly, to petroleum wax coating compositions widely used in forming protective coatings for wrapping paper and paperboard in the production of low-cost cartons for liquids.
  • the petroleum industry generally classifies petroleum waxes in three main categories, namely, (1) parains; (2) intermediate; and (3) microcrystalline waxes.
  • Other classes of waxes are known such as the scale waxes and slack waxes; these are low-cost crude waxes.
  • the paraflins are predominantly the normal paraflns, i.e., straight chain saturated hydrocarbons with minor amounts of isoparaflins.
  • the microcrystalline waxes are predominantly cyclic TAB LE I Paratnn Inter Mierocrysmediate talline Melting Point Range, ASTM D127, F 120-160 130-160 130-180 Molecular Weight Range... 340-400 S60-550 500-600 Density Rai 0. 80-0. 917 0. 85-0. 93 0. 89-0. 94 Gravity ASTM D287 AP 0 F 35-60 30-55 30-50 Distillation, Vacuum Corrected to 760 mm. Hg 5% Point, F... 750-810 825-900 950-1,
  • a typical parain wax has the following properties:
  • the upgrading of waxes by the addition of additives thereto has sought to improve the creased barrier properties of the coated material.
  • the property of a coating wax employed, for example, in the coating of paper and paperboard, in the manufacture of food wrappers and paper cartons, to minimize passage of moisture vapor through the creased or folded coated paper and paper: board is a most important factor in the commercial acceptance of that coating wax.
  • a standard test widely used in the wax coating art for measuring this property is the creased moisture vapor transmission rate (referred to herein as creased WVTR). This test is described in TAPPI 465 creased WVTR.
  • sealing strength values are determined by the standard Socony- Vacuum Seal Tester. Two coated specimens which are sealed together under the predetermined temperature, pressure and dwell time specified in the test procedure are pulled at 3 in./min. with a 100 gram load. The values given are the weight in grams required to pull apart the two coated specimens. In the case of the test results given in this specification, the test specimens are each rectangular, 12 inches long, 2 inches wide, arranged in superimposed relation with a l-inch seal at a temperature of ZOO-250 F., pressure of 6-10 p.s.i.g. for a dwell time of 1A: to 1.5 minutes.
  • Grease resistance is a measure of the time required for a drop of the specilied grease to penetrate through the coated, uncreased test specimen.
  • the grease used in the test results given herein was Wesson Oil applied at ambient temperature and maintained at F. until failure of the coating.
  • paraffin waxes are upgraded by blending therewith from 10% to 30% of a polybutene-l resin having a molecular weight of from 100,000 to 200,000 and an isotactic content of from 50% to 70%.
  • this invention involves wax coating compositions consisting essentially of a paraffin wax blended with from 10% to 30% by weight of a polybutene-l resin having a molecular weight of from 100,000 to 200,000 and an isotactic content of from 50% to 70%.
  • the drawing accompanying this specification and forming a part thereof is a graph showing the creased WVT'R values plotted against the percent concentra-tion of five different polybutene-l resins having the different isotactic contents indicated on the graph.
  • curve A shows the creased WVTR values for the base paraffin wax, which is a typical parain wax having the properties hereinabove given for such wax.
  • Curve B is the graph for a blend of this paraflin wax with a polybutene-l resin having a moleucular weight of 186,000 and an isotacticcon- -tent of 51%.
  • Curve C is the graph for a blend of this paralin wax with a polybutene-l resin having a molecular weight of 145,000, and an isotactic content of 57%.
  • Curve D is the graph for a blend of this parain wax with a polybutene-l resin having a molecular weight of 151,000 and an isotactic content of 64%.
  • Curve E is the graph for a blend of this parain wax with a polybutene-l resin having a molecular weight of 190,000 and an isotactic content of 68%.
  • Curve F 4 is the graph for a blend of this paraffin wax with a polybutene-1 resin having a molecular weight of 67,000 and an isotactic content of 92%.
  • the creased WVTR value for the base parain wax is 15.5.
  • the blending therewith of polybutene-l resin having a molecular weight of 186,000 and an isotacticity of 51% markedly improves the creased WVTR values; for a 20% concentration of this polybutene-l resin the creased WVTR value is reduced to 1.9; and for 25 concentration to 1.0.
  • ⁇ of polybutene-l resin having an isotacticity of 57% and a molecular weight of 145,000 a concentration of 20% reduces the creased WVTR value to 7.0, and for 25% concentration to 2.5.
