US2689167A - Production of gamma ferric oxide - Google Patents

Production of gamma ferric oxide Download PDF

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US2689167A
US2689167A US108226A US10822649A US2689167A US 2689167 A US2689167 A US 2689167A US 108226 A US108226 A US 108226A US 10822649 A US10822649 A US 10822649A US 2689167 A US2689167 A US 2689167A
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oxide
ferrosoferric
ferric oxide
ferrosoferric oxide
temperature
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US108226A
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Dovey Douglas Marshall
Chirnside Ralph Clark
Rooksby Harold Percy
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General Electric Co PLC
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General Electric Co PLC
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    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62—Record carriers characterised by the selection of the material
    • G11B5/68—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent
    • G11B5/70—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer
    • G11B5/706—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer characterised by the composition of the magnetic material
    • G11B5/70626—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer characterised by the composition of the magnetic material containing non-metallic substances
    • G11B5/70642—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer characterised by the composition of the magnetic material containing non-metallic substances iron oxides
    • G11B5/70652—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer characterised by the composition of the magnetic material containing non-metallic substances iron oxides gamma - Fe2 O3
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/02—Oxides; Hydroxides
    • C01G49/06—Ferric oxide [Fe2O3]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C01P2004/52—Particles with a specific particle size distribution highly monodisperse size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof

