US3764544A - Spot remover for wearing apparel - Google Patents

Spot remover for wearing apparel Download PDF

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Publication number
US3764544A
US3764544A US00169815A US3764544DA US3764544A US 3764544 A US3764544 A US 3764544A US 00169815 A US00169815 A US 00169815A US 3764544D A US3764544D A US 3764544DA US 3764544 A US3764544 A US 3764544A
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range
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percent
spot
acetate
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US00169815A
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L Haworth
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents

Definitions

  • ABSTRACT A cleansing solution for removing spots from cloth and the like comprising the following ingredients:
  • a detergent of polyethylene glycol ethers such as Union Carbide 15-5- 9, a9 mole ethylene oxide adduct of a secondary alcohol in the range of 10-30 percent by volume;
  • a suitable coupling agent for stability and as a clarifier such as a glycol ether solvent, for example, Dowanol EB, in the range of 2 -IO percent by volume; and
  • the present invention relates in general to cleansing solutions and more particularly to a cleansing solution for removing spots from fabrics and the like.
  • the operator had to have previous exposure as to the identification of the fabric and would seek information as to the type of spot on the fabric, such as lipstick, tea, coffee, paint, food, et cetera so as to be able to apply a particular chemical solution found to be most successful for the particular spot and the particular fabric involved.
  • the cleansing solution of the present invention can also be employed on carpets, drapes, vinyl floors, ovens, appliances, automobiles, woodwork, tiles, glassware, floors and the like.
  • the cleansing solution of the present invention has been found to be particularly useful in removing latex or acryllic paints from fabrics while not removing water based vegetable dyes from fabrics.
  • a single cleansing solution can be employed to remove spots from fabrics without knowledge of the particular fabric or spot involved. Such spots could be caused by lipstick, blood, tea, coffee, paints, foods, et cetera. Thus, the need for many different chemical solutions has been obviated. The cleansing is achieved without damage to the fabric.
  • the work of the spot removing operator at a dry cleaning establishment has been simplified and facilitated. It may be used prior to placing fabrics in the dry cleaning machine, or it may be used as an additive for the dry cleaning machine.
  • the detergent is of the polyethylene glycol ether of an alcohol with a carbon range of C r-C with a ethylene oxide adduct of a range of 7-15 mole EtO.
  • the detergent may be an ethoxylated alkyl phenol ofa carbon range of C -C with ethylene oxide adduct of 7-l5 moles EtO.
  • the ester solvent is of the group comprising amyl acetate, butyl acetate, hexyl acetate or ethyl acetate.
  • the acetate is amyl acetate.
  • the coupling agents could be a glycol ether solvent, such as Dowanol EB or its related esters of the glycol ether solvents class.
  • the use of a coupling agent is optional.
  • the coupling agent may also be an alcohol such as ethyl, propyl, methyl or butyl alcohols.
  • the coupling agents serve as active stain or spot removing ingredients in that it removes hydrocarbon, grease, oil and similar stains.
  • the detergent, amyl acetate and the coupling agent are poured into a suitable receptacle. Water is then added and the ingredients are mixed well to form the cleansing solution.
  • a spot remover for wearing apparel and the like consisting essentially of:
  • water of the range 30 percent by volume for removing a spot from wearing apparel water of the range 30 percent by volume for removing a spot from wearing apparel.
  • a spot remover for wearing apparel and the like consisting essentially of:
  • water of the range 30 80 percent by volume for removing a spot from wearing apparel water of the range 30 80 percent by volume for removing a spot from wearing apparel.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

A cleansing solution for removing spots from cloth and the like comprising the following ingredients: A DETERGENT OF POLYETHYLENE GLYCOL ETHERS SUCH AS Union Carbide 15-5-9, a 9 mole ethylene oxide adduct of a secondary alcohol in the range of 10-30 percent by volume; AN ACETATE SOLVENT OF THE GROUP INCLUDING AMYL ACETATE, ETHYL ACETATE, HEXYL ACETATE AND BUTYL ACETATE IN THE RANGE OF 10-30 PERCENT BY VOLUME; A SUITABLE COUPLING AGENT FOR STABILITY AND AS A CLARIFIER, SUCH AS A GLYCOL ETHER SOLVENT, FOR EXAMPLE, Dowanol EB, in the range of 2 1/2 -10 percent by volume; and WATER IN THE RANGE OF 30-80 PERCENT BY VOLUME.

