US3848532A - Projectile and cartridge arrangement - Google Patents
Projectile and cartridge arrangement Download PDFInfo
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- US3848532A US3848532A US00349710A US34971073A US3848532A US 3848532 A US3848532 A US 3848532A US 00349710 A US00349710 A US 00349710A US 34971073 A US34971073 A US 34971073A US 3848532 A US3848532 A US 3848532A
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- projectile
- projectile according
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/72—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material
- F42B12/76—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material of the casing
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/36—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
- F42B12/40—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information of target-marking, i.e. impact-indicating type
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B5/00—Cartridge ammunition, e.g. separately-loaded propellant charges
- F42B5/02—Cartridges, i.e. cases with charge and missile
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B5/00—Cartridge ammunition, e.g. separately-loaded propellant charges
- F42B5/02—Cartridges, i.e. cases with charge and missile
- F42B5/045—Cartridges, i.e. cases with charge and missile of telescopic type
Definitions
- This invention relates to an improved projectile arrangement which is of particular value in enabling the handling, firing and effective target impacting of projectiles which may desirably carry a flowable charge of material, and particularly a liquid agent.
- Projectiles have been employed which carry liquid agents for dissemination at a target.
- a projectile is provided which is frangible and is fired from a cartridge case, the projectile being protected at its forward end by enclosure within the forward open end of the case. While this is a satisfactory arrangement for some weapons, particularly those which employ relatively small cartridges and which have sufficient room in the cartridge-receiving chamber to enable the projectile to be satisfactorily fired from within the case and to effectively ride down the bore of the barrel, this nose-encompassing arrangement is not practical in all circumstances, and particularly in the larger gauge rounds, such as in rounds for existing large-caliber hand-held gas guns (e.g., 37- and 38-millimeter) and 40-millimeter grenade launchers.
- the bore-riding section of the projectile closely approximate the outside diameter of the cartridge case, in order to accommodate the various diametral conditions of barrel bore and cartridgereceiving chamber in which these rounds may be fired.
- the projectile extends beyond the cartridge case and is made frangible in its nose area, it will be apparent that the cartridge will be subject to undesirable breakage during handling, as particularly when the cartridge is inadvertently dropped onto a hard surface. It is accordingly a feature of the invention to provide projectile which will enable the projectile to be adequately protected when such is exposed and dropped.
- FIG. 1 is a perspective view of a cartridge incorporating a projectile according to the invention.
- FIG. 2 is a perspective view of a projectile according to the invention and contained in the cartridge of FIG'. 1.
- FIG. 3 is an end view of the projectile of FIG. 2.
- FIG. 4 is a longitudinal section view of the cartridge of FIG. 1.
- FIG. 5 is a perspective view, partly broken away, of a wad employed in the cartridge of FIG. 4.
- FIG. 6 is a fragmentary longitudinal section view diagramatically illustrating the operation of the wad during firing of the propellant in the cartridge of FIG. 5.
- FIG. 7 is a fragmentary longitudinal section view of a modification of the cartridge case arrangement.
- FIGS. 1 and 4 a cartridge 11 is illustrated in FIGS. 1 and 4 having a case 21 in which is secured a projectile 31, the nose 51 of which extends beyond the open forward end of the case 21.
- the case 21 has a closed base end 23 which houses a charge of propellant, as will be more particularly hereinafter described, for propelling the projectile 31 from the case and through the bore of a weapon barrel.
- Projectile 31 has a bore-riding section 41 which is cylindrical in external shape, and a nose 51 which has a circumferential forwardly extending guard ring generally indicated at 71, formed by a plurality of spaced guard posts 73 which extend forwardly of their base connections with the remaining portion of the nose.
- the nose 51 also has a rupture disc 61 surrounded by an annular rupture web 67 formed by reducing the thickness of the nose as by the employment of an annular groove 65, as indicated in FIG. 4.
- the rupture web is disposed inboard of the base of the guard ring posts 73, thereby enabling the rupture disc 61 to be ruptured either forwardly or rearwardly relative to the posts 73.
- the forward end of the projectile nose 51 is formed by.
- the guard ring 71 formed by posts 73 thus serves to provide a substantial measure of protection to the rupture disc 61 due to inadvertent dropping of the cartridge 11 or projectile 31 on its nose and, while enabling the rupture disc 61 to be ruptured on projectile impact at high velocities as may be encountered when the projectile is fired in the normal manner from the cartridge case 21.
- the guard ring 71 is externally inwardly tapered in the forward direction, including the convex external surfaces of the posts 73, as well as the external surface of the base portion therefor forward of the boreriding section 41 of the projectile. This is advantageous in affording not only good mold release of this part, but also in aiding in loading of the cartridge in a chamber and in providing a degree of streamlining of the nose 51, while still affording a desirable degree of projectile retardation and limiting of flight range.
- the tapering of the posts 73 tends to aid in penetration of some targets, thereby affording better barricade penetration and dissemination of the material F within the projectile upon impact and rupture of the nose section and other portions of the projectile body.
- the posts 73 are also preferably outwardly tapered on their internal surface 73b, and this also aids in target penetration, as well as affording better mold release of the part and more free forward rupture motion for the rupture disc 61 in those instances where forward motion of the rup ture disc may take place on target impact, such as for instance when the target is impacted at an angle and the momentum of the fill material F in the projectile tends to effect a forward rupture of the disc 61.
- the rupture disc 61 may take various shapes and configurations, as may the rupture web 67 associated therein, a preferred embodiment being as shown with a concaveshaped internal surface and a convex-shaped external surface 63, 63a.
- the nose 51 is formed separately from the rear section of the projectile, including the bore-riding section 41 and a tapered rear section 33 having fins 35 thereon.
- the projectile has a filling of flowable material F,
- the projectile 31 is preferably formed of frangible relatively rigid plastic material, which has sufficient strength to withstand the launch pressures encountered when the cartridge is fired, and which is sufficiently chemically inert to the fill material F to afford adequate storage life.