Definitions

  • This invention relates to the production of ferric oxide, and more particularly to a process for the production of -ferric oxide in the form of a finely-divided powder in which the particles are of substantially uniform size.
  • ferric oxide exists in two forms differing in their crystal structure and in magnetic properties, namely the ct form, which is paramagnetic, and the 7 form, which is ferromagnetic and possesses properties that make it suitable, in powdered form, for certain applications such as the formation of the magnetisable coating on recording tape.
  • the magnetic powder used should consist of particles which, whether formed of single crystals or aggregates of crystals, are of substantially uniform size and of small diameter, preferably of the order of one micron or less.
  • -ferric oxide can be obtained in the form of a finely-divided powder of substantially uniform particle size by heating finely-divided iron oxalate or iron formate at such a temperature that substantially only ferrosoferric oxide, F6304, is produced, and then subjecting the latter compound to controlled oxidation.
  • a process for the production of 'y-ferric oxide in the form of a finely-divided powder in which the particles are of substantially uniform size comprises heating finely-divided iron oxalate or iron formate consisting of particles of substantially uniform size, at a temperature below 600 C. in a substantially inert atmosphere until substantially complete conversion to ferrosoferric oxide has taken place, and then subjecting the product to suitably controlled oxidation in air at a temperature below 350 C.
  • the process according to the invention is advantageous in that it is a dry process, solution or fusion of the particles at any stage in the process being avoided, so that the ferrosoferric oxide formed in the first stage of the process and the -ferric oxide obtained as the final product are both pseudomorphs of the original crystals of iron oxalate or iron formate.
  • the size of the crystals of the y-ferric oxide produced is determined by the size of the crystals forming the starting material.
  • the latter therefore should be of substantially uniform size and preferably should be less than one micron in diameter.
  • the iron oxalate or iron formate employed consists of particles, whether single crystals or crystal aggregates, of diameter of the order of one micron or less.
  • the iron oxalate or iron formate is heated at a temperature below 600 C., a suitable temperature being approximately 450 C., in a container in which an atmosphere substantially inert to ferrosoferric oxide is maintained.
  • the atmosphere in the container consists of a gas or mixture of gases which will neither oxidise nor appreciably reduce the ferrosoferric oxide formed.
  • Suitable atmospheres are steam, carbon dioxide, or mixtures of one or both of these with nitrogen; a small proportion of hydrogen or carbon monoxide may also be present, provided that the concentration of these gases is not sufliciently great to cause any appreciable reduction of the ferrosoferric oxide.
  • a suitable gas mixture may be obtained by the combustion of town gas.
  • the initial heating is continued until the iron oxalate or iron formate is substantially completely converted into pseudomorphous ferrosoferric oxide, as indicated by the change of colour of the material from light green or yellow to black.
  • the time required for the conversion is a number of hours, depending on the amount of material being treated and the manner in which it is disposed in the container; for example, a layer of material about an inch thick will require to be heated for about 6 to 7 hours at 450 C.
  • the product does not contain any appreciable amount of ferrous oxide, a-ferric oxide or free iron, although traces of one or more of these substances may be present.
  • the crystals of ferrosoferric oxide are converted, substantially completely, into pseudornorphous *y-fGI'I'lC oxide by oxidation in air, the conditions being so controlled that the temperature of the oxide is maintained below 350 0., preferably between 100 C. and 200 (3., throughout the reaction.
  • this stage as well as in the first stage of the process of the invention, is necessary to ensure that the ferric oxide produced is predominantly or wholly in the 'y, and not in the cc form.
  • One very convenient method of carrying out the oxidation of the ferrosoferric oxide to -ferric oxide which is the preferred method particularly when a dense product is required, consists in mixing with the cooled ferrosoferric oxide suflicient water to damp it thoroughly, and then drying the damped oxide in air in an oven maintained at a temperature between 100 C. and 200 C., suitably at about 150 C. to 160 C. During the drying process the ferrosoferric oxide is converted substantially completely to -ferric oxide.
  • the water employed in this "method has the effect of preventing an undesired rise "in the temperature of the material during the oxidation process, and also appears to have a catalytic effect so that the oxidation takes place readily at a lower temperature (100 C. to 150 C.) than is the case when the ferrosoferr'ic oxide is .kept dry.
  • Another method of carrying out the oxidation step consists in heating the dry ferrosoferric oxide at a temperature below 350 .C., preferably between 150 C. and 200 C.., in.-a restriotedsupply of air, which may be provided byallowing a slow stream of air to flow over the oxide contained in a closed vessel in an oven or furnace maintained at the required temperature.
  • very careful control of the air supply is desirable in order to prevent a rapid rise in the temperature of the oxide, such as would result .in the formation of a-ferric oxide.
  • a .quantity of iron oxalate in the form of crystalline :particles consisting of crystals of substantially uniform size and less than one micron in diameter, is heated in va furnace at 450 -C. in .an atmosphere produced by the combustion of town gas, until the colour of the material changes completely from yellow to black, indicating that conversion to ferrosoferric oxide is substantially complete.
  • the ferrosoferric oxide is then cooled to room temperature, damped thoroughly with water and placed in an oven maintained at 160 :C. When 'dry, the product is crushed and consists of substantially pure -ferric oxide in the form of crystalline particles consisting :of crystals of diameter .less than one micron and .of a high degree of uni- .formity in size.
  • the v-ferric oxide powder obtained by the process according to the invention may contain some unchanged .ferrosoferric oxide, but, provided that the conditions described .above have :been observed, the amount of ferrosoferric oxide present is negligible, and other impurities, such as a-ferric oxide, are substantially absent.
  • the product of the oxidation step may be crushed to break down any cakes or loose aggregates-of 7-fBIIiC oxide crystals, so that the final product consists of very small crystalline particles of substantially uniform size, preferably less than one micron in diameter, and :mainly formed of single crystals, the size of the crystals depending, as explained above, on the size of the crystals of which "the .iron oxalate or iron :formate initially used .is composed.
  • a process for the production of substantially pure gamma ferricoxide in the .form of a powder .consisting of crystalline particles of substantially uniform size and :of diameter less than one micron, which comprises the steps of heating iron oxalate in the form of a yellow crystalline powder consisting of crystals of substantially uniform size and of diameter less than .one micron, at a temperature of 450 C. in an inert atmosphere, said heating being continued until the said yellow crystalline powder has been converted completely into .
  • a black material constituting ferrosoferric oxide, cooling the black material to about room temperature, thoroughly damping the black material throughout its mass with water, drying the damped material in :air in an oven maintained at a temperature of .C. to convert the ferrosoferric oxide to substantially pure gamma ferric oxide, crushing the dried material, andrecovering the gamma ferric oxide.
  • a process for the production of gamma ferric oxide in the form of .-a finely-divided crystalline powder consisting of particles of substantially uniform size which comprises the steps .of heat- .ing a finely-divided iron compound selected from the group consisting of iron oxalate and iron formate consisting of particles of substantially uniform size and in the form of small crystals, .of diameter not appreciably greater than one micron, which compound is capable of being-converted to ferrosoferric oxide-on heating, theheating being carried out at 'a temperature below 600 C.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compounds Of Iron (AREA)