Description

Elite 8 es Haworth Oct. 9, 1973 SPOT REMOVEIR FOR WEARING APPAREL [76] Inventor: Leon L. Haworth, 7160 Galli Ct.
No. 4, San Jose, Calif. 95129 [22] Filed: Aug. 6, 1971 21 Appl. No.: 169,815
Related U.S. Application Data [63] Continuation-impart of Ser. No. 59,681, July 30,
1970, abandoned.
OTHER PUBLICATIONS Nivens-lndustrial Detergency 1955 Reinhold Publ.
Co. TP990 pp. 106-107.
Primary ExaminerWilliam E. Schulz Attorney-Jack M. Wiseman [5 7] ABSTRACT A cleansing solution for removing spots from cloth and the like comprising the following ingredients:
a detergent of polyethylene glycol ethers such as Union Carbide 15-5- 9, a9 mole ethylene oxide adduct of a secondary alcohol in the range of 10-30 percent by volume;
an acetate solvent of the group including amyl acetate, ethyl acetate, hexyl acetate and butyl acetate in the range of 10-30 percent by volume;
a suitable coupling agent for stability and as a clarifier, such as a glycol ether solvent, for example, Dowanol EB, in the range of 2 -IO percent by volume; and
water in the range of 30-80 percent by volume.
4 Claims, No Drawings SPOT REMOVER FOR WEARING APPAREL RELATED APPLICATION This application is a continuation in part of my copending application, Ser. No. 59,681, filed on July 30, 1970 for Cleansing Solution now abandoned.
BACKGROUND OF THE INVENTION The present invention relates in general to cleansing solutions and more particularly to a cleansing solution for removing spots from fabrics and the like.
Heretofore, in the dry cleaning of cloth, a vast variety of cleansing solutions were employed to remove a given spot on a trial and error basis. It has been known that in the neighborhood of 15 spot removing chemicals would be on a board for the purpose of removing a spot. Such chemical solutions have been known to damage the color and the fabric and were only partially effective.
In addition, the operator had to have previous exposure as to the identification of the fabric and would seek information as to the type of spot on the fabric, such as lipstick, tea, coffee, paint, food, et cetera so as to be able to apply a particular chemical solution found to be most successful for the particular spot and the particular fabric involved.
SUMMARY OF THE INVENTION A spot removing solution for wearing apparel and the like comprising:
a detergent of polyethylene glycol ethers in the range V of l-30 percent by volume;
an ester solvent of the group including amyl acetate, hexyl acetate and butyl acetate in the range of -30 percent by volume;
a suitable coupling agent for stability and as a clarifier, in the range of 2 %-l0 percent by volume; and
water in the range of 30-80 percent by volume.
While the exemplary embodiment makes reference to spot removing from fabrics, the cleansing solution of the present invention can also be employed on carpets, drapes, vinyl floors, ovens, appliances, automobiles, woodwork, tiles, glassware, floors and the like.
The cleansing solution of the present invention has been found to be particularly useful in removing latex or acryllic paints from fabrics while not removing water based vegetable dyes from fabrics.
By virtue of the present invention, a single cleansing solution can be employed to remove spots from fabrics without knowledge of the particular fabric or spot involved. Such spots could be caused by lipstick, blood, tea, coffee, paints, foods, et cetera. Thus, the need for many different chemical solutions has been obviated. The cleansing is achieved without damage to the fabric.