- the material of the projectile 31 be capable of adequate bonding to afford a hermetic sealed condition for the fluid or other agent F therein,
- a suitable construction for spin-welding is afforded by the complementary stepped shoulders 39 and 55 on the nose and rear sections of the projectile respectively. If desired, other suitable joint or sealing connections may be employed for a particular embodiment.
- plastics which may be suitable for construction of the entire projectile 31, utilizing conventional injection molding techniques, are glass-filled nylon, (e.g., 30 percent glass-filled Type 6/6 nylon), and acetal resin (e.g., such as marketed under the trademarks Delrin and Celcon).
- acetal resin e.g., such as marketed under the trademarks Delrin and Celcon.
- the rear section of the projectile rearward of the annular bore-riding section 41 is tapered as indicated at 33, and has tapered fins 35 extending from its surface, the fins 35 being preferably canted to afford spin stabilization, and also to afford a rotational motion to the projectile 31, including its fill material F, which may aid in dissemination of the fill material at impact through the action of the angular momentum of the fill material.
- the projectile 31 is retained in the cartridge case 21 through the medium of a snap-ring lip and groove connection formed by an annular internally protruding lip 27 on the open end of the cartridge case wall 25, and a complementary groove 33a formed immediately rearward of the boreriding cylindrical surface 41 adjacent the nose end of the projectile.
- the outer surface of the case wall 25 may advantageously be of the same or approximately the same diameter as the bore-riding cylindrical section 41 of the projectile 31.
- Wall 25 may be formed of suitable thickness to provide the necessary cohesive strength to withstand the stresses encountered during firing of the cartridge within a given cartridge-receiving chamber in a weapon, it being understood that some weapon cartridge-receiving chambers are slightly oversize and require sufficient strength, ductility and/or elasticity to enable the case to expand, while other cartridgereceiving chambers are more close-fitting and require less strength, ductility and/or elasticity for the cartridge case.
- the cartridge case be formed of a sufficiently tough and ductile material to enable the satisfactory release of the projectile from the case upon firing of the cartridge.
- suitable injection moldable materials for the case 21 include thermoplastic resins such as polycarbonate, polyethylene, polyurethane, polypropylene and impact-grade polystyrene.
- the case may be formed of other materials, such as metal, including brass, aluminum, steel, etc., as well as tougher impact-grade rubber formulations and other elastomers of adequate strength and ductility.
- the external shape of the cartridge case 21 may be formed as may be required to enable placement in a given cartridge-receiving chamber for firing, and may include a stepped enlarged rear section and a conventional rim at the base section 23 thereof, or may have other external configurations as may be appropriate for a given desired utilization.
- a percussion primer 91 Disposed within the base 23 of the cartridge case 21 is a percussion primer 91 which enables the ignition firing of a suitable propellant mix 93 which is enclosed within a reduced diameter bore 92, with a bore.- restricting wad 81 across the entrance of the reduced diameter bore 92 and effectively forming a restricted volume chamber for initial holding of the propellant charge 93 and for subsequent restriction and timedelayed release of the propellant and propellant gases during firing, as will be more particularly described.
- propellant marketed under the name of WC Blank a particular quantity of approximately one gram having been sufficient to afford adequate firing and launching of a projectile of approximately 67 grams weight with an outer diameter of approximately 37 millimeters at the bore-riding diameter formed by the section 41.
- the wad 81 in the illustrative and preferred embodiment of FIG. 4, takes the form of a cylinder having an outer ring wall 85, engaging in frictional press fit relation within the bore 92, and having an obturating lip 85a formed thereon in interfacing relation to the propellant powder charge 93.
- a collapsible folding lateral wall 89 extends between a central stem or post 83 and the outer ring wall 85, with radial reinforcing webs 87.
- the central stem or post 83 may have an axial bore 83a formed therein to aid in insertion of the wad 81 within the bore 92, allowing air to escape during insertion, and a chamfer 92a may be formed on the forward edge of the bore 92 to likewise aid in insertion of the wad 81 within the bore 92. It is desirable that the granule size of the propellant mix 93 be sufficient to prevent exit of any material quantity thereof through the axial bore 83a, or that the bore otherwise be effectively closed by the contact and with the protruding rear end 37 of the projectile 31.
- the small cross sectional rearmost end 31 of the projectile may be slightly spaced from the central stem or post 83 if so desired, or as may be encountered in the course of manufacture on a production basis.
- the wad 81 may be formed of various materials which may be deformable under pressure, including various thermoplastic resins such as nylon, polyethylene, etc. The material is also preferably frangible in shear, as is afforded by these thermoplastic materials.
- the primer 91 is percussively fired as by a conventional firing pin (not shown) to thereby ignite the propellant mix 93, as schematically indicated in FIG. 6, this igintion of the propellant mix creating gases which increase the gas pressure within the chamber encompassing the burning propellant mix.
- This gas pressure exerts a forward motion force on the wad 81, tending to fold or otherwise move forwardly the collapsible folded lateral wall 89 and to collapse the central stem or post 83 against the small diameter end 37 of the projectile 31.
- the outer ring wall 85 is likewise moved forward under this gas pressure and is deformed and/or sheared by its contact with the rear end of the substantially stronger fins 35 on the projectile 31.
- the wad 81 may ultimately be defomed to the point of complete segmenting into smaller sheared sections by its contact with the fins 35, although this may not occur in all instances, particularly where a smaller effective charge of propellant is utilized for a given projectile mass per unit area condition.
- the retention of the projectile within the case 21, as well as the inertia of the projectile mass serves in conjunction with the interfacing contact made between the small reduced diameter rear 37 of the projectile and the wad 81 to retain the wad in the reduced diameter bore 92 over a period of time to aid in affording adequate burning of the propellant 93, thereby enabling the desirable utilization of a propellant which requires higher than atmospheric pressure for effective burning.
- the wad 81 will ultimately be moved in deformed condition into the chamber void area formed by the enlarged bore section of the case wall 25 surrounding the fins 35 and the tapered reduced diameter rear section 33 of the projectile 31, thereby enabling the full application of a reduced propellant gas pressure to the external rear body section of the projectile.