  • vEmploying a ⁇ polybutene-l resin having an isotacticity of 68% the creased WVTR value (16.8) for 10% concentration is, slightly higher than the creased WVTR for the base wax; for a concentration the value is 12.6 as compared with 15.5 for the parain base wax; and for a 30% concentration the creased WVTR value is 2.7, the same as for the polybutene-l resin having an isotactc content of 64%.
  • isotactc is used in its conventional sense to mean the material in the polymer remaining after extraction with diethyl ether; the isotactc material is substantially insoluble in hexane and naphtha.
  • the diethyl ether extraction removes the amorphous or atactic material (which is the material soluble in hexane and naphtha) and leaves a polymer containing the isotactc material.
  • the polybutene-l resin employed in forming lthe wax blends of the present invention can be prepared by polymerizing butene-l using a Ziegler type catalyst and conducting the polymerization under conditions to produce a polymer having the desired isotactc content of from 50% to 70% and desired molecular weight of from 100,000 to 200,000.
  • any of the known Ziegler catalysts can be used; for example, catalysts obtained by reaction between compounds of metals of Group IV-A (titanium, zirconium, hafnium or thorium), V-A (vanadium, columbium or tantalum), VI-A (chromium, molybdenum, tungsten or uranium) with alkyl compounds of aluminum or a metal of Group II (beryllium, magnesium, calcium, strontium, barium, Zinc or cadmium).
  • Group IV-A titanium, zirconium, hafnium or thorium
  • V-A vanadium, columbium or tantalum
  • VI-A chromium, molybdenum, tungsten or uranium
  • alkyl compounds of aluminum or a metal of Group II beryllium, magnesium, calcium, strontium, barium, Zinc or cadmium
  • Polybutene produced by p0- lymerization using stereospecic catalysts such as
  • polystyrene-l having the desired molecular weight and isotactic content.
  • Hydrogen can be introduced into the polymerization reaction mixture to control the molecular weight and percent isotacticity.
  • Polybutene-l polymers having an isotactc content of from 50% to 70% and a molecular weight of from 100,000 to 200,000 produced by any known procedure can be used.
  • Polybutene-l resins having the above noted isotactc contents and molecular weights blend readily with the paraffin wax.
  • polybutene-l with the paraffin wax can be effected in any known or desired manner. A typical procedure for effecting such lblending is described below.
  • a three-necked ask equipped with an electric drive stirrer, a thermometer, and a nitrogen inlet tube is charged with a measured amount of the wax.
  • the wax is heated under nitrogen with moderate stirring until a clear liquid results.
  • a charge of the polybutene-l resin having the molecular weight and isotacticity and in amount all as herein disclosed.
  • the mixture is heated to a temperature above the melting point of the wax and stirred to assist solution.
  • the mixture can be maintained under a continuous blanket of nitrogen during the heating and stirring, if desired, and particularly when the heating is carried out under higher temperatures than 150 C.
  • the polybutene-l charge is completely dissolved in the wax in approximately one-half hour; this is evident upon visual inspection. Desirably, however, heating of the blend is continued for an additional onequarter hour to insure complete dissolution of the resin in the wax.
  • the blend is thereupon allowed to cool to ambient temperature.
  • Table III which follows gives the grease resistance of blends of parain wax with a polybutene-l resin having a ⁇ nolecular weight of 150,000 and an isotactc content of 64% (hereinafter referred to as PB-l) in concentrations of 20% and 30%. This test was carried out with Wesson Oil applied at ambient temperature and maintained at F. on the uncreased paper.
  • the wax blends embodying the present invention are eminently satisfactory for use in existing coating equipment. They can be employed in a'll elds where Wax coatings of superior creased barrier properties, heat seal strength, or good grease resistance, ndapplication.
  • the blends of this invention in the molten state, can be applied Iby known coating techniques to foil, parchment, kraft, glassine, chipboard and other paper stocks to produce packaging materials having an attractive gloss and exceptionally good creased vapor barrier.
  • a petroleum Wax blend consisting of a parain wax distilling Within the temperature range of about 750-810 6 F. and from 10% to 30% by weight of a polybutene-l resin having a molecular weight of from 100,000 to 200,00 and an isotacti-c content of from to 70% by Weight, said 4blend having creased water vapor transmission rate value less than Ithat of said parafln Wax.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Wrappers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Lubricants (AREA)

