DK142148B - Fremgangsmåde til fremstilling af estere af sucrose med fedtsyrer. - Google Patents

Fremgangsmåde til fremstilling af estere af sucrose med fedtsyrer. Download PDF

Info

Publication number: DK142148B
Authority: DK; Denmark
Prior art keywords: sucrose; reaction; esters; solvent; ester
Prior art date: 1974-10-17

Application number

DK465675AA

Other languages

Danish (da)

English (en)

Other versions

DK142148C (no

DK465675A (no

Inventor

Kenneth James

Original Assignee

Tate & Lyle Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-10-17

Filing date

1975-10-16

Publication date

1980-09-08

1975-10-16 Application filed by Tate & Lyle Ltd filed Critical Tate & Lyle Ltd

1976-04-18 Publication of DK465675A publication Critical patent/DK465675A/da

1980-09-08 Publication of DK142148B publication Critical patent/DK142148B/da

1981-02-02 Application granted granted Critical

1981-02-02 Publication of DK142148C publication Critical patent/DK142148C/da

Links

229930006000 Sucrose Natural products 0.000 title description 63
239000005720 sucrose Substances 0.000 title description 63
238000000034 method Methods 0.000 title description 58
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 title description 55
235000014113 dietary fatty acids Nutrition 0.000 title description 33
239000000194 fatty acid Substances 0.000 title description 33
229930195729 fatty acid Natural products 0.000 title description 33
150000004665 fatty acids Chemical class 0.000 title description 24
150000002148 esters Chemical class 0.000 title description 13
238000002360 preparation method Methods 0.000 title description 8
238000006243 chemical reaction Methods 0.000 description 41
239000004094 surface-active agent Substances 0.000 description 31
239000002904 solvent Substances 0.000 description 26
238000005809 transesterification reaction Methods 0.000 description 22
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical group CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 18
239000003054 catalyst Substances 0.000 description 18
239000011541 reaction mixture Substances 0.000 description 18
-1 sucrose ester Chemical class 0.000 description 16
125000005907 alkyl ester group Chemical group 0.000 description 15
239000000047 product Substances 0.000 description 15
239000000203 mixture Substances 0.000 description 12
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
239000000344 soap Substances 0.000 description 11
239000007787 solid Substances 0.000 description 10
239000006227 byproduct Substances 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
125000004432 carbon atom Chemical group C* 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
150000004702 methyl esters Chemical class 0.000 description 6
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
238000000746 purification Methods 0.000 description 6
230000008901 benefit Effects 0.000 description 5
150000005690 diesters Chemical class 0.000 description 5
238000000605 extraction Methods 0.000 description 5
238000010438 heat treatment Methods 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
239000002245 particle Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
238000003756 stirring Methods 0.000 description 5
UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 5
239000002253 acid Substances 0.000 description 4
239000003599 detergent Substances 0.000 description 4
239000003995 emulsifying agent Substances 0.000 description 4
239000003921 oil Substances 0.000 description 4
235000019198 oils Nutrition 0.000 description 4
150000003626 triacylglycerols Chemical class 0.000 description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
239000003925 fat Substances 0.000 description 3
235000019197 fats Nutrition 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
229910000027 potassium carbonate Inorganic materials 0.000 description 3
239000000376 reactant Substances 0.000 description 3
235000000346 sugar Nutrition 0.000 description 3
239000000725 suspension Substances 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
239000003905 agrochemical Substances 0.000 description 2
150000004703 alkoxides Chemical class 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
150000007514 bases Chemical class 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000002537 cosmetic Substances 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000000284 extract Substances 0.000 description 2
238000005187 foaming Methods 0.000 description 2
235000013305 food Nutrition 0.000 description 2
239000002198 insoluble material Substances 0.000 description 2
239000000944 linseed oil Substances 0.000 description 2
235000021388 linseed oil Nutrition 0.000 description 2
239000000155 melt Substances 0.000 description 2
IPCSVZSSVZVIGE-UHFFFAOYSA-N n-hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
231100000252 nontoxic Toxicity 0.000 description 2
230000003000 nontoxic effect Effects 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000007858 starting material Substances 0.000 description 2
125000000185 sucrose group Chemical group 0.000 description 2
150000003445 sucroses Chemical class 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
101100188555 Arabidopsis thaliana OCT6 gene Proteins 0.000 description 1
GVGLGOZIDCSQPN-PVHGPHFFSA-N Heroin Chemical compound O([C@H]1[C@H](C=C[C@H]23)OC(C)=O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4OC(C)=O GVGLGOZIDCSQPN-PVHGPHFFSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
239000005642 Oleic acid Substances 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
235000019482 Palm oil Nutrition 0.000 description 1
235000021314 Palmitic acid Nutrition 0.000 description 1
235000019483 Peanut oil Nutrition 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
PPWHTZKZQNXVAE-UHFFFAOYSA-N Tetracaine hydrochloride Chemical compound Cl.CCCCNC1=CC=C(C(=O)OCCN(C)C)C=C1 PPWHTZKZQNXVAE-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000008065 acid anhydrides Chemical class 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
239000012675 alcoholic extract Substances 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
239000003674 animal food additive Substances 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000001642 boronic acid derivatives Chemical group 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000004359 castor oil Substances 0.000 description 1
235000019438 castor oil Nutrition 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000007810 chemical reaction solvent Substances 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000002385 cottonseed oil Substances 0.000 description 1
235000012343 cottonseed oil Nutrition 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
230000029087 digestion Effects 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
239000003814 drug Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
235000021588 free fatty acids Nutrition 0.000 description 1
125000005456 glyceride group Chemical group 0.000 description 1
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
125000005908 glyceryl ester group Chemical group 0.000 description 1
235000021552 granulated sugar Nutrition 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
239000004530 micro-emulsion Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
230000009965 odorless effect Effects 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
235000021313 oleic acid Nutrition 0.000 description 1
239000004006 olive oil Substances 0.000 description 1
235000008390 olive oil Nutrition 0.000 description 1
150000007530 organic bases Chemical group 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
239000000312 peanut oil Substances 0.000 description 1
239000000546 pharmaceutical excipient Substances 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000013014 purified material Substances 0.000 description 1
239000012264 purified product Substances 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000005060 rubber Substances 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
150000004760 silicates Chemical group 0.000 description 1
239000002002 slurry Substances 0.000 description 1
RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
239000003760 tallow Substances 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
- C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
- C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
- C07H13/06—Fatty acids
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/34—Higher-molecular-weight carboxylic acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
- C11C1/002—Sources of fatty acids, e.g. natural glycerides, characterised by the nature, the quantities or the distribution of said acids
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/02—Organic and inorganic agents containing, except water