- the forwardly exerted force on the projectile 31 will be sufficient to overcome the restraining force thereon by the snap ring connection 27, 33a between the case and the projectile 31 as well as the inertial force of the projectile and fill material therein.
- a desirable mode of operation is afforded when the case/projectile retention and projectile inertial forces are overcome after complete expulsion of the wad 81 from the reduced diameter bore 92, although this precise timing is not critical, as a degree of forward motion of the projectile may be initiated by the direct forces exerted on its rear end37 through wad stem 83, while the wad is in process of its short term time-delayed volume restricting and release action relative to the propellant chamber bore 92. It will be noted in this respect that the reduced diameter end 37 of the'projectile enables this deformed expulsion of the wad 81, without requiring that the projectile be moved forward to enable this explusion.
- this overall dual diameter bore, wad, and reduced diameter projectile arrangement affords a unique and advantageous high-low propellant firing arrangement which affords adequate propellant burning while providing for reduced pressures on the external exposed rear surface of the projectile, and thereby enabling the projectile body to be of lesser strength than would otherwise be required if the full burning pressure for and burning action of the propellant were exerted directly on the hollow wall portion of the projectile.
- the deformable and frangible wad or wadding 81 may take other forms, a modification being illustrated in FIG. 7 in which the wad 181 takes the form of a disc of cork, preferably a composition of particulate cork adhesively bonded into a common substantially disintegrable mass which may have frangible sheets of paper or the like on its front and rear surfaces for ease of handling and pre-firing self-integrity of shape and form.
- Cork wadding of this type is commercially available under the name Sacork, and the thickness may be varied to obtain a desired degree of gas-pressure retention capability before break-up and/or crushing sufficient to afford pressure release of the propellant gases into the expansion chamber formed by the enlarged bore of case wall 25.
- a projectile for firing from a cartridge and rupturable on target impact after firing from a cartridge comprising a front portion having a frontal wall and a guard around said frontal wall a cavity formed in said projectile for holding a flowable dispersable charge desired to be dispersed on target impact after said projectile having been fired from a cartridge,
- said guard having sufficient impact resistance to provide a measure of protection against the inadvertent rupture of the frontal wall during lower velocity handling frontal impact shocks, including dropping from hand-held positions of the projectile above a hard ground surface.
- said rupturable central zone including a rupture disc and a weakened web zone connecting said disc with adjoining portion of said nose.
- said rupture disc being externally convex.
- said guard extending forwardly at least to the effective longitudinal extent of said rupture disc.
- said guard comprising a ring of forwardly extending individual protuberances.
- said individual protuberances being circumferentially spaced forwardly extending impact-rupturable posts, the bases of which posts connect with and form a portion of a wall of said body enclosing said charge of flowable material.
- said posts being externally tapered inwardly from their bases.
- said frontal wall comprising a rupture disc.
- said body having a tapered rear end with stabilizing fins thereon, and having an enlarged bore-riding section between said tapered rear section and the forward end of said nose.
- said body having a hermetically sealed cavity within which is disposed said charge of flowable material
- prising a body having a tapered rear section with stabilizing fins thereon, a nose, and an enlarged bore-riding section between said nose and said tapered rear section.
- said cavity being formed in said body, and said frontal wall being a frontal wall of said body and formed by said nose.
- said rupturable wall being externally convex.
- said guard extended forwardly at least to the effective longitudinal extent of said externally convex frontal wall.
- said charge of flowable material comprising a fluid
- a projectile according to claim 16 said charge of flowable material comprising a liquid.
- liquid including a highly volatile liquid agent capable of forming minute dispersable particles upon impact release from the projectile after impacting a target.
- said liquid partially filling said cavity, and said cavity having an air space therein to accommodate thermal expansion of the liquid charge and vapor pressure therefrom.
- said charge of flowable material comprising flowable powder.
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- Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
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Abstract
A projectile having a guard ring of circumferentially spaced posts encompassing a convex nose rupture disc and web. The projectile is mounted in a case with the nose extending in exposed condition beyond the open case end.
Description
United States Patent 1191 1111 3,848,532 Abbott 1451 Nov. 19, 1974 PROJECTILE AND CARTRIDGE 3,002,453 /1961 Fedoret a1. 102/2 ARRANGEMENT 3,170,405 2/1965 Jungermann etai. 102/91 3,439,619 4/1969 Bock et al 102/92.7 Inventor: Davld Abbott, Deer Meadow 3,528,662 9/1970 Merchant et a1. 102/927 x Farm, Md. 3,557,702 1/1971 Benson 102/92.7 [73] Asslgfneez AAI Corporation, Cockeysvllle, Md. FOREIGN PATENTS OR APPLICATIONS [221 Flledl P 1973 530,433 10/1955 Belgium 102/53 21 App]. No.2 349,710
Related s Application Data Primary Examiner-Robert F. Stahl [62] Division Of Ser. N0. 183,487, Sept. 24, 1971, Pat. Attorney Agent firm-Reyna [52] US. Cl. 102/87, 102/1 M, 102/41, [57] ABSTRACT 102/92, 102/927 51 1111.01. F42b 11/18, F42b 13/36 A P19199919 havmg a guard mg of clrcumferentlally [58] Field of Search 102/92.7, 93, 91, 92, 53, spaced Posts encompassing a convex nose rupture disc 02 2 52 5 4 1 M and web. The projectile is mounted in a case with the nose extending in exposed condition beyond the open [56] References Cited Case UNITED STATES PATENTS Claims, 7 Drawing Figures 669,534 3/1901 Lowrey 102/53 23 33 25 3| 2| 27 4| 7 7 f 3 -51 //I Ill/IX I/I/I/l/I Ill/III III 850 A 87 37 T 7 3 92 35 F 11 330 s5 67 PROJECTILE AND CARTRIDGE ARRANGEMENT This is a division, of application Ser. No. 183,487 filed Sept. 24, 1971 now US. Pat. No. 8,776,137.
DISCLOSURE This invention relates to an improved projectile arrangement which is of particular value in enabling the handling, firing and effective target impacting of projectiles which may desirably carry a flowable charge of material, and particularly a liquid agent.