Description

June 20, 1967 R. A. SIGNORELLI ET Al. 3,326,834
PARAFFIN WAX POLYBUTENE-l RESIN BLENDS I Filed sept. 9, 1964 ATTORNEY United States Patent PARAFFIN WAX PLYBUTENE-l RESIN BLENDS Richard A. Signorelli, Clifton, and Joseph I. Wrozna, Tenaily, NJ., and .lohn J. Kaufman, New Brighton, Pa., assignors to Allied Chemical Corporation, New
York, N.Y., a corporation of New York Filed Sept. 9, 1964, Ser. No. 395,204 4 Claims. (Cl. 260-28.5)
` This invention relates to petroleum wax compositions and, more particularly, to petroleum wax coating compositions widely used in forming protective coatings for wrapping paper and paperboard in the production of low-cost cartons for liquids.
It is a principal object of this invention to upgrade refined parailin waxes with particular reference to improving their creased barrier properties, heat sealing properties and grease resistance.
Other objects and advantages of this invention will be apparent from the following detailed description thereof.
The petroleum industry generally classifies petroleum waxes in three main categories, namely, (1) parains; (2) intermediate; and (3) microcrystalline waxes. Other classes of waxes are known such as the scale waxes and slack waxes; these are low-cost crude waxes. The paraflins are predominantly the normal paraflns, i.e., straight chain saturated hydrocarbons with minor amounts of isoparaflins. The microcrystalline waxes are predominantly cyclic TAB LE I Paratnn Inter Mierocrysmediate talline Melting Point Range, ASTM D127, F 120-160 130-160 130-180 Molecular Weight Range... 340-400 S60-550 500-600 Density Rai 0. 80-0. 917 0. 85-0. 93 0. 89-0. 94 Gravity ASTM D287 AP 0 F 35-60 30-55 30-50 Distillation, Vacuum Corrected to 760 mm. Hg 5% Point, F... 750-810 825-900 950-1, 050
A typical parain wax has the following properties:
Gravity ASTM D287 API 41.3 Melting point ASTM D87 "F 140.1 Congealing point ASTM D938 F 138.0 Penetration ASTM D132l at 77 F. 14.0 at 100 F. 40.0 Flash point, F 455.0 Ultraviolet absorbtivity at 280 my. ASTM D2008 0.01 Iodine number 0.4 Molecular weight 442.0
Refractive index 1.4359 Distillation vacuum corrected to 760 mm. Hg 5% point, "F 804.0
The upgrading of waxes by the addition of additives thereto has sought to improve the creased barrier properties of the coated material. The property of a coating wax employed, for example, in the coating of paper and paperboard, in the manufacture of food wrappers and paper cartons, to minimize passage of moisture vapor through the creased or folded coated paper and paper: board is a most important factor in the commercial acceptance of that coating wax. A standard test widely used in the wax coating art for measuring this property is the creased moisture vapor transmission rate (referred to herein as creased WVTR). This test is described in TAPPI 465 creased WVTR. Briey, it involves the determination 3,320,834I Patented June 20, 1967 of the weight of water vapor in grams which passes in 24 hours through 100 square inches of accordion pleated test sample containing the Vspeciiied weight of coating. All values herein for creased WVTR are determined by this test procedure carried out at F. and 95% RH (relative humidity), are truly comparative because the same weight of coating was applied to all test samples (l5 pounds per 3000 square feet), and are given in al1 `cases in grams per 100 square inches for a 24 hours test period.
Among other properties sought to be improved by the addition of additives to the wax are the sealing strength of the wax coating and its grease resistance. Sealing strength values are determined by the standard Socony- Vacuum Seal Tester. Two coated specimens which are sealed together under the predetermined temperature, pressure and dwell time specified in the test procedure are pulled at 3 in./min. with a 100 gram load. The values given are the weight in grams required to pull apart the two coated specimens. In the case of the test results given in this specification, the test specimens are each rectangular, 12 inches long, 2 inches wide, arranged in superimposed relation with a l-inch seal at a temperature of ZOO-250 F., pressure of 6-10 p.s.i.g. for a dwell time of 1A: to 1.5 minutes.
