US459494A - Composition of matter for the purification and strengthening of iron and cast-steel - Google Patents
Composition of matter for the purification and strengthening of iron and cast-steel Download PDFInfo
- Publication number
- US459494A US459494A US459494DA US459494A US 459494 A US459494 A US 459494A US 459494D A US459494D A US 459494DA US 459494 A US459494 A US 459494A
- Authority
- US
- United States
- Prior art keywords
- iron
- cast
- composition
- compound
- matter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title description 38
- 229910052742 iron Inorganic materials 0.000 title description 20
- 239000000203 mixture Substances 0.000 title description 14
- 229910001208 Crucible steel Inorganic materials 0.000 title description 10
- 238000000746 purification Methods 0.000 title description 8
- 238000005728 strengthening Methods 0.000 title description 8
- 150000001875 compounds Chemical class 0.000 description 28
- 229910052751 metal Inorganic materials 0.000 description 28
- 239000002184 metal Substances 0.000 description 28
- 239000004411 aluminium Substances 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 6
- 235000015450 Tilia cordata Nutrition 0.000 description 6
- 235000011941 Tilia x europaea Nutrition 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-M fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 6
- 239000004571 lime Substances 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910000805 Pig iron Inorganic materials 0.000 description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 229910000460 iron oxide Inorganic materials 0.000 description 4
- 235000013980 iron oxide Nutrition 0.000 description 4
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 4
- 229910000499 pig iron Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- 239000011135 tin Substances 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 229910001296 Malleable iron Inorganic materials 0.000 description 2
- 241001676573 Minium Species 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910000754 Wrought iron Inorganic materials 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 230000001627 detrimental Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/02—Dephosphorising or desulfurising
- C21C1/025—Agents used for dephosphorising or desulfurising
Definitions
- My new composition of matter may be used in cupolas of any desired form, and is therefore adapted to be used in the ordinary cupolas.
- This composition of matter is a compound or alloy, and consists of the following ingredients, viz: metallic aluminium, oxide of aluminium, silica, fluoride of calcium, carbonate of lime, and oxide of copper.
- the foregoing ingredients are preferably combined in the followingproportions on the basis that the compound is composed of one hundred parts, viz: metallic aluminium, 7.3 per cent; oxide of aluminium, 34.7 per cent; silica, nineteen per cent; fluoride of calcium, 9.3 per cent; carbonate of lime, six percent; oxide of copper thereof, two per cent.
- the last-named item of eighteen per cent. is principally Water.
- the mode in which my composition is used is by adding it to the charge of cast-iron, caststeel, or malleable iron, as the case may be, in the cupola.
- the amount of my compound to be added will be varied according to the degree in which the strength of the said metal of the said charge is to be increased. For example, for every said charge of one thousand pounds, if the latter is to be increased ten per cent. in strength, I add thereto twelve pounds of my If the said charge is to be increased in strength twentyper cent, then fifteen pounds of my compound are to be added thereto. Should it be desired to increase the strength of said charge twenty-five per cent, then twenty pounds of my compound are to be added to said charge.
- the method of adding the compound or alloy in the cupola is substantially as follows: The fire is started in the cupola after the usual bottom is made. Then a bed of coke is placed on top of the fire. A charge of this alloy of the desired amount necessary to impart a given strength to the iron castings, as heretofore specified, is now added, and above the alloy is added one thousand pounds of pig-iron and two per cent. of Wrought-iron scrap. The above charges of alloy and iron are repeated to the extent of the iron it is desired to strengthen and run.
- My compound imparts increased strength to the metal by securingathorough chemical union and fluidity of the molten metal.
- My compound will free the cast metal from hard spots and the aforementioned blow-holes. It will lower the point at which said metal melts about 250 Fahrenheit, and willraise the point at which the said metal chills about 250 Fahrenheit. It will purify the molten metal from carbonic oxide, titanic oxide, and iron oxides, &c. It will enable the founder to use more scrap-iron and cheaper pig-iron. It will reduce the percentage of defective castings and save vexatious loss. It Will give tenacious and more homogeneous castings, and the latter will not oxidize (rust) so readilywhen exposed to moisture. It will increase the tensile strength of cast metal from twenty minium, oxide of alurnininni, oxide of copper,
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
compound.
UNITED STATES PATENT QFFIGE.
CHARLES L. HARTSFELD, OF NEWPORT, KENTUCKY.
COMPOSITION OF MATTER FOR THE PURIFICATION AND STRENGTHENING OF IRON AND CAST-STEEL.
SPECIFICATION forming part of Letters Patent No. 459,494, dated September 15, 1891. Application filed June 28, 1890. Serial No. 357,097. (No model.)