Projectiles have been employed which carry liquid agents for dissemination at a target. In one such arrangement, a projectile is provided which is frangible and is fired from a cartridge case, the projectile being protected at its forward end by enclosure within the forward open end of the case. While this is a satisfactory arrangement for some weapons, particularly those which employ relatively small cartridges and which have sufficient room in the cartridge-receiving chamber to enable the projectile to be satisfactorily fired from within the case and to effectively ride down the bore of the barrel, this nose-encompassing arrangement is not practical in all circumstances, and particularly in the larger gauge rounds, such as in rounds for existing large-caliber hand-held gas guns (e.g., 37- and 38-millimeter) and 40-millimeter grenade launchers. In such cases it is desirable that the bore-riding section of the projectile closely approximate the outside diameter of the cartridge case, in order to accommodate the various diametral conditions of barrel bore and cartridgereceiving chamber in which these rounds may be fired. However, if the projectile extends beyond the cartridge case and is made frangible in its nose area, it will be apparent that the cartridge will be subject to undesirable breakage during handling, as particularly when the cartridge is inadvertently dropped onto a hard surface. It is accordingly a feature of the invention to provide projectile which will enable the projectile to be adequately protected when such is exposed and dropped.
It is a further object of the invention to provide an improved projectile arrangement which not only affords improved drop protection for its rupturable nose section but which also is of advantage in affording desirable rupture characteristics on contact with a target, including hard targets struck flat on or at an angle, as well as the ground or other softer target struck flat on or at an angle.
It is a further object of the invention to provide a projectile arrangement which affords a relatively flat trajectory with limited range, and which thereby enables its use under more controlled conditions in circumstances where extended range is not desirable, such as police work.
Still other objects, features and attendant advantages will become apparent to one skilled in the art from a reading of the following detailed description of a preferred embodiment of the invention, taken in conjunction with the following drawings, wherein:
FIG. 1 is a perspective view of a cartridge incorporating a projectile according to the invention.
FIG. 2 is a perspective view of a projectile according to the invention and contained in the cartridge of FIG'. 1.
FIG. 3 is an end view of the projectile of FIG. 2.
FIG. 4 is a longitudinal section view of the cartridge of FIG. 1.
FIG. 5 is a perspective view, partly broken away, of a wad employed in the cartridge of FIG. 4.
FIG. 6 is a fragmentary longitudinal section view diagramatically illustrating the operation of the wad during firing of the propellant in the cartridge of FIG. 5.
FIG. 7 is a fragmentary longitudinal section view of a modification of the cartridge case arrangement.
Referring now in detail to the figures of the drawing, a cartridge 11 is illustrated in FIGS. 1 and 4 having a case 21 in which is secured a projectile 31, the nose 51 of which extends beyond the open forward end of the case 21. The case 21 has a closed base end 23 which houses a charge of propellant, as will be more particularly hereinafter described, for propelling the projectile 31 from the case and through the bore of a weapon barrel.
The forward end of the projectile nose 51 is formed by.
the frontal surface 63 of the rupture disc 61, which frontal surface is convex, and of a forward extent corresponding to the forward extent of the posts 73, although the forwardmost face 63a may extend slightly forwardly of the posts within the impact yield limits of the nose material, and may extend rearwardly of the posts as may be desired. The guard ring 71 formed by posts 73 thus serves to provide a substantial measure of protection to the rupture disc 61 due to inadvertent dropping of the cartridge 11 or projectile 31 on its nose and, while enabling the rupture disc 61 to be ruptured on projectile impact at high velocities as may be encountered when the projectile is fired in the normal manner from the cartridge case 21.
The guard ring 71 is externally inwardly tapered in the forward direction, including the convex external surfaces of the posts 73, as well as the external surface of the base portion therefor forward of the boreriding section 41 of the projectile. This is advantageous in affording not only good mold release of this part, but also in aiding in loading of the cartridge in a chamber and in providing a degree of streamlining of the nose 51, while still affording a desirable degree of projectile retardation and limiting of flight range. In addition, the tapering of the posts 73 tends to aid in penetration of some targets, thereby affording better barricade penetration and dissemination of the material F within the projectile upon impact and rupture of the nose section and other portions of the projectile body. The posts 73 are also preferably outwardly tapered on their internal surface 73b, and this also aids in target penetration, as well as affording better mold release of the part and more free forward rupture motion for the rupture disc 61 in those instances where forward motion of the rup ture disc may take place on target impact, such as for instance when the target is impacted at an angle and the momentum of the fill material F in the projectile tends to effect a forward rupture of the disc 61. The rupture disc 61 may take various shapes and configurations, as may the rupture web 67 associated therein, a preferred embodiment being as shown with a concaveshaped internal surface and a convex-shaped external surface 63, 63a.
The nose 51 is formed separately from the rear section of the projectile, including the bore-riding section 41 and a tapered rear section 33 having fins 35 thereon.
The projectile has a filling of flowable material F,
which may preferably be a partial charge of highly volatile liquid agent which will form minute particles upon impact release from the projectile 31. An air space is desirable within the projectile, to accommodate thermal expansion of the liquid F and the vapor pressure therefrom, or such other flowable or otherwise disseminable material F as may require such expansion space, such as some powdered materials having a high coefficient'of thermal expansion. The entire projectile 31 is preferably formed of frangible relatively rigid plastic material, which has sufficient strength to withstand the launch pressures encountered when the cartridge is fired, and which is sufficiently chemically inert to the fill material F to afford adequate storage life. In addition, it is desirable that the material of the projectile 31 be capable of adequate bonding to afford a hermetic sealed condition for the fluid or other agent F therein,
. A suitable construction for spin-welding is afforded by the complementary stepped shoulders 39 and 55 on the nose and rear sections of the projectile respectively. If desired, other suitable joint or sealing connections may be employed for a particular embodiment.
