US3753335A - Condensation of halohydrocarbons - Google Patents

Condensation of halohydrocarbons Download PDF

Info

Publication number
US3753335A
US3753335A US00088649A US3753335DA US3753335A US 3753335 A US3753335 A US 3753335A US 00088649 A US00088649 A US 00088649A US 3753335D A US3753335D A US 3753335DA US 3753335 A US3753335 A US 3753335A
Authority
US
United States
Prior art keywords
vapour
stream
halogenated hydrocarbon
calcium chloride
condensed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00088649A
Inventor
V Morris
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of US3753335A publication Critical patent/US3753335A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0078—Condensation of vapours; Recovering volatile solvents by condensation characterised by auxiliary systems or arrangements
    • B01D5/0087—Recirculating of the cooling medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0027—Condensation of vapours; Recovering volatile solvents by condensation by direct contact between vapours or gases and the cooling medium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives

Definitions

  • ABSTRACT [30] Foreign Application Priority Data Dec. 5, 1969 Great Britain 59,511/69 A Process for condensing halogenated hydrocarbon which comprises bringing a stream comprising haloge- 52 us. Cl. 55/29 mated hydrocarbon vapour, water vapour and [51] Int. Cl. B0ld 53/16 n nsa gas s int direct Contact with a liquid me- [58] Field of Search 55/29-32, 82 dium which is maintained at a Subnormal temperature 5 sufficient to condense both the halogenated hydrocarbon vapour and the water vapour and which retains [56] References Ci d condensed water in the liquid. phase.
  • Streams comprising halogenated hydrocarbon vapour, water vapour and non-condensable gases are encountered in industry and difficulties arise in the condensation of the halogenated hydrocarbon vapour. It is a common enough procedure to recover halogenated hydrocarbons from such a stream by bringing the stream into indirect contact with a fluid maintained at sub-zero temperatures (below C) circulating in a condenser. The halogenated hydrocarbon is thereby condensed and other components of the stream, for example, nitrogen pass out of the system as uncondensed gases.
  • ice is deposited on the condenser surface and this seriously affects heat exchange between the stream and the cold fluid.
  • ice can block the plant, for example in pipelines and in valves. The problem can be so acute that it becomes necessary to duplicate the condensation system so that while one system is in operation the other is being freed from ice.
  • a condensation process which comprises bringing a stream comprising halogenated hydrocarbon vapour, water vapour and non-condensable gases into direct contact with a liquid medium which is maintained at a sub-normal temperature sufficient to condense both the halogenated hydrocarbon vapour and the water vapour and which retains condensed water in the liquid pha e.
  • the liquid medium should be inert to the halogenated hydrocarbon. Good results are obtained when there is employed as liquid medium an aqueous solution of a metal salt which is substantially immiscible with the condensed halogenated hydrocarbon. Good results are obtained when using an aqueous calcium chloride brine.
  • concentration of calcium chloride brine will be such that freezing out or crystallisation of a solid phase does not occur at the lowest temperature employed in the system.
  • the present process is applicable to the treatment of a single halogenated hydrocarbon or mixtures thereof and finds its widest application in the treatment of chlo-. rinated hydrocarbons.
  • the water vapour associated with the halohydrocarbon may have been picked up by treatment of a hot crude exit stream. from a'reactor with aqueous quenching and washing treatments.
  • a hot crude exit stream from a'reactor with aqueous quenching and washing treatments.
  • the crude exit product may be submitted to various aqueous quenching and washing steps to reduce the temperature of the stream, to condense some of the 1,2- dichloroethane and to remove hydrogen chloride contained in the stream.
  • the temperature of the calcium chloride brine is suitably in the range 0C to 40C and of concentration to 32 percent by weight calcium chloride, when treating a stream comprising l,2-dichloroethane vapour, water vapour and non-condensable gases which is at a temperature in the range 50 to 0C.
  • FIG. 1 is a ring-packed tower
  • 2 is an inlet for the stream comprising halogenated hydrocarbon vapour, water vapour and non-condensable gases.
  • 3 is an inlet for cold calcium chloride brine.
  • 4 is a pipe for removing a mixture of calcium chloride brine and condensed halogenated hydrocarbon.
  • 5 is a gravity separator.
  • 6 is a pipe for withdrawal of the condensed halohydrocarbon layer.
  • 7 is a pipe for withdrawal of calcium chloride brine which passes via pump 8, pipes 9 and 10, and cooler 11 to pipe 3.
  • 12 is a pipe for withdrawal of a small amount of calcium chloride brine.
  • 13 is a pipe for discharge of uncondensed gases and vapours.
  • a stream (3250 kg/hr) at a temperature of 5C and at a pressure of 5 ats gauge consisting of kg/hr 1,2-dichloroethane vapour, 5 kg/hr water vapour, the remainder being nitrogen, carbon dioxide and ethylene is passed through pipe 2 to the tower 1.
  • the latter is 30 ft high and 2 ft diameter and is packed with 1% inch Raschig rings.
  • the stream meets a flow of 5% m /hr of calcium chloride brine of concentration 25 to 32 percent by weight calcium chloride which is at a temperature of 30C and enters via pipe 3 and flows down tower 1.
  • a mixture of condensed 1,2-dichloroethane and calcium chloride brine at 22C leaves the tower via pipe 4 to settle in gravity separator 5.
  • a bottom layer of condensed 1,2-dichloroethane leaves the separator via pipe 6.
  • Calcium chloride brine leaves the separator via pipe 7 and passes via pump 8 and pipes 9 and 10 to cooler 11 (through which is passed a refrigerant) and so to pipe 3 and tower 1.
  • Nitrogen, carbon dioxide, ethylene and a little l,2-dichloroethane vapour leave the tower via pipe 13 at 28C.
  • a small amount of calcium chloride brine leaves via pipe 12 for purging of part of the aqueous phase.
  • a condensation process which comprises bringing a stream comprising 1,2-dichloroethane, water vapor dichloroethane.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for condensing halogenated hydrocarbon which comprises bringing a stream comprising halogenated hydrocarbon vapour, water vapour and non-condensable gases into direct contact with a liquid medium which is maintained at a subnormal temperature sufficient to condense both the halogenated hydrocarbon vapour and the water vapour and which retains condensed water in the liquid phase.

