GB585755A - New and useful interpolymers of vinyl thiolesters - Google Patents
New and useful interpolymers of vinyl thiolestersInfo
- Publication number
- GB585755A GB585755A GB14597/44A GB1459744A GB585755A GB 585755 A GB585755 A GB 585755A GB 14597/44 A GB14597/44 A GB 14597/44A GB 1459744 A GB1459744 A GB 1459744A GB 585755 A GB585755 A GB 585755A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fumarate
- diethyl
- maleate
- dimethyl
- esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Vinyl thiol esters of aliphatic monocarboxylic acids are interpolymerized in bulk, solution or emulsion with an ester or anhydride of an acid containing the group <FORM:0585755/IV/1> the action of heat and/or light. Esters specified are vinyl thiol - formate, caproate, stearate, lactate, acetate and chloracetate. Other esters and anhydrides specified are dimethyl fumarate, diethyl maleate, diethyl fumarate, maleic anhydride, citraconic anhydride, diisobutyl fumarate, dioctyl fumarate, dimethyl maleate, dilauryl maleate, methyl ethyl fumarate, methyl octyl maleate, dimethyl and diethyl mesaconates and citraconates, diphenyl fumarate, dibenzyl fumarate, and dicyclohexyl fumarate. Benzoin, diethyl peroxide and diacetyl may be used as catalysts. In emulsion polymerization, polymethacrylic acid or the sodium salt of a product obtained by passing chlorine and sulphur dioxide through paraffin wax may be added. The interpolymers may be hot pressed into films or after-hydrolysed by potassium hydroxide in a benzene/methanol mixture and used as cation exchangers. Specification 568,565 and U.S.A. Specification 2,046,090 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US585755XA | 1943-07-30 | 1943-07-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB585755A true GB585755A (en) | 1947-02-24 |
Family
ID=22017678
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14597/44A Expired GB585755A (en) | 1943-07-30 | 1944-07-31 | New and useful interpolymers of vinyl thiolesters |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB585755A (en) |
-
1944
- 1944-07-31 GB GB14597/44A patent/GB585755A/en not_active Expired
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