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Microbiology (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Health & Medical Sciences (AREA)
Genetics & Genomics (AREA)
Molecular Biology (AREA)
Biochemistry (AREA)
Health & Medical Sciences (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Biotechnology (AREA)
Wood Science & Technology (AREA)
Materials Engineering (AREA)
Saccharide Compounds (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Detergent Compositions (AREA)

DK465675AA 1974-10-17 1975-10-16 Fremgangsmåde til fremstilling af estere af sucrose med fedtsyrer. DK142148B (da)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
GB4512274		1974-10-17
GB45122/74A GB1499989A (en)	1974-10-17	1974-10-17	Production of a surface active material containing sucrose esters
GB1622275		1975-04-18
GB1622275		1975-04-18

Publications (3)

Publication Number	Publication Date
DK465675A DK465675A (no)	1976-04-18
DK142148B true DK142148B (da)	1980-09-08
DK142148C DK142148C (no)	1981-02-02

Family

ID=26251906

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DK465675AA DK142148B (da)	1974-10-17	1975-10-16	Fremgangsmåde til fremstilling af estere af sucrose med fedtsyrer.

Country Status (21)

Country	Link
US (1)	US4032702A (no)
JP (1)	JPS5165704A (no)
AR (1)	AR212161A1 (no)
AT (1)	AT347410B (no)
BR (1)	BR7506830A (no)
CA (1)	CA1045130A (no)
CH (1)	CH606074A5 (no)
CU (1)	CU34398A (no)
DE (1)	DE2546716C3 (no)
DK (1)	DK142148B (no)
ES (1)	ES441908A2 (no)
FR (1)	FR2288143A2 (no)
GB (1)	GB1499989A (no)
IE (1)	IE42171B1 (no)
IT (1)	IT1048249B (no)
NL (1)	NL172761B (no)
NO (1)	NO140983C (no)
SE (1)	SE430339B (no)
SU (1)	SU906383A3 (no)
TR (1)	TR18880A (no)
ZA (1)	ZA756573B (no)