Description

United States Patent [1 1 Morris Aug. 21, 1973 CONDENSATION 0F 3,400,512 9/1968 McKay 55/82 HALOHYDROCARBONS 2,765,049 10/1956 Nafziger 55/29 3,403,522 10/1968 Henry 55/31 [75] lnventor: Victor William Morris, Runcorn,
England [73] Assignee: Imperial Chemical Industries Primary Examiner-Charles t Limited, London, En land Attorney-Cushman, Darby & Cushman [22] Filed: Nov. 12, 1970 [21] Appl. No.: 88,649
[57] ABSTRACT [30] Foreign Application Priority Data Dec. 5, 1969 Great Britain 59,511/69 A Process for condensing halogenated hydrocarbon which comprises bringing a stream comprising haloge- 52 us. Cl. 55/29 mated hydrocarbon vapour, water vapour and [51] Int. Cl. B0ld 53/16 n nsa gas s int direct Contact with a liquid me- [58] Field of Search 55/29-32, 82 dium which is maintained at a Subnormal temperature 5 sufficient to condense both the halogenated hydrocarbon vapour and the water vapour and which retains [56] References Ci d condensed water in the liquid. phase.
UNITED STATES PATENTS 3,589,104 6/1971 Panzanella 55/32 2 Claims, 1 Drawing Figure PATENTEDAUGZIW- I 3753335 I nvenlor V/erae M4 1 //7M No 02/5 A ttorneys CONDENSATION OF HALOHYDROCARBONS This invention relates to an improved process for the condensation of halogenated hydrocarbons.
Streams comprising halogenated hydrocarbon vapour, water vapour and non-condensable gases are encountered in industry and difficulties arise in the condensation of the halogenated hydrocarbon vapour. It is a common enough procedure to recover halogenated hydrocarbons from such a stream by bringing the stream into indirect contact with a fluid maintained at sub-zero temperatures (below C) circulating in a condenser. The halogenated hydrocarbon is thereby condensed and other components of the stream, for example, nitrogen pass out of the system as uncondensed gases. However, as the stream contains water vapour, ice is deposited on the condenser surface and this seriously affects heat exchange between the stream and the cold fluid. Furthermore ice can block the plant, for example in pipelines and in valves. The problem can be so acute that it becomes necessary to duplicate the condensation system so that while one system is in operation the other is being freed from ice.
It is an object of the present invention to provide an improved process which enables halogenated hydrocarbons to be condensed while at the same time it also avoids formation of ice.
According to the present invention therefore we provide a condensation process which comprises bringing a stream comprising halogenated hydrocarbon vapour, water vapour and non-condensable gases into direct contact with a liquid medium which is maintained at a sub-normal temperature sufficient to condense both the halogenated hydrocarbon vapour and the water vapour and which retains condensed water in the liquid pha e.
The liquid medium should be inert to the halogenated hydrocarbon. Good results are obtained when there is employed as liquid medium an aqueous solution of a metal salt which is substantially immiscible with the condensed halogenated hydrocarbon. Good results are obtained when using an aqueous calcium chloride brine. The concentration of calcium chloride brine will be such that freezing out or crystallisation of a solid phase does not occur at the lowest temperature employed in the system.
The present process is applicable to the treatment of a single halogenated hydrocarbon or mixtures thereof and finds its widest application in the treatment of chlo-. rinated hydrocarbons. The water vapour associated with the halohydrocarbon may have been picked up by treatment of a hot crude exit stream. from a'reactor with aqueous quenching and washing treatments. For example in the oxychlorination of ethylene the crude exit product may be submitted to various aqueous quenching and washing steps to reduce the temperature of the stream, to condense some of the 1,2- dichloroethane and to remove hydrogen chloride contained in the stream. Such a stream containing l,2-. dichloro-ethane vapour, water vapour and large amounts of uncondensable gases such as unreacted ethylene and nitrogen are eminently useful for treating according to the process of the present invention. The temperature of the calcium chloride brine is suitably in the range 0C to 40C and of concentration to 32 percent by weight calcium chloride, when treating a stream comprising l,2-dichloroethane vapour, water vapour and non-condensable gases which is at a temperature in the range 50 to 0C.