In addition to the foregoing, the work of the spot removing operator at a dry cleaning establishment has been simplified and facilitated. It may be used prior to placing fabrics in the dry cleaning machine, or it may be used as an additive for the dry cleaning machine.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Range By Volume Ingredients a detergent of polyethylene glycol ether l0%-30% an ester solvent l0%3 0% a coupling agent 2/z%l0% water 30%-80% The detergent is of the polyethylene glycol ether of an alcohol with a carbon range of C r-C with a ethylene oxide adduct of a range of 7-15 mole EtO. In the alternative, the detergent may be an ethoxylated alkyl phenol ofa carbon range of C -C with ethylene oxide adduct of 7-l5 moles EtO.
The ester solvent is of the group comprising amyl acetate, butyl acetate, hexyl acetate or ethyl acetate. Preferably, the acetate is amyl acetate.
For clarification and stability a suitable active coupling agent may be employed. The coupling agents could be a glycol ether solvent, such as Dowanol EB or its related esters of the glycol ether solvents class. The use of a coupling agent is optional. The coupling agent may also be an alcohol such as ethyl, propyl, methyl or butyl alcohols. The coupling agents serve as active stain or spot removing ingredients in that it removes hydrocarbon, grease, oil and similar stains.
The preferred embodiment of the cleansing solution of the present invention is as follows by volume:
a detergent of polyethylene In the preparation of the cleansing solution, the detergent, amyl acetate and the coupling agent are poured into a suitable receptacle. Water is then added and the ingredients are mixed well to form the cleansing solution..
I claim:
1. A spot remover for wearing apparel and the like consisting essentially of:
a polyethylene glycol ether detergent of an alcohol with a carbon range of C8-Cl7 with an ethylene oxide adduct of a range of 7 15 mole ETO, said polyethylene glycol ether detergent being of the range 10 30 percent by volume for removing a spot from wearing apparel,
an ester solvent of the group comprising an amyl acetate, ethyl acetate, butyl acetate and hexyl acetate of the range 10 30 percent by volume for removing a spot from wearing apparel; and
water of the range 30 percent by volume for removing a spot from wearing apparel.
2. A spot remover for wearing apparel and the like consisting essentially of:
an ethoxylated alkyl phenol of a carbon range of C8 C17 with ethylene oxide adduct of 7 l5 moles ETO, said ethoxylated alkyl phenol being of the range 10 30 percent by volume for removing a spot from wearing apparel,
an ester solvent of the group comprising an amyl acetate, ethyl acetate, butyl acetate and hexyl acetate of the range 10 30 percent by volume for removing a spot from wearing apparel; and
water of the range 30 80 percent by volume for removing a spot from wearing apparel.
3. A spot remover as claimed in claim 1 wherein a coupling agent is provided for stability and clarification of the range 2% 10 percent by volume, said coupling agent being of the group comprising, ethyl alcohol, propyl alcohol, methyl alcohol and butyl alcohol.
4. A spot remover as claimed in claim 2 wherein a coupling agent is provided for stability and clarification of the range 2% 10 percent by volume, said coupling agent being of the group comprising, ethyl alcohol, propyl alcohol, methol alcohol and butyl alcohol.