Grease resistance is a measure of the time required for a drop of the specilied grease to penetrate through the coated, uncreased test specimen. The grease used in the test results given herein was Wesson Oil applied at ambient temperature and maintained at F. until failure of the coating.
In accordance with this invention, paraffin waxes are upgraded by blending therewith from 10% to 30% of a polybutene-l resin having a molecular weight of from 100,000 to 200,000 and an isotactic content of from 50% to 70%. Thus this invention involves wax coating compositions consisting essentially of a paraffin wax blended with from 10% to 30% by weight of a polybutene-l resin having a molecular weight of from 100,000 to 200,000 and an isotactic content of from 50% to 70%.
In this specification, all percentages are given on a weight basis.
Surprisingly, we have found that the blending wtih paran waxes of -polybutene-l resins having an isotactic content of from 50% to 70% and a molecular weight of from 100,000 to 200,000 gives a marked and unexpected improvement in the creased WVIR values and in the heat sealing properties of the blend as well as an improvement in the grease resistance properties. Polybutene-1 resins having higher isotacticities than 70% have markedly poorer creased WVTR values.
The drawing accompanying this specification and forming a part thereof is a graph showing the creased WVT'R values plotted against the percent concentra-tion of five different polybutene-l resins having the different isotactic contents indicated on the graph. In this graph, curve A shows the creased WVTR values for the base paraffin wax, which is a typical parain wax having the properties hereinabove given for such wax. Curve B is the graph for a blend of this paraflin wax with a polybutene-l resin having a moleucular weight of 186,000 and an isotacticcon- -tent of 51%. Curve C is the graph for a blend of this paralin wax with a polybutene-l resin having a molecular weight of 145,000, and an isotactic content of 57%. Curve D is the graph for a blend of this parain wax with a polybutene-l resin having a molecular weight of 151,000 and an isotactic content of 64%. Curve E is the graph for a blend of this parain wax with a polybutene-l resin having a molecular weight of 190,000 and an isotactic content of 68%. Curve F 4is the graph for a blend of this paraffin wax with a polybutene-1 resin having a molecular weight of 67,000 and an isotactic content of 92%.
ascesi-s4.
It will be noted from FIGURE 1 that the creased WVTR value for the base parain wax is 15.5. The blending therewith of polybutene-l resin having a molecular weight of 186,000 and an isotacticity of 51% markedly improves the creased WVTR values; for a 20% concentration of this polybutene-l resin the creased WVTR value is reduced to 1.9; and for 25 concentration to 1.0. In the case `of polybutene-l resin having an isotacticity of 57% and a molecular weight of 145,000, a concentration of 20% reduces the creased WVTR value to 7.0, and for 25% concentration to 2.5. In the case of the polybutene-l resin having a molecular weight of 151,000 and an isotactic content of 64%, blending thereof in a concentration of 20% with the paran wax base reduces the WVTR value to and for a concentration of 30% of the polybu tene-l resin to 2.7.
vEmploying a `polybutene-l resin having an isotacticity of 68% the creased WVTR value (16.8) for 10% concentration is, slightly higher than the creased WVTR for the base wax; for a concentration the value is 12.6 as compared with 15.5 for the parain base wax; and for a 30% concentration the creased WVTR value is 2.7, the same as for the polybutene-l resin having an isotactc content of 64%.