Direct contact of the stream with the liquid medium can be easily effected, for example, in ring-packed towers or in trayed columns. The condensed halogenated hydrocarbon and liquid medium, for example, calcium chloride brine, are separated and the condensed halohydrocarbon, e.g. 1,2-dichloroethane is recovered. Conventional means may be provided for purifying the condensed halohydrocarbon, e.g. by fractional distillation. Water entrapped from the stream by the liquid medium, e.g. calcium chloride brine, can be removed by purging part of the brine or by concentrating the brine.
One suitable type of apparatus for carrying out the process of the invention is described in the accompanying drawing which is not drawn to scale. In the drawing 1 is a ring-packed tower, 2 is an inlet for the stream comprising halogenated hydrocarbon vapour, water vapour and non-condensable gases. 3 is an inlet for cold calcium chloride brine. 4 is a pipe for removing a mixture of calcium chloride brine and condensed halogenated hydrocarbon. 5 is a gravity separator. 6 is a pipe for withdrawal of the condensed halohydrocarbon layer. 7 is a pipe for withdrawal of calcium chloride brine which passes via pump 8, pipes 9 and 10, and cooler 11 to pipe 3. 12 is a pipe for withdrawal of a small amount of calcium chloride brine. 13 is a pipe for discharge of uncondensed gases and vapours.
Reference is now made to one particular process according to the invention carried out under specific conditions when using the apparatus illustrated in the drawing. A stream (3250 kg/hr) at a temperature of 5C and at a pressure of 5 ats gauge consisting of kg/hr 1,2-dichloroethane vapour, 5 kg/hr water vapour, the remainder being nitrogen, carbon dioxide and ethylene is passed through pipe 2 to the tower 1. The latter is 30 ft high and 2 ft diameter and is packed with 1% inch Raschig rings. The stream meets a flow of 5% m /hr of calcium chloride brine of concentration 25 to 32 percent by weight calcium chloride which is at a temperature of 30C and enters via pipe 3 and flows down tower 1. A mixture of condensed 1,2-dichloroethane and calcium chloride brine at 22C leaves the tower via pipe 4 to settle in gravity separator 5. A bottom layer of condensed 1,2-dichloroethane leaves the separator via pipe 6. Calcium chloride brine leaves the separator via pipe 7 and passes via pump 8 and pipes 9 and 10 to cooler 11 (through which is passed a refrigerant) and so to pipe 3 and tower 1. Nitrogen, carbon dioxide, ethylene and a little l,2-dichloroethane vapour leave the tower via pipe 13 at 28C. A small amount of calcium chloride brine leaves via pipe 12 for purging of part of the aqueous phase.
Although the process has been particularly described with reference to use of calcium chloride brine other liquid media can be used. Thus organic liquids, for example, ethylene glycol, may be employed. If the organic medium is miscible with the condensed halohydrocarbon then the condensed water will be associated with the medium in the mixed phase. Under such conditions the mixed phase can then be submitted to fractional distillation to separate the various components of the phase.
What we claim is:
l. A condensation process which comprises bringing a stream comprising 1,2-dichloroethane, water vapor dichloroethane.
2. A process as claimed in claim 1, in which the stream comprises 1,2-dichloroethane vapour, water vapour and non-condensable gases including ethylene and nitrogen produced by the oxychlorination of ethylene followed by aqueous quenching and washing steps. 1' 8i i i