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1593856A (en) *	1976-11-17	1981-07-22	Gist Brocades Nv	Process for the treatment of fruit and vegetables
JPS6037085B2 (ja) *	1978-09-22	1985-08-24	花王株式会社	棒状化粧料
JPS6026368B2 (ja) *	1978-09-29	1985-06-24	花王株式会社	粉末圧縮型化粧料
JPS5547610A (en) *	1978-09-29	1980-04-04	Kao Corp	Hair cosmetic
JPS6037086B2 (ja) *	1978-09-26	1985-08-24	花王株式会社	化粧料
JPS6037087B2 (ja) *	1978-09-28	1985-08-24	花王株式会社	化粧料
DE2965461D1 (en) *	1978-11-06	1983-07-07	Tate & Lyle Plc	Gramophone record composition and gramophone records produced therefrom
EP0011419A1 (en) *	1978-11-09	1980-05-28	TATE & LYLE PUBLIC LIMITED COMPANY	P.V.C. compositions for extrusion moulding
IE50028B1 (en) *	1979-12-19	1986-02-05	Tate & Lyle Plc	Process for the production of a surfactant containing sucrose esters
US4517360A (en) *	1983-06-23	1985-05-14	The Procter & Gamble Company	Synthesis of higher polyol fatty acid polyesters using carbonate catalysts
US4518772A (en) *	1983-06-23	1985-05-21	The Proctor & Gamble Company	Synthesis of higher polyol fatty acid polyesters using high soap:polyol ratios
JPS6115893A (ja) *	1984-06-29	1986-01-23	Dai Ichi Kogyo Seiyaku Co Ltd	シヨ糖脂肪酸エステルの精製法
NL8601904A (nl) *	1986-07-23	1988-02-16	Unilever Nv	Werkwijze voor de bereiding van polyol-vetzuurpolyesters.
JPS63179884A (ja) *	1987-01-17	1988-07-23	Mitsubishi Kasei Corp	シヨ糖脂肪酸エステルの製造方法
DE69028759T2 (de) *	1989-12-21	1997-02-20	Unilever Nv	Verfahren zur Raffinierung von Seife enthaltendem Rohprodukt aus einem Polyol-Fettsäure-Veresterungsgemisch
DE69123595T3 (de)	1990-09-11	2004-09-30	The Procter & Gamble Company, Cincinnati	Verfahren zur herstellung von polyolpolyestern
ES2121578T3 (es) *	1991-04-12	1998-12-01	Procter & Gamble	Procedimiento para mejorar la estabilidad a la oxidacion de poliesteres de acido graso-polioles.
US5945529A (en) *	1996-07-19	1999-08-31	The Procter & Gamble Company	Synthesis of polyol fatty acid polyesters using column with inert gas stripping
US5767257A (en) *	1996-07-19	1998-06-16	The Procter & Gamble Company	Methods for producing polyol fatty acid polyesters using atmospheric or superatmospheric pressure
CN1230963A (zh) *	1996-08-08	1999-10-06	普罗克特和甘保尔公司	多元醇多酯的合成
US6121440A (en) *	1998-01-29	2000-09-19	The Procter & Gamble Company	Process for synthesis of polyol fatty acid polyesters
EP1230003A2 (en) *	1999-06-01	2002-08-14	Astion Development APS	A method of producing organic emulsifiers and organic surfactants, products produced by said method, and the use of such products
GB0608512D0 (en)	2006-04-28	2006-06-07	Vincent Processes Ltd	Process for the production of esters of sugars and sugar derivatives
EP3031443A1 (de)	2014-12-12	2016-06-15	Basf Se	Zusammensetzung enthaltend Kohlehydratpartialester

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1200276B (de) *	1959-10-08	1965-09-09	Bayer Ag	Verfahren zum Herstellen von Carbonsaeureestern nichtreduzierender Zucker
DE1643795A1 (de) *	1967-08-04	1971-07-01	Cassella Farbwerke Mainkur Ag	Verfahren zur Herstellung von Zuckerestern
US3597417A (en) *	1968-07-23	1971-08-03	Procter & Gamble	Process for the preparation of fatty acid esters of sugar glycosides
DE2004899C2 (de) *	1969-02-05	1984-07-26	Dai-Ichi Kogyo Seiyaku Co.,Ltd., Kyoto	Verfahren zur Abtrennung von Verunreinigungen aus Saccharosefettsäureester-Rohprodukten
US3714144A (en) *	1969-05-29	1973-01-30	Us Agriculture	Process for the production of sucrose esters of fatty acids
GB1399053A (en) *	1973-03-16	1975-06-25	Tate & Lyle Ltd	Process for the production of surface active agents comprising sucrose esters

1974
- 1974-10-17 GB GB45122/74A patent/GB1499989A/en not_active Expired
1975
- 1975-04-18 TR TR18880A patent/TR18880A/xx unknown
- 1975-10-15 US US05/622,495 patent/US4032702A/en not_active Expired - Lifetime
- 1975-10-15 AR AR260811A patent/AR212161A1/es active
- 1975-10-16 NO NO753492A patent/NO140983C/no unknown
- 1975-10-16 DK DK465675AA patent/DK142148B/da not_active IP Right Cessation
- 1975-10-16 SE SE7511612A patent/SE430339B/xx unknown
- 1975-10-16 IT IT69587/75A patent/IT1048249B/it active
- 1975-10-17 CH CH1354075A patent/CH606074A5/xx not_active IP Right Cessation
- 1975-10-17 JP JP50124459A patent/JPS5165704A/ja active Pending
- 1975-10-17 CA CA237,872A patent/CA1045130A/en not_active Expired
- 1975-10-17 ZA ZA00756573A patent/ZA756573B/xx unknown
- 1975-10-17 DE DE2546716A patent/DE2546716C3/de not_active Expired
- 1975-10-17 ES ES441908A patent/ES441908A2/es not_active Expired
- 1975-10-17 NL NLAANVRAGE7512252,A patent/NL172761B/xx not_active IP Right Cessation
- 1975-10-17 AT AT793375A patent/AT347410B/de not_active IP Right Cessation
- 1975-10-17 BR BR7506830A patent/BR7506830A/pt unknown
- 1975-10-17 SU SU752184053A patent/SU906383A3/ru active
- 1975-10-17 FR FR7531806A patent/FR2288143A2/fr active Granted
- 1975-10-17 IE IE2270/75A patent/IE42171B1/en unknown
- 1975-11-12 CU CU34398A patent/CU34398A/es unknown