Particular plastics which may be suitable for construction of the entire projectile 31, utilizing conventional injection molding techniques, are glass-filled nylon, (e.g., 30 percent glass-filled Type 6/6 nylon), and acetal resin (e.g., such as marketed under the trademarks Delrin and Celcon). In addition, it is feasible to form the projectile or portions thereof from other materials, suchas tempered glass or metal (e.g., zinc, aluminum, lead alloys, etc.) of suitable strength characteristics to accommodate the forces and pressures encountered and as may be readily calculated for a given construction and conditions of anticipated use.
As noted above, the rear section of the projectile rearward of the annular bore-riding section 41 is tapered as indicated at 33, and has tapered fins 35 extending from its surface, the fins 35 being preferably canted to afford spin stabilization, and also to afford a rotational motion to the projectile 31, including its fill material F, which may aid in dissemination of the fill material at impact through the action of the angular momentum of the fill material.
- The projectile 31 is retained in the cartridge case 21 through the medium of a snap-ring lip and groove connection formed by an annular internally protruding lip 27 on the open end of the cartridge case wall 25, and a complementary groove 33a formed immediately rearward of the boreriding cylindrical surface 41 adjacent the nose end of the projectile. Thus, the outer surface of the case wall 25 may advantageously be of the same or approximately the same diameter as the bore-riding cylindrical section 41 of the projectile 31.
It is desirable that the cartridge case be formed of a sufficiently tough and ductile material to enable the satisfactory release of the projectile from the case upon firing of the cartridge. In the particular illustrative embodiment as illustrated, suitable injection moldable materials for the case 21 include thermoplastic resins such as polycarbonate, polyethylene, polyurethane, polypropylene and impact-grade polystyrene. Inaddition, the case may be formed of other materials, such as metal, including brass, aluminum, steel, etc., as well as tougher impact-grade rubber formulations and other elastomers of adequate strength and ductility.
The external shape of the cartridge case 21 may be formed as may be required to enable placement in a given cartridge-receiving chamber for firing, and may include a stepped enlarged rear section and a conventional rim at the base section 23 thereof, or may have other external configurations as may be appropriate for a given desired utilization.
Disposed within the base 23 of the cartridge case 21 is a percussion primer 91 which enables the ignition firing of a suitable propellant mix 93 which is enclosed within a reduced diameter bore 92, with a bore.- restricting wad 81 across the entrance of the reduced diameter bore 92 and effectively forming a restricted volume chamber for initial holding of the propellant charge 93 and for subsequent restriction and timedelayed release of the propellant and propellant gases during firing, as will be more particularly described. While various propellant formulations may be employed, a suitable propellant formulation has been afforded by propellant marketed under the name of WC Blank, a particular quantity of approximately one gram having been sufficient to afford adequate firing and launching of a projectile of approximately 67 grams weight with an outer diameter of approximately 37 millimeters at the bore-riding diameter formed by the section 41. r
The wad 81 in the illustrative and preferred embodiment of FIG. 4, takes the form of a cylinder having an outer ring wall 85, engaging in frictional press fit relation within the bore 92, and having an obturating lip 85a formed thereon in interfacing relation to the propellant powder charge 93. A collapsible folding lateral wall 89 extends between a central stem or post 83 and the outer ring wall 85, with radial reinforcing webs 87. The central stem or post 83 may have an axial bore 83a formed therein to aid in insertion of the wad 81 within the bore 92, allowing air to escape during insertion, and a chamfer 92a may be formed on the forward edge of the bore 92 to likewise aid in insertion of the wad 81 within the bore 92. It is desirable that the granule size of the propellant mix 93 be sufficient to prevent exit of any material quantity thereof through the axial bore 83a, or that the bore otherwise be effectively closed by the contact and with the protruding rear end 37 of the projectile 31. By making the hole 83 a very minute, or otherwise by sacrificing the air equalization characteristic as by elimination of the bore 83a, the small cross sectional rearmost end 31 of the projectile may be slightly spaced from the central stem or post 83 if so desired, or as may be encountered in the course of manufacture on a production basis. The wad 81 may be formed of various materials which may be deformable under pressure, including various thermoplastic resins such as nylon, polyethylene, etc. The material is also preferably frangible in shear, as is afforded by these thermoplastic materials.
In firing the cartridge to propel the projectile 31 therefrom, the primer 91 is percussively fired as by a conventional firing pin (not shown) to thereby ignite the propellant mix 93, as schematically indicated in FIG. 6, this igintion of the propellant mix creating gases which increase the gas pressure within the chamber encompassing the burning propellant mix. This gas pressure exerts a forward motion force on the wad 81, tending to fold or otherwise move forwardly the collapsible folded lateral wall 89 and to collapse the central stem or post 83 against the small diameter end 37 of the projectile 31. The outer ring wall 85 is likewise moved forward under this gas pressure and is deformed and/or sheared by its contact with the rear end of the substantially stronger fins 35 on the projectile 31. The wad 81 may ultimately be defomed to the point of complete segmenting into smaller sheared sections by its contact with the fins 35, although this may not occur in all instances, particularly where a smaller effective charge of propellant is utilized for a given projectile mass per unit area condition. In any event, as shown in FIG. 6, the retention of the projectile within the case 21, as well as the inertia of the projectile mass, serves in conjunction with the interfacing contact made between the small reduced diameter rear 37 of the projectile and the wad 81 to retain the wad in the reduced diameter bore 92 over a period of time to aid in affording adequate burning of the propellant 93, thereby enabling the desirable utilization of a propellant which requires higher than atmospheric pressure for effective burning. The wad 81 will ultimately be moved in deformed condition into the chamber void area formed by the enlarged bore section of the case wall 25 surrounding the fins 35 and the tapered reduced diameter rear section 33 of the projectile 31, thereby enabling the full application of a reduced propellant gas pressure to the external rear body section of the projectile. At some point during this propellant firing and gas expansion cycle, the forwardly exerted force on the projectile 31 will be sufficient to overcome the restraining force thereon by the snap ring connection 27, 33a between the case and the projectile 31 as well as the inertial force of the projectile and fill material therein. A desirable mode of operation is afforded when the case/projectile retention and projectile inertial forces are overcome after complete expulsion of the wad 81 from the reduced diameter bore 92, although this precise timing is not critical, as a degree of forward motion of the projectile may be initiated by the direct forces exerted on its rear end37 through wad stem 83, while the wad is in process of its short term time-delayed volume restricting and release action relative to the propellant chamber bore 92. It will be noted in this respect that the reduced diameter end 37 of the'projectile enables this deformed expulsion of the wad 81, without requiring that the projectile be moved forward to enable this explusion. It will be appreciated that this overall dual diameter bore, wad, and reduced diameter projectile arrangement affords a unique and advantageous high-low propellant firing arrangement which affords adequate propellant burning while providing for reduced pressures on the external exposed rear surface of the projectile, and thereby enabling the projectile body to be of lesser strength than would otherwise be required if the full burning pressure for and burning action of the propellant were exerted directly on the hollow wall portion of the projectile.