Claims (1)

  1. 2. A process as claimed in claim 1, in which the stream comprises 1,2-dichloroethane vapour, water vapour and non-condensable gases including ethylene and nitrogen produced by the oxychlorination of ethylene followed by aqueous quenching and washing steps.
US00088649A 1969-12-05 1970-11-12 Condensation of halohydrocarbons Expired - Lifetime US3753335A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5951169 1969-12-05

Publications (1)

Publication Number Publication Date
US3753335A true US3753335A (en) 1973-08-21

Family

ID=10483897

Family Applications (1)

Application Number Title Priority Date Filing Date
US00088649A Expired - Lifetime US3753335A (en) 1969-12-05 1970-11-12 Condensation of halohydrocarbons

Country Status (4)

Country Link
US (1) US3753335A (en)
BE (1) BE759602A (en)
GB (1) GB1322902A (en)
ZA (1) ZA707672B (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4575387A (en) * 1983-04-29 1986-03-11 Institut Francais Du Petrole Process for separating a multi-component gaseous mixture
US4604107A (en) * 1983-11-10 1986-08-05 Linde Aktiengesellschaft Low temperature separation of fluids by formation of phases having different densities
WO2004043566A2 (en) * 2002-11-13 2004-05-27 Deka Products Limited Partnership Distillation with vapour pressurization
US20050016828A1 (en) * 2002-11-13 2005-01-27 Deka Products Limited Partnership Pressurized vapor cycle liquid distillation
US20050238499A1 (en) * 2002-11-13 2005-10-27 Deka Products Limited Partnership Fluid transfer using devices with rotatable housings
US20070017192A1 (en) * 2002-11-13 2007-01-25 Deka Products Limited Partnership Pressurized vapor cycle liquid distillation
US8006511B2 (en) 2007-06-07 2011-08-30 Deka Products Limited Partnership Water vapor distillation apparatus, method and system
US8069676B2 (en) 2002-11-13 2011-12-06 Deka Products Limited Partnership Water vapor distillation apparatus, method and system
US8359877B2 (en) 2008-08-15 2013-01-29 Deka Products Limited Partnership Water vending apparatus
US8511105B2 (en) 2002-11-13 2013-08-20 Deka Products Limited Partnership Water vending apparatus
US11826681B2 (en) 2006-06-30 2023-11-28 Deka Products Limited Partneship Water vapor distillation apparatus, method and system
US11885760B2 (en) 2012-07-27 2024-01-30 Deka Products Limited Partnership Water vapor distillation apparatus, method and system
US11884555B2 (en) 2007-06-07 2024-01-30 Deka Products Limited Partnership Water vapor distillation apparatus, method and system