Also Published As

Publication number	Publication date
DE2546716C3 (de)	1983-11-17
IE42171L (en)	1976-04-17
AR212161A1 (es)	1978-05-31
BR7506830A (pt)	1976-08-31
AT347410B (de)	1978-12-27
NO753492L (no)	1976-04-21
SE7511612L (sv)	1976-04-20
FR2288143B2 (no)	1979-02-02
CH606074A5 (no)	1978-10-13
IT1048249B (it)	1980-11-20
NL172761B (nl)	1983-05-16
DK142148C (no)	1981-02-02
DK465675A (no)	1976-04-18
NO140983C (no)	1979-12-19
ES441908A2 (es)	1977-07-01
CU34398A (no)	1977-06-08
US4032702A (en)	1977-06-28
IE42171B1 (en)	1980-06-18
NO140983B (no)	1979-09-10
ZA756573B (en)	1976-09-29
JPS5165704A (no)	1976-06-07
SE430339B (sv)	1983-11-07
SU906383A3 (ru)	1982-02-15
CA1045130A (en)	1978-12-26
DE2546716A1 (de)	1976-04-29
ATA793375A (de)	1978-05-15
FR2288143A2 (fr)	1976-05-14
NL7512252A (nl)	1976-04-21
AU8582875A (en)	1977-04-21
DE2546716B2 (de)	1981-04-09
TR18880A (tr)	1977-10-13
GB1499989A (en)	1978-02-01

Legal Events

Date	Code	Title	Description
1985-06-10	PBP	Patent lapsed

Publication	Publication Date	Title
DK142148B (da)	1980-09-08	Fremgangsmåde til fremstilling af estere af sucrose med fedtsyrer.
US3996206A (en)	1976-12-07	Process of making sucrose esters
US3480616A (en)	1969-11-25	Esterification of polyhydric compounds in the presence of transparent emulsifying agent
US4611055A (en)	1986-09-09	Production of sucrose fatty acid polyester
US2893990A (en)	1959-07-07	Process for producing sugar esters
US3748324A (en)	1973-07-24	Method for the purification of sucrose esters of fatty acids
US5079355A (en)	1992-01-07	Process for the synthesis of polyol fatty acid polyesters
EP0320043B1 (en)	1994-04-13	Process for the synthesis of polyol fatty acid esters
US2013034A (en)	1935-09-03	Sugar acylation
NL8500191A (nl)	1986-08-18	Werkwijze voor het bereiden van esters van een niet-reducerende suiker en een of meer vetzuren.
US4104464A (en)	1978-08-01	Purification of sucrose esters
US4377685A (en)	1983-03-22	Process of preparing sucroglycerides
JPH0421655A (ja)	1992-01-24	石鹸含有粗ポリオール脂肪酸ポリエステル反応生成物の精製方法
US3634473A (en)	1972-01-11	Process for manufacture of symmetrical glycerides
US3249600A (en)	1966-05-03	Process for the preparation of purified sucrose esters and products obtained thereby
JP2786253B2 (ja)	1998-08-13	ポリグリセリンのイソプロピリデン誘導体の脂肪酸−またはヒドロキシ脂肪酸エステルを製造する方法
AU2007339287B2 (en)	2013-01-10	Process for recovering sterols from a crude source containing sterol esters
EP1047659B1 (en)	2005-06-08	A process for making high purity fatty acid lower alkyl esters
US3141013A (en)	1964-07-14	Purification of transesterification mixtures
US3349081A (en)	1967-10-24	Process for preparing sucrose esters of high molecular weight fatty acids
CN112940054B (zh)	2023-01-20	一种高单酯含量蔗糖酯制备方法
US2399959A (en)	1946-05-07	Process of producing esters
CA1182474A (en)	1985-02-12	Process for the manufacture of soap
US2071459A (en)	1937-02-23	Process of purifying polyglycerol esters
JPS5917120B2 (ja)	1984-04-19	シヨ糖エステルの製造方法