In the case of polybutene-l resins having isotactc contents above 70%, e.g., 92%, curve F in the drawing, throughout the range of from 10% to 30% concentration the. creasedk WVTR values are higher than that of the base paraffin wax; at 10% concentration of polybutene-l resinr having an isotactc content Iof 92% the creased WVTR value is 21.1; at 20% concentration of this resin theY creased WVTR value is 20.4 and at 30% concentration the, creased WVTR value is 17.6 for this polybutenel resin.`
The discovery that by blending a polybutene-l resin having a molecular weight of from ,100,000 to 200,000 and an isotactic content of from 50% to 70% in amount of from 10% to 30% by weight, with a paralin base wax, a waxv composition is obtained having improved creased WVTR values and heat sealing properties as compared with the properties of blends of the same paraflin wax with polybutene-l resins of higher isotactc content, is indeed, surprising and unexpected. This phenomenon is peculiar to parainbase waxes. -In the case of other waxes such as the intermediate waxesand microcrystalline waxes, as a general rule, increase in iso-tacticity ofthe polybutene- 1 resin above 70% used `for blending with the .wax tends to improve creased WVTR values and the heat sealing ,properties of the resultant blend. Blends of intermediate and microcrystalline waxes with isotactc polybutene-l are morefully described in co-pending application Serial No. 395,205, tiled September 9, 196,4.
In Table II which follows is given the creased WVTR 'values and sealing strength values for a typical parain wax (Atlantic Oil Companys Paraflin 1116). In this table M.W. means molecular weight.
In this specifica-tion, the expression isotactc is used in its conventional sense to mean the material in the polymer remaining after extraction with diethyl ether; the isotactc material is substantially insoluble in hexane and naphtha. The diethyl ether extraction removes the amorphous or atactic material (which is the material soluble in hexane and naphtha) and leaves a polymer containing the isotactc material.
The polybutene-l resin employed in forming lthe wax blends of the present invention can be prepared by polymerizing butene-l using a Ziegler type catalyst and conducting the polymerization under conditions to produce a polymer having the desired isotactc content of from 50% to 70% and desired molecular weight of from 100,000 to 200,000. Any of the known Ziegler catalysts can be used; for example, catalysts obtained by reaction between compounds of metals of Group IV-A (titanium, zirconium, hafnium or thorium), V-A (vanadium, columbium or tantalum), VI-A (chromium, molybdenum, tungsten or uranium) with alkyl compounds of aluminum or a metal of Group II (beryllium, magnesium, calcium, strontium, barium, Zinc or cadmium). Polybutene produced by p0- lymerization using stereospecic catalysts such as Cr03 or an SIO2--Al2O3 support or a catalyst consisting of a promoted M003 may also be used. In all cases the polymerization must be timed and moderated to produce a polybutene-l having the desired molecular weight and isotactic content. Hydrogen can be introduced into the polymerization reaction mixture to control the molecular weight and percent isotacticity. Polybutene-l polymers having an isotactc content of from 50% to 70% and a molecular weight of from 100,000 to 200,000 produced by any known procedure can be used.
Polybutene-l resins having the above noted isotactc contents and molecular weights blend readily with the paraffin wax.
The blending of polybutene-l with the paraffin wax can be effected in any known or desired manner. A typical procedure for effecting such lblending is described below.