T0 whom it may concern:
Be it known that I, CHARLES L. HARTSFELD,
a citizen of the United States, and a resident.
of the city of Newport, in the county of Campbell and State of Kentucky, have invented a new and useful Composition of Matter for the Purification and Strengthening of Iron and Cast-Steel, of which the following is a speci fication.
My new composition of matter may be used in cupolas of any desired form, and is therefore adapted to be used in the ordinary cupolas. This composition of matter is a compound or alloy, and consists of the following ingredients, viz: metallic aluminium, oxide of aluminium, silica, fluoride of calcium, carbonate of lime, and oxide of copper.
The foregoing ingredients are preferably combined in the followingproportions on the basis that the compound is composed of one hundred parts, viz: metallic aluminium, 7.3 per cent; oxide of aluminium, 34.7 per cent; silica, nineteen per cent; fluoride of calcium, 9.3 per cent; carbonate of lime, six percent; oxide of copper thereof, two per cent. Other chemical substances-via, traces of zinc and tin and lead, and water, &c.eighteen per cent., making a total of a little over ninetyseven per cent. The last-named item of eighteen per cent. is principally Water. The ingredients of said item-viz, water and traces of zinc and tin and lead-are not a necessary part of the compound, but will usually be present in the compound unless the ingredients thereof are absolutely pure. Such absolute purity is difficult to obtain, adds greatly to the expense of the compound, and is not necessary to the successful use of the compound.
The mode in which my composition is used is by adding it to the charge of cast-iron, caststeel, or malleable iron, as the case may be, in the cupola. To increase the strength of the said charge of metal in the cupola, the amount of my compound to be added will be varied according to the degree in which the strength of the said metal of the said charge is to be increased. For example, for every said charge of one thousand pounds, if the latter is to be increased ten per cent. in strength, I add thereto twelve pounds of my If the said charge is to be increased in strength twentyper cent, then fifteen pounds of my compound are to be added thereto. Should it be desired to increase the strength of said charge twenty-five per cent, then twenty pounds of my compound are to be added to said charge.
The method of adding the compound or alloy in the cupola is substantially as follows: The fire is started in the cupola after the usual bottom is made. Then a bed of coke is placed on top of the fire. A charge of this alloy of the desired amount necessary to impart a given strength to the iron castings, as heretofore specified, is now added, and above the alloy is added one thousand pounds of pig-iron and two per cent. of Wrought-iron scrap. The above charges of alloy and iron are repeated to the extent of the iron it is desired to strengthen and run.
It is a well-known fact that carbonic, ti-
tanic, and iron oxides are present in greater or less quantities in all unreduced molten iron or steel. I have ascertained that aluminium alloy will reduce these detrimental oxides at a lower melting-point of the metal than heretofore. Any blow-holes due to gases cannot be formed while aluminium is present in the molten metal. The prevention of blowholes in the metal to be cast imparts additional strength to said metal. My compound prevents the presence of blow-holes-in the cast metal.
My compound imparts increased strength to the metal by securingathorough chemical union and fluidity of the molten metal.
My said compound-viz., said aluminium alloy-will make hard iron softer with less shrinkage than is otherwise obtainable.
My compound will free the cast metal from hard spots and the aforementioned blow-holes. It will lower the point at which said metal melts about 250 Fahrenheit, and willraise the point at which the said metal chills about 250 Fahrenheit. It will purify the molten metal from carbonic oxide, titanic oxide, and iron oxides, &c. It will enable the founder to use more scrap-iron and cheaper pig-iron. It will reduce the percentage of defective castings and save vexatious loss. It Will give tenacious and more homogeneous castings, and the latter will not oxidize (rust) so readilywhen exposed to moisture. It will increase the tensile strength of cast metal from twenty minium, oxide of alurnininni, oxide of copper,
to twenty-five per cent. silica, fluoride of calcium, and carbonate of What I claim as new and of my invention, lime, in the proportions set forth. and desire to secure by Letters Patent, is CHARLES L. HARTSFELD. 5 Theherein-described composition of mat- Attest:
ter for the purification and strengthening of F. W. BROWNE,
iron and cast-steel,consisting'of metallic alu- K. SMITH.
Publications (1)
Publication Number | Publication Date |
---|---|
US459494A true US459494A (en) | 1891-09-15 |
Family
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Family Applications (1)
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US459494D Expired - Lifetime US459494A (en) | Composition of matter for the purification and strengthening of iron and cast-steel |
Country Status (1)
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US (1) | US459494A (en) |
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- US US459494D patent/US459494A/en not_active Expired - Lifetime
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