Description

Patented Sept. 14, 1954 raonno'rron or GAMMA FERRIC OXIDE Douglas Marshall Dovey, Hampstead, Ralph Clark Chirnside, Wembley, and Harold Percy Rooksby, Wealdstone, Harrow, England, assignors to The General Electric Company, Limited, London, England No Drawing. Application August 2, 1949, Serial No. 108,226
Claims priority, application Great Britain August 6, 1948 4 Claims.
This invention relates to the production of ferric oxide, and more particularly to a process for the production of -ferric oxide in the form of a finely-divided powder in which the particles are of substantially uniform size.
It is known that ferric oxide, F6203, exists in two forms differing in their crystal structure and in magnetic properties, namely the ct form, which is paramagnetic, and the 7 form, which is ferromagnetic and possesses properties that make it suitable, in powdered form, for certain applications such as the formation of the magnetisable coating on recording tape. For this purpose in particular it is desirable that the magnetic powder used should consist of particles which, whether formed of single crystals or aggregates of crystals, are of substantially uniform size and of small diameter, preferably of the order of one micron or less.
It is the object of this invention to provide a method of producing -ferric oxide powder conforming to the above conditions.
We have found that -ferric oxide can be obtained in the form of a finely-divided powder of substantially uniform particle size by heating finely-divided iron oxalate or iron formate at such a temperature that substantially only ferrosoferric oxide, F6304, is produced, and then subjecting the latter compound to controlled oxidation.
According to the present invention, therefore, a process for the production of 'y-ferric oxide in the form of a finely-divided powder in which the particles are of substantially uniform size comprises heating finely-divided iron oxalate or iron formate consisting of particles of substantially uniform size, at a temperature below 600 C. in a substantially inert atmosphere until substantially complete conversion to ferrosoferric oxide has taken place, and then subjecting the product to suitably controlled oxidation in air at a temperature below 350 C.
The process according to the invention is advantageous in that it is a dry process, solution or fusion of the particles at any stage in the process being avoided, so that the ferrosoferric oxide formed in the first stage of the process and the -ferric oxide obtained as the final product are both pseudomorphs of the original crystals of iron oxalate or iron formate. Thus the size of the crystals of the y-ferric oxide produced is determined by the size of the crystals forming the starting material. The latter therefore should be of substantially uniform size and preferably should be less than one micron in diameter. Preferably also the iron oxalate or iron formate employed consists of particles, whether single crystals or crystal aggregates, of diameter of the order of one micron or less.
In carrying out the first stage of the process the iron oxalate or iron formate is heated at a temperature below 600 C., a suitable temperature being approximately 450 C., in a container in which an atmosphere substantially inert to ferrosoferric oxide is maintained. Thus the atmosphere in the container consists of a gas or mixture of gases which will neither oxidise nor appreciably reduce the ferrosoferric oxide formed. Suitable atmospheres are steam, carbon dioxide, or mixtures of one or both of these with nitrogen; a small proportion of hydrogen or carbon monoxide may also be present, provided that the concentration of these gases is not sufliciently great to cause any appreciable reduction of the ferrosoferric oxide. A suitable gas mixture may be obtained by the combustion of town gas. The initial heating is continued until the iron oxalate or iron formate is substantially completely converted into pseudomorphous ferrosoferric oxide, as indicated by the change of colour of the material from light green or yellow to black. The time required for the conversion is a number of hours, depending on the amount of material being treated and the manner in which it is disposed in the container; for example, a layer of material about an inch thick will require to be heated for about 6 to 7 hours at 450 C. When the heating is carried out under the conditions described, the product does not contain any appreciable amount of ferrous oxide, a-ferric oxide or free iron, although traces of one or more of these substances may be present.
In the second stage of the process, the crystals of ferrosoferric oxide are converted, substantially completely, into pseudornorphous *y-fGI'I'lC oxide by oxidation in air, the conditions being so controlled that the temperature of the oxide is maintained below 350 0., preferably between 100 C. and 200 (3., throughout the reaction. The maintenance of a relatively low temperature, in
this stage as well as in the first stage of the process of the invention, is necessary to ensure that the ferric oxide produced is predominantly or wholly in the 'y, and not in the cc form.
One very convenient method of carrying out the oxidation of the ferrosoferric oxide to -ferric oxide, which is the preferred method particularly when a dense product is required, consists in mixing with the cooled ferrosoferric oxide suflicient water to damp it thoroughly, and then drying the damped oxide in air in an oven maintained at a temperature between 100 C. and 200 C., suitably at about 150 C. to 160 C. During the drying process the ferrosoferric oxide is converted substantially completely to -ferric oxide. The water employed in this "method has the effect of preventing an undesired rise "in the temperature of the material during the oxidation process, and also appears to have a catalytic effect so that the oxidation takes place readily at a lower temperature (100 C. to 150 C.) than is the case when the ferrosoferr'ic oxide is .kept dry.
