ES423464A1 - A PROCEDURE FOR THE PREPARATION OF N ', N'-DIOXIDE OF METHYL 3- (2-QUINOXALINYL METHYLENE) CARBAZATE. - Google Patents
A PROCEDURE FOR THE PREPARATION OF N ', N'-DIOXIDE OF METHYL 3- (2-QUINOXALINYL METHYLENE) CARBAZATE.Info
- Publication number
- ES423464A1 ES423464A1 ES423464A ES423464A ES423464A1 ES 423464 A1 ES423464 A1 ES 423464A1 ES 423464 A ES423464 A ES 423464A ES 423464 A ES423464 A ES 423464A ES 423464 A1 ES423464 A1 ES 423464A1
- Authority
- ES
- Spain
- Prior art keywords
- acid
- carbazate
- methyl
- dioxide
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- SOEMFPLGOUBPJQ-NTUHNPAUSA-N methyl n-[(e)-quinoxalin-2-ylmethylideneamino]carbamate Chemical compound C1=CC=CC2=NC(/C=N/NC(=O)OC)=CN=C21 SOEMFPLGOUBPJQ-NTUHNPAUSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- XYPISWUKQGWYGX-UHFFFAOYSA-N 2,2,2-trifluoroethaneperoxoic acid Chemical compound OOC(=O)C(F)(F)F XYPISWUKQGWYGX-UHFFFAOYSA-N 0.000 abstract 1
- GLVYLTSKTCWWJR-UHFFFAOYSA-N 2-carbonoperoxoylbenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1C(O)=O GLVYLTSKTCWWJR-UHFFFAOYSA-N 0.000 abstract 1
- LJGHYPLBDBRCRZ-UHFFFAOYSA-N 3-(3-aminophenyl)sulfonylaniline Chemical compound NC1=CC=CC(S(=O)(=O)C=2C=C(N)C=CC=2)=C1 LJGHYPLBDBRCRZ-UHFFFAOYSA-N 0.000 abstract 1
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 abstract 1
- NHQDETIJWKXCTC-UHFFFAOYSA-N 3-chloroperbenzoic acid Chemical compound OOC(=O)C1=CC=CC(Cl)=C1 NHQDETIJWKXCTC-UHFFFAOYSA-N 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/36—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems
- C07D241/50—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems with hetero atoms directly attached to ring nitrogen atoms
- C07D241/52—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/36—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems
- C07D241/38—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems with only hydrogen or carbon atoms directly attached to the ring nitrogen atoms
- C07D241/40—Benzopyrazines
- C07D241/42—Benzopyrazines with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Luminescent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The novel process for the preparation of methyl 3-(2-quinoxalinylmethylene)carbazate N1, N4-dioxide which comprises contacting methyl 3-(2-quinoxalinylmethylene)carbazate with oxidizing agent in reaction-inert solvent at a temperature of from about 20 DEG C. up to 100 DEG C. until reaction is substantially complete, said oxidizing agent being selected from the group consisting of peracetic acid, perbenzoic acid, m-chloroperbenzoic acid, perphthalic acid, performic acid, trifluoroperacetic acid and hydrogen peroxide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US338906A US3926991A (en) | 1973-03-07 | 1973-03-07 | Process for producing quinoxaline-di-N-oxides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES423464A1 true ES423464A1 (en) | 1976-05-01 |
Family
ID=23326639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES423464A Expired ES423464A1 (en) | 1973-03-07 | 1974-02-21 | A PROCEDURE FOR THE PREPARATION OF N ', N'-DIOXIDE OF METHYL 3- (2-QUINOXALINYL METHYLENE) CARBAZATE. |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US3926991A (en) |
| JP (1) | JPS5024282A (en) |
| AR (1) | AR200516A1 (en) |
| CA (1) | CA982584A (en) |
| CH (1) | CH580096A5 (en) |
| CS (1) | CS180003B2 (en) |
| DK (1) | DK138945B (en) |
| ES (1) | ES423464A1 (en) |
| FI (1) | FI59404C (en) |
| FR (1) | FR2220524B1 (en) |
| GB (1) | GB1459561A (en) |
| HK (1) | HK47177A (en) |
| HU (1) | HU170488B (en) |
| IE (1) | IE39170B1 (en) |
| IT (1) | IT1056054B (en) |
| LU (1) | LU69471A1 (en) |
| MY (1) | MY7800013A (en) |
| NL (1) | NL7401966A (en) |
| PL (1) | PL94858B1 (en) |
| SE (1) | SE420603B (en) |
| SU (1) | SU539527A3 (en) |
| YU (1) | YU39150B (en) |