The deformable and frangible wad or wadding 81 may take other forms, a modification being illustrated in FIG. 7 in which the wad 181 takes the form of a disc of cork, preferably a composition of particulate cork adhesively bonded into a common substantially disintegrable mass which may have frangible sheets of paper or the like on its front and rear surfaces for ease of handling and pre-firing self-integrity of shape and form. Cork wadding of this type is commercially available under the name Sacork, and the thickness may be varied to obtain a desired degree of gas-pressure retention capability before break-up and/or crushing sufficient to afford pressure release of the propellant gases into the expansion chamber formed by the enlarged bore of case wall 25.
While the invention has been described with respect to illustrative physical embodiments in accordance with various aspects thereof, it will be apparent that various modifications and improvements may be made without departing from the scope of the invention. Accordingly it is to be understood that the invention is not to be limited by the illustrative physical embodiments but only by the scope of the appended Claims.
1 claim: 1. A projectile for firing from a cartridge and rupturable on target impact after firing from a cartridge, comprising a front portion having a frontal wall and a guard around said frontal wall a cavity formed in said projectile for holding a flowable dispersable charge desired to be dispersed on target impact after said projectile having been fired from a cartridge,
the forward end of said cavity being bounded by said frontal wall, which frontal wall is rupturable to release such a charge from said cavity when the projectile strikes a target at a velocity consistent with its having been fired from a cartridge,
said guard having sufficient impact resistance to provide a measure of protection against the inadvertent rupture of the frontal wall during lower velocity handling frontal impact shocks, including dropping from hand-held positions of the projectile above a hard ground surface.
2. A projectile according to claim 1,
said rupturable central zone including a rupture disc and a weakened web zone connecting said disc with adjoining portion of said nose.
3. A projectile according to claim 2,
said rupture disc being externally convex.
4. A projectile according to claim 3,
said guard extending forwardly at least to the effective longitudinal extent of said rupture disc.
5. A projectile according to claim 1,
said guard comprising a ring of forwardly extending individual protuberances.
6. A projectile according to claim 5,
said individual protuberances being circumferentially spaced forwardly extending impact-rupturable posts, the bases of which posts connect with and form a portion of a wall of said body enclosing said charge of flowable material.
7. A projectile according to claim 6,
said posts being externally tapered inwardly from their bases.
8. A projectile according to claim 1,
said frontal wall comprising a rupture disc.
9. A projectile according to claim 8,
said body having a tapered rear end with stabilizing fins thereon, and having an enlarged bore-riding section between said tapered rear section and the forward end of said nose.
10. A projectile according to claim 9,
said and an annular case-retention groove formed in the outer surface of said body rearward of and adjoining said bore-riding section.
11. A projectile according to claim 10,
said body having a hermetically sealed cavity within which is disposed said charge of flowable material,
prising a body having a tapered rear section with stabilizing fins thereon, a nose, and an enlarged bore-riding section between said nose and said tapered rear section.
said cavity being formed in said body, and said frontal wall being a frontal wall of said body and formed by said nose.
13. A projectile according to claim 1,
said rupturable wall being externally convex.
14. A projectile according to claim 13,
said guard extended forwardly at least to the effective longitudinal extent of said externally convex frontal wall.
15. A projectile according to claim 14,
said projectile enclosing therein a charge of flowable dispersable material for impact dispersion on projected impact and rupture of said body with a target at a velocity consistent with its being fired from a cartridge.
16. A projectile according to claim 15,
said charge of flowable material comprising a fluid.
17. A projectile according to claim 16., said charge of flowable material comprising a liquid.
18. A projectile according to claim 17, liquid including a highly volatile liquid agent capable of forming minute dispersable particles upon impact release from the projectile after impacting a target.
19. A projectile according to claim 18,
said liquid partially filling said cavity, and said cavity having an air space therein to accommodate thermal expansion of the liquid charge and vapor pressure therefrom.
20. A projectile according to claim 15,
said charge of flowable material comprising flowable powder.
UNITED STATES PATENT AND TRADEMARK OFFICE CERTIFICATE OF CORRECTION PATENT NO. I 3,848,532
DATED November 19, 1974 |NVENTOR(S) 1 David D. Abbott It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
Correct title to read ---PROJ'ECTILE ARRANGEMENT--- Column 1, Line 4, change "No. 8,776, 137" to --=-No. 3,776,l37--- Column 1, Line 33, change "cartridgereceiving" to ---cartridge-receiving--- Column 1, Line 40, after "to provide" insert ---a--- Column 2 Line 65, change "surface to ---surfaces--- Column 3, Line 32, change "preferably" to --preferable-- Column 5, Line 19, change "iginition" to ---ignition--- Column 7, Line 20, delete "said" Column 8, Line 23, after "17," insert ---said--- Signed and Scaled this Twelfth D y Of April 1977 [SEAL] Arrest:
RUTH 0. insert c. MARSHALL DANN Arresting Officer Commissioner nj'larems and Trademarks PATENT NO.