Another method of carrying out the oxidation step consists in heating the dry ferrosoferric oxide at a temperature below 350 .C., preferably between 150 C. and 200 C.., in.-a restriotedsupply of air, which may be provided byallowing a slow stream of air to flow over the oxide contained in a closed vessel in an oven or furnace maintained at the required temperature. In this case very careful control of the air supply is desirable in order to prevent a rapid rise in the temperature of the oxide, such as would result .in the formation of a-ferric oxide.
Onemethod of producing v -ferricoxideaccording to the invention will now be described by way of example.
In this method, a .quantity of iron oxalate, in the form of crystalline :particles consisting of crystals of substantially uniform size and less than one micron in diameter, is heated in va furnace at 450 -C. in .an atmosphere produced by the combustion of town gas, until the colour of the material changes completely from yellow to black, indicating that conversion to ferrosoferric oxide is substantially complete. The ferrosoferric oxide is then cooled to room temperature, damped thoroughly with water and placed in an oven maintained at 160 :C. When 'dry, the product is crushed and consists of substantially pure -ferric oxide in the form of crystalline particles consisting :of crystals of diameter .less than one micron and .of a high degree of uni- .formity in size.
The v-ferric oxide powder obtained by the process according to the invention may contain some unchanged .ferrosoferric oxide, but, provided that the conditions described .above have :been observed, the amount of ferrosoferric oxide present is negligible, and other impurities, such as a-ferric oxide, are substantially absent.
The product of the oxidation step may be crushed to break down any cakes or loose aggregates-of 7-fBIIiC oxide crystals, so that the final product consists of very small crystalline particles of substantially uniform size, preferably less than one micron in diameter, and :mainly formed of single crystals, the size of the crystals depending, as explained above, on the size of the crystals of which "the .iron oxalate or iron :formate initially used .is composed.
We claim:
'1. A process;for the-production of substantially ,"pure'gamma ferric oxidein the form :of :a finelydivided powder consisting of crystalline particles of substantially uniform size and diameter less than one micron, which comprises the steps of heating a finely-divided compound consisting of crystalline particles of substantially uniform size and of diameter less than one micron, which compound is a member of the group consisting of iron oxalate and iron formate, at a temperature below 600 "C. in an atmosphere which is substantially non-reactive with ferrosoferric oxide at temperatures below 600 C., said heating being continued until the said compound is substantially completely converted to ferrosoferric oxide, cooling to about room temperature the ferrosoferric oxide thus formed, thoroughly damping the cooled ferrosoferric oxide throughout its mass with Water, drying the damped ferrosoferric oxide in air at a temperature between C. and 200 C. to convert the ferrosoferric oxide to substantially pure gamma ferric oxide, crushing the dried product, and recovering the gamma ferric oxide.
2. A process according to claim 1 wherein the first :said step of heating said finely-divided iron compound is carried out at a temperature of approximately 450 C.
3. A process :for the production of substantially pure gamma ferricoxide in the .form of a powder .consisting of crystalline particles of substantially uniform size and :of diameter less than one micron, which comprises the steps of heating iron oxalate in the form of a yellow crystalline powder consisting of crystals of substantially uniform size and of diameter less than .one micron, at a temperature of 450 C. in an inert atmosphere, said heating being continued until the said yellow crystalline powder has been converted completely into .a black material constituting ferrosoferric oxide, cooling the black material to about room temperature, thoroughly damping the black material throughout its mass with water, drying the damped material in :air in an oven maintained at a temperature of .C. to convert the ferrosoferric oxide to substantially pure gamma ferric oxide, crushing the dried material, andrecovering the gamma ferric oxide.
4. A process for the production of gamma ferric oxide in the form of .-a finely-divided crystalline powder consisting of particles of substantially uniform size, which comprises the steps .of heat- .ing a finely-divided iron compound selected from the group consisting of iron oxalate and iron formate consisting of particles of substantially uniform size and in the form of small crystals, .of diameter not appreciably greater than one micron, which compound is capable of being-converted to ferrosoferric oxide-on heating, theheating being carried out at 'a temperature below 600 C. in a non-oxidizing atmosphere until the said compound is substantially completely con verted to ferrosoferric oxide, cooling to about room temperature the ferrosoferric oxide thus formed, thoroughly damping the cooled ferrosoferric oxide throughout its mass with water, subjecting the damped ferrosoferric oxide to oxida- .tion in air at a temperature below 350 C. to convert the ferrosoferric oxide to substantially pure gamma ferric oxide, the rate of oxidation being controlled so as to prevent an exothermic rise in the temperature of the oxide above 350 0., and recovering the gamma ferric oxide.
"(References :on following page) References Cited in the file of this patent UNITED STATES PATENTS Number Name Date 2,463,413 Neel Mar. 1, 1949 2,497,268 Neel Feb. 14, 1950 FOREIGN PATENTS Number Country Date 466,023 Great Britain May 18, 1937 610,514 Great Britain Oct. 13, 1948 OTHER REFERENCES Mellor: Comprehensive Treatise on Inorganic and Theoretical Chemistry, pages 739 and 780, vol. 13 (1934), published by Longmans, Green and C0.
pages 188, 190 (1944), Handbook Publishers, Inc.,
sandusky, Ohio.