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1549181A (en) * 1975-07-23 1979-08-01 Bp Chem Int Ltd Method and apparatus for the recovery of volatile liquids
GB1582955A (en) * 1976-07-28 1981-01-21 Boc Ltd Condensation of the vapour of a volatile liquid
US4331375A (en) * 1978-11-28 1982-05-25 Tokyo Shibaura Denki Kabushiki Kaisha Electrical contact assembly
BR8504651A (en) * 1985-09-23 1986-03-04 Sanbra Algodoeira Soc VACUUM PROCESS FOR DEODORIZATION / PHYSICAL REFINING OF OILS AND FATS THROUGH DIRECT STEAM CONDENSATION
US4932984A (en) * 1989-07-27 1990-06-12 The Dow Chemical Company Process for reduction of chlorinated solvent emissions

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2765049A (en) * 1954-02-01 1956-10-02 Columbia Southern Chem Corp Production of hci
US3400512A (en) * 1966-07-05 1968-09-10 Phillips Petroleum Co Method for removing water and hydrocarbons from gaseous hci
US3403522A (en) * 1965-04-26 1968-10-01 Walter L. Henry Apparatus for low temperature dehydration of gases
US3589104A (en) * 1969-06-26 1971-06-29 Dow Chemical Co Recovery of chemicals from off-gases

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2765049A (en) * 1954-02-01 1956-10-02 Columbia Southern Chem Corp Production of hci
US3403522A (en) * 1965-04-26 1968-10-01 Walter L. Henry Apparatus for low temperature dehydration of gases
US3400512A (en) * 1966-07-05 1968-09-10 Phillips Petroleum Co Method for removing water and hydrocarbons from gaseous hci
US3589104A (en) * 1969-06-26 1971-06-29 Dow Chemical Co Recovery of chemicals from off-gases