A three-necked ask equipped with an electric drive stirrer, a thermometer, and a nitrogen inlet tube is charged with a measured amount of the wax. The wax is heated under nitrogen with moderate stirring until a clear liquid results. To the melted wax is added a charge of the polybutene-l resin having the molecular weight and isotacticity and in amount all as herein disclosed. The mixture is heated to a temperature above the melting point of the wax and stirred to assist solution. The mixture can be maintained under a continuous blanket of nitrogen during the heating and stirring, if desired, and particularly when the heating is carried out under higher temperatures than 150 C. The polybutene-l charge is completely dissolved in the wax in approximately one-half hour; this is evident upon visual inspection. Desirably, however, heating of the blend is continued for an additional onequarter hour to insure complete dissolution of the resin in the wax. The blend is thereupon allowed to cool to ambient temperature.
Table III which follows gives the grease resistance of blends of parain wax with a polybutene-l resin having a `nolecular weight of 150,000 and an isotactc content of 64% (hereinafter referred to as PB-l) in concentrations of 20% and 30%. This test was carried out with Wesson Oil applied at ambient temperature and maintained at F. on the uncreased paper.
The time for failure to occur in the case of the paraffin wax was one hour. Thus this test shows a marked improvement in grease resistance properties of the blends of this invention as compared with the base paraffin wax.
Examples of this invention have been given in the above including the tables which give comparative data demonstrating the improvements in creased WV IR values and sealing s-trength of the blends of paran wax with polybutene-l resins having a molecular Weight of from 100,000 to 200,000 and an isotactic content of from 50% to 70% as compared with these properties of the base parain Wax.
The wax blends embodying the present invention are eminently satisfactory for use in existing coating equipment. They can be employed in a'll elds where Wax coatings of superior creased barrier properties, heat seal strength, or good grease resistance, ndapplication. The blends of this invention, in the molten state, can be applied Iby known coating techniques to foil, parchment, kraft, glassine, chipboard and other paper stocks to produce packaging materials having an attractive gloss and exceptionally good creased vapor barrier.
Since certain changes in the petroleum wax polybu- -tene-l blends embodying this invention can be made Without departing from the scope of this invention, it is intended that a'll matter contained in the description shall be interpreted as illustrative and not in ra limiting sense.
What is claimed is:
1. A petroleum Wax blend consisting of a parain wax distilling Within the temperature range of about 750-810 6 F. and from 10% to 30% by weight of a polybutene-l resin having a molecular weight of from 100,000 to 200,00 and an isotacti-c content of from to 70% by Weight, said 4blend having creased water vapor transmission rate value less than Ithat of said parafln Wax.
2. A petroleum wax lblend of claim 1, in Which the polybutene-l resin has a molecular weight of about 186,000 and an isotactic content of about 51%.
3. A petroleum Wax blend of claim 1, in which the poly'butene-l resin has a molecular Weight of about 145,000 and an isotactic content of about 57%.
4. A petroleum Wax blend of claim 1, in which the polybutene-l resin has a molecular Weight of about 151,000 and an isotactic content of about 64%.
References Cited UNITED STATES PATENTS 2,691,647 10/ 1954 Field etal.
2,824,089 2/'1958` Peters et al. 260-881 2,882,246 4/'1959 Leatherman et al.
2,932,633 4/1960 Juveland et all. 260-94.9
MORRIS LIE'BMAN, Primary Examiner.
B. A. AMERNICK, Assistant Examiner.