| ZA (1) | ZA74745B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4006142A (en) * | 1973-03-07 | 1977-02-01 | Pfizer Inc. | Preparation of methyl-3-(2-quinoxalinylmethylene)carbazate-N1,N4 -dioxide |
| US4740652A (en) * | 1985-05-23 | 1988-04-26 | Uop Inc. | Process for the oligomerization of olefins |
| US4737479A (en) * | 1986-03-21 | 1988-04-12 | Uop Inc. | Process for the oligomerization of olefins and a catalyst thereof |
| US4737480A (en) * | 1986-03-25 | 1988-04-12 | Uop Inc. | Process for the oligomerization of olefins and a catalyst thereof |
| US4795851A (en) * | 1987-03-12 | 1989-01-03 | Uop Inc. | Process for the oligomerization of olefins and a catalyst thereof |
| US4795852A (en) * | 1987-03-13 | 1989-01-03 | Uop Inc. | Process for the oligomerization of olefins and a catalyst thereof |
| US4935575A (en) * | 1988-12-12 | 1990-06-19 | Uop | Process for the oligomerization of olefins and a catalyst thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2626259A (en) * | 1953-01-20 | Ffiii-ce | ||
| US2545786A (en) * | 1951-03-20 | S-methoxyquinoxaline-l | ||
| GB1170807A (en) * | 1967-03-21 | 1969-11-19 | Ici Ltd | Quinoxaline Derivatives |
| DE2015676A1 (en) * | 1970-04-02 | 1971-10-21 | Farbenfabriken Bayer Ag, 5090 Leverkusen | New imines of 2-formyl-quinoxalinedi-N-oxide carbonic acid- (3) and their salts, processes for their preparation and their use as antimicrobial agents |
| GB1298268A (en) * | 1970-06-18 | 1972-11-29 | Ici Ltd | Process for the manufacture of quinoxaline dioxides |
| ZA725675B (en) * | 1971-06-21 | 1973-05-30 | Ciba Geigy Ag | New heterocyclic compounds |
-
1973
- 1973-03-07 US US338906A patent/US3926991A/en not_active Expired - Lifetime
-
1974
- 1974-02-04 IE IE197/74A patent/IE39170B1/en unknown
- 1974-02-05 SE SE7401528A patent/SE420603B/en not_active IP Right Cessation
- 1974-02-05 ZA ZA740745A patent/ZA74745B/en unknown
- 1974-02-13 NL NL7401966A patent/NL7401966A/xx unknown
- 1974-02-20 FI FI490/74A patent/FI59404C/en active
- 1974-02-20 YU YU00439/74A patent/YU39150B/en unknown
- 1974-02-20 IT IT48504/74A patent/IT1056054B/en active
- 1974-02-21 ES ES423464A patent/ES423464A1/en not_active Expired
- 1974-02-21 DK DK92574AA patent/DK138945B/en not_active IP Right Cessation
- 1974-02-21 JP JP49019992A patent/JPS5024282A/ja active Pending
- 1974-02-22 CH CH254874A patent/CH580096A5/xx not_active IP Right Cessation
- 1974-02-22 FR FR7406155A patent/FR2220524B1/fr not_active Expired
- 1974-02-22 AR AR252487A patent/AR200516A1/en active
- 1974-02-22 LU LU69471A patent/LU69471A1/xx unknown
- 1974-02-28 HU HUPI408A patent/HU170488B/hu unknown
- 1974-02-28 CS CS7400001493A patent/CS180003B2/en unknown
- 1974-03-01 PL PL1974169209A patent/PL94858B1/pl unknown
- 1974-03-01 SU SU2002363A patent/SU539527A3/en active
- 1974-03-05 CA CA194,053A patent/CA982584A/en not_active Expired
- 1974-03-06 GB GB1014974A patent/GB1459561A/en not_active Expired
-
1977
- 1977-09-15 HK HK471/77A patent/HK47177A/en unknown
-
1978
- 1978-12-30 MY MY13/78A patent/MY7800013A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2220524A1 (en) | 1974-10-04 |
| LU69471A1 (en) | 1974-09-25 |
| ZA74745B (en) | 1974-12-24 |
| NL7401966A (en) | 1974-09-10 |
| CS180003B2 (en) | 1977-12-30 |
| FI59404C (en) | 1981-08-10 |
| CA982584A (en) | 1976-01-27 |
| PL94858B1 (en) | 1977-09-30 |
| FI59404B (en) | 1981-04-30 |
| US3926991A (en) | 1975-12-16 |
| HU170488B (en) | 1977-06-28 |
| SE420603B (en) | 1981-10-19 |
| YU39150B (en) | 1984-06-30 |
| HK47177A (en) | 1977-09-23 |
| IE39170L (en) | 1974-09-07 |
| DK138945C (en) | 1979-05-07 |
| GB1459561A (en) | 1976-12-22 |
| SU539527A3 (en) | 1976-12-15 |
| AR200516A1 (en) | 1974-11-15 |
| FR2220524B1 (en) | 1977-03-04 |
| IE39170B1 (en) | 1978-08-16 |
| IT1056054B (en) | 1982-01-30 |
| MY7800013A (en) | 1978-12-31 |
| CH580096A5 (en) | 1976-09-30 |
| DK138945B (en) | 1978-11-20 |
| YU43974A (en) | 1982-06-30 |
| JPS5024282A (en) | 1975-03-15 |
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