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4575387A (en) * 1983-04-29 1986-03-11 Institut Francais Du Petrole Process for separating a multi-component gaseous mixture
US4604107A (en) * 1983-11-10 1986-08-05 Linde Aktiengesellschaft Low temperature separation of fluids by formation of phases having different densities
US7597784B2 (en) 2002-11-13 2009-10-06 Deka Products Limited Partnership Pressurized vapor cycle liquid distillation
US8069676B2 (en) 2002-11-13 2011-12-06 Deka Products Limited Partnership Water vapor distillation apparatus, method and system
WO2004043566A3 (en) * 2002-11-13 2004-08-26 Deka Products Lp Distillation with vapour pressurization
US20050016828A1 (en) * 2002-11-13 2005-01-27 Deka Products Limited Partnership Pressurized vapor cycle liquid distillation
US20050238499A1 (en) * 2002-11-13 2005-10-27 Deka Products Limited Partnership Fluid transfer using devices with rotatable housings
US20070017192A1 (en) * 2002-11-13 2007-01-25 Deka Products Limited Partnership Pressurized vapor cycle liquid distillation
US9194392B2 (en) 2002-11-13 2015-11-24 Deka Products Limited Partnership Fluid transfer using devices with rotatable housings
US7465375B2 (en) 2002-11-13 2008-12-16 Deka Products Limited Partnership Liquid ring pumps with hermetically sealed motor rotors
US7488158B2 (en) 2002-11-13 2009-02-10 Deka Products Limited Partnership Fluid transfer using devices with rotatable housings
US20090185918A1 (en) * 2002-11-13 2009-07-23 Deka Products Limited Partnership Fluid Transfer Using Devices with Rotatable Housings
US20040099521A1 (en) * 2002-11-13 2004-05-27 Deka Products Limited Partnership Liquid ring pumps with hermetically sealed motor rotors
US20080105610A1 (en) * 2002-11-13 2008-05-08 Deka Products Limited Partnership Pressurized Vapor Cycle Liquid Distillation
US8506762B2 (en) 2002-11-13 2013-08-13 Deka Products Limited Partnership Pressurized vapor cycle liquid distillation
US8282790B2 (en) 2002-11-13 2012-10-09 Deka Products Limited Partnership Liquid pumps with hermetically sealed motor rotors
US8517052B2 (en) 2002-11-13 2013-08-27 Deka Products Limited Partnership Pressurized vapor cycle liquid distillation
US8366883B2 (en) 2002-11-13 2013-02-05 Deka Products Limited Partnership Pressurized vapor cycle liquid distillation
WO2004043566A2 (en) * 2002-11-13 2004-05-27 Deka Products Limited Partnership Distillation with vapour pressurization
US8511105B2 (en) 2002-11-13 2013-08-20 Deka Products Limited Partnership Water vending apparatus
US11826681B2 (en) 2006-06-30 2023-11-28 Deka Products Limited Partneship Water vapor distillation apparatus, method and system
US8006511B2 (en) 2007-06-07 2011-08-30 Deka Products Limited Partnership Water vapor distillation apparatus, method and system
US11884555B2 (en) 2007-06-07 2024-01-30 Deka Products Limited Partnership Water vapor distillation apparatus, method and system
US8359877B2 (en) 2008-08-15 2013-01-29 Deka Products Limited Partnership Water vending apparatus
US11285399B2 (en) 2008-08-15 2022-03-29 Deka Products Limited Partnership Water vending apparatus
US11885760B2 (en) 2012-07-27 2024-01-30 Deka Products Limited Partnership Water vapor distillation apparatus, method and system

Also Published As

Publication number Publication date
GB1322902A (en) 1973-07-11
BE759602A (en) 1971-04-30
ZA707672B (en) 1972-06-28

Similar Documents

Publication Publication Date Title
US3753335A (en) Condensation of halohydrocarbons
US4234510A (en) Recovery of acrylonitrile or methacrylonitrile by condensation
US2904511A (en) Method and apparatus for producing purified water from aqueous saline solutions
US1422182A (en) Treating gaseous hydrocarbon mixtures
US3192128A (en) Process for purifying aqueous hydrochloric acid
US1942131A (en) Separation of gas mixtures
US3927153A (en) Process for direct cooling of corrosive industrial cases
US1422183A (en) Process of treating gaseous mixtures
US3985863A (en) Process for the separation and recovery of ammonia and acid gases
US3247649A (en) Absorption process for separating components of gaseous mixtures
US2357095A (en) Process for the manufacture of anhydrous hydrogen halide
CA1044591A (en) Recovery of hydrogen chloride from gaseous product streams containing chlorinated hydrocarbons such as chloromethanes
JPH0366633A (en) Reduction of liberation of chlorinated solvent
US10551120B2 (en) Method for condensing a CO2 vapor stream beyond the frost point
US2336643A (en) Process for treatment of hydrocarbons
US3758572A (en) Process for recovering urea from pyrolysis systems
US3657375A (en) Production of acetylene
US1231123A (en) Production of chlorinated hydrocarbons.
US2252536A (en) Purifying pyrolysates of halohydrocarbons
CA1165781A (en) Chlorocarbon recovery apparatus
US2822889A (en) Chlorine purification
US2048838A (en) Process of producing vinylacetylene
US2088048A (en) Hydrofluoric acid product and method of producing the same
US2708490A (en) Recovery of condensable components from a gas and vapour mixture
US3095295A (en) Chemical process