Claims (1)

1. A PETROLEUM WAX BLEND CONSISTING OF A PARAFFIN WAX DISTILLING WITHIN THE TERMPERATURE RANGE OF ABOUT 750-810* F. AND FROM 10% TO 30% BY WEIGHT OF A POLYBUTENE-1 RESIN HAVNG A MOLECULAR WEIGHT OF FROM 100,000 TO 200,000 AND AN ISOTACTIC CONTENT OF FROM 50% TO 70% BY WEIGHT, SAID BLEND HAVING CREASED WATER VAPOR TRANSMISSION RATE VALUE LESS THAN THAT OF SAID PARAFFIN WAX.
US395204A 1964-09-09 1964-09-09 Paraffin wax polybutene-1 resin blends Expired - Lifetime US3326834A (en)

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BE669415D BE669415A (en) 1964-09-09
US395204A US3326834A (en) 1964-09-09 1964-09-09 Paraffin wax polybutene-1 resin blends
GB38424/65A GB1060196A (en) 1964-09-09 1965-09-08 Paraffin wax polybutene-1 resin blends
GB38429/65A GB1062855A (en) 1964-09-09 1965-09-08 Petroleum wax blend
FR30963A FR1446710A (en) 1964-09-09 1965-09-09 Mixtures of polybutene-1 resins and paraffin waxes
DE19651570065 DE1570065A1 (en) 1964-09-09 1965-09-09 Compounds containing petroleum wax and polybutene-1
NL6511754A NL6511754A (en) 1964-09-09 1965-09-09

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3389107A (en) * 1965-06-21 1968-06-18 Chevron Res Wax-(propene/butene copolymer) films
US3519586A (en) * 1967-10-12 1970-07-07 Eastman Kodak Co Blends of waxes and crystalline copolymers of butene-1 and propylene or ethylene
US3619272A (en) * 1967-09-01 1971-11-09 Princeton Chemical Res Inc Method for coating polyolefin or paper supports with chlorinated butene-1 polymer coatings
US3635849A (en) * 1969-09-08 1972-01-18 University Patents Inc Polyisobutylene paraffin wax and oil blends

Families Citing this family (1)

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Publication number Priority date Publication date Assignee Title
US4092285A (en) * 1976-07-30 1978-05-30 Wyrough And Loser, Inc. Encapsulation of critical chemicals

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US2691647A (en) * 1952-12-06 1954-10-12 Standard Oil Co Conversion of ethylene and/or propylene to solid polymers in the presence of group 6a metal oxides and alkali metals
US2824089A (en) * 1955-03-08 1958-02-18 Standard Oil Co Hydrocarbon conversion
US2882246A (en) * 1954-06-01 1959-04-14 Phillips Petroleum Co Polyethylene-wax composition and process of blending same
US2932633A (en) * 1956-03-28 1960-04-12 Standard Oil Co Catalytic conversion and catalysts

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2691647A (en) * 1952-12-06 1954-10-12 Standard Oil Co Conversion of ethylene and/or propylene to solid polymers in the presence of group 6a metal oxides and alkali metals
US2882246A (en) * 1954-06-01 1959-04-14 Phillips Petroleum Co Polyethylene-wax composition and process of blending same
US2824089A (en) * 1955-03-08 1958-02-18 Standard Oil Co Hydrocarbon conversion
US2932633A (en) * 1956-03-28 1960-04-12 Standard Oil Co Catalytic conversion and catalysts

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3389107A (en) * 1965-06-21 1968-06-18 Chevron Res Wax-(propene/butene copolymer) films
US3619272A (en) * 1967-09-01 1971-11-09 Princeton Chemical Res Inc Method for coating polyolefin or paper supports with chlorinated butene-1 polymer coatings
US3519586A (en) * 1967-10-12 1970-07-07 Eastman Kodak Co Blends of waxes and crystalline copolymers of butene-1 and propylene or ethylene
US3635849A (en) * 1969-09-08 1972-01-18 University Patents Inc Polyisobutylene paraffin wax and oil blends

Also Published As

Publication number Publication date
GB1062855A (en) 1967-03-22
GB1060196A (en) 1967-03-01
NL6511754A (en) 1966-03-10
BE669415A (en)
DE1570065A1 (en) 1969-07-24

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