Claims (1)

1. A PROCESS FOR THE PRODUCTION OF SUBSTANTIALLY PURE GAMMA FERRIC OXIDE IN THE FORM OF A FINELYDIVIDED POWDER CONSISTING OF CRYSTALLINE PARTICLES OF SUBSTANTIALLY UNIFORM SIZE AND DIAMETER LESS THAN ONE MICRON, WHICH COMPRISES THE STEPS OF HEATING A FINELY-DIVIDED COMPOUND CONSISTING OF CRYSTALLINE PARTICLES OF SUBSTANTIALLY UNIFORM SIZE AND OF DIAMETER LESS THAN ONE MICRON, WHICH COMPOUND IS A MEMBER OF THE GROUP CONSISTING OF IRON OXALATE AND IRON FORMATE, AT A TEMPERATURE BELOW 600* C. IN AN ATMOSPHERE WHICH IS SUBSTANTIALLY NON-REACTIVE WITH FERROSOFERRIC OXIDE AT TEMPERATURES BELOW 600* C., SAID HEATING BEING CONTINUED UNTIL THE SAID COMPOUND IS SUBSTANTIALLY COMPLETELY CONVERTED TO FERROSOFERRIC OXIDE, COOLING TO ABOUT ROOM TEMPERATURE THE FERROSOFERRIC OXIDE THUS FORMED, THOROUGHLY DAMPING THE COOLED FERROSOFERRIC OXIDE THROUGHOUT ITS MASS WITH WATER, DRYING THE DAMPED FERROSOFERRIC OXIDE IN AIR AT A TEMPERATURE BETWEEN 100* C. AND 200* C. TO CONVERT THE FERROSOFERRIC OXIDE TO SUBSTANTIALLY PURE GAMMA FERRIC OXIDE, CRUSHING THE DRIED PRODUCT, AND RECOVERING THE GAMMA FERRIC OXIDE.
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2900236A (en) * 1955-08-03 1959-08-18 Audio Devices Inc Production of ferromagnetic iron oxide
US2989411A (en) * 1957-12-09 1961-06-20 Francis Earle Lab Inc Nacreous iron oxide pigment and method of preparation
US3042639A (en) * 1956-06-11 1962-07-03 Reeves Soundcraft Corp Magnetic iron oxide coating compositions for recording tape
US3047428A (en) * 1958-01-27 1962-07-31 Fuji Photo Film Co Ltd Magnetic recording material
US3185775A (en) * 1958-03-10 1965-05-25 Iit Res Inst Oriented tape
US3399142A (en) * 1963-10-02 1968-08-27 Georgia Kaolin Co Magnetic materials and methods of making the same
US3542685A (en) * 1966-07-01 1970-11-24 Nippon Electric Co Method of producing spinel type ferrites
US3970738A (en) * 1974-07-15 1976-07-20 Toda Kogyo Corporation Process for producing iron oxide products from waste liquids containing ferrous salts
US4179387A (en) * 1974-03-12 1979-12-18 Fuji Photo Film Co., Ltd. Process for producing magnetic FE oxide
US20040202606A1 (en) * 2002-03-18 2004-10-14 Sud Chemie Mt S.R.L. Method for preparing iron oxides

