GB585755A - New and useful interpolymers of vinyl thiolesters - Google Patents

New and useful interpolymers of vinyl thiolesters

Info

Publication number
GB585755A
GB585755A GB14597/44A GB1459744A GB585755A GB 585755 A GB585755 A GB 585755A GB 14597/44 A GB14597/44 A GB 14597/44A GB 1459744 A GB1459744 A GB 1459744A GB 585755 A GB585755 A GB 585755A
Authority
GB
United Kingdom
Prior art keywords
fumarate
diethyl
maleate
dimethyl
esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB14597/44A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of GB585755A publication Critical patent/GB585755A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F28/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Vinyl thiol esters of aliphatic monocarboxylic acids are interpolymerized in bulk, solution or emulsion with an ester or anhydride of an acid containing the group <FORM:0585755/IV/1> the action of heat and/or light. Esters specified are vinyl thiol - formate, caproate, stearate, lactate, acetate and chloracetate. Other esters and anhydrides specified are dimethyl fumarate, diethyl maleate, diethyl fumarate, maleic anhydride, citraconic anhydride, diisobutyl fumarate, dioctyl fumarate, dimethyl maleate, dilauryl maleate, methyl ethyl fumarate, methyl octyl maleate, dimethyl and diethyl mesaconates and citraconates, diphenyl fumarate, dibenzyl fumarate, and dicyclohexyl fumarate. Benzoin, diethyl peroxide and diacetyl may be used as catalysts. In emulsion polymerization, polymethacrylic acid or the sodium salt of a product obtained by passing chlorine and sulphur dioxide through paraffin wax may be added. The interpolymers may be hot pressed into films or after-hydrolysed by potassium hydroxide in a benzene/methanol mixture and used as cation exchangers. Specification 568,565 and U.S.A. Specification 2,046,090 are referred to.
GB14597/44A 1943-07-30 1944-07-31 New and useful interpolymers of vinyl thiolesters Expired GB585755A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US585755XA 1943-07-30 1943-07-30

Publications (1)

Publication Number Publication Date
GB585755A true GB585755A (en) 1947-02-24

Family

ID=22017678

Family Applications (1)

Application Number Title Priority Date Filing Date
GB14597/44A Expired GB585755A (en) 1943-07-30 1944-07-31 New and useful interpolymers of vinyl thiolesters

Country Status (1)

Country Link
GB (1) GB585755A (en)

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