Claims (3)

  1. 2. A spot remover for wearing apparel and the like consisting essentially of: an ethoxylated alkyl phenol of a carbon range of C8 - C17 with ethylene oxide adduct of 7 - 15 moles ETO, said ethoxylated alkyl phenol being of the range 10 - 30 percent by volume for removing a spot from wearing apparel, an ester solvent of the group comprising an amyl acetate, ethyl acetate, butyl acetate and hexyl acetate of the range 10 - 30 percent by volume for removing a spot from wearing apparel; and water of the range 30 - 80 percent by volume for removing a spot from wearing apparel.
  2. 3. A spot remover as claimed in claim 1 wherein a coupling agent is provided for stability and clarification of the range 2 1/2 - 10 percent by volume, said coupling agent being of the group comprising, ethyl alcohol, propyl alcohol, methyl alcohol and butyl alcohol.
  3. 4. A spot remover as claimed in claim 2 wherein a coupling agent is provided for stability and clarification of the range 2 1/2 - 10 percent by volume, said coupling agent being of the group comprising, ethyl alcohol, propyl alcohol, methol alcohol and butyl alcohol.
US00169815A 1971-08-06 1971-08-06 Spot remover for wearing apparel Expired - Lifetime US3764544A (en)

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Cited By (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4093418A (en) * 1977-03-23 1978-06-06 Basf Wyandotte Corporation Method of spotting garments to be laundered
US4124542A (en) * 1977-08-25 1978-11-07 Devine Michael J Spot cleaning composition for carpets and the like
US4199482A (en) * 1977-03-31 1980-04-22 Colgate-Palmolive Company Laundry pre-spotter composition and method of using same
US4225471A (en) * 1978-06-28 1980-09-30 Chemed Corporation Cleaning composition containing mineral spirits alkanolamide, and oleyl dimethylamine oxide
US4666626A (en) * 1986-03-21 1987-05-19 C.L.M., Inc. Paint stripper compositions
US4834900A (en) * 1987-03-07 1989-05-30 Henkel Kommanditgesellschaft Auf Aktien Process for removing stains from fabrics
WO1993025654A1 (en) * 1992-06-18 1993-12-23 Unilever Plc Improvements relating to cleaning compositions
EP0598023A1 (en) * 1991-08-09 1994-05-25 General Dynamics Corporation Cleaning formulation and method that alleviates current problems
US5531927A (en) * 1992-03-20 1996-07-02 Bio-Safe Specialty Products, Inc. Stain removing compositions and methods of using the same
US5547476A (en) * 1995-03-30 1996-08-20 The Procter & Gamble Company Dry cleaning process
US5591236A (en) * 1995-03-30 1997-01-07 The Procter & Gamble Company Polyacrylate emulsified water/solvent fabric cleaning compositions and methods of using same
US5597792A (en) * 1993-04-02 1997-01-28 The Dow Chemical Company High water content, low viscosity, oil continuous microemulsions and emulsions, and their use in cleaning applications
US5613984A (en) * 1994-12-23 1997-03-25 Exfoliation Systems, Ltd. Process for laundering paint soiled garments
US5630848A (en) * 1995-05-25 1997-05-20 The Procter & Gamble Company Dry cleaning process with hydroentangled carrier substrate
US5630847A (en) * 1995-03-30 1997-05-20 The Procter & Gamble Company Perfumable dry cleaning and spot removal process
US5632780A (en) * 1995-03-30 1997-05-27 The Procter & Gamble Company Dry cleaning and spot removal proces
US5681355A (en) * 1995-08-11 1997-10-28 The Procter & Gamble Company Heat resistant dry cleaning bag
US5687591A (en) * 1995-06-20 1997-11-18 The Procter & Gamble Company Spherical or polyhedral dry cleaning articles
US5762648A (en) * 1997-01-17 1998-06-09 The Procter & Gamble Company Fabric treatment in venting bag
US5789368A (en) * 1996-01-26 1998-08-04 The Procter & Gamble Company Fabric care bag
US5804548A (en) * 1995-03-30 1998-09-08 The Procter & Gamble Company Dry cleaning process and kit
US5840675A (en) * 1996-02-28 1998-11-24 The Procter And Gamble Company Controlled released fabric care article
US5849039A (en) * 1997-01-17 1998-12-15 The Procter & Gamble Company Spot removal process
US5872090A (en) * 1996-10-25 1999-02-16 The Procter & Gamble Company Stain removal with bleach
US5891197A (en) * 1996-08-02 1999-04-06 The Proctor & Gamble Company Stain receiver for dry cleaning process
US5912408A (en) * 1995-06-20 1999-06-15 The Procter & Gamble Company Dry cleaning with enzymes
US5942484A (en) * 1995-03-30 1999-08-24 The Procter & Gamble Company Phase-stable liquid fabric refreshment composition
US6233771B1 (en) 1996-01-26 2001-05-22 The Procter & Gamble Company Stain removal device
US6670315B1 (en) * 2000-04-03 2003-12-30 Henkel Corporation Low pollution solvents and emulsions especially useful in cleaning soils from painted and unpainted metal and plastic surfaces
US20060052269A1 (en) * 2004-09-01 2006-03-09 Panandiker Rajan K Premoistened disposable wipe
US20060276356A1 (en) * 2004-09-01 2006-12-07 Global General Premoistened wipe
US20060277706A1 (en) * 2004-09-01 2006-12-14 Clark Melissa D Implement for use with a cleaning sheet
US20070037721A1 (en) * 2004-09-01 2007-02-15 The Procter & Gamble Company Moistened disposable wipe for controlling allergens

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2971920A (en) * 1956-02-29 1961-02-14 Wurmbock Egon Finger nail polish remover
US3124537A (en) * 1964-03-10 Spot remover for cleaning clothes
US3150048A (en) * 1958-03-21 1964-09-22 Ciba Ltd Nail lacquer removing preparations

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3124537A (en) * 1964-03-10 Spot remover for cleaning clothes
US2971920A (en) * 1956-02-29 1961-02-14 Wurmbock Egon Finger nail polish remover
US3150048A (en) * 1958-03-21 1964-09-22 Ciba Ltd Nail lacquer removing preparations

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Nivens Industrial Detergency 1955 Reinhold Publ. Co. TP990 pp. 106 107. *