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB466023A (en) * 1935-11-18 1937-05-18 Ig Farbenindustrie Ag Improvements in the manufacture and production of sound record carriers
GB610514A (en) * 1943-03-01 1948-10-18 Electro Chimie Metal Improvements in or relating to the manufacture of iron powder and products produced therefrom
US2463413A (en) * 1943-08-21 1949-03-01 Electro Chimie Metal Manufacture of permanent oxide magnets
US2497268A (en) * 1944-07-26 1950-02-14 Electro Chimie Metal Permanent magnets and method for the obtention of the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB466023A (en) * 1935-11-18 1937-05-18 Ig Farbenindustrie Ag Improvements in the manufacture and production of sound record carriers
GB610514A (en) * 1943-03-01 1948-10-18 Electro Chimie Metal Improvements in or relating to the manufacture of iron powder and products produced therefrom
US2463413A (en) * 1943-08-21 1949-03-01 Electro Chimie Metal Manufacture of permanent oxide magnets
US2497268A (en) * 1944-07-26 1950-02-14 Electro Chimie Metal Permanent magnets and method for the obtention of the same

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2900236A (en) * 1955-08-03 1959-08-18 Audio Devices Inc Production of ferromagnetic iron oxide
US3042639A (en) * 1956-06-11 1962-07-03 Reeves Soundcraft Corp Magnetic iron oxide coating compositions for recording tape
US2989411A (en) * 1957-12-09 1961-06-20 Francis Earle Lab Inc Nacreous iron oxide pigment and method of preparation
US3047428A (en) * 1958-01-27 1962-07-31 Fuji Photo Film Co Ltd Magnetic recording material
US3185775A (en) * 1958-03-10 1965-05-25 Iit Res Inst Oriented tape
US3399142A (en) * 1963-10-02 1968-08-27 Georgia Kaolin Co Magnetic materials and methods of making the same
US3542685A (en) * 1966-07-01 1970-11-24 Nippon Electric Co Method of producing spinel type ferrites
US4179387A (en) * 1974-03-12 1979-12-18 Fuji Photo Film Co., Ltd. Process for producing magnetic FE oxide
US3970738A (en) * 1974-07-15 1976-07-20 Toda Kogyo Corporation Process for producing iron oxide products from waste liquids containing ferrous salts
US20040202606A1 (en) * 2002-03-18 2004-10-14 Sud Chemie Mt S.R.L. Method for preparing iron oxides
US7442362B2 (en) * 2002-03-18 2008-10-28 Sud Chemie Mt S.R.L. Method for preparing iron oxides
US20090324487A1 (en) * 2002-03-18 2009-12-31 Sud Chemie Mt S.R.L. Method for preparing iron oxides
US8574450B2 (en) 2002-03-18 2013-11-05 Sud Chemie Mt S.R.L. Method for preparing iron oxides

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