DATED |NV ENTOR(S) November 19, 1974 David D. Abbott It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
Correct title to read ---PROJECTILE ARRANGEMENT--- Column 1, Line Column 1, Line Column 1, Line Column 2, Line Column 3, Line Column 5, Line Column 7, Line Column 8, Line [SEAL] Signed and Sealed this Twelfth Day of April 1971 Arrest:
C. MARSHALL DANN Commissioner oflarems and Trademark:
RUTH c. msoN A nesting Officer
Claims (20)
1. A projectile for firing from a cartridge and rupturable on target impact after firing from a cartridge, comprising a front portion having a frontal wall and a guard around said frontal wall a cavity formed in said projectile for holding a flowable dispersable charge desired to be dispersed on target impact after said projectile having been fired from a cartridge, the forward end of said cavity being bounded by said frontal wall, which frontal wall is rupturable to release such a charge from said cavity when the projectile strikes a target at a velocity consistent with its having been fired from a cartridge, said guard having sufficient impact resistance to provide a measure of protection against the inadvertent rupture of the frontal wall during lower velocity handling frontal impact shocks, including dropping from hand-held positions of the projectile above a hard ground surface.
2. A projectile according to claim 1, said rupturable central zone including a rupture disc and a weakened web zone connecting said disc with adjoining portion of said nose.
3. A projectile according to claim 2, said rupture disc being externally convex.
4. A projectile according to claim 3, said guard extending forwardly at least to the effective longitudinal extent of said rupture disc.
5. A projectile according to claim 1, said guard comprising a ring of forwardly extending individual protuberances.
6. A projectile according to claim 5, said individual protuberances being circumferentially spaced forwardly extending impact-rupturable posts, the bases of which posts connect with and form a portion of a wall of said body enclosing said charge of flowable material.
7. A projectile according to claim 6, said posts being externally tapered inwardly from their bases.
8. A projectile according to claim 1, said frontal wall comprising a rupture disc.
9. A projectile according to claim 8, said body having a tapered rear end with stabilizing fins thereon, and having an enlarged bore-riding section between said tapered rear section and the forward end of said nose.
10. A projectile according to claim 9, said and an annular case-retention groove formed in the outer surface of said body rearward of and adjoining said bore-riding section.
11. A projectile according to claim 10, said body having a hermetically sealed cavity within which is disposed said charge of flowable material, said body being forward of two sections of thermoplastic relatively rigid, yet elastic and impact rupturable, resin bonded together along a ring zone adjacent said bore-riding section.
12. A projectile according to claim 1, further comprising a body having a tapered rear section with stabilizing fins thereon, a nose, and an enlarged bore-riding section between said nose and said tapered rear section. said cavity being formed in said body, and said frontal wall being a frontal wall of said body and formed by said nose.
13. A projectile according to claim 1, said rupturable wall being externally convex.
14. A projectile according to claim 13, said guard extended forwardly at least to the effective longitudinal extent of said externally convex frontal wall.
15. A projectile according to claim 14, said projectile enclosing therein a charge of flowable dispersable material for impact dispersion on projected impact and rupture of said body with a target at a velocity consistent with its being fired from a cartridge.
16. A projectile according to claim 15, said charge of flowable material comprising a fluid.
17. A projectile according to claim 16, said charge of flowable material compRising a liquid.
18. A projectile according to claim 17, liquid including a highly volatile liquid agent capable of forming minute dispersable particles upon impact release from the projectile after impacting a target.
19. A projectile according to claim 18, said liquid partially filling said cavity, and said cavity having an air space therein to accommodate thermal expansion of the liquid charge and vapor pressure therefrom.
20. A projectile according to claim 15, said charge of flowable material comprising flowable powder.
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00183487A US3776137A (en) | 1971-09-24 | 1971-09-24 | Projectile and cartridge arrangement |
CA149,619A CA1015215A (en) | 1971-09-24 | 1972-08-17 | Projectile and cartridge arrangement |
AU45823/72A AU461922B2 (en) | 1971-09-24 | 1972-08-22 | Projectile and cartridge arrangement |
GB3972172A GB1382860A (en) | 1971-09-24 | 1972-08-25 | Projectile for firing from a cartridge |
DE2265398A DE2265398C3 (en) | 1971-09-24 | 1972-08-28 | cartridge |
DE2242719A DE2242719C3 (en) | 1971-09-24 | 1972-08-28 | Ammunition with a cartridge case |
SE7212177A SE396814B (en) | 1971-09-24 | 1972-09-21 | PROJECTILE |
FR7233766A FR2154236A5 (en) | 1971-09-24 | 1972-09-22 | |
JP9606372A JPS5646080B2 (en) | 1971-09-24 | 1972-09-25 | |
US00349710A US3848532A (en) | 1971-09-24 | 1973-04-10 | Projectile and cartridge arrangement |
CA252,735A CA1023997A (en) | 1971-09-24 | 1976-05-18 | Projectile and cartridge arrangement |
CA275,317A CA1017200A (en) | 1971-09-24 | 1977-04-01 | Projectile and cartridge arrangement |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US18348771A | 1971-09-24 | 1971-09-24 | |
US00349710A US3848532A (en) | 1971-09-24 | 1973-04-10 | Projectile and cartridge arrangement |
Publications (1)
Publication Number | Publication Date |
---|---|
US3848532A true US3848532A (en) | 1974-11-19 |