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4093418A (en) * 1977-03-23 1978-06-06 Basf Wyandotte Corporation Method of spotting garments to be laundered
US4199482A (en) * 1977-03-31 1980-04-22 Colgate-Palmolive Company Laundry pre-spotter composition and method of using same
US4124542A (en) * 1977-08-25 1978-11-07 Devine Michael J Spot cleaning composition for carpets and the like
US4225471A (en) * 1978-06-28 1980-09-30 Chemed Corporation Cleaning composition containing mineral spirits alkanolamide, and oleyl dimethylamine oxide
US4666626A (en) * 1986-03-21 1987-05-19 C.L.M., Inc. Paint stripper compositions
US4834900A (en) * 1987-03-07 1989-05-30 Henkel Kommanditgesellschaft Auf Aktien Process for removing stains from fabrics
EP0598023A4 (en) * 1991-08-09 1997-05-07 Gen Dynamics Corp Cleaning formulation and method that alleviates current problems.
EP0598023A1 (en) * 1991-08-09 1994-05-25 General Dynamics Corporation Cleaning formulation and method that alleviates current problems
US5531927A (en) * 1992-03-20 1996-07-02 Bio-Safe Specialty Products, Inc. Stain removing compositions and methods of using the same
WO1993025654A1 (en) * 1992-06-18 1993-12-23 Unilever Plc Improvements relating to cleaning compositions
US5811383A (en) * 1993-04-02 1998-09-22 The Dow Chemical Company High water content, low viscosity, oil continuous microemulsions and emulsions, and their use in cleaning applications
US5597792A (en) * 1993-04-02 1997-01-28 The Dow Chemical Company High water content, low viscosity, oil continuous microemulsions and emulsions, and their use in cleaning applications
US5613984A (en) * 1994-12-23 1997-03-25 Exfoliation Systems, Ltd. Process for laundering paint soiled garments
US5591236A (en) * 1995-03-30 1997-01-07 The Procter & Gamble Company Polyacrylate emulsified water/solvent fabric cleaning compositions and methods of using same
US5630847A (en) * 1995-03-30 1997-05-20 The Procter & Gamble Company Perfumable dry cleaning and spot removal process
US5632780A (en) * 1995-03-30 1997-05-27 The Procter & Gamble Company Dry cleaning and spot removal proces
US5942484A (en) * 1995-03-30 1999-08-24 The Procter & Gamble Company Phase-stable liquid fabric refreshment composition
US5804548A (en) * 1995-03-30 1998-09-08 The Procter & Gamble Company Dry cleaning process and kit
US5547476A (en) * 1995-03-30 1996-08-20 The Procter & Gamble Company Dry cleaning process
US5630848A (en) * 1995-05-25 1997-05-20 The Procter & Gamble Company Dry cleaning process with hydroentangled carrier substrate
US5687591A (en) * 1995-06-20 1997-11-18 The Procter & Gamble Company Spherical or polyhedral dry cleaning articles
US5912408A (en) * 1995-06-20 1999-06-15 The Procter & Gamble Company Dry cleaning with enzymes
US5681355A (en) * 1995-08-11 1997-10-28 The Procter & Gamble Company Heat resistant dry cleaning bag
US6233771B1 (en) 1996-01-26 2001-05-22 The Procter & Gamble Company Stain removal device
US5789368A (en) * 1996-01-26 1998-08-04 The Procter & Gamble Company Fabric care bag
US5840675A (en) * 1996-02-28 1998-11-24 The Procter And Gamble Company Controlled released fabric care article
US5891197A (en) * 1996-08-02 1999-04-06 The Proctor & Gamble Company Stain receiver for dry cleaning process
US5872090A (en) * 1996-10-25 1999-02-16 The Procter & Gamble Company Stain removal with bleach
US5849039A (en) * 1997-01-17 1998-12-15 The Procter & Gamble Company Spot removal process
US5762648A (en) * 1997-01-17 1998-06-09 The Procter & Gamble Company Fabric treatment in venting bag
US6670315B1 (en) * 2000-04-03 2003-12-30 Henkel Corporation Low pollution solvents and emulsions especially useful in cleaning soils from painted and unpainted metal and plastic surfaces
US20060052269A1 (en) * 2004-09-01 2006-03-09 Panandiker Rajan K Premoistened disposable wipe
US20060276356A1 (en) * 2004-09-01 2006-12-07 Global General Premoistened wipe
US20060277706A1 (en) * 2004-09-01 2006-12-14 Clark Melissa D Implement for use with a cleaning sheet
US20070037721A1 (en) * 2004-09-01 2007-02-15 The Procter & Gamble Company Moistened disposable wipe for controlling allergens
US7947086B2 (en) 2004-09-01 2011-05-24 The Procter & Gamble Company Method for cleaning household fabric-based surface with premoistened wipe

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