Family
ID=26879178
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00183487A Expired - Lifetime US3776137A (en) | 1971-09-24 | 1971-09-24 | Projectile and cartridge arrangement |
US00349710A Expired - Lifetime US3848532A (en) | 1971-09-24 | 1973-04-10 | Projectile and cartridge arrangement |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00183487A Expired - Lifetime US3776137A (en) | 1971-09-24 | 1971-09-24 | Projectile and cartridge arrangement |
Country Status (8)
Country | Link |
---|---|
US (2) | US3776137A (en) |
JP (1) | JPS5646080B2 (en) |
AU (1) | AU461922B2 (en) |
CA (1) | CA1015215A (en) |
DE (2) | DE2265398C3 (en) |
FR (1) | FR2154236A5 (en) |
GB (1) | GB1382860A (en) |
SE (1) | SE396814B (en) |
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- 1972-08-25 GB GB3972172A patent/GB1382860A/en not_active Expired
- 1972-08-28 DE DE2265398A patent/DE2265398C3/en not_active Expired
- 1972-08-28 DE DE2242719A patent/DE2242719C3/en not_active Expired
- 1972-09-21 SE SE7212177A patent/SE396814B/en unknown
- 1972-09-22 FR FR7233766A patent/FR2154236A5/fr not_active Expired
- 1972-09-25 JP JP9606372A patent/JPS5646080B2/ja not_active Expired
-
1973
- 1973-04-10 US US00349710A patent/US3848532A/en not_active Expired - Lifetime
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US3002453A (en) * | 1958-12-30 | 1961-10-03 | Joseph V Fedor | Anti-ricochet device |
US3170405A (en) * | 1962-03-17 | 1965-02-23 | Karlsruhe Augsburg Iweka | Disintegrating training ammunition for firearms |
US3439619A (en) * | 1966-07-16 | 1969-04-22 | Diehl | Practice ammunition |
US3528662A (en) * | 1967-08-28 | 1970-09-15 | John M Merchant | Material dispensing projectile |
US3557702A (en) * | 1968-10-17 | 1971-01-26 | Victor Comptometer Corp | Projectile with target cutting means |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4446794A (en) * | 1979-04-02 | 1984-05-08 | Aktiebolaget Bofors | Practice shell particularly useful for training purposes |
EP0337903A1 (en) * | 1988-04-13 | 1989-10-18 | Verney Carron S.A. | Ammunition for the low-pressure launching of voluminous low-mass projectiles |
FR2630203A1 (en) * | 1988-04-13 | 1989-10-20 | Verney Carron Sa | AMMUNITION FOR LOW PRESSURE PROPULSION OF LOW MASS VOLUMINOUS PROJECTILES |
FR2709822A1 (en) * | 1993-09-08 | 1995-03-17 | Rheinmetall Gmbh | Ejectable submunition mine. |
US5501155A (en) * | 1994-10-24 | 1996-03-26 | The United States Of America As Represented By The Secretary Of The Army | Hollow training round |
US7194960B2 (en) | 1996-11-18 | 2007-03-27 | Pepperball Technologies, Inc. | Non-lethal projectiles for delivering an inhibiting substance to a living target |
US20050066841A1 (en) * | 1996-11-18 | 2005-03-31 | Jaycor Tactical Systems, Inc. | Non-lethal projectiles for delivering an inhibiting substance to a living target |
US20050188886A1 (en) * | 1996-11-18 | 2005-09-01 | Pepperball Technologies, Inc. | Non-lethal projectile systems |
FR2762385A1 (en) * | 1997-04-21 | 1998-10-23 | Jean Pierre Denis | Projectile with low impact energy for dissuasion or marking target |
US7647763B2 (en) * | 2002-10-18 | 2010-01-19 | Physical Sciences, Inc. | Polyoxymethylene as structural support member and propellant |
US20090313967A1 (en) * | 2002-10-18 | 2009-12-24 | Physical Sciences, Inc. | Polyoxymethylene as structural support member and propellant |
US8033021B2 (en) | 2002-10-18 | 2011-10-11 | Physical Sciences, Inc. | Method for fabricating structural propellants |
US20100180443A1 (en) * | 2002-10-18 | 2010-07-22 | Physical Sciences, Inc. | Method For Fabricating Structural Propellants |
US20090320974A1 (en) * | 2002-10-18 | 2009-12-31 | Physical Sciences, Inc. | Polyoxymethylene as structural support member and propellant |
US20050016412A1 (en) * | 2003-02-10 | 2005-01-27 | Pepperball Technologies, Inc., A Delaware Corporation | Stabilized non-lethal projectile systems |
US20090266262A1 (en) * | 2003-02-10 | 2009-10-29 | Pepperball Technologies, Inc. | Stabilized non-lethal projectile systems |
US7526998B2 (en) * | 2003-02-10 | 2009-05-05 | Pepperball Technologies, Inc. | Stabilized non-lethal projectile systems |
WO2006057658A3 (en) * | 2004-04-09 | 2007-11-22 | Pepperball Technologies Inc | Primer launched projectile systems |
WO2006057658A2 (en) * | 2004-04-09 | 2006-06-01 | Pepperball Technologies, Inc. | Primer launched projectile systems |
US20060027223A1 (en) * | 2004-05-12 | 2006-02-09 | Pepperball Technologies, Inc. | Compact projectile launcher |
US20060075671A1 (en) * | 2004-10-08 | 2006-04-13 | Grimes Paul J | Firearm for extinguishing a fire from a position remote from the fire |
US7752974B2 (en) | 2007-09-18 | 2010-07-13 | Pepperball Technologies, Inc. | Systems, methods and apparatus for use in distributing irritant powder |
US20170199019A1 (en) * | 2016-01-11 | 2017-07-13 | Lehigh Defense, LLC | Armor-piercing cavitation projectile |
US10036619B2 (en) * | 2016-01-11 | 2018-07-31 | Lehigh Defense, LLC | Armor-piercing cavitation projectile |
US10345085B2 (en) * | 2017-01-20 | 2019-07-09 | Lehigh Defense, LLC | Projectile having leading surface standoffs |
US20200064111A1 (en) * | 2017-01-20 | 2020-02-27 | Lehigh Defense, LLC | Projectile having leading surface standoffs |
US10866075B2 (en) * | 2017-01-20 | 2020-12-15 | Lehigh Defense, LLC | Projectile having leading surface standoffs |
Also Published As
Publication number | Publication date |
---|---|
DE2242719A1 (en) | 1973-04-19 |
JPS5646080B2 (en) | 1981-10-30 |
FR2154236A5 (en) | 1973-05-04 |
JPS4862300A (en) | 1973-08-30 |
DE2265398B1 (en) | 1980-10-16 |
AU461922B2 (en) | 1975-06-12 |
DE2265398C3 (en) | 1981-07-02 |
DE2242719C3 (en) | 1981-04-23 |
CA1015215A (en) | 1977-08-09 |
GB1382860A (en) | 1975-02-05 |
SE396814B (en) | 1977-10-03 |
US3776137A (en) | 1973-12-04 |
AU4582372A (en) | 1974-02-28 |
DE2242719B2 (en) | 1980-06-26 |
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